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Science and Cooking
From Haute Cuisine to Soft Matter Science

   Chocolate cake
   with raspberry-yogurt spheres,
   orange sauce and jelly
Creation of the course

    Cast of characters
Dave Weitz   Otger Campas
Ferran Adrià
Michael
Brenner
Amy Rowat
Highlights from 2010

Using Science to Teach Science
Science and Cooking 2011

     New and Improved
Weekly schedule
List of topics
    1    Introduction
    2    Phase Transitions
    3    Food Components
    4    Elasticity and Viscosity
    5    Polymers and Gelation
    6    Diffusion and Entropy
    7    Emulsions and Foams
    8    Proteins and Enzymes
    9    Molecular Basis of Sensation
    10   Production Methods
    11   Beverages
    12   Experimental Design
    13   Desserts
Week 1. Harold McGee
The Curious Cook
Week 1. Dave Arnold
Cooking Issues
Week 1. Introduction
Scientific rigor, historical context
Week 2. Joan Roca
El Celler de Can Roca
Week 2. Phase Transitions
Solid, liquid, gas; phase transitions
Week 3. Ramón Morató
Aula Chocovic
Week 3. Food Components
Carbohydrates, fats, and proteins
Week 4. Carles Tejedor
Via Veneto
Week 4. Fina Puigdevall & Pere Planaguma
Les Cols
Week 4. Elasticity and Viscosity
Elasticity and viscosity measurements
Week 5. Grant Achatz
Alinea, Next, Aviary
Week 5. Polymers and Gelation
Thickeners, spherification
Recipe #1
Orange sauce and jelly

                         Thick
                         sauce
       Orange
         Juice
                         Firm
                         gel
Carbohydrates as thickeners
Table sugar is not very effective


                   s
           s
   s               s
           water
       s               s
               s
                                    sugar
Flour as a thickener
Long chains can form a network




     sugar                 sugar
                sugar              sugar
Xanthan gum
Very long chains of sugars
• Derived from the fermentation of sugars by a
  particular species of bacteria (Xanthomonas
  campestris)
Locust bean (carob) gum
Very long chains of sugars
• Derived from the seed of the carob tree.
  – Slightly sweet and tastes a little like cocoa
  – Often used as a chocolate substitute
Locust bean + xanthan gum
Carbohydrates for carob tree seeds
Week 6. José Andrés
ThinkFoodGroup
Week 6. Diffusion and entropy
Diffusion of ions and heat
Recipe #2
Yogurt spheres




       Yogurt    sphere
Spherification
chemically induced gelation using alginate
• In 1881, E.C. Stanford
  discovered alginate
• Aglinate is
   – A carbohydrate found in
     brown seaweed cell walls
   – Thickener and gelling agent
• Industrially produced
  since 1927
   – ~30,000 tons annually
   – ~10,000 tons used for food
Alginate is a block copolymer
Alternating sequence of two sugars

                              and

             α-L-Guluronate         β-D-Mannuronate




         G          G         M         M             G
G-block regions can bind calcium



       G    G     M     M      G
Calcium cross-links aglinate strands




                      +   Ca+2
Forward Spherification
Add alginate solution to calcium bath


            Alginate-Flavor
            solution




                    Calcium
                    Bath
Week 7. Nandu Jubany
Can Jubany
Week 7. Carles Gaig
Fonda GAIG
Week 7. Emulsions and Foams
Elasticity of emulsions, stabilization of foams
Week 8. Wylie Dufrense
wd~50
Week 8. Proteins and Enzymes
Enzymatic browning, transglutaminase
Week 9. Carme Ruscalleda
Sant Pau
Week 9. Molecular Basis of Sensation
Aroma, taste perception
Week 10. Dan Barber
Blue Hill
Week 10. Methods of production
Agriculture and sustainability
Week 11. Beverages
Fermented beverages, thermodynamics of cocktails
Week 11. Local chefs
a panel of renowned chefs from the Boston area
Week 12. Nathan Myhrvold
Modernist Cuisine
Week 12. Experimental Design
Science in the kitchen, computer modeling
Week 13. Bill Yosses
White House Pastry Chef
Week 13. Desserts
Review of concepts with pastry applications
Recipe #3
Chocolate cake


          Flour
          Cocoa
          Sugar   Foam
          Eggs
Week 14. Ferran Adria
el Bulli
Public Lecture Series
seas.harvard.edu/cooking



       • Runs parallel to the GenEd class
       • Mondays at 7 pm at Science Center C
       • Also on iTunes and YouTube
Questions?
Science Lesson #1

Polymers can thicken liquids or turn
          them into gels.
Foams are stabilized by the lecithin
molecules, which collect at the air-water
boundaries.
The energy required to form the bubbles
depends on their size and the surface tension.




     U = 4sp R                          2
Highlights from 2010

Students, chefs, and science
Science Lesson #2

How to turn oils into powders
Tapioca maltodextrin is made of chains of sugar
molecules, called glucose.
The sugar chains bind to oil, but dissolve rapidly
in the presence of water.
Science Lesson #3

Applications to beverages…
Spherification:
Biology, chemistry and physics
• Derived form brown seaweed cell walls
• block copolymers composed of repeating units
  of mannopyranosyluronic and
  gulopyranosyluronic acids.
G-block regions can bind calcium




      G   G    M     M     G
Alginate production
Calcium ions cross-links the aglinate
Calcium ions cross-links the aglinate
Calcium ions cross-links the aglinate




                  +   Ca+2

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Science and Cooking: Lessons in Soft Matter Science

Hinweis der Redaktion

  1. NAVEEN: I’m here with current Head TF John McGee and Preceptor Pia Sorenson. In keeping with the summer camp theme, we’ll be making PBJ like you’ve never had it before. Along the way, you’ll get an overview of the Science and Cooking class.
  2. This course involved dozens of people spread across two continents. Here’s a brief history of the key players, although many others were instrumental in making the course possible.
  3. NAVEEN: I’m the Forrest Gump of the Science of Cooking course [explain]. Continuing with Forrest Gump theme…this is the “box of chocolates” at el Bulli, possibly the most influential restaurant in the world. The head chef, FerranAdria, changed the way a generation of chefs thought about flavor and texture.
  4. NAVEEN: Otger had initial idea. Prof. Weitz (my advisor) wrote letter.
  5. NAVEEN: Ferran came in early 2009. I bought wine for reception. At epic meal at Clio, Ferran signed memo to initiate collaboration with Harvard.
  6. NAVEEN: As part of the agreement, Ferran would help with science and cooking course. Prof. Brenner (my other advisor) worked to develop curriculum. After asking about it for months, I finally joined the team in the summer of 2010 to develop course.
  7. NAVEEN: I helped Amy to develop the course. John McGee joined soon after me.
  8. NAVEEN: Here’s an example of a technique pioneered by Ferran. [JOHN, do you have a good way to explain “airs” in context?]
  9. This course involved dozens of people spread across two continents. Here’s a brief history of the key players, although many others were instrumental in making the course possible.
  10. JOHN: [interesting anecdote about Tejedor]
  11. JOHN: [tasty ceviche, scrupulous note-taking[
  12. JOHN: [Jose Andres anecdote]
  13. NAVEEN: EnricRovira – marble slab, microwave, etc.
  14. NAVEEN: he built a house!
  15. PIA: [intro about Achatz]
  16. NAVEEN: Yosses…
  17. JOHN: [witty remark about equations’
  18. JOHN: [some way to make boiling water sound more interesting]
  19. NAVEEN: tried to make final exam more interesting by adding chefs
  20. NAVEEN: cookies are the only thing Michael has cooked.
  21. JOHN: [convey epic nature of science fair]
  22. This course involved dozens of people spread across two continents. Here’s a brief history of the key players, although many others were instrumental in making the course possible.
  23. The font size is 22…let me know if you have any better ideas.
  24. He wrote your textbook here at Harvard. He travels around the world and eats lots of food. He earns his money through book contracts.
  25. Dave Arnold is the world expert in culinary technology. He majored in Philosophy and got a Masters in Metal Working, then he got into food. He’s an artist and a scientist. He’ll share both with us. He’s very personable and a great speaker. Great demos and talks.
  26. This is an image of the first pressure cooker. No lab this week.
  27. His restaurant is one of the best in the world. It’s a beautiful restaurant with a beautiful wine cellar. It’s three brothers. He wrote the first book on sous vide cooking. He is a master of precision.
  28. Picture of a slow cooked egg, and of ice cream under an electron microscope
  29. Ramon morato. Master chcolatier. He has a school in Spain. Speaks fluent english, when talking about chocolate.
  30. The font size is 22…let me know if you have any better ideas.
  31. Carles has a great restaurant in Barcelona. He blends traditional cooking with modern techniques. Speaks english.
  32. Great restaurant in the Catalan countryside. Fina Pooch-de-call and PerePlawn-a-gooma.
  33. The studens got these last year in lecture. They were delicious.
  34. Carles has a great restaurant in Barcelona. He blends traditional cooking with modern techniques. Speaks english.
  35. One of the best chefs in America. One of the best restaurants in the world. Modern techniques to achieve new experiences. He has a new memoir, “Life, On the Line.” He had tongue cancer. He treated it with chemo and now his sense of taste has returned.
  36. The font size is 22…let me know if you have any better ideas.
  37. We can put in portraits of each chef/speaker here.
  38. Many restaurants in DC, larger-than-life, TV chef (“Made in Spain”), lots of fun. Supports food operation in DC.
  39. The font size is 22…let me know if you have any better ideas.
  40. We can put in portraits of each chef/speaker here.
  41. Historical/Industrial context
  42. Chemistry. Maybe demo dissolving some in water to show it gets thickerFrom http://books.google.com/books?id=A-AiYsGTd38C&pg=PA307&lpg=PA307&dq=egg+box+alginate&source=bl&ots=zG2Q8I9igj&sig=A112nkcsfzKFpbWOpkQP8jLpEKw&hl=en&ei=CXh7TvKFKY3I0AHs8cnCCA&sa=X&oi=book_result&ct=result&resnum=5&ved=0CFYQ6AEwBA#v=onepage&q=egg%20box%20alginate&f=false100,000’s of units
  43. Needs next slideFrom http://books.google.com/books?id=A-AiYsGTd38C&pg=PA307&lpg=PA307&dq=egg+box+alginate&source=bl&ots=zG2Q8I9igj&sig=A112nkcsfzKFpbWOpkQP8jLpEKw&hl=en&ei=CXh7TvKFKY3I0AHs8cnCCA&sa=X&oi=book_result&ct=result&resnum=5&ved=0CFYQ6AEwBA#v=onepage&q=egg%20box%20alginate&f=false
  44. Demo – put calcium in alginate solution make it solid blob
  45. Animate to show diffusion concept. Then go make cocktail of Cointreau caviar in champagne. Serve to front row.
  46. Party chef. Fun guy. Very strong arm. Emulsions. Likes going to discoteques. Really tasty food.
  47. Grandfather of Barcelona cooking. Car-leys Gaitch.
  48. The font size is 22…let me know if you have any better ideas.
  49. Leadingpracticioner of transglutaminase…taken it further than anyone else. He’s a blast. Has lots of problems for us. One of the winning projects last year was a project from his kitchen.
  50. We can put in portraits of each chef/speaker here.
  51. Peanut butter pasta with TGase
  52. Delicious food. Most decorated female chef in the world.
  53. Fantastic speaker. More intellectual. Goes beyond just cooking, into sustainability and broader social issues. He looks into how traditional techniques evolved. He studied political science at Tufts.
  54. The font size is 22…let me know if you have any better ideas.
  55. The font size is 22…let me know if you have any better ideas.
  56. Barbara Lynch’s gluten-free noodles inspired another winning science fair project.
  57. Did PhD with Stephen Hawking. Former CTO of Microsoft. Founded Microsoft Research. Dinosaur Hunter. SETI.
  58. This is from the mcgee physics world paper where they used a basic differential equation to model heat transfer due to flipping a steak
  59. Expert on chocolate.
  60. Ice cream made with a traditional turkish root that contains a polymer which rends the ice cream stretchy
  61. Party chef. Fun guy. Very strong arm. Emulsions. Likes going to discoteques. Really tasty food.
  62. We can put in portraits of each chef/speaker here.
  63. Expert on chocolate.
  64. DEMO TIME! NAVEEN: How do you incorporate air into a liquid without all the bubbles collapsing.MIX GRAPE JUICE. Adding soap would work, but wouldn’t taste good. What about lecithin? MIX GRAPE JUICE WITH LECITHIN: [expression of amazement]
  65. NAVEEN: Here’s what happens at the molecular level.
  66. NAVEEN: Since Michael is an applied math professor, each week had an equation.
  67. NAVEEN: Now John can tell you about some of the highlights of the course.
  68. JOHN: [interesting anecdote about Tejedor]
  69. JOHN: [tasty ceviche, scrupulous note-taking[
  70. JOHN: [Jose Andres anecdote]
  71. NAVEEN: EnricRovira – marble slab, microwave, etc.
  72. NAVEEN: he built a house!
  73. NAVEEN: Yosses…
  74. JOHN: [witty remark about equations’
  75. JOHN: [some way to make boiling water sound more interesting]
  76. NAVEEN: tried to make final exam more interesting by adding chefs
  77. NAVEEN: cookies are the only thing Michael has cooked.
  78. JOHN: [convey epic nature of science fair]
  79. PIA: [intro about Achatz]
  80. PIA: [PBJ demo intro]
  81. Blueberry demo (I haven’t tried this recipe): http://blog.khymos.org/2007/03/30/first-experiments-with-sodium-alginate/Fun facts from here: http://www.pharmaquality.com/ME2/Audiences/dirmod.asp?sid=325598564E8C4B3EB736C7159241312D&nm=&type=Publishing&mod=Publications%3A%3AArticle&mid=D3E3C719D8D44216836DCA4F4144BEC4&tier=4&id=31AEAEED467E498A88520D670948F40A&AudID=5648A5C28C97462DBBDB309539B820EF1881 Named by British chemist E. C. Stanford1927 started commercial production30,000 tons per year worldwide; ~10K tons for food; 20K for industrial, pharmaceutical, and dental applications.2nd most abundant marine biopolymer and, after cellulose (the most abundant biopolymer in the world)
  82. From http://books.google.com/books?id=A-AiYsGTd38C&pg=PA307&lpg=PA307&dq=egg+box+alginate&source=bl&ots=zG2Q8I9igj&sig=A112nkcsfzKFpbWOpkQP8jLpEKw&hl=en&ei=CXh7TvKFKY3I0AHs8cnCCA&sa=X&oi=book_result&ct=result&resnum=5&ved=0CFYQ6AEwBA#v=onepage&q=egg%20box%20alginate&f=false
  83. Images from http://blog.khymos.org/2006/09/17/video-on-alginates/Chemistry - http://blog.khymos.org/wp-content/2006/09/calcium-alginate.jpgChains - http://blog.khymos.org/wp-content/2006/09/calcium-alginate2.jpgBrown algea - http://farm3.static.flickr.com/2472/3989151026_c9bfe5fce7_z.jpg?zz=1
  84. http://www.fao.org/docrep/006/y4765e/y4765e08.htm