3. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 3
Introduction:
Most of the operations in the textile processing such
as scouring, bleaching, dyeing and printing are carried
out by use of basic chemicals like acid, alkalis oxidizing,
reducing agents dyestuffs etc.
Besides this other chemical are also used in relatively
small quantity proportion to increase the efficiency of
above process. These substances are called Textile
Auxiliaries.
4. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 4
What Does Auxiliary
Mean in Textiles?
It is defined as a chemical or a formulated chemical product which
enables a processing operation. The various processing operations may
be in the functions of preparation, dyeing, printing or finishing.
Auxiliaries help by speeding up these processes or carry out the
processes in a more efficient manner. This is necessary to obtain the
desired effect.
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Southeast
University
5/22/2014 5
Carrier or Swelling agent,Levelling agent, Antifoaming agents,
Dispersing agents, Detergents and Wetting agents etc.
Same example of
auxilaries
6. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 6
Objectives:
To know about the different types of Auxiliaries and their function.
To know the dyeing and finishing auxiliaries.
7. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 7
Primary functions
of auxiliaries
To prepare or improve the substrate for coloration
To modify the sorption characteristics of colorants
To stabilize the application medium
To protect or modify the substrate
To improve the fastness of dyeing
To enhance the properties of laundering formulations
(fluorescent brightening agents).
8. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 8
Soda ash Hydrogen Peroxide
Some
Auxiliaries
9. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 9
Caustic Soda ( Flakes)
Some
Auxiliaries
Acetic Acid
10. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 10
Hydrochloric Acid
Some
Auxiliaries
11. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 11
Classification of
Dyeing Auxiliaries
Sequestrant..
pH Control and
buffer system
Lubricants /
Anticreasant.
.Acetic acid
Desizing Agent
Wetting Agents
Dye fixing agent
Softener
Levelling Agent.
Mercerising agent
Antifoaming
agent.
Enzyme
Bleaching agent
Soaping Agent
Optical
Brightener.
Peroxide Killer.
12. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 12
Auxiliaries and its function
Used to remove hardness and metal ion present in dyeing
liquor. Hardness of dyeing liquor can occurred due to
hardness of fabric after pretreatment which is 35 ppm and
also from salt which is 70 ppm
Sequestering
Agent
POLIAC 194 FE, POLIAC 195, POLIAC BIO
Example of
Sequestering
agent
13. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 13
Desizing Agent
Desizing is the process of removing the size material from
the warp yarn in woven fabrics.
Example of
Desizing Agent
DISAPPRETTANTE SG, DISAPPRETTANTE HT etc.
14. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 14
Bleaching agent
Hydrogen peroxide is used for bleaching of cotton fabric and
remove natural color.Bleaching removes contamination from
finished cotton. Full range of bleaching agents like peroxide
bleaching agent.
H2O2
Bleaching
agent
15. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 15
Peroxide Killer.
Peroxide Killer.
It is used in the removal of residual hydrogen peroxide used in
bleaching of textiles before dyeing.
SYNTHOKILL-P
Example
of PK
Basopal FB PK, SYNTHOKILL-P
16. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 16
pH Control and buffer
system
Many disperse dyes required controlled 4.5-5 and practically all
disperse dyes give good results in this pH range and are much more
sensitive to minor changes in pH.
A buffered system is necessary for precise control of pH.
PH
Regulato
rs
Eulysin PC
17. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 17
Levelling Agent.
Trade Name
Form
lonic* Application
ABLUTEX RL Liquid A
Levelling agent of
direct and reactive
dyes, clear and deep
color.
Levelling Agent use for cotton fabric
18. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 18
Levelling Agent.
Trade Name Form lonic* Application
ABLUTEX
RT430
Liquid A/N Dispersing and
levelling agent
for high-
temperature jet
dyeing
Levelling Agent use for polyester fabric.
19. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 19
Levelling Agent
Levelling Agent use for Nylon
Trade Name Form lonic* Application
ABLUTEX LN Liquid N Levelling agent
for dyeing nylon
fibers with acid
dyes.
20. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 20
Wetting Agent
To reduce surface tension of water thus ensures easy
penetrating of chemicals and dye to the fabric.
BIPON BOD anionic Yellowish liquid Wetting /
Detergent is used for preparation of cotton and
blends. BIODEGRADABLE
Wetting
Agent
21. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 21
Mercerising agent
Mercerizing is a process used to increase the luster of cotton.Mercerizing is a process used to increase the luster of cotton.
Mercerizing is a process used to increase the luster of cotton.
Mercerized cotton is often used in cotton crafts and yarns.
NaOH
Example of
mercerising
agent
22. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 22
Soaping Agent
Functions of soaping agent
Disperse the unfixed substanted hydrolyzed dyes, and solubilise and
mulsify these into the aqueous medium and keep these substances in
suspension.
Prevent redeposition of hydrolyzed dyes and other particles of
colloidal substance into the textile material
Prevent the precipitation of insoluble calcium or magnesium salt
23. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 23
Trade Name Form lonic* Application
ABLUTEX TS330 Liquid A
Soaping agent for dyed or printed with
reactive dyes. Effective in Preventing
white ground from being stained.
Example of
Soaping
agent
24. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 24
Optical Brightener
An Optical Brightening Agent (OBA), also called Fluorescent Brightening
Agent (FBA) or Fluorescent whiteners (FW), are strongly fluorescent
substance that emits light in the blue-violet region of the visible spectrum.
Example
of OBA
Ultraphor FB CA, Ultraphor FB IN
25. School of Science and Engineering, Department of Textile Engineering
Southeast
University
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NAME OF CHEMICALS FUNCTION
Felosen Jet Wetting agent
Sirrix 2UD Sequestering agent, Maintain pH
UNJ Antifoaming agent
Ladiquest Wetting agent, Detergent, Levelling agent
Stabilol P Stabilizer (Organic)
Cibacell DBC Levelling agent (Dye bath)
Tubinagol Finishing agent
Thinofix Finishing agent (cationic)
Belfosin GT Finishing agent
FUNCTION OF DIFFERENT CHEMICALS WHICH
IS USED IN SINHA DYEING & FINISHING
26. School of Science and Engineering, Department of Textile Engineering
Southeast
University
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Printing
The textile printing is the art of design by mechanical and chemical application
Printing Chemicals
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Southeast
University
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Synthetic Thickening Agents for Pigment Printing
Lutexal GP
ECO
High polymer, Acrylic Synthetic thickner
Very high electrolyte stable, sharp defined prints, suitable for
photographic prints and multicolour design. More environment-friendly
because of low hydrocarbon emission.
28. School of Science and Engineering, Department of Textile Engineering
Southeast
University
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Synthetic Thickening Agents for Reactive Printing
Lutexal F-RP Acrylic co polymer
Synthetic thickener, substitute for sodium
alginate imparts higher colour yield and
sharp defined prints. Used for printing cotton
and viscose with reactive dyes.
.
29. School of Science and Engineering, Department of Textile Engineering
Southeast
University
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Binders for Pigment
Printing
Helizarin Binder
TOW
Thermally crosslink able aqueous acrylate
dispersion (APEO free)
Binder for pigment prints that are fast to
dry-cleaning having extremely soft handle
excellent all round fastness and very high
rubbing fastness. Used in Soft Print recipe.
30. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 30
Acrylic product
Binder for khadi printing having good
running properties & better fastness.
Gives very good coverage to khadi prints.
Binders for Khadi Printing
Helizarin Binder
FB KH
31. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 31
Crosslin king Agents and
Fixers
Cross linking agent for improving the wash and
rub fastness of pigment prints on synthetic
fibers and regenerated cellulose, and on their
blends with cotton. For prints with a low
formaldehyde content. Suitable for oeko-tex
requirements.
Helizarin Fixing
Agent LF
32. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 32
Fixers for
Disperse Printing
Luprintan FB
FA
Mixture of ethoxylates
Fixation auxiliary for the high
temperature-steam fixation of disperse
dyes in direct printing of polyester
materials.
33. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 33
Antifoam for Pigment
Printing
Entschaumer
- TC ECO
Eco Blend of synthetic copolymers and
emulsifiers (APEO free)
Solvent free and Antifoaming Agent for
Textile Printing.
34. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 34
Softeners
Luprimol SIG Concentrated silicon based auxiliary
Softener, improves fastness giving high quality
pigment prints having soft handle & high dry
rubbing fastness. Improves colour brilliancy.
Bilsoft FB-S Softener that gives an extremely soft feel to pigment prints.
35. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 35
White Pastes for
Pigment Printing
Helizarin White,
Paste FB T
Titanium dioxide in an aqueous acrylic binder system
Ready to use white paste having good covering properties.
Used for printing on dark grounds. Suitable for mainly woven
fabric.
36. School of Science and Engineering, Department of Textile Engineering
Southeast
University
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Process Flow Chart for Knit Dyeing: For
Pink color
Fabric : Single Jersey Quantity : 1310 kg
GSM : 180 M: L=1:7 (During Pretreatment)
8. (During Dyeing)
Color : Pink Water - 9200 lit (Pretreatment)
10500 lit (During
Dyeing)
37. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 37
No. Commercial name of Dyes & Chemicals Amount
(g/l or %)
Total amount
Pretreatment:
1. Wetting Agent-Proder_SCPC/LD/NO-LF 0.5 4.48 kg
2. Gintex ECO GS CONE (S.A) 0.1 896gm
3 Peroxide Stabilizer SR/Stabilizer A/Stopa-52 0.4 3.584kg
4 Anticrease-AULIT-PAC(8460) 0.8 7.360 kg
5 Caustic soda 3.0 27.6 kg
6 H2O2 2.75 25.3 kg
7 Peroxide Killer Geizyme OEM/Cetatex PC 0.5 4.6 kg
8 Acetic Acid 1.0 9.2 kg
Dye Bath Chemical:
9 Acetic Acid 0.2 2.1 kg
10 Gintex ECO GS CONE (S.A) 0.2 2.1 kg
11 Anticrease-AULIT-PAC(8460) 0.8 8.4 kg
12 Leveling Drimegen E2R/Secho IND/Jinleve 1.0 10.50 kg
Dyeing
13 Rea yellow HW 0.01% 0.131 kg
14 Rea. Orange-MEZRL 0.07% 0.917 kg
15 Syno. Red-HF6BN 0.80% 10.48 kg
16 Salt 30 314.4 kg
17 Soda ash 8 83.84 kg
After treatment:
18 Acetic Acid 1.0 9.2 kg
19 Soaping Asugal-ALBI 0.6 5.520 kg
20 Colour Softener Gensoft-100/150/ASUMIN B 0.7% 9.170 kg
Recipe
38. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 38
Textile finishing is a term commonly applied to different process
that the textile material under go after pretreatment, dyeing or
printing for final embellishment to enhance there attractiveness
and sale appeal as well as for comfort and usefulness
Finishing
39. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 39
Water Repellents Chemicals
Lurotex TX-C Anionic aqueous solution of inorganic salts
Universal product, applicable for finishing woven-and knitted
goods from cotton and blends of cotton with synthetic fibres.
Lurotex TX-S Especially suitable for finishing woven-and knitted goods from
synthetic fibres and blends with cellulosic fibres. Very soft
handle
40. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 40
Antistatic Agents
Siligen APE
Slightly cationic quaternary ammonium compound
For antistatic finishing of natural or synthetic fibres and their
blends. No adverse effects on the fabric handle.
41. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 41
Additives and Binders
Perapret PU New
Polyurethane Dispersion
Polyurethane additive and binder for finishing textiles with
and without pigments. Suitable for embossed and chintz
finishes.
42. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 42
Antipilling and Non Slip Finish
Perapret HVN
Antipilling agent and resin finishing additive for woven and
knitted fabrics composed of cellulosic fibres and their blends
with synthetic fibres. Increases tear strength and abrasion
resistance.
43. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 43
Crosslinking Agents
Fixapret AP
Low formaldehyde modified dimethyloldihydroxyethylene
urea
Crosslinking agent for low-formaldehyde, wash-resistant
resin finishing of woven and knitted fabrics composed of
cellulosic fibres and their blends with synthetic fibres.
44. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 44
Additives, Smoothing Agents and Softeners
Basosoft FB EUK
Universal cationic softener for all fibres and blends, imparts
a very soft handle. It can be used on loose stock, tops, yarn
or piece goods, and applied by all sorts of different methods,
such as dipping, padding and spraying
Siligen F Jet
Silicone fluid additive, softener and smoothening agent for
woven and knitted fabrics composed of cellulosic fibres and
their blends with synthetic fibres. Product has good shearing
stability and is suitable for the exhaust application
45. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 45
Optical Brightener Agent
Fluorescent Brighteners
Ultraphor FB CA
Anionic high affinity fluorescent brightener for cotton,
recommended for exhaust.
Ultraphor SFR
Plus Liq
Stable, fluorescent brightener for polyester and blends. It has
good fastness to sublimation.
46. School of Science and Engineering, Department of Textile Engineering
Southeast
University
5/22/2014 46
Thanks To All
47. School of Science and Engineering, Department of Textile Engineering
Southeast
University