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Nitrogen Removal from Municipal
          Wastewater




                 Amy Lowell
       Assistant Wastewater Manager

                                March 6th, 2013
Town of Falmouth Overview
Falmouth Wastewater Overview
• ~ 3% of developed properties (~700) in town
  connected to Main WWTF collection system
• Majority of the rest of the properties have septic
  systems or cesspools – WWTF handles this
  septage as well
• Municipal New Silver Beach WWTF serves an
  additional ~ 200 properties
• Some clusters and advanced individual systems
Falmouth Main WWTF




Original WWTF Constructed in 1980s; Upgrade
             completed 2005
West Falmouth Harbor Watershed
Groundwater Discharge Permit Limits
• 800,000 gpd (no more than 570,000 gpd from
  outside the West Falmouth Watershed)
• Total Nitrogen: 10 mg/L daily maximum
• Additional TN targets:
   – Effluent TN: 3 mg/L
   – Annual effluent TN load of no more than 5,204
     lbs/year to the West Falmouth Harbor watershed
• TSS / BOD: 30 mg/L
• Oil / Grease: 15 mg/L
• Fecal coliform 200 cfu/100 mL
WWTF Background
• Variable influent flow and load: seasonal
  community + septage receiving
• Flow ranges from 200,000 gpd to 700,000 gpd
• Influent BOD and TSS range from < 100 to > 350
  mg/L; average < 200 mg/L
• Effluent BOD average < 3 mg/L, TSS average < 5
  mg/L
• Effluent TN average < 5 mg/L since start up;
  lower in past 2 yrs
Falmouth Main WWTF
Biological Nitrogen Removal
Bacteria do work of nitrogen removal
Influent contains nitrogen in 2 forms: ammonia
and organic nitrogen

Ammonification:
Organic matter  ammonia
(much of this occurs in collection system)
Biological Nitrogen Removal
Nitrification:
two-step oxidation of ammonia to nitrate by
bacteria, summarized:

NH4+ + 2 O2  NO3- + 2H+ + H2O

Requires oxygen (and alkalinity)
Biological Nitrogen Removal
              (Continued)
Denitrification:
Conversion of nitrate to nitrogen gas by bacteria,
summarized:

6 NO3- + 5 CH3OH  5 CO2 + 3 N2 + 7 H2O + 6 OH-

Requires carbon, absence of oxygen
SBR Phases
Sequencing Batch Reactor
Nitrogen Removal Limits
• 3 mg/L is generally achievable for our WWTF
• However would be concerned about enforceable 3
  mg/L effluent limit because:
   – 3 mg/L is “limit of technology” for “enhanced
     nitrogen removal processes” like SBRs + denit
   – Insufficient flexibility for issues that arise under
     normal operation: variation in influent
     characteristics (flow, load, toxicity, etc), operator
     error, mechanical problems
   – Biological processes take time to recover,
     particularly in cold weather
   – “refractory nitrogen” – eff TKN sometimes > 3 mg/L
Nitrogen (mg/L)


                                                                                   10




            0
                1
                    2
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                                   5
                                        6
                                              7
                                                  8




                              4
                                                      9
 1/1/2011

 2/1/2011

 3/1/2011

 4/1/2011
                                                          NH4




 5/1/2011

 6/1/2011

 7/1/2011
                                                          NO3




 8/1/2011

 9/1/2011

10/1/2011
                                                          TKN




11/1/2011

12/1/2011

 1/1/2012
                                                          NO2




 2/1/2012

 3/1/2012

 4/1/2012

 5/1/2012
                                                          Eff TN (mg/L)




 6/1/2012

 7/1/2012

 8/1/2012

 9/1/2012

10/1/2012

11/1/2012
                                                                                        Falmouth WWTF Effluent Nitrogen - 2011 to Current
                                                          Linear (Eff TN (mg/L))




12/1/2012

 1/1/2013

 2/1/2013
The Value of Falmouth’s Estuaries
                      Falmouth has more estuaries than any
                      other town in Massachusetts
                      (15 total)
                       Home to a wide variety of marine life




       A focal point
for community recreation -
 fishing, boating, passive
        enjoyment
Our Estuaries are in Trouble




    Little Pond, 1950              Little Pond, 2009

Excess nitrogen is the main cause of the decline of our
                       estuaries
At least 75% of the controllable nitrogen input comes
                 from septic systems
Estimated % Wastewater Nitrogen
     Removal to Meet TMDLs
Falmouth’s
         Estuaries Restoration Plan
April 2011 Town Meeting unanimously passed Article
17, appropriating $2.7 million to proceed with sewer design and
alternative demonstration projects

Voters approved this measure on a town-wide ballot, supporting it
by a 2:1 margin in every precinct.

In August 2013, Board of Selectmen unanimously approved a Draft
Comprehensive Wastewater Management Plan (DCWMP) with
these elements and submitted it to the state.
Included in Plan Approved by
        Selectmen and Town Meeting:
•   Eco-toilets
•   Shellfish Cultivation
•   Permeable Reactive Barriers
•   Denitrifying Septic Systems
•   Road Runoff Remediation
•   Bournes Pond Inlet Widening
•   Lower Little Pond Sewering
Bournes Pond Inlet Widening




•   90 foot opening provides optimal flushing
•   Could remove as much nitrogen as sewering over 350 homes
•   Cost of inlet widening is less than 40% of sewering costs
•   Benefits to Bournes Pond are immediate
Sewering Lower Little Pond Watershed

 An important
 and cost-effective
 project:

 – Little Pond is town’s most degraded estuary
 – Many very small lots (5000 square feet or less)
 – Area almost at build-out
 – Many homes still have cesspools
Lower Little Pond Collection System
        Preliminary Design
Discussion

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Nitrogen Removal From Municipal Wastewater

  • 1. Nitrogen Removal from Municipal Wastewater Amy Lowell Assistant Wastewater Manager March 6th, 2013
  • 2. Town of Falmouth Overview
  • 3. Falmouth Wastewater Overview • ~ 3% of developed properties (~700) in town connected to Main WWTF collection system • Majority of the rest of the properties have septic systems or cesspools – WWTF handles this septage as well • Municipal New Silver Beach WWTF serves an additional ~ 200 properties • Some clusters and advanced individual systems
  • 4. Falmouth Main WWTF Original WWTF Constructed in 1980s; Upgrade completed 2005
  • 6. Groundwater Discharge Permit Limits • 800,000 gpd (no more than 570,000 gpd from outside the West Falmouth Watershed) • Total Nitrogen: 10 mg/L daily maximum • Additional TN targets: – Effluent TN: 3 mg/L – Annual effluent TN load of no more than 5,204 lbs/year to the West Falmouth Harbor watershed • TSS / BOD: 30 mg/L • Oil / Grease: 15 mg/L • Fecal coliform 200 cfu/100 mL
  • 7. WWTF Background • Variable influent flow and load: seasonal community + septage receiving • Flow ranges from 200,000 gpd to 700,000 gpd • Influent BOD and TSS range from < 100 to > 350 mg/L; average < 200 mg/L • Effluent BOD average < 3 mg/L, TSS average < 5 mg/L • Effluent TN average < 5 mg/L since start up; lower in past 2 yrs
  • 8.
  • 10. Biological Nitrogen Removal Bacteria do work of nitrogen removal Influent contains nitrogen in 2 forms: ammonia and organic nitrogen Ammonification: Organic matter  ammonia (much of this occurs in collection system)
  • 11. Biological Nitrogen Removal Nitrification: two-step oxidation of ammonia to nitrate by bacteria, summarized: NH4+ + 2 O2  NO3- + 2H+ + H2O Requires oxygen (and alkalinity)
  • 12. Biological Nitrogen Removal (Continued) Denitrification: Conversion of nitrate to nitrogen gas by bacteria, summarized: 6 NO3- + 5 CH3OH  5 CO2 + 3 N2 + 7 H2O + 6 OH- Requires carbon, absence of oxygen
  • 15. Nitrogen Removal Limits • 3 mg/L is generally achievable for our WWTF • However would be concerned about enforceable 3 mg/L effluent limit because: – 3 mg/L is “limit of technology” for “enhanced nitrogen removal processes” like SBRs + denit – Insufficient flexibility for issues that arise under normal operation: variation in influent characteristics (flow, load, toxicity, etc), operator error, mechanical problems – Biological processes take time to recover, particularly in cold weather – “refractory nitrogen” – eff TKN sometimes > 3 mg/L
  • 16. Nitrogen (mg/L) 10 0 1 2 3 5 6 7 8 4 9 1/1/2011 2/1/2011 3/1/2011 4/1/2011 NH4 5/1/2011 6/1/2011 7/1/2011 NO3 8/1/2011 9/1/2011 10/1/2011 TKN 11/1/2011 12/1/2011 1/1/2012 NO2 2/1/2012 3/1/2012 4/1/2012 5/1/2012 Eff TN (mg/L) 6/1/2012 7/1/2012 8/1/2012 9/1/2012 10/1/2012 11/1/2012 Falmouth WWTF Effluent Nitrogen - 2011 to Current Linear (Eff TN (mg/L)) 12/1/2012 1/1/2013 2/1/2013
  • 17. The Value of Falmouth’s Estuaries Falmouth has more estuaries than any other town in Massachusetts (15 total) Home to a wide variety of marine life A focal point for community recreation - fishing, boating, passive enjoyment
  • 18. Our Estuaries are in Trouble Little Pond, 1950 Little Pond, 2009 Excess nitrogen is the main cause of the decline of our estuaries At least 75% of the controllable nitrogen input comes from septic systems
  • 19. Estimated % Wastewater Nitrogen Removal to Meet TMDLs
  • 20. Falmouth’s Estuaries Restoration Plan April 2011 Town Meeting unanimously passed Article 17, appropriating $2.7 million to proceed with sewer design and alternative demonstration projects Voters approved this measure on a town-wide ballot, supporting it by a 2:1 margin in every precinct. In August 2013, Board of Selectmen unanimously approved a Draft Comprehensive Wastewater Management Plan (DCWMP) with these elements and submitted it to the state.
  • 21. Included in Plan Approved by Selectmen and Town Meeting: • Eco-toilets • Shellfish Cultivation • Permeable Reactive Barriers • Denitrifying Septic Systems • Road Runoff Remediation • Bournes Pond Inlet Widening • Lower Little Pond Sewering
  • 22. Bournes Pond Inlet Widening • 90 foot opening provides optimal flushing • Could remove as much nitrogen as sewering over 350 homes • Cost of inlet widening is less than 40% of sewering costs • Benefits to Bournes Pond are immediate
  • 23. Sewering Lower Little Pond Watershed An important and cost-effective project: – Little Pond is town’s most degraded estuary – Many very small lots (5000 square feet or less) – Area almost at build-out – Many homes still have cesspools
  • 24. Lower Little Pond Collection System Preliminary Design