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Kinetic Particle Theory
Learning Outcomes
• At the end of the lesson, the students should be
able to:
– describe the solid, liquid and gaseous states of matter
and explain their interconversion in terms of the kinetic
particle theory and of the energy changes involved
States of Matter
• Matter can exist as a solid, a liquid or a
gas.
• Kinetic particle theory states that
– all matter is made up of tiny particles and
– that these particles are in constant random
motion.
Comparing the 3 states
Property

Solid

Liquid

Gas

Shape

Fixed

Not fixed

Not fixed

Volume

Fixed

Fixed

Not fixed

Cannot be
compressed

Cannot be
compressed

Can be
compressed

Strong

Weaker than
that in solid

weak

Compressibility
Forces of
attraction
between
particles
Comparing the 3 states
Property

Solid

Liquid

Gas

Arrangement
of particles

closely
packed in
orderly
manner

closely
packed in
random order

far apart
Comparing the 3 states
Property
Movement of
particles

Solid

Liquid

cannot move, free to move
vibrates and
within the
rotates about
liquid,
their fixed
vibrates and
position
slides over
one another

Gas
free to move,
move rapidly
in any
direction
Changes in States of Matter
• The physical state of a substance
depends on the temperature and pressure
of the surroundings.
• For example
– At room temperature (25 oC), water is in the
liquid state.
– At -10 oC, water is in the solid state.
Changes in State
• Heat is a form of energy.
• When matter is heated, the particles
absorb energy.
• When matter is cooled, the particles lose
energy.
• the heat taken in or given out causes the
kinetic energy of the particles to change.
• Hence, the substance changes it state.
Changes in States of Matter
condense
melt

boil
condense

freeze
sublime
Changes in States of Matter
Melting

Physical
change
Energy
change

Boiling

Freezing

Condensation

Sublimation

Solid to
liquid

liquid to
gas

liquid to
solid

gas to
liquid

solid to
gas

Energy
Energy
Energy
Energy
Energy
absorbed absorbed given out given out absorbed
Changes in States of Matter
• What happens during melting
– particles gain energy,
– particles vibrate faster,
– particles overcome attractive forces between
them,
– particles break away from their fixed positions
Changes in States of Matter
• What happens during boiling
– particles gain kinetic energy,
– particles move faster,
– particles overcome forces holding them
together,
– particles spread far apart,
– particles move rapidly in all directions
Changes in States of Matter
• What happens during freezing
– particles lose kinetic energy,
– particles move more slowly until they no
longer have enough energy to move about
freely,
– particles settle into fixed position
Changes in States of Matter
• What happens during condensation
– particles lose energy,
– particles move more slowly,
– becomes a liquid
Sublimation
• Particles at the surface of the solid have
enough energy to break away from the
solid and escape as a gas
Changes in States of Matter
Melting
Temp at
which
change
occurs

Boiling

melting
point

boiling
point

Freezing Condensation
Freezing
point

-
Wake Up Call 1
1. When water vapour condenses to water, the
particles in the vapour
A
gains energy.
B
decrease in density
C
move closer to each other
D
mover further apart from each other.
Answer: C
Wake Up Call 1
1.

Three substances have the following properties:
X: melts at -180 oC and boils at -167 oC
Y: has shiny crystalline surface at r.t.p
Z: can flow and take the shape of container at rtp; has boiling
point of 160 oC
What is the state of each substance at room temperature and
pressure?
X

Y

Z

A

Gas

Solid

Liquid

B

Gas

Liquid

Liquid

C

Liquid

Solid

Solid

D

Gas

Liquid

Solid
Answer: A
Wake Up Call 1
3 (a)

For the following substances state the physical state
(solid, liquid or gaseous) they are in at a temperature of 1500 oC.

Substance

Melting Point / oC

Boiling Point / oC

Copper

1084

2562

Calcium

842

1484

Iron

1538

3134

Gold

1064

2856

Physical State
Wake Up Call 1
b)

Hence draw and describe the arrangement and
movement of particles of copper, calcium and iron at
the temperature of 1000 oC.

(i) Copper

Arrangement:
–
closely packed in orderly
manner
Movement:
–
cannot move, vibrates and
rotates about their fixed
position

(ii) Calcium

Arrangement
– closely packed in random
order
Movement
– free to move within the liquid,
vibrates and slides over one
another
Temperature Changes
• When matter is heated
energy causes
temperature to increase.
• Temperature stops
increasing at melting /
boiling points.
• Particles absorb the heat
energy to vibrate faster
and move further apart.
• Matter changes state.

Figure showing the heating curve
of water

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LSS Kinetic Particle Theory

  • 2. Learning Outcomes • At the end of the lesson, the students should be able to: – describe the solid, liquid and gaseous states of matter and explain their interconversion in terms of the kinetic particle theory and of the energy changes involved
  • 3. States of Matter • Matter can exist as a solid, a liquid or a gas. • Kinetic particle theory states that – all matter is made up of tiny particles and – that these particles are in constant random motion.
  • 4. Comparing the 3 states Property Solid Liquid Gas Shape Fixed Not fixed Not fixed Volume Fixed Fixed Not fixed Cannot be compressed Cannot be compressed Can be compressed Strong Weaker than that in solid weak Compressibility Forces of attraction between particles
  • 5. Comparing the 3 states Property Solid Liquid Gas Arrangement of particles closely packed in orderly manner closely packed in random order far apart
  • 6. Comparing the 3 states Property Movement of particles Solid Liquid cannot move, free to move vibrates and within the rotates about liquid, their fixed vibrates and position slides over one another Gas free to move, move rapidly in any direction
  • 7. Changes in States of Matter • The physical state of a substance depends on the temperature and pressure of the surroundings. • For example – At room temperature (25 oC), water is in the liquid state. – At -10 oC, water is in the solid state.
  • 8. Changes in State • Heat is a form of energy. • When matter is heated, the particles absorb energy. • When matter is cooled, the particles lose energy. • the heat taken in or given out causes the kinetic energy of the particles to change. • Hence, the substance changes it state.
  • 9. Changes in States of Matter condense melt boil condense freeze sublime
  • 10. Changes in States of Matter Melting Physical change Energy change Boiling Freezing Condensation Sublimation Solid to liquid liquid to gas liquid to solid gas to liquid solid to gas Energy Energy Energy Energy Energy absorbed absorbed given out given out absorbed
  • 11. Changes in States of Matter • What happens during melting – particles gain energy, – particles vibrate faster, – particles overcome attractive forces between them, – particles break away from their fixed positions
  • 12. Changes in States of Matter • What happens during boiling – particles gain kinetic energy, – particles move faster, – particles overcome forces holding them together, – particles spread far apart, – particles move rapidly in all directions
  • 13. Changes in States of Matter • What happens during freezing – particles lose kinetic energy, – particles move more slowly until they no longer have enough energy to move about freely, – particles settle into fixed position
  • 14. Changes in States of Matter • What happens during condensation – particles lose energy, – particles move more slowly, – becomes a liquid
  • 15. Sublimation • Particles at the surface of the solid have enough energy to break away from the solid and escape as a gas
  • 16. Changes in States of Matter Melting Temp at which change occurs Boiling melting point boiling point Freezing Condensation Freezing point -
  • 17. Wake Up Call 1 1. When water vapour condenses to water, the particles in the vapour A gains energy. B decrease in density C move closer to each other D mover further apart from each other. Answer: C
  • 18. Wake Up Call 1 1. Three substances have the following properties: X: melts at -180 oC and boils at -167 oC Y: has shiny crystalline surface at r.t.p Z: can flow and take the shape of container at rtp; has boiling point of 160 oC What is the state of each substance at room temperature and pressure? X Y Z A Gas Solid Liquid B Gas Liquid Liquid C Liquid Solid Solid D Gas Liquid Solid Answer: A
  • 19. Wake Up Call 1 3 (a) For the following substances state the physical state (solid, liquid or gaseous) they are in at a temperature of 1500 oC. Substance Melting Point / oC Boiling Point / oC Copper 1084 2562 Calcium 842 1484 Iron 1538 3134 Gold 1064 2856 Physical State
  • 20. Wake Up Call 1 b) Hence draw and describe the arrangement and movement of particles of copper, calcium and iron at the temperature of 1000 oC. (i) Copper Arrangement: – closely packed in orderly manner Movement: – cannot move, vibrates and rotates about their fixed position (ii) Calcium Arrangement – closely packed in random order Movement – free to move within the liquid, vibrates and slides over one another
  • 21. Temperature Changes • When matter is heated energy causes temperature to increase. • Temperature stops increasing at melting / boiling points. • Particles absorb the heat energy to vibrate faster and move further apart. • Matter changes state. Figure showing the heating curve of water