Modern glass technologies has brought an abundance of new applications to our lives. The change to thin TV and computer screens and the incredibly tough glass on our smartphones etc are just two examples. This presentation shows the manufacturing technologies which have reshaped the way glass can be produced to create electricity from transparent cells, to allow for adjustable light entry as well as privacy in hospitals etc. The presentation also mentions the enormous advantages of recycling glass in a world where sustainability has become an issue. What are the new applications for glass and what will be their future importance for the industrial minerals market?
Presented by Murray Lines of Stratum Resources at June 2016 Prague Industrial Minerals International Congress and Exhibition
3. Agenda
Glass intro ‐ a remarkable material
Glass recycling – important for sustainability
New glass technologies /applications by leading
companies
Industrial minerals involved
Nano‐materials use in glass
6. Glass is a remarkable material
• Transparency UV‐lamps, light protecting packaging
• Chemical resistance packaging material for pharmaceuticals, labs
• Temperature resistance halogen lamps, laboratory, flash lamps
• Electrically insulating X‐ray tubes
• Thermal expansion halogen lamps, solar receivers, flash lamps
• Impermeability display industry, solar receiver, X‐ray tubes, halogen lamps
• Refractive index fibre optics, light guides for endoscopy
• Dielectric strength diodes
• Mechanical properties various such as sprinklers in hotel room etc
Glass properties Technical applications include
Source: Schott literature
9. Soda‐lime‐silicate glass used in buildings
Composition:
• ‐ silica, the raw material, in the form of sand (70 ‐ 72 %)
‐ soda, the flux, as carbonate and sulphate (~ 14 %)
‐ lime, a stabiliser, in the form of limestone (~ 10 %)
‐ various other oxides such as alumina & magnesia, to improve the physical properties of
the glass, including its resistance to atmospheric pollutants
‐ for body‐tinted glasses, metal oxides can also be incorporated
• e.g. SGG PARSOL is a body‐tinted glass, manufactured in the same way as clear float glass
but with additions of special metal oxides.
• SGG PARSOL is intended for universal applications where an attractive appearance or basic
solar control properties are required:
‐ Interior applications for decoration, fittings and furniture.
‐ External applications in single or double‐glazing, for facades & overhead glazing
• ADVANTAGES
• SGG PARSOL provides additional solar control to reduce the burden on air‐conditioning
through the warmer months & also provides different colours
17. Recycling of Glass – beneficial & profitable
• The use of cullet reduces energy and raw
material needs, CO2 emissions and the use of
landfill sites.
• Consumers often come in contact with
recycled products without knowing it.
• Besides new glass containers, recycled glass is
also used for products such as glass wool &
foamed glass.
• Glass wool is used for wall & ceiling insulation
& foamed glass aggregate is mostly used in
construction and to protect infrastructure &
buildings against frost heave in cold climates.
22. Glass bottles& float glass offcuts
Glassflour
Grinding & classifying
Product
Foam Glass
Raw material
Cleaning &
drying to <8%
moisture
Heating & air
injection to
produce bubbles
23. Alpine Classifier Ventoplex
• energy efficient classifier
• with integrated ventilator
• fineness d97 in the range 30 µm to 800
µm adjustable
• model range: throughput
from 1 t/h to 30 t/h
Concepts and Machine Designs:
Foam Glass production needs top cut limiting of the glass flour.
The ball mill runs in a loop with an air swept classifier….
fine coarse
feeding
31. HPA (High purity alumina/sapphire) Market Demand
• The global HPA market was estimated at 19 ktpa in 2014 & is
expected to increase to 48ktpa by 2018
• The global HPA market is used to produce: Light Emitting Diode
(LED) products (55%), semiconductors (22%), phosphor plasma
display panels (16%) & industrial/chemical/medical applications
(7%).
• HPA is increasing demand in electronic devices.
• HPA’s superior qualities are pertinent features for a range of
existing & new applications, e.g. sapphire glass for smartphones.
• The price for the 4N HPA product is a high‐value product which
ranges from US +$20/kg.
Source: Altech Chemicals
36. Technical glass tubing ‐ Biofuel production
Schott glass for algae cultivation ‐
• Closed looped systems made of Duran® glass.
• A photo‐bioreactor uses a light source to cultivate phototrophic microorganisms for
biofuel production.
• A photo‐bioreactor allows much higher growth rates & purity levels
SCHOTT is a leading international technology group in the areas of specialty glass & glass‐ceramics.
41. Pyrex ™ Glass – addition of boric acid & lithium carbonate
Pyrex has a droplet in matrix phase structure. The silicon
dioxide creates the basic matrix. The borate material
creates the droplets within that structure.
The borate former can come from a material like sodium
tetraborate.
Prior to manufacture, this compound is chemically
reduced with sulphuric acid to create boric acid.
When boric acid is mixed with silicon dioxide and heated,
it oxidises into boric oxide.
Boric oxide is responsible for the unique Pyrex
molecular structure & makes up anywhere ~ 5‐20% of
Pyrex glass.
Secondary ingredients used in glass production include
fluxes, stabilizers, and colourants.
Fluxes are included in glass mixtures to reduce the
melting temperature of borosilicate glass.
Fluxes used in manufacture include soda ash, potash, &
lithium carbonate.
They make up about 5% of a Pyrex glass composition.
52. Corning – a leader in glassware
• Corning, Incorporated, with
headquarters in Corning, NY has
a long history of science‐based
innovations in glassware & ceramics.
• Although many collectors associate
Corning Glass with consumer product
brands, such as PYREX, Corningware
and Corelle, the company’s core focus
has always been on scientific and
industrial applications.
http://pyrexpassion.com/research.html
Corning Inc.
53. Apple iPhone 8 ‐ will glass
replace aluminium case? • KGI analyst Ming‐Chi Kuo, predicts
that the iPhone 8 will replace its
aluminum chassis with an all‐glass
enclosure.
• Flexibility ‐ Innovations &
advancements in manufacturing glass
that is thinner & stronger than ever
would easily allow Apple to develop a
new curved iPhone that has strong
glass bent around all the right angles.