Systematic analysis of algalbio-fuel production integrated with domestic wastewater treatment in Armenia. The presentation evaluates using algae to treat wastewater and produce biofuels. It discusses using algae cultivation technologies like open ponds and photobioreactors, and the processes of algae harvesting, oil extraction, and biodiesel production. Future work could involve using photo bioreactors for decentralized wastewater treatment and biodiesel production. In conclusion, algae is a potential solution that can make wastewater treatment cost-competitive while producing biofuels to reduce carbon emissions.
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Final Presentation 2010 Up
1. Systematic analysis of algalbio-fuel production integrated with domestic wastewater treatment in Armenia By: Mambreh Gharakhani Supervisors: Dr. Artak Hambarian Dr. Edwin Safari Referee: Dr. Aram Hajian Special Thanks to: Dr.Knel Touryan Special Thanks to: Prof. Evrik Afrikian
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4. The plan (?) Waste water Algae Green house gasses(CO2, NO2, CH4) Biomass, Biofuel fertilizer, etc..
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6. The existing networks collect waste water from 60-80% of urban areas, while rural areas do not basically have sewage systems, so that waste water is entirely discharged into the river basin.Eutrophication (algal bloom) We are Dying
9. Algae: simple plants, they do not have complex system (Xylem and phloem) to circulate water and nutrients Autotrophic: Using sunlight Heterotrophic: does not require sunlight and Use organic Carbon (CH2O)n instead carbon dioxide + water + sunlight-> carbohydrate + oxygen multicellular forms: seaweed (Macro algae) and unicellular species which Microalgae: unicellular ,exist individually, or in chains or groups
10. Algae are the source of planet’s oxygen and absorb most of CO2 – “Dirty Water”. Species flourish in brackish, Saline and wastewater. • Wastewater nutrients support highly productive algal cultures
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13. Biomass: is low cost plant matter for production of commodities (feeds, fuels, foods, fibers, chemicals) Algae yield: 30 tones/acre. year Other crops: 15 tones/ acre. year
14. comparison of oil yield for various oilseed crops Source: Bennenmen,2008
19. Grow Crops in both fresh and sea water, also in wastewater (sewage)Bonus: microalgae can be used in the wastewater treatment as the micro organisms influencing the cleaning process Well we can! >> Micro-algae will do all these things
20. What algae needs for growth and productivity of biomass? A little bit of everything… • Sunlight •Temperature •Water (Fresh, brackish, wastewater, etc.) •Supply of carbon dioxide (use exhaust of power plants) •Macronutrients: C, N, P, Mg, Ca, K, Na, Cl, NO3, NH4 •Micronutrients (Trace elements): Fe, B, Zn, Mn, Mo, Cu, SO4, Co, Al, Br, Etc..
21. Energy from photosynthesis The energy - in the form of biomass - that can be obtained via photosynthesis thus depends on the level of PAR and the efficiency of the conversion process Q. Ebiomass= PAR x Q Micro algae eight photons to capture one molecule of CO2into carbohydrate (CH2O)nGiven that one mole of CH2O has a heating value of 468kJ and that the mean energy of a mole of PAR photons is 217.4kJ, then the maximum theoretical conversion efficiency of PAR energy into carbohydrates is: 468kJ/(8 x 217.4kJ) = 27% In Practical Case: decreases to 10%
23. Which Algae Production Technology? Microalgae were first mass cultured on rooftop at MIT during the early 1950s, first mention of algae biofuels in report of that project. The energy shocks of the 1970s led renewed study of microalgae biofuels, methane combination with wastewater treatment . 1980 - 1995
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26. Which Algae Production Technology? Closed photobioreactors are economic for high value applications (nutraceuticals) but are presently not cost effective for biofuel production
27. Technologies Based On wastewater treatment Biodiesel production from algae grown in wastewater has the potential to address three important goals: Development of new energy sources (oil production) Management of agricultural wastes to protect aquatic environment Reduction of the global anthropogenic green house effect
28. Direct Cost Direct production costs(combined annual maintenance and operating costs) contribute highest: 68% Nutrient expenses: 33.7% Labor and overheads: 24% Water: 16% Electricity: 7%
29. Ideal Goal: Biofuels from Algae: using Non-Fresh Water Sources
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31. The site is in city of Gavar near to second largest wastewater treatment plant
32. It dumps the incomplete treated wastewater with a flow rate of 2400 cubic meter per day.
35. Comparative capital cost for Different WWT Technologies Capital Cost Comparison between WWT technologies + 80000 $ each year for maintenance Total electricity requirements measured in kWh/MGD at various flow rates
38. BOD5 and suspended solids values were very low: not metered water consumption, leaking water pipes causing large infiltration amounts in the sewers and connections existing between sewerage and storm water network.
39. Same latitude as Denver city~ 30000 liters oil/ hectare . Year (Kristina M. Weyer, Al Darzins, “Theoretical and maximum algal production”, Springerlink.com)
40. Table. 1: Input parameters for wastewater in Gavar 30000 × 100 × 80% × 10-3 = 2400
41. The Alternative options for the solution (Cultivation of algae) 1. The traditional wastewater ponds system 2. Advance integrated wastewater treatment 3. Photobioreactor integrated with wastewater treatment Algal biomass harvesting Oil extraction
42. Traditional wastewater ponds Primary Facultative pond Secondary facultative pond (algal high rate pond) Algae settling ponds Maturation pond
44. NH4- ammonia is the source of nitrogen Biological Oxygen Demand
45. Secondary facultative pond (algal high rate pond) Wastewater treatment High Rate Algal Ponds are presently the only option for cost-effective biofuel production due to co-benefits of wastewater treatment, nutrient recovery and GHG abatement + The various byproducts.
46. Settlingponds To increase the concentration of algae in up to 3 g/l Decrease the operational and power consumption costs 50 to 80 percent of algae can be removed. If higher degrees of algae are required secondary harvesting method is required.
48. Algal Settling Ponds Advanced Facultative Pond Maturation Pond High Rate Pond Paddlewheel (3–6 rpm) Fermentation pit Raw Wastewater Effluent 4.0 - 6.0 m deep 0.1- 0.3 m deep 1.0 m deep 1.0-2.0 m deep Advanced Integrated Ponds system
55. Algae Harvesting Concentration of diluted algae suspension until a thick Algae paste is obtained Primary harvesting Auto flocculation Flocculation Centrifugation
56. Oil extraction Extracting oil from algae paste (algal bio mass) with 90-95% efficiency Solvent extraction: Using Hexane + Mechanical Pressing
59. Algal oil to Biodiesel Transesterification Transesterification is the process that the algae oil must go through to become biodiesel. It is a simple chemical reaction requiring only four steps and two chemicals: 1. Mix methanol and sodium hydroxide creates sodium methoxide 2. Mix sodium methoxide into algae oil 3. Allow to settle for about 8 hours 4. Drain glycerin and filter biodiesel to 5 microns
62. Onsite systems which are flexible and can be moved can be used
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64. Special thanks…. Dr. Antonyan Dr. Al. Darzin, NREL Dr. Treq Lundquist, CalPol University Kate Riley ,Yield Energy Ryan Davis, NREL Mark van Schagen, Evodos Special thanks to family And friends Also Siranush Vopyan