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SOLAR THERMAL POWER!
      GEEN 4830 – ECEN 5007!




8. Thermal Storage and Hybridization!



          Manuel A. Silva Pérez
                              !
            silva@esi.us.es !
CSP Markets

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                  13/07/11
CSP Markets

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              13/07/11
Thermal storage and Hybrization

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                                  13/07/11
Thermal Storage
}    http://www.youtube.com/watch?v=bxCUYPzHsug




                                                   13/07/11
Why Energy Storage?
}  Increase operational stability
}  Reduce intermittence.
}  Increase plant utilization and capacity factor
}  Provides “peak-shaving” ability (time-shifted operation)
}  Reduce generation cost (as long as storage is cheaper than
    increasing rated power!)




                                                       13/07/11
Profile of the electricity demand




                                    13/07/11
Solar-only electricity generation




                                    13/07/11
Solar + Thermal Storage




                          13/07/11
Thermal energy storage
}    A fraction of the thermal energy produced at the solar field is
      stored, increasing the internal energy of the storage medium.
      }    Sensible heat
      }    Latent heat
      }    (Thermochemical)




                                                           13/07/11
Types of thermal storage
}    By utilization
      }    Short term
            }    Provide operational stability
      }    Medium term
            }    Increase capacity factor
            }    Shift electrical generation hours
}    By type
      }    Direct (same substance as working fluid, does not require HX)
      }    Indirect (different substance, requires HX)




                                                                   13/07/11
Technical Requirements for TES materials
}  High energy density (per-unit mass or per-unit volume)
}  Good heat conductivity
}  Good heat transfer between heat transfer fluid (HTF) and the
    storage medium
}  Mechanical and chemical stability
}  Chemical compatibility between HTF, heat exchanger and/or
    storage medium
}  Reversibility for a large number of charging/discharging cycles
}  Low thermal losses
}  Easy to control




                                                         13/07/11
Thermal storage options
   Solid materials	





 Liquid materials	





Source: Gil, A. et al. State of the art on high temperature thermal energy storage for power generation. 
Part 1—Concepts, materials and modellization. Renewable and Sustainable Energy Reviews. January 2010	

	

                                                                                            13/07/11
Thermal storage options - PCM




Source: Gil, A. et al. State of the art on high temperature thermal energy storage for power generation. 
Part 1—Concepts, materials and modellization. Renewable and Sustainable Energy Reviews. January 2010	

	

                                                                                            13/07/11
Thermal storage past experiences




    Source: Survey of thermal storage for parabolic trough power plants, Pilkington Solar Int. (2000)	


                                                                                              13/07/11
TES – STP commercial installations
}    Short term: pressurized water
      }    PS10 and PS20


}    Mid term: Molten salt, 2 tank
      }    Direct (CRS) – Gema Solar (Solar Tres)
      }    Indirect (PT) – Andasol I




                                                     13/07/11
Short term TES
                                          PS10 / PS20
}    Pressurized water
}    Sliding pressure during discharge
}    Pressure vessel


   
                                     


   
   


                                                        13/07/11
Molten salt storage, 2 tank, direct

}    Thermal capacity proportional   Solar Two (Barstow, CA)
      to ΔT	
  
}    Hot – cold tank design
}    Commercial (salt widely used
      in process industry)
       

       

       

                                                        13/07/11
Molten salt TES

}    GEMASOLAR (Torresol Energy)




                                    13/07/11
GEMASOLAR

}    Type:               2 tanks, molten salts
}    Fluid:              NO3 mixture
                          (60% NaNO3 - 40% KNO3)
}    Freezing point:     223°C
}    Capacity:           640 MWh
                          (~15 h full load operation)
}    Tank size:          14 m high, 23 m diameter
}    Molten salt mass:   8000 tons approx
}    T cold tank:        290° C
}    T hot tank:         565°C




                                                        13/07/11
Molten salt TES, 2 tanks, indirect
ANDASOL and other
     




 
 
 
                    )
 


                                     13/07/11
Andasol TES – Technical characterisitics

}    Type:               2 tanks, molten salts
}    Fluid:              NO3 mixture
                          (60% NaNO3 - 40% KNO3)
}    Freezing point:     223°C
}    Capacity:           1,010 MWh
                          (~7.5 h full load operation)
}    Tank size:          14 m high, 37 m diameter
}    Molten salt mass:   27,500 tons
}    T cold tank:        292° C
}    T hot tank:         386°C




                                                         13/07/11
ANDASOL




          13/07/11
RD Activities. Concrete storage
Dual medium




                                   13/07/11
RD activities.
Thermocline, phase change, sand storage




                                     13/07/11
RD activities. Thermocline
}  Single tank system, .
}  Hot and cold fluids separated by stratification; the zone
    between the hot and cold fluids is called the thermocline.
}  Usually a filler material is used to help the thermocline effect.
}  Sandia National Laboratories identified quartzite rock and silica
    sands as potential filler materials.
}  Depending on the cost of the storage fluid, the thermocline
    can result in a substantially low cost storage system.
}  This system has an additional advantage: most of the storage
    fluid can be replaced with a low cost filler material, for
    example, quartzite rock and sand.


                                                         13/07/11
Thermocline tank




                   13/07/11
Latent heat storage (Phase change)
}  Isothermal thermal energy storage as the latent heat of phase
    changephase change materials (PCM).
}  Reduced in size compared to single-phase sensible heating
    systems.
}  Heat transfer design and media selection are more difficult,
}  Degradation of salts after moderate number of freeze–melt
    cycles (experience with low-temp salts).
}  Phase change materials allow large amounts of energy to be
    stored in relatively small volumes, resulting in some of the
    lowest storage media costs of any storage concepts.


                                                       13/07/11
RD activities. Phase change.
Cascaded LHS




                                13/07/11
RD activities. Phase change. DISTOR project




                                      13/07/11
RD activities. Sand (fluidised bed)




                                       13/07/11
TES costs and benefits
} 


}    Facilitates Dispatchability
}    If adequately designed, can improve
      } 
      } 

} 


} 
      } 
      } 

} 



                                            13/07/11
Hybridization options




                        13/07/11
SEGS 30 MW




             13/07/11
Andasol-type plants
(thermal storage and auxiliary boiler)




                                    13/07/11
ISCCS
}    3 projects in North Africa (Morocco, Algeria, Egypt)




                                                             13/07/11
Hybridization
Costs and benefits

¢ 
¢    Faciltates dispatchability
¢ 
¢ 
¢ 
¢ 
¢ 
¢ 




                                   13/07/11
Simulating operational strategies with EOS
Clear day, summer




                                    13/07/11
Simulating operational strategies with EOS
Cloudy day, winter




                                    13/07/11

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Cu stp 08_tes+hybrid

  • 1. SOLAR THERMAL POWER! GEEN 4830 – ECEN 5007! 8. Thermal Storage and Hybridization! Manuel A. Silva Pérez ! silva@esi.us.es !
  • 2. CSP Markets }  }  }  }  }  }  }  13/07/11
  • 3. CSP Markets }  }  }  }  }  }  }  13/07/11
  • 4. Thermal storage and Hybrization }  }  }  }  }  }  }  13/07/11
  • 5. Thermal Storage }  http://www.youtube.com/watch?v=bxCUYPzHsug 13/07/11
  • 6. Why Energy Storage? }  Increase operational stability }  Reduce intermittence. }  Increase plant utilization and capacity factor }  Provides “peak-shaving” ability (time-shifted operation) }  Reduce generation cost (as long as storage is cheaper than increasing rated power!) 13/07/11
  • 7. Profile of the electricity demand 13/07/11
  • 9. Solar + Thermal Storage 13/07/11
  • 10. Thermal energy storage }  A fraction of the thermal energy produced at the solar field is stored, increasing the internal energy of the storage medium. }  Sensible heat }  Latent heat }  (Thermochemical) 13/07/11
  • 11. Types of thermal storage }  By utilization }  Short term }  Provide operational stability }  Medium term }  Increase capacity factor }  Shift electrical generation hours }  By type }  Direct (same substance as working fluid, does not require HX) }  Indirect (different substance, requires HX) 13/07/11
  • 12. Technical Requirements for TES materials }  High energy density (per-unit mass or per-unit volume) }  Good heat conductivity }  Good heat transfer between heat transfer fluid (HTF) and the storage medium }  Mechanical and chemical stability }  Chemical compatibility between HTF, heat exchanger and/or storage medium }  Reversibility for a large number of charging/discharging cycles }  Low thermal losses }  Easy to control 13/07/11
  • 13. Thermal storage options Solid materials Liquid materials Source: Gil, A. et al. State of the art on high temperature thermal energy storage for power generation. Part 1—Concepts, materials and modellization. Renewable and Sustainable Energy Reviews. January 2010 13/07/11
  • 14. Thermal storage options - PCM Source: Gil, A. et al. State of the art on high temperature thermal energy storage for power generation. Part 1—Concepts, materials and modellization. Renewable and Sustainable Energy Reviews. January 2010 13/07/11
  • 15. Thermal storage past experiences Source: Survey of thermal storage for parabolic trough power plants, Pilkington Solar Int. (2000) 13/07/11
  • 16. TES – STP commercial installations }  Short term: pressurized water }  PS10 and PS20 }  Mid term: Molten salt, 2 tank }  Direct (CRS) – Gema Solar (Solar Tres) }  Indirect (PT) – Andasol I 13/07/11
  • 17. Short term TES PS10 / PS20 }  Pressurized water }  Sliding pressure during discharge }  Pressure vessel     
     13/07/11
  • 18. Molten salt storage, 2 tank, direct }  Thermal capacity proportional Solar Two (Barstow, CA) to ΔT   }  Hot – cold tank design }  Commercial (salt widely used in process industry)       13/07/11
  • 19. Molten salt TES }  GEMASOLAR (Torresol Energy) 13/07/11
  • 20. GEMASOLAR }  Type: 2 tanks, molten salts }  Fluid: NO3 mixture (60% NaNO3 - 40% KNO3) }  Freezing point: 223°C }  Capacity: 640 MWh (~15 h full load operation) }  Tank size: 14 m high, 23 m diameter }  Molten salt mass: 8000 tons approx }  T cold tank: 290° C }  T hot tank: 565°C 13/07/11
  • 21. Molten salt TES, 2 tanks, indirect ANDASOL and other           )   13/07/11
  • 22. Andasol TES – Technical characterisitics }  Type: 2 tanks, molten salts }  Fluid: NO3 mixture (60% NaNO3 - 40% KNO3) }  Freezing point: 223°C }  Capacity: 1,010 MWh (~7.5 h full load operation) }  Tank size: 14 m high, 37 m diameter }  Molten salt mass: 27,500 tons }  T cold tank: 292° C }  T hot tank: 386°C 13/07/11
  • 23. ANDASOL 13/07/11
  • 24. RD Activities. Concrete storage Dual medium 13/07/11
  • 25. RD activities. Thermocline, phase change, sand storage 13/07/11
  • 26. RD activities. Thermocline }  Single tank system, . }  Hot and cold fluids separated by stratification; the zone between the hot and cold fluids is called the thermocline. }  Usually a filler material is used to help the thermocline effect. }  Sandia National Laboratories identified quartzite rock and silica sands as potential filler materials. }  Depending on the cost of the storage fluid, the thermocline can result in a substantially low cost storage system. }  This system has an additional advantage: most of the storage fluid can be replaced with a low cost filler material, for example, quartzite rock and sand. 13/07/11
  • 27. Thermocline tank 13/07/11
  • 28. Latent heat storage (Phase change) }  Isothermal thermal energy storage as the latent heat of phase changephase change materials (PCM). }  Reduced in size compared to single-phase sensible heating systems. }  Heat transfer design and media selection are more difficult, }  Degradation of salts after moderate number of freeze–melt cycles (experience with low-temp salts). }  Phase change materials allow large amounts of energy to be stored in relatively small volumes, resulting in some of the lowest storage media costs of any storage concepts. 13/07/11
  • 29. RD activities. Phase change. Cascaded LHS 13/07/11
  • 30. RD activities. Phase change. DISTOR project 13/07/11
  • 31. RD activities. Sand (fluidised bed) 13/07/11
  • 32. TES costs and benefits }  }  Facilitates Dispatchability }  If adequately designed, can improve }  }  }  }  }  }  }  13/07/11
  • 34. SEGS 30 MW 13/07/11
  • 35. Andasol-type plants (thermal storage and auxiliary boiler) 13/07/11
  • 36. ISCCS }  3 projects in North Africa (Morocco, Algeria, Egypt) 13/07/11
  • 37. Hybridization Costs and benefits ¢  ¢  Faciltates dispatchability ¢  ¢  ¢  ¢  ¢  ¢  13/07/11
  • 38. Simulating operational strategies with EOS Clear day, summer 13/07/11
  • 39. Simulating operational strategies with EOS Cloudy day, winter 13/07/11