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Environmental Solutions
PFAS soil & water treatment
January 2020
www.hmvt.eu
Environmental Solutions
PFAS remediation of Soil
• HMVT partners with TRS US to provide in- and ex-situ thermal remediation.
• This via our Joint Venture company called TRS Europe.
• PFAS soil treatment is therefore carried out via TRS Europe
PFAS treatment of Water
• HMVT can offer different water treatment solutions.
• Activated Carbon, Ion Exchange or PerfluorAd Technology.
• For PerfluorAd Technology HMVT partners with Cornelsen GMBH.
• This presentation focusses on the proven technology of PerfluorAd.
Environmental Solutions
PFAS remediation of Soil & treatment of Water
Environmental Solutions
PFAS remediation of Soil
PFAS remediation of Soil
• HMVT partners with TRS US to provide in- and ex-situ thermal remediation.
• This via our Joint Venture company called TRS Europe.
• PFAS soil treatment is therefore carried out via TRS Europe
Technology
• Use of Conductive Heating (CH)
• In-situ Vadose Zone
• Ex-situ Cells
Environmental Solutions
PFAS remediation of Soil
Contaminant Boling Points
TCE PCE Xylenes Napthalene PCB Dioxin PFAS
PAH
Electrical Resistance Heating
Thermal Conduction Heating
100°C 200°C 300°CBoiling Points:
Steam Enhanced Extraction
Chlorobenzenes
Environmental Solutions
PFAS remediation of Soil
Proof of Concept
• Pilot Tests carried out
• Ex-situ Cells
Environmental Solutions
PFAS remediation of Soil
Proof of Concept
Ex-situ Cell heat-up
Environmental Solutions
PFAS remediation of Soil
Proof of Concept
PFAS Volatilization from Soil: Time & Temperature
Environmental Solutions
PFAS
Starting Concentration
(ppb)
% reduction
PFOS 21000 >99.999%
PFBA 91 >99.999%
PFPeA 100 >99.999%
PFBS 41 >99.999%
PFHxA 200 >99.999%
PFHpA 27 >99.998%
PFHxS 1600 >99.999%
PFNA 16 >99.997%
PFDS 48 >99.999%
PFOA 64 >99.865%
PFAS remediation of Soil
Proof of Concept
PFAS Soil removal at 400 oC
Environmental Solutions
• Heating & evaporation
• Condensation of steam & PFAS
• Water treatment (GAC or PerfluorAd)
• Vapor treatment (GAC)
Heat
Exchanger Scrubber
Blower/Vacuum
Pump
Vapors to Stack
Cooling Water
Return
Cooling Water
Upper Vadose Zone
Treated at 350°C
Transition Zone
(100 - 350°C)
Not Treated
Water Table
Source
Air Phase
GAC
To Water Treatment
PFAS remediation of Soil
Treatment System
Environmental Solutions
PFAS remediation of Soil
Next steps
• Test results.
• Temperatures achieved.
• Two U.S. Government Projects – in-situ and ex-situ – awarded.
• 1x ex-situ pile treatment
• 1x in-situ vadose zone
Environmental Solutions
PFAS treatment of Water
PFAS treatment of Water
• HMVT can offer different water treatment solutions.
• Activated Carbon, Ion Exchange or PerfluorAd Technology.
• For PerfluorAd Technology HMVT partners with Cornelsen GMBH.
• This presentation focusses on:
• The proven technology of PerfluorAd.
• An example project in Amsterdam.
Traditional GAC treatment
Environmental Solutions
PFAS treatment of Water
The PerfluorAd Technology
PerfluorAd treatment
Environmental Solutions
PFAS treatment of Water
The PerfluorAd Technology
• PerfluorAd is a liquid flocculant.
• Dosing in a reactor.
• Based on differences in electrical charges
between the PFAS molecules.
• Creation of micro-flocs between PerfluorAd and
PFAS molecules.
• PFAS flocs removed by filtration/precipitation.
• Proven Technology & ITRC proved.
• Multiple successful projects in Germany.
• HMVT carried out a first successful project in The Netherlands: ‘Cruqiusweg Amsterdam’.
• PerfluorAd removes the bulk of the PFAS (up to >98%).
• No negative influence by DOC or other pollutants.
• Activated carbon only needed for polishing.
Environmental Solutions
PFAS treatment of Water
The PerfluorAd Technology
Environmental Solutions
PFAS treatment of Water
PerfluorAd vs Activated Carbon
• Carbon or PerfluorAd: always custom made.
• Carbon:
• Very low concentrations of PFAS in water (<1 µg/l)
• Low mass of PFAS in water
• Short period or very low water flow.
• PerfluorAd:
• Hi concentrations: source zones, fire foams.
• A lot of pollutant mass
• Long project period
• Competing pollutants in water.
• Tipping point often favours PerfluorAd
Environmental Solutions
PFAS treatment of Water
PerfluorAd Reference ‘Cruqiusweg Amsterdam’
Project outline
• Groundwater from dewatering during excavation.
• Groundwater is collected in a big storage tank.
• Flow rate 1,5-2,0 m³/hr.
• Discharge limit for PFAS was 1 µg/l.
Environmental Solutions
PFAS treatment of Water
PerfluorAd Reference ‘Cruqiusweg Amsterdam’
Results
Environmental Solutions

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Behandeling PFAS in grond en grondwater (HMVT)

  • 1. Environmental Solutions PFAS soil & water treatment January 2020 www.hmvt.eu Environmental Solutions
  • 2. PFAS remediation of Soil • HMVT partners with TRS US to provide in- and ex-situ thermal remediation. • This via our Joint Venture company called TRS Europe. • PFAS soil treatment is therefore carried out via TRS Europe PFAS treatment of Water • HMVT can offer different water treatment solutions. • Activated Carbon, Ion Exchange or PerfluorAd Technology. • For PerfluorAd Technology HMVT partners with Cornelsen GMBH. • This presentation focusses on the proven technology of PerfluorAd. Environmental Solutions PFAS remediation of Soil & treatment of Water
  • 3. Environmental Solutions PFAS remediation of Soil PFAS remediation of Soil • HMVT partners with TRS US to provide in- and ex-situ thermal remediation. • This via our Joint Venture company called TRS Europe. • PFAS soil treatment is therefore carried out via TRS Europe Technology • Use of Conductive Heating (CH) • In-situ Vadose Zone • Ex-situ Cells
  • 4. Environmental Solutions PFAS remediation of Soil Contaminant Boling Points TCE PCE Xylenes Napthalene PCB Dioxin PFAS PAH Electrical Resistance Heating Thermal Conduction Heating 100°C 200°C 300°CBoiling Points: Steam Enhanced Extraction Chlorobenzenes
  • 5. Environmental Solutions PFAS remediation of Soil Proof of Concept • Pilot Tests carried out • Ex-situ Cells
  • 6. Environmental Solutions PFAS remediation of Soil Proof of Concept Ex-situ Cell heat-up
  • 7. Environmental Solutions PFAS remediation of Soil Proof of Concept PFAS Volatilization from Soil: Time & Temperature
  • 8. Environmental Solutions PFAS Starting Concentration (ppb) % reduction PFOS 21000 >99.999% PFBA 91 >99.999% PFPeA 100 >99.999% PFBS 41 >99.999% PFHxA 200 >99.999% PFHpA 27 >99.998% PFHxS 1600 >99.999% PFNA 16 >99.997% PFDS 48 >99.999% PFOA 64 >99.865% PFAS remediation of Soil Proof of Concept PFAS Soil removal at 400 oC
  • 9. Environmental Solutions • Heating & evaporation • Condensation of steam & PFAS • Water treatment (GAC or PerfluorAd) • Vapor treatment (GAC) Heat Exchanger Scrubber Blower/Vacuum Pump Vapors to Stack Cooling Water Return Cooling Water Upper Vadose Zone Treated at 350°C Transition Zone (100 - 350°C) Not Treated Water Table Source Air Phase GAC To Water Treatment PFAS remediation of Soil Treatment System
  • 10. Environmental Solutions PFAS remediation of Soil Next steps • Test results. • Temperatures achieved. • Two U.S. Government Projects – in-situ and ex-situ – awarded. • 1x ex-situ pile treatment • 1x in-situ vadose zone
  • 11. Environmental Solutions PFAS treatment of Water PFAS treatment of Water • HMVT can offer different water treatment solutions. • Activated Carbon, Ion Exchange or PerfluorAd Technology. • For PerfluorAd Technology HMVT partners with Cornelsen GMBH. • This presentation focusses on: • The proven technology of PerfluorAd. • An example project in Amsterdam.
  • 12. Traditional GAC treatment Environmental Solutions PFAS treatment of Water The PerfluorAd Technology PerfluorAd treatment
  • 13. Environmental Solutions PFAS treatment of Water The PerfluorAd Technology • PerfluorAd is a liquid flocculant. • Dosing in a reactor. • Based on differences in electrical charges between the PFAS molecules. • Creation of micro-flocs between PerfluorAd and PFAS molecules. • PFAS flocs removed by filtration/precipitation.
  • 14. • Proven Technology & ITRC proved. • Multiple successful projects in Germany. • HMVT carried out a first successful project in The Netherlands: ‘Cruqiusweg Amsterdam’. • PerfluorAd removes the bulk of the PFAS (up to >98%). • No negative influence by DOC or other pollutants. • Activated carbon only needed for polishing. Environmental Solutions PFAS treatment of Water The PerfluorAd Technology
  • 15. Environmental Solutions PFAS treatment of Water PerfluorAd vs Activated Carbon • Carbon or PerfluorAd: always custom made. • Carbon: • Very low concentrations of PFAS in water (<1 µg/l) • Low mass of PFAS in water • Short period or very low water flow. • PerfluorAd: • Hi concentrations: source zones, fire foams. • A lot of pollutant mass • Long project period • Competing pollutants in water. • Tipping point often favours PerfluorAd
  • 16. Environmental Solutions PFAS treatment of Water PerfluorAd Reference ‘Cruqiusweg Amsterdam’ Project outline • Groundwater from dewatering during excavation. • Groundwater is collected in a big storage tank. • Flow rate 1,5-2,0 m³/hr. • Discharge limit for PFAS was 1 µg/l.
  • 17. Environmental Solutions PFAS treatment of Water PerfluorAd Reference ‘Cruqiusweg Amsterdam’ Results