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Glass: Future Applications & Market 
Demands –focus on raw materials
Murray Lines
Stratum Resources, Sydney, 
Australia
Acknowledgments include:
Pilkington Activ™
Glass Alliance Europe is the European Alliance of Glass Industries. It has the unique feature of regrouping all the glass 
industries to work on common issues. It is composed of 19 national glass associations & of the main sectors of the glass 
industries: container glass, flat glass, special glass, domestic glass and continuous filament glass fibres.
Mineral Holdings 
Melbourne
Agenda 
 Glass intro ‐ a remarkable material
 Glass recycling  – important for sustainability
 New glass technologies /applications  by leading 
companies
 Industrial minerals involved 
 Nano‐materials use in glass
Highly engineered glass – future touch screen technology
Highly engineered glass will become a part of everyday life. 
Corning is committed to improving lifestyles through 
innovative design/build solutions and the integration of 
current technologies 
A day made of glass – video by Corning
Glass is everywhere
• Almost no other man‐made material provides so many possibilities across so 
many industries & disciplines
• Preferred for food & beverages
• Important role in transportation
• Key element in architecture & buildings
• Part of renewable energy strategy
• Crucial in modern communications
• Many pharmaceutical, health & science applications.
Glass is an unlimited material & the number of applications is constantly evolving 
&  is often used in combination with other material for high‐tech applications.
Glass is a remarkable material
• Transparency UV‐lamps, light protecting packaging
• Chemical resistance packaging material for pharmaceuticals, labs 
• Temperature resistance     halogen lamps, laboratory, flash lamps
• Electrically insulating X‐ray tubes 
• Thermal expansion            halogen lamps, solar receivers, flash lamps
• Impermeability display industry, solar receiver, X‐ray tubes, halogen lamps
• Refractive index                  fibre optics, light guides for endoscopy   
• Dielectric strength              diodes
• Mechanical properties      various such as sprinklers in hotel room etc
Glass properties       Technical applications include
Source: Schott literature
Windows design for reduced heat transfer
•Compare the cost of 
two sheets of glass 
with one sheet plus 
the additional cost 
of the applied nano 
coating layers.
Glass manages solar heat 
by 3 mechanisms
1) Reflectance – the proportion of 
solar radiation reflected back into 
the atmosphere
(2) Direct transmittance – the 
proportion of solar radiation 
transmitted directly through the 
glass
(3) Absorptance – the proportion of 
solar radiation absorbed by the 
glass.
Soda‐lime‐silicate glass used in buildings
Composition:
• ‐ silica, the raw material, in the form of sand (70 ‐ 72 %)
‐ soda, the flux, as carbonate and sulphate (~ 14 %)
‐ lime, a stabiliser, in the form of limestone (~ 10 %)
‐ various other oxides such as alumina & magnesia, to improve the physical properties of 
the glass, including its resistance to atmospheric pollutants   
‐ for body‐tinted glasses, metal oxides can also be incorporated
• e.g. SGG PARSOL is a body‐tinted glass, manufactured in the same way as clear float glass 
but with additions of special metal oxides.
• SGG PARSOL is intended for universal applications where an attractive appearance or basic 
solar control properties are required:
‐ Interior applications for decoration, fittings and furniture.
‐ External applications in single or double‐glazing, for facades & overhead glazing
• ADVANTAGES
• SGG PARSOL provides additional solar control to reduce the burden on air‐conditioning 
through the warmer months & also provides different colours
Due to its properties, glass is at the cutting‐edge of technology
• Chemical : Corrosion resistance and Inertness
• Thermal shock resistance
• Optical :  Reflects, bends, transmits and absorbs light
• Electrical insulation
• Mechanical:  Surface is hard (scratch & abrasion resistant) & Elastic
Glass  has enabled huge progress in space exploration, medical 
research, optics and telecommunications 
The future of glass is opening many opportunities
• Research is opening up tremendous opportunities 
for the development of future glass products & 
the way we currently use glass in various 
applications. 
• Smart glass bottles & containers whose colour 
changes depending on the liquid temperature 
(medicines, wines, perishable products, etc.)
• Photovoltaic sunroof to provide electricity to 
hybrid & electric vehicles
• Architectural glass for temperature control, self 
cleaning, aesthetics , fire control etc
• Complex glass shapes & improved insulation 
properties to free architects from constraints
• Better  performing photovoltaic electricity 
generation equipment  whose integration would 
become easier to fulfil most of our energy needs.
In China a smart window has been designed to 
save & generate energy using VO2  as a 
transparent coating .       Photo Reuters
Sustainability & the Environment
• Glass is a sustainable, fully recyclable 
material which provides great 
environmental benefits. 
• Low energy light globes.
• Glass can help to save energy.
• insulating glass for windows 
• light ‐weighting  reinforcement 
glass fibre used in auto & aviation
• Fibreglass is used in wind turbines, 
using light weight reinforcement 
glass fibres
• CFL lights use 1/3 ‐1/5 power & last 
8‐15 times longer
Source:  USGS
The Benefits of recycling  
Saving landfill space 
• Recyclable material makes up ~ 80% of total household waste, so every item 
recycled is one less to be buried in our rapidly filling landfills.
What’s more ‐ glass takes ~ a million years to break down naturally. This means 
that every piece of glass that has ever been sent to landfill is still sitting there –
taking up valuable space. 
Conserving natural resources 
• Each glass bottle recycled keeps valuable non‐renewable resources such as 
bauxite, iron‐ore and sand in the ground. 
• Because recycled glass takes less energy to manufacture than producing glass 
from virgin materials, finite natural resources such as natural gas is saved.
• As more countries become developed increasing waste is a growing issue.
Recyclers of Glass in Europe include:
FERVER
• Life Cycle Thinking, Recyclability, Recycling & 
collection targets
• End of Waste: transforming waste into a product
• End of Life of Vehicles: automotive glass
• Heavy metals, Vitroceramics
• Glass recycling targets
• Carbon emissions
• Use of aggregates
• sustainability
• FERVER is the association of glass recycling companies in Europe.  
• Members are spread over 16 countries.
• 70% of glass is recycled by Ferver members.
Website: www.ferver.be/en
Batch contains  
~26% recycled 
glass cullet 
Glass recycling rate compared to other waste‐streams
Counter tops of recycled glass
Recycling of Glass – beneficial & profitable 
• The use of cullet reduces energy and raw 
material needs, CO2 emissions and the use of 
landfill sites.
• Consumers often come in contact with 
recycled products without knowing it. 
• Besides new glass containers, recycled glass is 
also used for products such as glass wool & 
foamed glass.
• Glass wool is used for wall & ceiling insulation 
& foamed glass aggregate is mostly used in 
construction and to protect infrastructure & 
buildings against frost heave in cold climates.
Hosokawa ‐ Alpine  Glass Grinding for Foam Glass Production
Foamed GlassBroken glass 
Grinding & classification of glass powder
Foam glass is a heat insulating material made   of foamed glass for the 
construction & civil engineering / industrial installations, dimensionally stable 
boards, pipe sections, segments & other parts .
Foam glass is even used in extreme conditions. Insulation of buildings against 
ground in hydraulic water situations.  
Heat & air 
bubbles
Ball Mill with direct drive‐SOCL
direct driven by side shield
Ideal equipment 
for grinding glass 
waste chips into 
powdered glass
Foam Glass requires fine  Glassflour
• For the Foamglass production there are demands as:
• Foam Glass gravel  Glassflour < 100 micron )
• Foam Glass fine balls  0,1‐10 mm  Glassflour < 40 micron )
• Boards or Blocks of Foam Glass :  Glassflour < 25 micron
Foam Glass in Construction
• What is Foam Glass and what it is used for ?
• Foam Glass is made from recycled glass & constitutes of millions of closed , 
gas filled cells. 
• Foam Glass is a porous expanded material mostly granular, which is used in 
civil constructions 
due to porousity proporties it is used mostly as a thermal insulation 
material, bedding in road construction, flat roof insulation, for soil water 
barrier, 
• it increases the compressive strength of construction materials , is 
waterproof,  non‐rotting, odourless, fire‐resistant…
Glass bottles& float glass offcuts 
Glassflour
Grinding & classifying

Product
Foam Glass
Raw material
Cleaning & 
drying to <8% 
moisture
Heating & air 
injection to 
produce bubbles
Alpine Classifier Ventoplex
• energy efficient classifier
• with integrated ventilator 
• fineness d97 in the range 30 µm to 800 
µm adjustable
• model range: throughput 
from 1 t/h to 30 t/h
Concepts and Machine Designs:
Foam Glass production needs top cut limiting of the glass flour.
The ball mill runs in a loop with an air swept classifier….
fine coarse
feeding
Foam‐glass is environmentally friendly insulation material which is prepared from the 
purified recycled glass.
It is ideal for frost insulation & gravel material for road structures, as well as for thermal 
insulation of all buildings & light weight foundations.
Reference Plant: SO Ball Mill + Ventoplex for  Glassflour 
of Foamglass Production
Electronic glass waste recycling  
~16% OF 
ELECTRONIC 
WASTE IS 
GLASS
High index glass beads for reflective road signs etc
•High Index Standard (180‐250 microns) High 
Performance reflective glass beads made using a 
unique manufacturing process. 
•“Auto glass offcuts” are melted in a vertical drop furnace 
into highly reflective materials & shaped to fine glass beads.
• These beads offer high performance & durability due to their 
extremely smooth surfaces, greater than > 98 % roundness & 
less than 1% air inclusions.
• Applications include reflective sheeting, high performance 
road & airport lines, signs,  reflective paints etc. 
•Type 3 beads have a refractive index of >1.93
Potters USA 
Benefits of Smart Glass Technologies
• Suspended particle devices (SPD)
• In suspended particle devices (SPDs), a thin film laminate of rod‐like nano‐
scale particles is suspended in a liquid and placed between two pieces of 
glass or plastic, or attached to one layer. 
• When no voltage is applied, the suspended particles are randomly 
organized, thus blocking & absorbing light.
• When voltage is applied, the suspended particles align & let light pass. 
• Varying the voltage of the film varies the orientation of the suspended 
particles, thereby regulating the tint of the glazing & the amount of light 
transmitted.    
• Other smart glass technologies include:
• Electro‐chromic
• Photo‐chromic
• Thermo‐chromic
• Micro‐blind
• Polymer dispersed liquid crystal devices
Source: Genesisnanotechnology
In‐Cell Touch Technology
• In‐cell technology refers to a standard of displays that emerged in 2012 & 
allow mobile devices to be thinner & lighter even though larger in size.
• In‐cell displays are revolutionary in the sense that they combine a digitizer, 
use touch input, & integrate an LCD screen into a single‐layer display. 
• Also  in‐cell technology displays provide better resolution than standard LCD 
screens.
• In‐cell displays emerged in 2012 that Apple's upgrade included this new 
technology to reduce the thickness of the screen. 
• Less advanced touchscreen devices, including many smartphones & tablets, 
tend to have two separate display layers that need to be combined internally. 
ITO = Indium tin oxide
Gorilla glass has been used on more 
than 1 billion devices to date !
HPA (High purity alumina/sapphire) Market Demand
• The global HPA market was estimated at 19 ktpa in 2014 & is 
expected to increase to 48ktpa by 2018
• The global HPA market is used to produce:  Light Emitting Diode 
(LED) products (55%), semiconductors (22%), phosphor plasma 
display panels (16%) & industrial/chemical/medical applications 
(7%). 
• HPA is increasing demand in electronic devices.
• HPA’s superior qualities are pertinent features for a range of 
existing & new applications, e.g. sapphire glass for smartphones. 
• The price for the 4N HPA product is a high‐value product which 
ranges from US +$20/kg.
Source: Altech Chemicals
Solar cell efficiencies – slow & steady improvement
There is a need for low iron glass to allow maximum light of all wavelengths to maximise cell efficiency
Sun Partner Technology – Smart glass
WYSIPS® TECHNOLOGIES
(What You See Is Photovoltaic Surface) 
Transforms any surface into a solar panel that 
can generate electricity from natural or 
artificial light
• Wysips® Glass is a transparent technology 
that integrates into the glazing & generates 
energy locally. 
• The window can then power its own 
features, such as electronic dimming, 
lighting, automated opening systems/alarms, 
or help power semi‐transparent screens 
integrated into the glazing.
Wysips® Glass
http://sunpartnertechnologies.com
New partner
Quartz for lighting
Four main quartz application types can be 
separated for lighting equipment:
• Transparent vitreous silica for high‐
temperature devices (mercury, halogen lamp)
• Transparent vitreous silica tubes with titanium 
dioxide additions (medical bactericidal lamps)
• Transparent vitreous silica tubes with cerium 
additions, disabling ultraviolet radiation
• Synthetic ultrapure silica tubes which applied 
as constructive elements of medical, chemical 
equipment & semiconductor devices
Schott Glass tubing for Halogen lamps  
Electronics  Pure quartz glass crucible
• The semiconductor industry needs high purity 
quartz.
• Quartz crucibles (special shaped pots for metal 
melt), quartz tubes, other equipment (cuvettes, 
cups, containers) are used to obtain single‐
crystalline silicon. Quartz powder is needed to 
reduce losses of large diameter crucibles to 
reinforce their inner surface.
• Electronic industry requires high purity quartz to 
avoid contamination during the process of silicon 
recovery.
Quartz crucibles
Technical glass tubing  ‐ Biofuel production
Schott glass for algae cultivation ‐
• Closed looped systems made of Duran® glass. 
• A photo‐bioreactor uses a light source to cultivate phototrophic microorganisms for 
biofuel production.
• A photo‐bioreactor allows much higher growth rates  &  purity levels
SCHOTT is a leading international technology group in the areas of specialty glass & glass‐ceramics.
Fibre Optics
• Fibre optics is one of the most advanced and high‐
technology industry & it uses quartz for production 
of optical conductors. 
• Quartz tubes are used to spread finest fibre are 
made both from natural & synthetic quartz (from 
silicon tetrachloride)
• Today, more than 2 billion km of optical fibre make 
up the world’s telecommunications network.
• The vast majority of today’s voice, video, & data still 
zooms through optical fibre. (Source: www.corning.com)
Optics
• Optical use of quartz is conditional upon 
its main characteristic that is a range of 
optical transmission including ultraviolet 
& infra‐red bands. 
• Uni‐component and multi‐component 
glass for different applications is “melted” 
based on quartz:
• Optical systems
• Telescopes
• Gyroscopes
• Thermal imagers 
• Microscopes 
• Objectives  Source: Telescopemirrorblanks
“Super windows” for large commercial buildings 
• Pass light but reflect heat
• This will save massive 
amounts of energy (both 
heating & cooling)
• Thin film solar cell 
technologies
• Potentially many 
buildings will be able to 
produce part of their 
own power 
requirements
Source: Rocky Mountain Institute www.rmi.org
& Inst of Photonic Sciences www.icfo.eu
Lithium applications by sector including glass
Source: Canaccord Genuity
~20% of lithium 
used in glass & 
glass‐ceramics
Pyrex ™ Glass – addition of boric acid & lithium carbonate
Pyrex has a droplet in matrix phase structure. The silicon 
dioxide creates the basic matrix. The borate material 
creates the droplets within that structure. 
The borate former can come from a material like sodium 
tetraborate.
Prior to manufacture, this compound is chemically 
reduced with sulphuric acid to create boric acid. 
When boric acid is mixed with silicon dioxide and heated, 
it oxidises into boric oxide.
Boric oxide is responsible for the unique Pyrex 
molecular structure & makes up anywhere ~ 5‐20% of 
Pyrex glass. 
Secondary ingredients used in glass production include 
fluxes, stabilizers, and colourants. 
Fluxes are included in glass mixtures to reduce the 
melting temperature of borosilicate glass.
Fluxes used in manufacture include soda ash, potash, & 
lithium carbonate.  
They make up about 5% of a Pyrex glass composition. 
Glass‐ceramics – useful thermomechanical properties 
• Glass‐ceramics involves a mix of lithium & alumino‐silicates 
giving an array of materials with useful thermomechanical 
properties.
• A key property being impervious to thermal shock. 
• Glass‐ceramics have become extremely useful for 
countertop cooking. 
• The negative thermal expansion coefficient (CTE) of the 
crystalline ceramic phase can be balanced with the positive 
CTE of the glassy phase.
• At a certain point (~70% crystalline) glass‐ceramic has a net 
CTE near zero. 
• Glass‐ceramics exhibits excellent mechanical properties & 
can sustain repeated & quick temperature changes up to 
1000 °C
Lithium as basis for ongoing Lithium demand in Glass
Glass as a basis for 
future lithium 
consumption
Traditional use      
Glass (& ceramics) 
estimated usage ~46kt. 
Spodumene
& LiCO3
Existing lithium supply & new sources of supply vs demand 2012‐2020e
Corning’s proprietary fusion manufacturing process
• This process is at the core of their leadership in glass 
technology & the cover glass industry.
• This extraordinarily precise, highly automated draw 
process produces a thin sheet cover glass with pristine 
surface quality, outstanding optical clarity & inherent 
dimensional stability – qualities essential for cover glass 
for consumer applications.
• The process begins when raw materials are blended into a 
glass composition, which is melted & conditioned. 
• The molten glass is fed into a trough called an “isopipe,” 
overfilling until the glass flows evenly over both sides.
• It then fuses, at the bottom, where it is drawn down to 
form a continuous sheet of flat glass that is so thin it is 
measured in microns. 
• The glass is untouched by human hands or anything else 
that will introduce flaws into the surface.
Fusion process – designed by Corning 
• This same fusion process is at the heart of Corning’s industry‐
leading LCD glass. 
• The composition of Corning® Gorilla® Glass enables a deep layer 
of chemical strengthening through an ion‐exchange process 
where individual glass parts are cut from the “mother sheet” & 
undergo an ion‐exchange process.
Indium tin oxide  (ITO)
• ITO is a ternary composition of indium, tin & 
oxygen in varying proportions. 
• Depending on the oxygen content, it can either 
be described as a ceramic or alloy.
• Indium tin oxide is typically encountered as an 
oxygen saturated composition with a formulation 
of 74% In, 18% O2, and 8% Sn by weight. 
• It is transparent & colourless in thin layers while 
in bulk form it is yellowish to grey. In the infrared 
region of the spectrum it acts as a metal‐like 
mirror.
• Indium Tin Oxide(ITO) Nanopowder ITO 
90:10 20‐30nm  price guide ~$900‐1,100 per kg
Source: Photonics.com
Application of nanomaterial to glass surface
Coating line
Mirror coating machine                         Magnetron sputtering deposition technology 
Source: 
Nanoparticles
Corning Glass ‐ a world leader in glass technology  
• Silica sand ~60‐80%
• Boric acid ~5‐20%
• Fluxes Soda ash, potash, 
lithium carbonate. ~5%
• Stabilizers ~2%
• Other Fining, colouring, 
oxidising 
Know‐how 100%
Various industrial minerals used to manufacture this amazing glassware
Glass for Automotive sector
Source: IHS
Types of technology for glass screens include: In‐cell TFT, On‐cell 
TFT, On‐cell AMOLED.
Industry is centred in China/Korea/Japan/Taiwan
Smart Auto Glass
Swapping traditional soda‐lime 
glass & laminates for today’s 
lighter‐weight glass alternatives in 
windshields, side windows, & 
sunroofs can trim up to 20 
kilograms from the overall weight 
of an average vehicle.
Also self‐tinting, self cleaning etc
Source: Corning
Corning – a leader in glassware
• Corning, Incorporated, with 
headquarters in Corning, NY has 
a long history of science‐based 
innovations in glassware & ceramics. 
• Although many collectors associate 
Corning Glass with consumer product 
brands, such as PYREX, Corningware
and Corelle, the company’s core focus 
has always been on scientific and 
industrial applications.
http://pyrexpassion.com/research.html
Corning Inc.
Apple iPhone 8 ‐ will glass 
replace aluminium case? • KGI analyst Ming‐Chi Kuo, predicts 
that the iPhone 8 will replace its 
aluminum chassis with an all‐glass 
enclosure.
• Flexibility ‐ Innovations & 
advancements in manufacturing glass 
that is thinner & stronger than ever 
would easily allow Apple to develop a 
new curved iPhone that has strong 
glass bent around all the right angles.
Spodumene mine in Western Australia
Hard rock lithium ore
Glass as substrate for solar panel
Next generation photovoltaic panels based on hybrid & 
dye solar cell technologies.
The “lotus effect” The lotus effect refers to self‐
cleaning properties that are a result 
of very high water repellence 
(superhydrophobicity), as exhibited 
by the leaves of the lotus flower 
(Nelumbo).
Pilkington Activ™ Blue Self‐Cleaning Glass
Pilkington Activ™ Blue is an attractive blue glass that 
combines dual‐action, self‐cleaning properties with 
medium solar control performance helping to create a 
cooler internal environment which can be used all year 
round.
The coating has revolutionary photo‐catalytic and 
hydrophilic properties, and works in two stages:
Stage 1 ‐ The coating reacts with natural daylight to break 
down and loosen organic dirt.
Stage 2 ‐ When it rains, instead of forming droplets, the 
water spreads evenly over the surface of the glass, helping 
to wash away any dirt and reduce streaking.
In a dual‐action process organic dirt is broken down by 
nano TiO2 particles applied at time of glass manufacture.
Source: Company literature
Major Markets for Glass‐making Silica sand ‐ Asia
Key S.E.Asian Sources of Silica Sand for Glass
Comments:
• Vietnam volumes growing 
at expense of traditional 
Australian sources
• Governments encouraging 
adding value e.g. making 
glass or sodium silicate 
/specialty silicas such as 
precipitated silica, colloidal 
silica & silica gel.
New facility 
Silica sand for Glass making – Asia Pacific
Regional Glass Sectors by % in tonnes
Glass shaped by additive manufacturing (3D Printing)
• Fused‐deposition modelling works by 
extruding a filament of semi‐molten material 
(in desktop applications this is usually a 
thermoplastic) through a mobile nozzle in a 
pattern controlled by a computer. This builds 
up whatever object the software is 
programmed to create. Using glass instead of 
plastic requires higher temperatures, but the 
principle is the same. 
• Dr Neri Oxman and Mr Peter Houk have already used their device 
to print a range of objects, including optical prisms & decorative 
vessels. (Massachusetts Institute of Technology)Source: The Economist
How self‐cleaning glass works
• Self‐cleaning windows were one of the first 
architectural applications of nanotechnology. 
• The special hydrophilic coating on Pilkington Activ 
self‐cleaning glass causes water to sheet off the 
surface, leaving a clean exterior with minimal 
spotting or streaking.
• Reduces the need for cleaning exterior glazing 
through a dual‐action coating.
• It uses daylight and rain to break down and wash 
away organic dirt.
Source: www.pilkington.com
Photo‐catalytic & hydrophilic coating 
that works in two in two stages
The unique dual‐action self‐cleaning coating is 
located on the external glass pane.
It has got photo‐catalytic and hydrophilic properties, 
and works in two stages:
(Stage 1) The coating reacts with natural daylight to 
break down and loosen organic dirt 
(Stage 2) When it rains, instead of forming droplets, 
the water spreads evenly over the surface of the 
glass, forming a thin film and helping to wash away 
any dirt and reduce streaks.
Corning – “A day (in the future) made of glass” (1) 
http://itechfuture.com/future‐touch‐screen‐technology/ 
• Photovoltaic glass – high efficiency optically durable
• LCD Television glass – large format, ultra thin frameless design
• Architectural display glass – pristine surface, electronics enabling, touch 
sensitive
• Architectural surface glass – tough, thermally durable, display enabling
• Appliance veneer glass – seamless design, electronics enabling, scratch 
& resistant
• Handheld display glass‐ thin& lightweight, damage resistant, touch 
sensitive
• Automotive display glass‐ streamlined design, advanced functionality
• Automotive design glass‐ photosensitive, durable
Corning – “A day (in the future) made of glass” (2)            
Video to catch our imagination  www.youtube.com/watch?v=X‐GXO_urMow
• Large format display glass‐weather resistant, electro‐optics enabling, optically 
adaptable
• All weather surface glass‐display enabling, touch sensitive
• Wall format display glass – large scale, seamless design, touch sensitive 
• Work surface display glass – durable, versatile, application enabling
• Electronics ready glass – pristine surface, exceptional optical clarity, interactive
• Large pane display glass – high visual impact, multifunctional, interactive
• Flexible display glass‐ultra thin, electronically enabling
• 3D TV Glass‐vivid & immersive, thin & lightweight, frameless design
Coatings
• Insulating nanoparticles can be applied to substrates using chemical vapour 
deposition, dip, meniscus, spray, & plasma coating to create a layer bound to the 
base material.
• Nanoparticle coatings can be applied by these methods to achieve a wide variety 
of performance characteristics, including:
• Self‐cleaning
• Depolluting
• Scratch‐resistant
• Anti‐icing &anti‐fogging
• Antimicrobial
• UV protection
• Corrosion‐resistant
• Waterproofing
Self‐cleaning coatings
• Self‐cleaning surfaces have become a reality thanks to 
photocatalytic coatings containing titanium dioxide (TiO2) 
nanoparticles. 
• These nanoparticles initiate photo‐catalysis, a process by which dirt is broken 
down by exposure to the sun’s ultraviolet rays & washed away by rain.
• Volatile organic compounds are oxidized into CO2 & water. 
• Self‐cleaning surfaces are made by:
• applying a thin nano‐coating film by vapour deposition
• painting  on a nano‐coating 
• integrating nanoparticles into the surface layer of a substrate material
Solar control glass products
• The highest performing, off‐line coated, solar control and low‐emissivity 
products within the Pilkington Suncool™ range  
• On‐line environmental control glasses that combine good performance 
solar control with low‐emissivity such as Pilkington Eclipse Advantage™ and 
Pilkington Solar‐E™ 
• Medium performance reflective glasses such as Pilkington Eclipse™ Gold, 
Pilkington SunShade™ Silver, 
• Pilkington Reflite™ and High Performance Tints such as Pilkington Arctic 
Blue™ 
• Low‐performance, body‐tinted glass in the Pilkington Optifloat™ Tint range 
• Solar control glass combined with the revolutionary self‐cleaning Pilkington 
Activ™.
Self‐cleaning glass
The Pilkington Activ brand by 
Pilkington is claimed by the 
company to be the first self‐
cleaning glass. 
Pilkington Activ™ consists of a 
20–30 nm layer of 
nanocrystalline anatase 
titanium dioxide deposited by 
an atmospheric pressure 
chemical vapour deposition 
technique onto soda‐lime 
silicate float glass
Major Flat Glass Manufacturers
• Nippon Sheet Glass Co., Ltd. (Nihon Ita‐Garasu Kabushiki‐gaisha) is a 
Japanese glass manufacturing company. In 2006 it purchased 
Pilkington of the United Kingdom.
• This makes NSG/Pilkington one of the four largest glass companies in 
the world alongside another Japanese company
• Asahi Glass,
• Saint‐Gobain, and 
• Guardian Industries.
Pilkington Activ™ nano TiO2 coating
• The Pilkington Activ™ coating, located on surface #1 of the glass, works in two stages. 
• Firstly, it reacts with natural daylight to break down and loosen organic dirt. 
• Secondly, when it rains, instead of forming droplets, the water spreads evenly over the 
surface of the glass, forming a thin film and helping to wash any dirt away, preventing the 
formation of drying spots and streaks, and helping the glass to dry very quickly. 
• In installations where condensation is a problem, it reduces its visibility and helps it to 
evaporate more quickly.
• The Pilkington Activ™ coating works also on cloudy days and during the night. 
• During dry spells the glass can be cleaned by simply hosing it down with clean water.
Nano coating added here 
Chemical Vapour Deposition (CVD)
CVD is an atmosphere controlled 
process conducted at elevated 
temperatures (~1,051° C) in a CVD
reactor. 
During this process, thin‐film 
coatings are formed as the result of 
reactions between various gaseous 
phases & the heated surface of 
glass substrate within the CVD
reactor.
Chemistry for  CVD Coatings
CVD  Process & equipment –coater location 
Projections of Light‐Duty Vehicle Fleet Growth                   
affecting demand for auto glass
Source: International Energy Agency (IEA) 
Recycling fundamentals
• Recycling Fundamentals
• If done right, there is no doubt that recycling saves energy & raw 
materials, & reduces pollution. 
• As well as trying to recycle more, it is also important to try to recycle 
better.
• As technologies and materials evolve, there is room for improvement 
& cause for optimism.
• In the end, “waste is really a design flaw.”
Self cleaning glass using TiO2
Embedded nanoparticles for smart glass devices
• Australian researchers at the University of Adelaide 
have developed a method for embedding light‐
emitting nanoparticles into glass without losing any of 
their unique properties – a major step towards ‘smart 
glass’ applications such as 3D display screens or 
remote radiation sensors.
• This new “hybrid glass” successfully combines the 
properties of these special luminescent (or light‐
emitting) nanoparticles  with the well‐known aspects of 
glass, such as transparency and the ability to be 
processed into various shapes including very fine optical 
fibres.
• The research, in collaboration with Macquarie 
University & University of Melbourne.
Source: Journal Advanced Optical Materials
Sawa Mines 
Our mines has rich proved mineable mineral reserves and located in close proximity to 
our sand washing plant in Sawa, District Chittorgarh , Rajasthan in the North‐West of 
India. This Mine has massive deposit of clean silica sand & kaolin
R&D for the future of glass
• Special coatings for buildings:  Smart mirrors & highly insulating glass 
windows for photosensitive, switchable or electrochromic glazing
• Anti‐reflection properties & technologies for clean energy generation
• Strength: If glass of any type were available at 50 times its current strength, 
new products & opportunities could emerge in the market place, like ultra 
thin & light container glass & lighter flat glass & fibreglass for composites. 
Some applications already make glass stronger by 2 to 6 times
• Functional integration in glass that can then become an ideal substrate for 
OLED lighting, touch screens, audio‐visual displays, etc.
• Bendable glass, scratch resistance, audio glass, thinner glass
• Improved recycling of all glass types for energy savings & sustainability
Artificial photosynthesis – Pathway from sunlight to fuels 
Source: Royal society of chemistry
Thank you
www.stratum.com.au

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