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Application of rare earths in consumer
   electronics and challenges for recycling
                    ICCE 2011, 08.09.2011



Ran Liu
Matthias Buchert
Stefanie Dittrich
Andreas Manhart
Cornelia Merz
Doris Schüler
Contents

    Rare earth elements

    Global production and reserves

    Environmental aspects of rare earth during mining
     and processing

    Rare earths used in consumer electronics

    Developing a recycling scheme

    Conclusions                                         2
Rare Earth Elements (REEs)


                                    Heavy REE
                                    Light REE




LREE: lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium
(Pm), samarium (Sm), europium (Eu), and scandium (Sc)

HREE: yttrium (Y), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho),
                                                                                   3
erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu)
Global production and reserves


       Global production in 2010:                                      133 600 t

       Reserves according to USGS:                               110 000 000 t              (factor 823)

        (reserve which can be economically extracted)


World Mine production in 2010                                      Rare earth reserves by countries (USGS 2011)
(USGS 2011). REO: rare earth oxide
                                                                   other countries    United States
                                                                    22 Mio t REO      13 Mio t REO      Australia
Country                      t REO       Share                          19%               11%         2 Mio t REO
                                                                                                          1%
China                      130 000        97,3%      India
                                                  3 Mio t REO
Brazil                           550      0,4%        3%

India                          2 700      2,0%

Malaysia                         350      0,3%

World Total*               133 600       100,0%             CIS
                                                        19 Mio t REO                              China
                                                            17%                                55 Mio t REO
                                                                                                                4
 * without 20 000 t REO illegal mining                                                             48%
Global demand and development of
   the demand
  2008
                     Phosphors, Luminescence
                                 9 000 t       Others         Glass, Polishing, Ceramics

                                  7%           5%                33 000 – 42 000 t

  Metal alloys /                                                             30%
   batteries
  17 – 23 000 t
       18%




                     Catalysts
                                                            Magnets
                  20 000 – 25 000 t
                                                        21 000 – 27 000 t
                       20%
                                                              20%

Unit: t REO per year

Source: Compiled by Oeko-Institut from the sources Jefferies 2010, Oakdene Hollins 2010,
                                                                                           5
Kingsnorth 2010, GWMG 2010, BGR 2009 and Lynas 2010
Rare earths used in consumer electronics
          Products         Rare earth/Components           Amount                  Unit
Variable-frequency air                                     100-200                g/unit
conditioning                      NdFeB                      250                  g/unit
DVD Player/DVD
ROM/Driver                        NdFeB                         5                 g/unit
                                                              500                 g/unit
E-Bike                            NdFeB                       300                 g/unit
                                                               15                 g/unit
Hard disc drives (HDD)             NdFeB                       22                 g/unit
                                  Magnet                      153                 g/unit
Loudspeaker                        NdFeB                       50                 g/unit
Mobil phone                  Permanent magnet                   5                 g/unit
Mobil phone                   light phosphors                0.006                g/unit
Laptop                        light phosphors              0.05-0.6               g/unit
LCD TV                        light phosphors                4.5-6                g/unit
Plasma TV                     light phosphors              100-125                g/unit
LCD Display                   light phosphors               1.5-2.5               g/unit
                                Lanthanum                     0.35                g/unit
                                  Cerium                      0.46                g/unit
                                 Europium                     0.20                g/unit
fluorescent lamp (market          Terbium                     0.19                g/unit
average)                          Yttrium                     2.87                g/unit
Example: NdFeB: 15g/unit                   9765t NdFeB≈3039t REO                            6
HDD shipment in 2010: 651 million           13% of global demand of rare earth for magnets
Global magnet production

                                                  97 % i n China
              RE Mining & Concentration




                                                  97 % in Chi na
            Separation of Ores into Oxides




                                                  a lmost 100%
             Refining of Oxides to Metals         In China




                                                  7 5 - 80% in Chi na
       Forming Metals into Magnet Alloy Powders   2 0 - 25% in Japan




                                                  7 5 - 80% in Chi na
                                                  1 7 - 25% in Japan
            NdFeB Magnet Man ufacturing
                                                   3 - 5% in Europe


                                                                        7
Energy efficient lighting

  Most new energy efficient lighting systems contain rare
   earths (compact fluorescent lamps, LED, plasma
   displays, LCD displays)

 High growth rates due to the ban on classic
  incandescent bulbs, dissemination of LEDs and shift
  to plasma and LCD displays

 Substitutions are rare.  R & D required for alternative
  phosphors with high efficiency and high light quality



                                                         8
Price ($/kg)




                                                                              0
                                                                                   50
                                                                                             100
                                                                                                          150
                                                                                                                       200
                                                                                                                                    250
                                                                                                                                               300
                                                                                                                                                       350
                                                                      2001

                                                                      2002

                                                                      2003

                                                                      2004

                                                                      2005

                                                                      2006

                                                                      2007

                                                                      2008

                                                                      2009

                                                                  June 2010

                                                                  Aug 2010




                          Cerium Oxide
                                                                  Nov 2010

                                                                  Dec 2010




      Lanthanum Oxide
                                           Neodymium Oxide
                                                                   Jan 2011

                                                                   Feb 2011

                                                                March 2011
                                                                                                                               Nd




                                                                   Apr 2011
                                                                                                                                                              Light rare earth elements




                                                                  May 2011
                                                                                                            Ce

                                                                                                La




                                                             14th June 2011
                                                                                                                                                                                          Development of prices




                                                                                                     Price ($/kg)
                                                                              0
                                                                                  500
                                                                                         1000
                                                                                                   1500
                                                                                                                2000
                                                                                                                             2500
                                                                                                                                      3000
                                                                                                                                                3500
                                                                                                                                                       4000




                                                                      2001

                                                                      2002

                                                                      2003

                                                                      2004

                                                                      2005

                                                                      2006

                                                                      2007

                                                                      2008

                                                                      2009
                        Terbium Oxide
                                         Europium Oxide




                                                                 June 2010
    Dysprosium Oxide




                                                                  Aug 2010

                                                                  Nov 2010

                                                                  Dec 2010

                                                                  Jan 2011

                                                                  Feb 2011

                                                                March 2011
                                                                                                Tb




                                                                  Apr 2011
                                                                                                                                                              Heavy rare earth elements




9




                                                                 May 2011
                                                                                                                                          Eu




                                                                                        Dy




                                                             14th June 2011
Risks of REE mining without
Environmental Protection Systems




                                            Tailings:
  Waste rock                             (impoundment
   storage                                  areas or
                                           stockpiles)




   Mining                                                                 Further
                               Milling    Floatation
                                                                        processing
               (< 1-10% REO)                             (~60% REO)
               Ores with low
                                                          concentrate
               concentration




                                                                                10
Advantages of recycling


Secondary REE potential in Europe.
Lower dependency on foreign material supply.
Build-up of know-how on rare earth processing.
No radioactive waste in processing.
Environmental benefits regarding air emissions.
 groundwater protection, acidification, eutrophication
 and climate protection.


                                                   11
Developing a recycling scheme

                                             European Material Flow Analysis
           Identification
                of
           stakeholders               Identification of initial products to be recycled



            European
                                  Development of Pre-treatment & Collection Schemes
           Competence
 Basic
           Network on
research
            Rare Earth
                                                                                     Promotion
                              Installation of Pilot Plants for Recycling / R&D
                                                                                     of re-use



                      Financial support                Improvement of legal framework in EU



               Implementation of large scale collection and recycling for initial products


                                                                                             12
Promotion of sustainable mining

Green technologies call for “green metals”
  There are manifold initiatives for sustainable mining.
  Among them are certification schemes addressing different
   problems:
     Environmental, small-scale mining, safety issues, human rights.
  Increasing interest in politics and industry on certified minerals
  Today’s mining companies could be interested in certification
   schemes or similar co-operations in order to highlight their
   environmental efforts.
  The Analytical Fingerprint is a control instrument if other control
   mechanism fail.


                                                                         13
Conclusions
 Identification of REE with high relevance: Dysprosium;
Terbium; Yttrium; Lanthanum; Neodymium; Europium;
Praseodymium
      potential shortages in the short-term
      important role in Green Technologies
 Rare Earth Mining and Processing shows high environmental
risks  sustainable mining initiatives like certification schemes
should be integrated into an environmentally sound strategy.
 R & D needed for all applications concerning
      avoidance / substitution
      higher material efficiency
      recycling
                                                                    14
Thank you for your attention!

   The work which led to the results presented here was
   financed by: the Greens/European Free Alliance
   in the European Parliament.




More detailed information can be found on the following websites:
                          www.oeko.de
                     www.resourcefever.org


                                                                    15

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Application of rare earths in consumer electronics and challenges for recycling

  • 1. Application of rare earths in consumer electronics and challenges for recycling ICCE 2011, 08.09.2011 Ran Liu Matthias Buchert Stefanie Dittrich Andreas Manhart Cornelia Merz Doris Schüler
  • 2. Contents  Rare earth elements  Global production and reserves  Environmental aspects of rare earth during mining and processing  Rare earths used in consumer electronics  Developing a recycling scheme  Conclusions 2
  • 3. Rare Earth Elements (REEs) Heavy REE Light REE LREE: lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), and scandium (Sc) HREE: yttrium (Y), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), 3 erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu)
  • 4. Global production and reserves  Global production in 2010: 133 600 t  Reserves according to USGS: 110 000 000 t (factor 823) (reserve which can be economically extracted) World Mine production in 2010 Rare earth reserves by countries (USGS 2011) (USGS 2011). REO: rare earth oxide other countries United States 22 Mio t REO 13 Mio t REO Australia Country t REO Share 19% 11% 2 Mio t REO 1% China 130 000 97,3% India 3 Mio t REO Brazil 550 0,4% 3% India 2 700 2,0% Malaysia 350 0,3% World Total* 133 600 100,0% CIS 19 Mio t REO China 17% 55 Mio t REO 4 * without 20 000 t REO illegal mining 48%
  • 5. Global demand and development of the demand 2008 Phosphors, Luminescence 9 000 t Others Glass, Polishing, Ceramics  7%  5% 33 000 – 42 000 t Metal alloys /  30% batteries 17 – 23 000 t  18% Catalysts Magnets 20 000 – 25 000 t 21 000 – 27 000 t 20%  20% Unit: t REO per year Source: Compiled by Oeko-Institut from the sources Jefferies 2010, Oakdene Hollins 2010, 5 Kingsnorth 2010, GWMG 2010, BGR 2009 and Lynas 2010
  • 6. Rare earths used in consumer electronics Products Rare earth/Components Amount Unit Variable-frequency air 100-200 g/unit conditioning NdFeB 250 g/unit DVD Player/DVD ROM/Driver NdFeB 5 g/unit 500 g/unit E-Bike NdFeB 300 g/unit 15 g/unit Hard disc drives (HDD) NdFeB 22 g/unit Magnet 153 g/unit Loudspeaker NdFeB 50 g/unit Mobil phone Permanent magnet 5 g/unit Mobil phone light phosphors 0.006 g/unit Laptop light phosphors 0.05-0.6 g/unit LCD TV light phosphors 4.5-6 g/unit Plasma TV light phosphors 100-125 g/unit LCD Display light phosphors 1.5-2.5 g/unit Lanthanum 0.35 g/unit Cerium 0.46 g/unit Europium 0.20 g/unit fluorescent lamp (market Terbium 0.19 g/unit average) Yttrium 2.87 g/unit Example: NdFeB: 15g/unit 9765t NdFeB≈3039t REO 6 HDD shipment in 2010: 651 million  13% of global demand of rare earth for magnets
  • 7. Global magnet production 97 % i n China RE Mining & Concentration 97 % in Chi na Separation of Ores into Oxides a lmost 100% Refining of Oxides to Metals In China 7 5 - 80% in Chi na Forming Metals into Magnet Alloy Powders 2 0 - 25% in Japan 7 5 - 80% in Chi na 1 7 - 25% in Japan NdFeB Magnet Man ufacturing 3 - 5% in Europe 7
  • 8. Energy efficient lighting  Most new energy efficient lighting systems contain rare earths (compact fluorescent lamps, LED, plasma displays, LCD displays)  High growth rates due to the ban on classic incandescent bulbs, dissemination of LEDs and shift to plasma and LCD displays  Substitutions are rare.  R & D required for alternative phosphors with high efficiency and high light quality 8
  • 9. Price ($/kg) 0 50 100 150 200 250 300 350 2001 2002 2003 2004 2005 2006 2007 2008 2009 June 2010 Aug 2010 Cerium Oxide Nov 2010 Dec 2010 Lanthanum Oxide Neodymium Oxide Jan 2011 Feb 2011 March 2011 Nd Apr 2011 Light rare earth elements May 2011 Ce La 14th June 2011 Development of prices Price ($/kg) 0 500 1000 1500 2000 2500 3000 3500 4000 2001 2002 2003 2004 2005 2006 2007 2008 2009 Terbium Oxide Europium Oxide June 2010 Dysprosium Oxide Aug 2010 Nov 2010 Dec 2010 Jan 2011 Feb 2011 March 2011 Tb Apr 2011 Heavy rare earth elements 9 May 2011 Eu Dy 14th June 2011
  • 10. Risks of REE mining without Environmental Protection Systems Tailings: Waste rock (impoundment storage areas or stockpiles) Mining Further Milling Floatation processing (< 1-10% REO) (~60% REO) Ores with low concentrate concentration 10
  • 11. Advantages of recycling Secondary REE potential in Europe. Lower dependency on foreign material supply. Build-up of know-how on rare earth processing. No radioactive waste in processing. Environmental benefits regarding air emissions. groundwater protection, acidification, eutrophication and climate protection. 11
  • 12. Developing a recycling scheme European Material Flow Analysis Identification of stakeholders Identification of initial products to be recycled European Development of Pre-treatment & Collection Schemes Competence Basic Network on research Rare Earth Promotion Installation of Pilot Plants for Recycling / R&D of re-use Financial support Improvement of legal framework in EU Implementation of large scale collection and recycling for initial products 12
  • 13. Promotion of sustainable mining Green technologies call for “green metals”  There are manifold initiatives for sustainable mining.  Among them are certification schemes addressing different problems:  Environmental, small-scale mining, safety issues, human rights.  Increasing interest in politics and industry on certified minerals  Today’s mining companies could be interested in certification schemes or similar co-operations in order to highlight their environmental efforts.  The Analytical Fingerprint is a control instrument if other control mechanism fail. 13
  • 14. Conclusions  Identification of REE with high relevance: Dysprosium; Terbium; Yttrium; Lanthanum; Neodymium; Europium; Praseodymium  potential shortages in the short-term  important role in Green Technologies  Rare Earth Mining and Processing shows high environmental risks  sustainable mining initiatives like certification schemes should be integrated into an environmentally sound strategy.  R & D needed for all applications concerning  avoidance / substitution  higher material efficiency  recycling 14
  • 15. Thank you for your attention! The work which led to the results presented here was financed by: the Greens/European Free Alliance in the European Parliament. More detailed information can be found on the following websites: www.oeko.de www.resourcefever.org 15