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September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 1
Commercializing a next-generation source of green nuclear energy
Contact: 1-312-861-0115
lewisglarsen@gmail.com
http://www.slideshare.net/lewisglarsen/presentations
LENRs transmute plant Carbon
Carbon-rich Lignin comprises 33% of total plant biomass
Lignin is composed of aromatic molecules that can be extracted
Convert aromatics to LENR fuels: >5,000x energy density of gasoline
Ultralow energy neutron reactions (LENRs) = renewable nuclear energy
Release
CO2-free
thermal
energy
Lattice Energy LLC
Aromatic plant biomass can be basis for revolutionary green bionuclear fuels
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 2
Evolution of nuclear technology
Commercializing ultralow energy neutron reactions (LENRs)
for stationary, mobile, and portable power generation applications
Breakthrough in nuclear technology: no dangerous radiation or wastes
• LENR fuels get transmuted by absorbing neutrons which releases enormous heat
• Sustainable CO2-free transmutation of Carbon could replace combustion processes
Widom-Larsen theory enables LENR power generation devices
Widom-Larsen
Theory of LENRs
Few-body
Strong interaction
Many-body collective
Weak interaction
Nuclear weapons
Fission and fusion power plants
No weapons
Safe: even portable power plants
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 3
Image credit: co-author Domenico Pacifici
From: “Nanoscale plasmonic interferometers for
multispectral, high-throughput biochemical sensing”
J. Feng et al., Nano Letters pp. 602 - 609 (2012)
Revolutionary new type of safe nuclear energy technology
Laura 13
September 14, 2015 Lattice Energy LLC, Copyright 2015 All Rights Reserved 3
Unique advantages of ultralow energy neutron reactions (LENRs)
Widom-Larsen theory rigorously explains all of these unique attributes
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 4
LENRs are green: no energetic radiation or radwastes
Lack of hard radiation obviates need for shielding and containment
Major opportunity to develop safe, battery-like portable LENR power sources
Revolution in green
nuclear technology
Fission reactors need 1 foot of steel and 3 feet of concrete
to protect humans from hard radiation and wastes emitted
by reactor; makes systems intrinsically large and heavy
LENRs enable devices something like
this: small, portable battery-like power
sources that are safe and disposable
Much larger LENR devices based on dusty
plasma embodiments can potentially scale-up
to megawatts; akin to today’s power plants
Fission and fusion processes both emit deadly MeV-energy neutron and gamma radiation
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 5
Fossil fuels could be converted into green LENR fuels
Breakthroughs in physics and nanotechnology make this possible
Bitumen, heavy oil, and coal may be much more valuable as CO2-free LENR fuels
Canadian natural bitumen Heavy viscous oils found in many fields Various grades of coal
These fossil hydrocarbons contain aromatic ring molecules on which LENRs can be triggered
In 2009 Larsen discovered that aromatic molecules can potentially
be extracted and processed to be converted into green LENR fuels
in which there would be no hard radiation emissions, no production
of any long-lived radioactive wastes or emission of gaseous CO2 into
the atmosphere; would instead release > 5,000 times more thermal
energy versus combustion of Carbon-based molecules with Oxygen
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 6
Grand challenge: turn biomass into renewable nuclear fuels
Biomass contains substantial % of aromatic polymer called Lignin
Lignin can be chemically broken-up into smaller aromatic molecules
Green LENRs can be triggered on such molecules: become bionuclear fuels
 Two of three major components in biomass - cellulose and hemicellulose - are
polymerized sugars that can readily be chemically fermented to create
renewable biofuels (this is now occurring commercially); the third, Lignin, is
much more resistant to chemical degradation into smaller aromatic molecules
 Until recently, Lignin was more-or-less ignored by industry and academic
biotech researchers, being regarded more as just a waste product to be burned
 Importantly, Lignin is only known major natural source of renewable aromatics
 Out in Nature, Lignins are mainly broken-down by various fungi and bacteria
 Biotechnologists are now beginning to focus on improving various chemical and
enzymatic processes that reduce Lignin to smaller molecules, e.g. aromatics
 In 2014, Larsen became aware of improvements in Lignin digestion methods
 Advances in chemical processing of Lignin to yield basic aromatic molecules
opens-up future possibility of creating revolutionary CO2-free LENR fuels with
5,000x greater energy density than gasoline from renewable biomass aromatics
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 7
Lattice Energy LLC
Commercializing a next-generation source of green nuclear energy
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 7
If mankind continues to
use today’s combustion
we will run-out of fossil
fuels in < 200 years.
If we instead develop and deploy LENR
power sources using green nuclear fuels
created from aromatic Carbon in fossil
fuels and biomass, we move man’s day of
reckoning on energy out millions of years.
?
How can we ever
bridge this gap
with truly green
forms of energy?
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 8
Oil, coal, and lignin could be processed to produce CO2-free LENR fuels
Carbon atoms found on aromatic rings good fuel for radiation-free transmutation
Neutrons + LENR fuel elements heavier elements + decay products +
+
Catalytic neutron
‘match’
Neutrons are readily absorbed by
LENR fuels such as Nickel, Titanium,
Lithium, or aromatic Carbon atoms
Direct conversion of neutron capture
and decay-related gammas to IR and
beta/alpha particles create heat
n0
Carbon
Radiation-free LENR transmutation
Process does not emit any deadly radiation or produce troublesome radwastes
Fossil Carbon can be transmuted rather than combusted
capture on LENR fuel elements produces heat
BTUs
Absorbed
by fuel
elements
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 9
CH
H
H H
H
H
Aromatic ring:
6 Carbon
atoms
CC
C C
C
6 Carbon atoms arranged in hexagonal ring bonded to 6 Hydrogen atoms
Fossil Carbon can be transmuted rather than combusted
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 9
Benzene
molecule
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 10
Convert ring Hydrogen atoms (protons) into safe neutrons
Neutrons are captured by ring Carbon atoms that are then transmuted
In this example a Carbon atom is transmuted into a Nitrogen with LENR process
LENR neutron
capture catalyzed
Process does not emit any deadly radiation or produce troublesome radwastes
Aromatic Carbon molecules from biomass become revolutionary bionuclear fuels
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 11
Lignin molecules comprise ~40% of cord of split hardwood
Who would have dreamed it might be converted into a bionuclear fuel?
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 12
Biomass is composed of ~33% Lignin: an aromatic polymer
Figure source: T. Wang et al., Green Chemistry 16 pp. 548 - 572 (2014)
http://pubs.rsc.org/en/content/articlelanding/2013/gc/c3gc41365a#!divMetrics
Biomass has three major components: Cellulose, Hemicellulose, Lignin
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 13
Lignins are large complex molecules with structural variants
Can comprise up to ~40% of biomass in woody deciduous trees
Key function in plants: provide sturdy structural support material
Source: http://study.com/academy/lesson/lignin-definition-properties-function.html
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 14
Lignin: complex molecule and major constituent of biomass
Technically speaking it is a natural, renewable aromatic polymer
Must digest it into smaller aromatic molecules to make LENR fuels
http://www.igb.fraunhofer.de/en/competences/molecular-biotechnology/industrial-biotechnology/aromatic-lignin-monomers.html
Copyright: Fraunhofer-Gesellschaft
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 15
Chemists create improved Lignin digestion techniques
New papers reporting advances in methods now occurring more often
Most methods would probably be useful in development of renewable LENR fuels
Selected examples of relevant information sources:
http://www.warf.org/documents/ipstatus/P130104US01.PDF
Patent # US 8,969,534 B2 Issued March 3, 2015 Assignee: W.A.R.F.
“Simple aerobic alcohol oxidation method for conversion of Lignin into simple aromatic
compounds”
Abstract: “Described is a method to oxidize lignin or lignin sub-units. The method
includes oxidation of secondary benzylic alcohol in the lignin or lignin sub-unit to a
corresponding ketone in the presence of unprotected primary aliphatic alcohol in the
lignin or lignin sub-unit. The optimal catalyst system consists of HNO3 in combination
with another Brønsted acid, in the absence of a metal-containing catalyst, thereby
yielding a selectively oxidized lignin or lignin sub-unit. The method may be carried out in
the presence or absence of additional reagents including TEMPO or TEMPO derivatives
“Making the most from Carbon in plants”
Pacific Northwest National Laboratory Released: September 9, 2015
Abstract: “Researchers are looking for more effective ways to get at all the carbon in
biomass to create more energy and biochemicals. However, a lot of the carbon is in lignin -
support tissues in plants, which makes up about a third of the biomass. International
teams of scientists are working together to better understand how lignin can be efficiently
deconstructed to release its carbon for a more renewable and sustainable energy future.”
http://www.sciencedaily.com/releases/2015/09/150909091224.htm
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 16
Many moieties contain or are convertible into aromatics
Variety of simple and
complex aromatic
molecules
Examples:
Green
CO2-free
LENR
fuels
5,000x
greater
energy
density
Process into
Heavy oils
and natural
bitumen
Coal
Contain aromatic
molecules
Examples:
CH4 natural gas
Lignin and
other plant
biomass
Extract
Extract
Digest
Mo catalyst
Chemical
process
Chemical
processing
plus
nanotech
Benzene
Phenanthrene
CO2 C nanofibers
Enormous gain in energy
density makes processing
conversions $$$ economic
Bottom line: just about any
Carbon-based moiety can
be converted into aromatic
ring-structure molecules
using a chemical process
Processing
LENR fuels can be created from many different natural Carbon sources
Nanoparticulate fuelsBase feedstock Aromatic molecules
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 17
Nanoparticulate LENR fuels could be used in many systems
Huge energy density advantages vs. fossil fuels & chemical batteries
Bionuclear LENR fuels energy densities could be 5,000x larger vs. gasoline
LENR fuels would be inert and benign and could use existing package delivery systems
for resupply; typical gasoline or diesel tanker truck carries ~5,000 - 12,000 US Gallons of
liquid fuel; LENR fuels producing same # of BTUs could be shipped in 1 - 2 FedEx boxes
Consequence: an automobile powered by LENRs could travel around the entire
world on a quantity of nanoparticulate fuel that fits into just a single FedEx box
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 18
Key to commercializing game-
changing bionuclear fuels from
Lignin is ability to reliably trigger
production of LENR neutrons on
Carbonaceous aromatic molecules
emplaced on purpose-built
engineered nanoparticles
composed of appropriate materials.
Lattice Energy LLC
Commercializing a next-generation source of green nuclear energy
September 14, 2015 Lattice Energy LLC, Copyright 2015 All Rights Reserved 18
Image credit: NASA
PAH molecules in space
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 19
Lattice’s commercialization strategy akin to computer chips
Scale-up LENR system power outputs and integrate energy conversion
 LENRs can presently reach temperatures of 4,000 - 6,000o K and boil refractory metals
in limited numbers of microscopic LENR-active hot spot sites on laboratory device
surfaces. Lattice plans to use its unique proprietary knowledge of LENR engineering
physics and key operating parameters (e.g., achieving and maintaining very high local
surface electric fields) to first get heat production working well microscopically. That is:
reproducibly trigger LENRs on specific, purpose-designed nanoparticulate structures
with dimensions ranging from nanometers to microns that are fabricated using existing,
off-the-shelf nanotech processes and then deliberately emplaced at what will become
LENR-active sites located on Hydrogen-loaded substrate or nanoparticle surfaces
 In principle, output of such LENR heat sources could be readily scaled-up: either by
fabricating larger area-densities of affixed nanostructures that facilitate formation of
LENR-active hot spots on device surfaces, or by injecting larger quantities of specially
designed fuel nanoparticles into volumetrically larger reaction chambers containing
turbulent dusty plasmas, with or without spatially organized magnetic fields present
 A variety of off-the-shelf energy conversion subsystems could potentially be integrated
with commercial versions of LENR-based heat sources. These include thermoelectric;
thermophotovoltaic cells; steam engines; Rankine cycle steam turbines; Brayton cycle
gas turbines, boilers, etc. Other speculative possibilities involve new types of direct
energy conversion technologies that are still under development, e.g. harvesting of β -
Use existing nanotech and power conversion to cut development time/risks
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 20
 Over time, plan to ride down manufacturing experience cost curve; similar to
build-cost reduction and market penetration strategies used by electronics
manufacturers; e.g., microprocessors, memory chips, PCs, and smartphones
 As product manufacturing experience accumulates and internal build costs are
progressively reduced, leverage enormous energy density/longevity advantages
of LENRs (> 5,000x larger than any chemical); price LENR-based systems to
drastically undercut price/performance provided by competing thermal sources
and chemically-based power generation systems --- this strategy can be applied
to portable, distributed stationary, mobile, and central station power markets
 Small-scale LENR systems might seem to be light years away from being able to
compete with huge 500 - 1,500 MW coal-fired and Uranium-fission power plant
behemoths. However, please recall history of personal computers versus large
mainframes. When PCs were first introduced 35 years ago, mainframe computer
manufacturers regarded them as just toys, information processing jokes of no
consequence. Less than 10 years later, mainframe companies weren’t laughing
any more. Today, except for just a handful of survivors like IBM, mainframe and
minicomputer dinosaurs have disappeared, replaced by microprocessor arrays
Lattice’s market penetration strategy akin to computer chips
Maximize unit volumes and ride experience curve to attack markets
LENR technology enables opportunity to create a Moore’s Law for energy
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 21
LENRs could enable vast increases in product performance
Intrinsic energy density of LENRs at least 5,000x > chemical processes
Commercial LENR systems could easily achieve 10x - 100x chemical systems
Product Name
Present capabilities with today’s
power sources
Range (endurance)
Vastly enhanced capabilities with
future LENR-based power sources
10x chemical 100x chemical
GreenWing e430 180 miles (~3 hours @ 60 mph) 1,800 (30) 18,000 (300)
Airbus E-Fan 2.0 99 miles (1 hour @ 99 mph) 990 (10) 9,900 (100)
Predator MQ-1 1,800 miles (24 hours @ 75 mph) 18,000 (240) 180,000 (2,400)
Super Heron
est. ~4,000 miles (45 hours @ 89
mph?)
40,000 (450+) 400,000 (4,500)
Springtail 184 miles (2.2+ hours @ 94 mph ) 1,840 (200+) 18,400 (2,000+)
Crazyflie Speed not measured (3 - 10 minutes) ? (30 - 100 min.) ? (maybe 5 - 17 hrs.)
InstantEye est. ~8 miles (18 - 20 min @ 25 mph) est. 80 (3.2 hrs.) 800 (32 hrs.)
Tesla Model S car ~300 miles (4 - 5 hours @ 70 mph) 3,000 (40 - 50) 30,000 (400 - 500)
Shkval torpedo
6.8 - 9.3 miles (1.8 - 2.4 min @230
mph)
68 - 93 (18 - 24
min)
680 - 930 (3 - 4 hrs)
Exoskeletons and
autonomous robots
Require tether cables connected to
some type of external power source
Duration of autonomous activity might be
extended up to weeks or even months
Variousaircraft
Note: roughly 730 hours in a month and 8,760 hours in a year; average U.S. car’s IC engine runs for ~5,000 hrs over lifetime
Enhancements in product range and endurance if LENR technology were commercialized
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 22
LENRs could end combustion of coal: CH4 + 2 O2 → CO2 + 2 H2O + heat
Opportunity: retrofit old coal plants with CgNgO boilers
LENRs would change boiler, coal
pulverizer, and environmental
subsystems (for zero NOx or SO2)
Retrofit strategy conserves capital; LENR plants would emit Oxygen O2 like trees
New LENR-powered boilers could be engineered to seamlessly replace original coal-fired boilers
Retrofit with LENR boiler
O2
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 23
Commercializing a next-generation source of green CO2-free nuclear energy
https://www.youtube.com/watch?v=GEPhLqwKo6g
Lattice Energy LLC
Commercializing a next-generation source of green nuclear energy
September 14, 2015 Logo copyright, Apple Inc. 23
“Think different" was an advertising slogan for Apple Inc. (formerly Apple Computer Inc.) in 1997 created by
the Los Angeles office of advertising agency TBWAChiatDay (unreleased version narrated by Steve Jobs himself)
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 24
Widom-Larsen theory of ultralow energy neutron reactions
Three key publications that start in March 2006 referenced below
Many-body collective quantum effects enable electroweak catalysis
“Ultra low momentum neutron catalyzed nuclear reactions on metallic
hydride surfaces”
A. Widom and L. Larsen
European Physical Journal C - Particles and Fields 46 pp. 107 - 112 (2006)
http://www.slideshare.net/lewisglarsen/widom-and-larsen-ulm-neutron-
catalyzed-lenrs-on-metallic-hydride-surfacesepjc-march-2006
“A primer for electro-weak induced low energy nuclear reactions”
Y. Srivastava, A. Widom, and L. Larsen
Pramana - Journal of Physics 75 pp. 617 - 637 (2010)
http://www.ias.ac.in/pramana/v75/p617/fulltext.pdf
“Theoretical Standard Model rates of proton to neutron conversions near
metallic hydride surfaces”
A. Widom and L. Larsen
Cornell physics preprint arXiv:nucl-th/0608059v2 12 pages (2007)
http://arxiv.org/pdf/nucl-th/0608059v2.pdf
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 25
Electroweak reaction in Widom-Larsen theory is simple
Protons or deuterons react directly with electrons to make neutrons
Need input energy source such as electricity to drive LENR neutron production
EnergyE-field + e-
sp g e-*sp + p+ g n0 + νe
Collective many-body quantum effects:
many electrons each transfer little bits
of energy to a much smaller number of
electrons also bathed in the very same
extremely high local electric field
Quantum electrodynamics (QED): smaller number of
electrons that absorb energy directly from local electric
field will increase their effective masses (m = E/c2)
above key thresholds β0 where they can react directly
with a proton (or deuteron) neutron and neutrino
νe neutrinos: ghostly unreactive particles that fly-off into space; n0 neutrons capture on nearby atoms
Neutrons + fuel elements heavier elements + decay products
Neutrons induce nuclear transmutations that release enormous amounts of clean, CO2-free heat
Input energy creates electric fields > 2.5 x1011 V/m Heavy-mass e-* electrons react directly with protons
electrons + protons (Hydrogen) g neutrons + neutrinos (benign particles, fly into space)
Radiation-free LENR transmutation
Require source(s) of input energy Many-body collective electroweak neutron production
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 26
LENR transmutations move left-to-right across rows of Table
C N O
Transmutation of Carbon to O2 releases 5,000x > heat than combustion
September 14, 2015 Lattice Energy LLC, Copyright 2015 All Rights Reserved 26
Any element in Periodic Table can be LENR fuel - some better than others
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 27
LENR C g N gO releases 5 million x more heat vs. burning
Carbon transmuted to O2 instead of being combusted with O2 g CO2
6C-12
Stable 98.7%
6C-13
Stable 1.3%
6C-14
HL=5.7x103 y
7N-14
Stable 99.6%
0.2
6C-15
HL= 2.5 sec
7N-15
Stable 0.4%
6C-16
HL=747 msec
7N-16
HL=7.1 sec
8O-16
Stable 99.76%
8.0
10.4
6C-17
HL=193 msec
7N-17
HL=4.2 sec
8O-17
Stable 0.04%
13.2
8.7
6C-18
HL=92 msec
7N-18
HL=622 msec
8O-18
Stable 0.20%
11.8
13.9
6C-19
HL=46 msec
7N-19
HL=271 msec
8O-19
HL=26.5 sec
9F-19
~Stable 100%
16.6
12.5
5.0 8.2 1.2 4.3 0.8 4.2 0.6
10.8 2.5 2.85.9 5.3
4.1 8.0 4.0
2.9
2.2
6.6
7.6
2He-4 pool
Stable 99.99%
Bosonic sink
Increasing values of A
IncreasingvaluesofZ
7.5
7.5
Beta-delayed alpha
decays are denoted by
orange arrows with
decay energy in MeV:
3.3
2.3
7.7
7.5
[BR = 12.2 %]
[BR = 0.0025 %]
[BR = 0.001 %]
Note: not shown on LENR
network chart - for a variety of
sound physics reasons, beta-
delayed neutron emissions are
almost totally suppressed in
condensed matter LENRs
Nitrogen
Oxygen
Gamma emissions from neutron captures
and decays not shown on chart because
they are automatically converted directly
into benign infrared photons by heavy SP
electrons per the Widom-Larsen theory;
issued Lattice patent US# 7,893,414 B2
Totally stable isotopes are
indicated by green boxes;
some with extremely long
half-lives are labeled
~stable; natural abundances
denoted in %
Unstable isotopes are
indicated by purplish boxes;
when measured, half-lives
are shown as “HL = xx”
http://www.slideshare.net/lewisglarsen/us-
patent-7893414-b2
9.8
Carbon
Fluorine
LENR transmutation
network cannot get past
production of elemental
Oxygen (O2) unless ultra
low energy neutron
fluxes are made to be
> 1010 neutrons cm2/sec
Fluorine’s “valley of death”
H + F reaction disrupts sites
Legend:
ULM neutron captures
proceed from left to right; Q-
value of capture reaction in
MeV is on top of green
horizontal arrow:
Beta decays proceed from
top to bottom; denoted with
blue vertical arrow with Q-
value in MeV in blue to left:
4.8
Aromatic Carbon transmutation naturally stops at Oxygen - akin to plants
September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 28
Further in-depth reading for those who wish to learn more
Incredible opportunity to develop green renewable nuclear power
LENR fuels derived from biomass --- an inexhaustible energy source
“Index and User Guide to the Widom-Larsen theory and ultralow energy
neutron reactions (LENRs)” [133 slides]
http://www.slideshare.net/lewisglarsen/lattice-energy-llc-hyperlinked-index-to-
documents-re-widomlarsen-theory-and-lenrs-september-7-2015
http://www.slideshare.net/lewisglarsen/lattice-energy-llc-lenr-transmutation-of-carbon-
better-energy-strategy-than-obama-clean-power-plan-aug-3-2015
“LENR transmutation of Carbon is superior energy strategy - Slashes CO2
emissions for vehicles as well as electric power generation” [32 slides]
http://www.slideshare.net/lewisglarsen/lattice-energy-llc-compelling-economics-of-
transmutation-vs-combustion-of-carbonaceous-energy-sources-jan-14-2015
“Compelling economics of transmutation vs. combustion of
carbonaceous energy sources” [44 slides]
“Transmutation vs. combustion - Are LENRs a Chicxulub for fossil fuel
dinosaurs?” [49 slides]
http://www.slideshare.net/lewisglarsen/lattice-energy-llc-transmutation-vs-combustion-
are-lenrs-chicxulub-for-fossil-fuel-dinosaurs-oct-6-2014

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Lattice Energy LLC - Renewable lignin biomass aromatics convert into green radiation-free LENR fuels - Sept 14 2015

  • 1. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 1 Commercializing a next-generation source of green nuclear energy Contact: 1-312-861-0115 lewisglarsen@gmail.com http://www.slideshare.net/lewisglarsen/presentations LENRs transmute plant Carbon Carbon-rich Lignin comprises 33% of total plant biomass Lignin is composed of aromatic molecules that can be extracted Convert aromatics to LENR fuels: >5,000x energy density of gasoline Ultralow energy neutron reactions (LENRs) = renewable nuclear energy Release CO2-free thermal energy Lattice Energy LLC Aromatic plant biomass can be basis for revolutionary green bionuclear fuels
  • 2. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 2 Evolution of nuclear technology Commercializing ultralow energy neutron reactions (LENRs) for stationary, mobile, and portable power generation applications Breakthrough in nuclear technology: no dangerous radiation or wastes • LENR fuels get transmuted by absorbing neutrons which releases enormous heat • Sustainable CO2-free transmutation of Carbon could replace combustion processes Widom-Larsen theory enables LENR power generation devices Widom-Larsen Theory of LENRs Few-body Strong interaction Many-body collective Weak interaction Nuclear weapons Fission and fusion power plants No weapons Safe: even portable power plants
  • 3. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 3 Image credit: co-author Domenico Pacifici From: “Nanoscale plasmonic interferometers for multispectral, high-throughput biochemical sensing” J. Feng et al., Nano Letters pp. 602 - 609 (2012) Revolutionary new type of safe nuclear energy technology Laura 13 September 14, 2015 Lattice Energy LLC, Copyright 2015 All Rights Reserved 3 Unique advantages of ultralow energy neutron reactions (LENRs) Widom-Larsen theory rigorously explains all of these unique attributes
  • 4. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 4 LENRs are green: no energetic radiation or radwastes Lack of hard radiation obviates need for shielding and containment Major opportunity to develop safe, battery-like portable LENR power sources Revolution in green nuclear technology Fission reactors need 1 foot of steel and 3 feet of concrete to protect humans from hard radiation and wastes emitted by reactor; makes systems intrinsically large and heavy LENRs enable devices something like this: small, portable battery-like power sources that are safe and disposable Much larger LENR devices based on dusty plasma embodiments can potentially scale-up to megawatts; akin to today’s power plants Fission and fusion processes both emit deadly MeV-energy neutron and gamma radiation
  • 5. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 5 Fossil fuels could be converted into green LENR fuels Breakthroughs in physics and nanotechnology make this possible Bitumen, heavy oil, and coal may be much more valuable as CO2-free LENR fuels Canadian natural bitumen Heavy viscous oils found in many fields Various grades of coal These fossil hydrocarbons contain aromatic ring molecules on which LENRs can be triggered In 2009 Larsen discovered that aromatic molecules can potentially be extracted and processed to be converted into green LENR fuels in which there would be no hard radiation emissions, no production of any long-lived radioactive wastes or emission of gaseous CO2 into the atmosphere; would instead release > 5,000 times more thermal energy versus combustion of Carbon-based molecules with Oxygen
  • 6. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 6 Grand challenge: turn biomass into renewable nuclear fuels Biomass contains substantial % of aromatic polymer called Lignin Lignin can be chemically broken-up into smaller aromatic molecules Green LENRs can be triggered on such molecules: become bionuclear fuels  Two of three major components in biomass - cellulose and hemicellulose - are polymerized sugars that can readily be chemically fermented to create renewable biofuels (this is now occurring commercially); the third, Lignin, is much more resistant to chemical degradation into smaller aromatic molecules  Until recently, Lignin was more-or-less ignored by industry and academic biotech researchers, being regarded more as just a waste product to be burned  Importantly, Lignin is only known major natural source of renewable aromatics  Out in Nature, Lignins are mainly broken-down by various fungi and bacteria  Biotechnologists are now beginning to focus on improving various chemical and enzymatic processes that reduce Lignin to smaller molecules, e.g. aromatics  In 2014, Larsen became aware of improvements in Lignin digestion methods  Advances in chemical processing of Lignin to yield basic aromatic molecules opens-up future possibility of creating revolutionary CO2-free LENR fuels with 5,000x greater energy density than gasoline from renewable biomass aromatics
  • 7. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 7 Lattice Energy LLC Commercializing a next-generation source of green nuclear energy September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 7 If mankind continues to use today’s combustion we will run-out of fossil fuels in < 200 years. If we instead develop and deploy LENR power sources using green nuclear fuels created from aromatic Carbon in fossil fuels and biomass, we move man’s day of reckoning on energy out millions of years. ? How can we ever bridge this gap with truly green forms of energy?
  • 8. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 8 Oil, coal, and lignin could be processed to produce CO2-free LENR fuels Carbon atoms found on aromatic rings good fuel for radiation-free transmutation Neutrons + LENR fuel elements heavier elements + decay products + + Catalytic neutron ‘match’ Neutrons are readily absorbed by LENR fuels such as Nickel, Titanium, Lithium, or aromatic Carbon atoms Direct conversion of neutron capture and decay-related gammas to IR and beta/alpha particles create heat n0 Carbon Radiation-free LENR transmutation Process does not emit any deadly radiation or produce troublesome radwastes Fossil Carbon can be transmuted rather than combusted capture on LENR fuel elements produces heat BTUs Absorbed by fuel elements
  • 9. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 9 CH H H H H H Aromatic ring: 6 Carbon atoms CC C C C 6 Carbon atoms arranged in hexagonal ring bonded to 6 Hydrogen atoms Fossil Carbon can be transmuted rather than combusted September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 9 Benzene molecule
  • 10. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 10 Convert ring Hydrogen atoms (protons) into safe neutrons Neutrons are captured by ring Carbon atoms that are then transmuted In this example a Carbon atom is transmuted into a Nitrogen with LENR process LENR neutron capture catalyzed Process does not emit any deadly radiation or produce troublesome radwastes Aromatic Carbon molecules from biomass become revolutionary bionuclear fuels
  • 11. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 11 Lignin molecules comprise ~40% of cord of split hardwood Who would have dreamed it might be converted into a bionuclear fuel?
  • 12. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 12 Biomass is composed of ~33% Lignin: an aromatic polymer Figure source: T. Wang et al., Green Chemistry 16 pp. 548 - 572 (2014) http://pubs.rsc.org/en/content/articlelanding/2013/gc/c3gc41365a#!divMetrics Biomass has three major components: Cellulose, Hemicellulose, Lignin
  • 13. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 13 Lignins are large complex molecules with structural variants Can comprise up to ~40% of biomass in woody deciduous trees Key function in plants: provide sturdy structural support material Source: http://study.com/academy/lesson/lignin-definition-properties-function.html
  • 14. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 14 Lignin: complex molecule and major constituent of biomass Technically speaking it is a natural, renewable aromatic polymer Must digest it into smaller aromatic molecules to make LENR fuels http://www.igb.fraunhofer.de/en/competences/molecular-biotechnology/industrial-biotechnology/aromatic-lignin-monomers.html Copyright: Fraunhofer-Gesellschaft
  • 15. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 15 Chemists create improved Lignin digestion techniques New papers reporting advances in methods now occurring more often Most methods would probably be useful in development of renewable LENR fuels Selected examples of relevant information sources: http://www.warf.org/documents/ipstatus/P130104US01.PDF Patent # US 8,969,534 B2 Issued March 3, 2015 Assignee: W.A.R.F. “Simple aerobic alcohol oxidation method for conversion of Lignin into simple aromatic compounds” Abstract: “Described is a method to oxidize lignin or lignin sub-units. The method includes oxidation of secondary benzylic alcohol in the lignin or lignin sub-unit to a corresponding ketone in the presence of unprotected primary aliphatic alcohol in the lignin or lignin sub-unit. The optimal catalyst system consists of HNO3 in combination with another Brønsted acid, in the absence of a metal-containing catalyst, thereby yielding a selectively oxidized lignin or lignin sub-unit. The method may be carried out in the presence or absence of additional reagents including TEMPO or TEMPO derivatives “Making the most from Carbon in plants” Pacific Northwest National Laboratory Released: September 9, 2015 Abstract: “Researchers are looking for more effective ways to get at all the carbon in biomass to create more energy and biochemicals. However, a lot of the carbon is in lignin - support tissues in plants, which makes up about a third of the biomass. International teams of scientists are working together to better understand how lignin can be efficiently deconstructed to release its carbon for a more renewable and sustainable energy future.” http://www.sciencedaily.com/releases/2015/09/150909091224.htm
  • 16. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 16 Many moieties contain or are convertible into aromatics Variety of simple and complex aromatic molecules Examples: Green CO2-free LENR fuels 5,000x greater energy density Process into Heavy oils and natural bitumen Coal Contain aromatic molecules Examples: CH4 natural gas Lignin and other plant biomass Extract Extract Digest Mo catalyst Chemical process Chemical processing plus nanotech Benzene Phenanthrene CO2 C nanofibers Enormous gain in energy density makes processing conversions $$$ economic Bottom line: just about any Carbon-based moiety can be converted into aromatic ring-structure molecules using a chemical process Processing LENR fuels can be created from many different natural Carbon sources Nanoparticulate fuelsBase feedstock Aromatic molecules
  • 17. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 17 Nanoparticulate LENR fuels could be used in many systems Huge energy density advantages vs. fossil fuels & chemical batteries Bionuclear LENR fuels energy densities could be 5,000x larger vs. gasoline LENR fuels would be inert and benign and could use existing package delivery systems for resupply; typical gasoline or diesel tanker truck carries ~5,000 - 12,000 US Gallons of liquid fuel; LENR fuels producing same # of BTUs could be shipped in 1 - 2 FedEx boxes Consequence: an automobile powered by LENRs could travel around the entire world on a quantity of nanoparticulate fuel that fits into just a single FedEx box
  • 18. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 18 Key to commercializing game- changing bionuclear fuels from Lignin is ability to reliably trigger production of LENR neutrons on Carbonaceous aromatic molecules emplaced on purpose-built engineered nanoparticles composed of appropriate materials. Lattice Energy LLC Commercializing a next-generation source of green nuclear energy September 14, 2015 Lattice Energy LLC, Copyright 2015 All Rights Reserved 18 Image credit: NASA PAH molecules in space
  • 19. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 19 Lattice’s commercialization strategy akin to computer chips Scale-up LENR system power outputs and integrate energy conversion  LENRs can presently reach temperatures of 4,000 - 6,000o K and boil refractory metals in limited numbers of microscopic LENR-active hot spot sites on laboratory device surfaces. Lattice plans to use its unique proprietary knowledge of LENR engineering physics and key operating parameters (e.g., achieving and maintaining very high local surface electric fields) to first get heat production working well microscopically. That is: reproducibly trigger LENRs on specific, purpose-designed nanoparticulate structures with dimensions ranging from nanometers to microns that are fabricated using existing, off-the-shelf nanotech processes and then deliberately emplaced at what will become LENR-active sites located on Hydrogen-loaded substrate or nanoparticle surfaces  In principle, output of such LENR heat sources could be readily scaled-up: either by fabricating larger area-densities of affixed nanostructures that facilitate formation of LENR-active hot spots on device surfaces, or by injecting larger quantities of specially designed fuel nanoparticles into volumetrically larger reaction chambers containing turbulent dusty plasmas, with or without spatially organized magnetic fields present  A variety of off-the-shelf energy conversion subsystems could potentially be integrated with commercial versions of LENR-based heat sources. These include thermoelectric; thermophotovoltaic cells; steam engines; Rankine cycle steam turbines; Brayton cycle gas turbines, boilers, etc. Other speculative possibilities involve new types of direct energy conversion technologies that are still under development, e.g. harvesting of β - Use existing nanotech and power conversion to cut development time/risks
  • 20. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 20  Over time, plan to ride down manufacturing experience cost curve; similar to build-cost reduction and market penetration strategies used by electronics manufacturers; e.g., microprocessors, memory chips, PCs, and smartphones  As product manufacturing experience accumulates and internal build costs are progressively reduced, leverage enormous energy density/longevity advantages of LENRs (> 5,000x larger than any chemical); price LENR-based systems to drastically undercut price/performance provided by competing thermal sources and chemically-based power generation systems --- this strategy can be applied to portable, distributed stationary, mobile, and central station power markets  Small-scale LENR systems might seem to be light years away from being able to compete with huge 500 - 1,500 MW coal-fired and Uranium-fission power plant behemoths. However, please recall history of personal computers versus large mainframes. When PCs were first introduced 35 years ago, mainframe computer manufacturers regarded them as just toys, information processing jokes of no consequence. Less than 10 years later, mainframe companies weren’t laughing any more. Today, except for just a handful of survivors like IBM, mainframe and minicomputer dinosaurs have disappeared, replaced by microprocessor arrays Lattice’s market penetration strategy akin to computer chips Maximize unit volumes and ride experience curve to attack markets LENR technology enables opportunity to create a Moore’s Law for energy
  • 21. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 21 LENRs could enable vast increases in product performance Intrinsic energy density of LENRs at least 5,000x > chemical processes Commercial LENR systems could easily achieve 10x - 100x chemical systems Product Name Present capabilities with today’s power sources Range (endurance) Vastly enhanced capabilities with future LENR-based power sources 10x chemical 100x chemical GreenWing e430 180 miles (~3 hours @ 60 mph) 1,800 (30) 18,000 (300) Airbus E-Fan 2.0 99 miles (1 hour @ 99 mph) 990 (10) 9,900 (100) Predator MQ-1 1,800 miles (24 hours @ 75 mph) 18,000 (240) 180,000 (2,400) Super Heron est. ~4,000 miles (45 hours @ 89 mph?) 40,000 (450+) 400,000 (4,500) Springtail 184 miles (2.2+ hours @ 94 mph ) 1,840 (200+) 18,400 (2,000+) Crazyflie Speed not measured (3 - 10 minutes) ? (30 - 100 min.) ? (maybe 5 - 17 hrs.) InstantEye est. ~8 miles (18 - 20 min @ 25 mph) est. 80 (3.2 hrs.) 800 (32 hrs.) Tesla Model S car ~300 miles (4 - 5 hours @ 70 mph) 3,000 (40 - 50) 30,000 (400 - 500) Shkval torpedo 6.8 - 9.3 miles (1.8 - 2.4 min @230 mph) 68 - 93 (18 - 24 min) 680 - 930 (3 - 4 hrs) Exoskeletons and autonomous robots Require tether cables connected to some type of external power source Duration of autonomous activity might be extended up to weeks or even months Variousaircraft Note: roughly 730 hours in a month and 8,760 hours in a year; average U.S. car’s IC engine runs for ~5,000 hrs over lifetime Enhancements in product range and endurance if LENR technology were commercialized
  • 22. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 22 LENRs could end combustion of coal: CH4 + 2 O2 → CO2 + 2 H2O + heat Opportunity: retrofit old coal plants with CgNgO boilers LENRs would change boiler, coal pulverizer, and environmental subsystems (for zero NOx or SO2) Retrofit strategy conserves capital; LENR plants would emit Oxygen O2 like trees New LENR-powered boilers could be engineered to seamlessly replace original coal-fired boilers Retrofit with LENR boiler O2
  • 23. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 23 Commercializing a next-generation source of green CO2-free nuclear energy https://www.youtube.com/watch?v=GEPhLqwKo6g Lattice Energy LLC Commercializing a next-generation source of green nuclear energy September 14, 2015 Logo copyright, Apple Inc. 23 “Think different" was an advertising slogan for Apple Inc. (formerly Apple Computer Inc.) in 1997 created by the Los Angeles office of advertising agency TBWAChiatDay (unreleased version narrated by Steve Jobs himself)
  • 24. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 24 Widom-Larsen theory of ultralow energy neutron reactions Three key publications that start in March 2006 referenced below Many-body collective quantum effects enable electroweak catalysis “Ultra low momentum neutron catalyzed nuclear reactions on metallic hydride surfaces” A. Widom and L. Larsen European Physical Journal C - Particles and Fields 46 pp. 107 - 112 (2006) http://www.slideshare.net/lewisglarsen/widom-and-larsen-ulm-neutron- catalyzed-lenrs-on-metallic-hydride-surfacesepjc-march-2006 “A primer for electro-weak induced low energy nuclear reactions” Y. Srivastava, A. Widom, and L. Larsen Pramana - Journal of Physics 75 pp. 617 - 637 (2010) http://www.ias.ac.in/pramana/v75/p617/fulltext.pdf “Theoretical Standard Model rates of proton to neutron conversions near metallic hydride surfaces” A. Widom and L. Larsen Cornell physics preprint arXiv:nucl-th/0608059v2 12 pages (2007) http://arxiv.org/pdf/nucl-th/0608059v2.pdf
  • 25. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 25 Electroweak reaction in Widom-Larsen theory is simple Protons or deuterons react directly with electrons to make neutrons Need input energy source such as electricity to drive LENR neutron production EnergyE-field + e- sp g e-*sp + p+ g n0 + νe Collective many-body quantum effects: many electrons each transfer little bits of energy to a much smaller number of electrons also bathed in the very same extremely high local electric field Quantum electrodynamics (QED): smaller number of electrons that absorb energy directly from local electric field will increase their effective masses (m = E/c2) above key thresholds β0 where they can react directly with a proton (or deuteron) neutron and neutrino νe neutrinos: ghostly unreactive particles that fly-off into space; n0 neutrons capture on nearby atoms Neutrons + fuel elements heavier elements + decay products Neutrons induce nuclear transmutations that release enormous amounts of clean, CO2-free heat Input energy creates electric fields > 2.5 x1011 V/m Heavy-mass e-* electrons react directly with protons electrons + protons (Hydrogen) g neutrons + neutrinos (benign particles, fly into space) Radiation-free LENR transmutation Require source(s) of input energy Many-body collective electroweak neutron production
  • 26. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 26 LENR transmutations move left-to-right across rows of Table C N O Transmutation of Carbon to O2 releases 5,000x > heat than combustion September 14, 2015 Lattice Energy LLC, Copyright 2015 All Rights Reserved 26 Any element in Periodic Table can be LENR fuel - some better than others
  • 27. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 27 LENR C g N gO releases 5 million x more heat vs. burning Carbon transmuted to O2 instead of being combusted with O2 g CO2 6C-12 Stable 98.7% 6C-13 Stable 1.3% 6C-14 HL=5.7x103 y 7N-14 Stable 99.6% 0.2 6C-15 HL= 2.5 sec 7N-15 Stable 0.4% 6C-16 HL=747 msec 7N-16 HL=7.1 sec 8O-16 Stable 99.76% 8.0 10.4 6C-17 HL=193 msec 7N-17 HL=4.2 sec 8O-17 Stable 0.04% 13.2 8.7 6C-18 HL=92 msec 7N-18 HL=622 msec 8O-18 Stable 0.20% 11.8 13.9 6C-19 HL=46 msec 7N-19 HL=271 msec 8O-19 HL=26.5 sec 9F-19 ~Stable 100% 16.6 12.5 5.0 8.2 1.2 4.3 0.8 4.2 0.6 10.8 2.5 2.85.9 5.3 4.1 8.0 4.0 2.9 2.2 6.6 7.6 2He-4 pool Stable 99.99% Bosonic sink Increasing values of A IncreasingvaluesofZ 7.5 7.5 Beta-delayed alpha decays are denoted by orange arrows with decay energy in MeV: 3.3 2.3 7.7 7.5 [BR = 12.2 %] [BR = 0.0025 %] [BR = 0.001 %] Note: not shown on LENR network chart - for a variety of sound physics reasons, beta- delayed neutron emissions are almost totally suppressed in condensed matter LENRs Nitrogen Oxygen Gamma emissions from neutron captures and decays not shown on chart because they are automatically converted directly into benign infrared photons by heavy SP electrons per the Widom-Larsen theory; issued Lattice patent US# 7,893,414 B2 Totally stable isotopes are indicated by green boxes; some with extremely long half-lives are labeled ~stable; natural abundances denoted in % Unstable isotopes are indicated by purplish boxes; when measured, half-lives are shown as “HL = xx” http://www.slideshare.net/lewisglarsen/us- patent-7893414-b2 9.8 Carbon Fluorine LENR transmutation network cannot get past production of elemental Oxygen (O2) unless ultra low energy neutron fluxes are made to be > 1010 neutrons cm2/sec Fluorine’s “valley of death” H + F reaction disrupts sites Legend: ULM neutron captures proceed from left to right; Q- value of capture reaction in MeV is on top of green horizontal arrow: Beta decays proceed from top to bottom; denoted with blue vertical arrow with Q- value in MeV in blue to left: 4.8 Aromatic Carbon transmutation naturally stops at Oxygen - akin to plants
  • 28. September 14, 2015 Lattice Energy LLC, Copyright 2015, All rights reserved 28 Further in-depth reading for those who wish to learn more Incredible opportunity to develop green renewable nuclear power LENR fuels derived from biomass --- an inexhaustible energy source “Index and User Guide to the Widom-Larsen theory and ultralow energy neutron reactions (LENRs)” [133 slides] http://www.slideshare.net/lewisglarsen/lattice-energy-llc-hyperlinked-index-to- documents-re-widomlarsen-theory-and-lenrs-september-7-2015 http://www.slideshare.net/lewisglarsen/lattice-energy-llc-lenr-transmutation-of-carbon- better-energy-strategy-than-obama-clean-power-plan-aug-3-2015 “LENR transmutation of Carbon is superior energy strategy - Slashes CO2 emissions for vehicles as well as electric power generation” [32 slides] http://www.slideshare.net/lewisglarsen/lattice-energy-llc-compelling-economics-of- transmutation-vs-combustion-of-carbonaceous-energy-sources-jan-14-2015 “Compelling economics of transmutation vs. combustion of carbonaceous energy sources” [44 slides] “Transmutation vs. combustion - Are LENRs a Chicxulub for fossil fuel dinosaurs?” [49 slides] http://www.slideshare.net/lewisglarsen/lattice-energy-llc-transmutation-vs-combustion- are-lenrs-chicxulub-for-fossil-fuel-dinosaurs-oct-6-2014