This presentation gives a brief introduction to chemical heat treatment of steels and surface hardening techniques
Keywords: Carburising, Nitriding, Carbonitriding, Flame hardening, Laser hardening, Induction hardening
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Heat treatment of steels- II
1. Heat treatment of steels - II
By:
Nishant S. Khatod
Assistant Professor
STC, Latur
2. Introduction
Components like ball and tapered bearings, gears, rock drill bits, camshafts,
crankpins, axles require outer surface to be hard and wear resistant and inner
core more ductile and tougher
Such properties ensure long service life and sufficient toughness to withstand
shock loads
Ways to achieve such combination of properties:
Thermochemical treatment – Change in surface composition by diffusion of C
and N2 – Carburising and Nitriding
Phase transformation of outer surface by rapid heating and cooling –
Flame, Induction, electron, and laser beam hardening
3. Carburising
Also known as cementation OR case carburising OR case hardening
Carburising – Method of increasing carbon
Applicable: Low carbon steels with % C = 0.1 to 0.25
Process:
Heating to 900 to 930ᵒC in presence of solid, liquid or gas rich in carbon
Holding for definite period till desired case depth is achieved
Cooling
Carbon diffused into steel when heated in austenitic region
Surface layer enriched with 0.7 to 0.9% carbon
Fully austenitic steel is essential because solubility of carbon is more in
austenite than in ferrite
Depending upon the medium, it can be classified as;
Solid OR Pack OR Box carburising
Liquid carburising or salt bath carburising
Gas carburising
Vacuum carburising
4. Solid carburising
Components to be carburised packed with a compound rich in carbon in steel or
CI boxes and sealed with clay
If not sealed properly medium comes in contact with air and burns without
carburising
Medium: 50 to 55% hardwood charcoal, 30 to 32% coke and remaining
energiser or accelerator like BaCO3
Process:
Heating boxes in a furnace upto 930ᵒC
Holding for definite period till required case depth is achieved
Cooling
High temperature helps in aborption of carbon on surface
Reactions:
O2 (from box) + C (medium) CO2
BaCO3 BaO + CO2
CO2 + C (from medium) 2CO
2CO + Fe Fe (C) + CO2
Liberated CO2 + C (from medium) 2CO
5. Solid carburising
This is indirect carburising
Direct carburising: Carburising @ steel in direct contact with medium, Not
desirable because of local variations; Non uniform hardness.
Maximum carbon @ the surface and case depth depend upon temperature
of carburising and holding time
Higher the temperature, higher is the case depth but grain coarsening occurs
Higher the holding time, higher is the case depth without change in maximum
concentration at the surface
Carburising time of 6 to 8 hrs for case depth of 1 to 2mm @ 900ᵒ C
Used when extreme uniformity in carbon content is not desired
NOTE:
Case depth: The perpendicular distance from the surface of the steel to the
point at which change in hardness, chemical composition or microstructure of
the case and core cannot be distinguished
6. Liquid carburising
Also known as salt bath carburising
Carburising done by immersing the steel components in a carbonaceous fused
salt bath medium containing sodium or potassium cyanide, sodium and
potassium chloride and barium chloride which acts as a activator
Bath heated in the range of 815 - 900ᵒC
Reactions:
BaCl2 + 2NaCN Ba (CN)2 + 2NaCl
Ba (CN)2 + Fe Fe (C) + BaCN2 (Barium cynamide)
Some beneficial nitrogen may also diffuse through oxidation of sodium
cyanide
2NaCN + O2 2NaCNO
3NaCNO NaCN + Na2CO3 + C + 2N
Nitriding helps in increasing hardness and wear resistance
Carbursing time of 0.5 to1 hour for case depth of 0.1 to 0.5mm (Relatively
thinner than pack carburising) @ 900ᵒ C
7. Liquid carburising
Advantages
Uniform and rapid heat transfer
Low distortion
Negligible surface oxidation
High uniformity in case depth and carbon content
Disadvantages
Highly poisonous sodium cyanide; hence care should be taken while storage,
use and disposal
Salt sticks to the components and must be removed while washing
8. Gas carburising
Components heated in the range of 870 to 950ᵒ C in the presence of
carbonaceous gases like methane, ethane, propane or butane diluted with a
carrier gas containing 40% N2, 40% H2, 20% CO, 0.3% CO2, 0.5% CH4,
0.8% water vapor and traces of oxygen
Reactions:
C3H8 2CH4 + C [Cracking]
CH4 + Fe Fe (C) + 2H2
CH4 + CO2 2CO + 2H2
2CO + Fe Fe (C) + CO2
Carburising mainly occurs due to CO to CO2 conversion
H2 reacts with CO2 and increases CO concentration
H2 + CO2 CO + H2O
Traces of oxygen are also present due to the following reactions;
2CO2 2CO + O2
CO2 + Fe Fe (C) + O2
To avoid dead spots and formation of soot: Control on gas composition and
proper circulation of gas is essential for constant and uniform rate of carbon
diffusion
9. Gas carburising
Carburising time of 1 to 2 hrs for case depth from 0.2 to 0.5mm @ 900ᵒ C
Suited for large volume production
Accurate control on case depth and surface carbon content
Less labor cost but skilled labor required for accurate control
10. Vacuum carburising
Medium: Vacuum or Reduced pressure
Two stage process:
1. Carbon made available for absorption
Component introduced in a furnace
Furnace evacuated till required degree of vacuum
Heated in the range of 925 to 1050ᵒ C
Gaseous hydrocarbon like methane or ethane introduced in the furnace.
Amount of hydrocarbon depends upon size of component, surface area to be
carburised, case depth and concentration of carbon to be introduced
Gaseous hydrocarbon cracks when comes in contact with surface which results
in extremely fine carbon deposition on surface
Process continues till sufficient amount of carbon is absorbed
Inflow of gas is stopped and excess gas removed by vacuum pumps
2. Controlled diffusion cycle commences and continues till required carbon
concentration is formed and required case depth is achieved
11. Vacuum carburising
Oil quenching is used
Advantages:
Components are free from oxides, microcracks and decarburization
Energy saving process
Disadvantages:
Limited to batch type production
Limitation on size of workpiece due to limited size of vacuum furnace
Reasons for energy saving:
Heating is carried out by radiation , improved efficiency due to vacuum
Heat zones occupy less volume
Not necessary to keep the furnace ON throughout the process.
Absence of atmosphere
Only 1% gas required compared to conventional process
12. Post carburising treatment
Need for post carburising:
Overheating may occur due to high carburising temperatures which results in
grain coarsening throughout the c/s
Objectives of post carburising:
Improve microstructure and refine grain size of core and case
Achieve high hardness at the surface
Break carbide network which may be formed due high carbon content (1% C)
Following heat treatments can be used ;
Direct quench
Double quench
Other quenching cycles
13. Cyaniding
Applicable to steels with 0.3 to 0.4% C
Surface hardened by addition by addition of carbon and nitrogen
Process:
Medium: Parts immersed in liquid bath containing NaCN varying between 25%
and 90%
Bath heated in the range of 800 to 960ᵒ C
Measured amount of air passed through the molten bath
Reactions:
2NaCN + O2 2NaCNO
2NaCNO + O2 Na2CO3 + CO + 2N
2CO CO2 + C
C and N2 so formed diffuse into steel and give thin wear resistant layer of
carbonitride ϵ phase
Quenched in oil or water
Low temperature tempering
Cyaniding time of 1.5 to 6hrs for case depth of 0.13 to 0.35mm @ 850ᵒ C
Higher the temperature, higher the C diffusion (0.8 to 1.2%) on surface as
compared to N (0.2 to 0.3%)
Case hardness: 850VHN
14. Cyaniding
Advantages:
Less time consuming
Less distortion due to use of salt bath
Disadvantage:
Not suitable for components subjected to shock, fatigue and impact because
nitrogen has adverse effect on these properties
Difference between cyaniding and liquid carburising:
Absence of alkaline earth salts in cyaniding
High % of NaCN in case of cyaniding
High N and lower C in case of cyaniding
Thin cases in case of cyaniding
15. Carbonitriding
Also known as dry cyaniding, gas cyaniding, and ni-carbing
Applicable to steels with 0.3 to 0.4% C
Surface hardened by addition by addition of carbon and nitrogen
Used to improve wear resistance of mild steel and low alloy steel
Process:
Medium: Gas mixture consisting of 15% NH3, 5% CH4 and 80% neutral carrier gas
Heated in the range of 800 to 870ᵒ C
C and N2 diffuse into steel
Quenching in oil to avoid cracking
Tempering @ 150 to 180ᵒ C
Case depth : 0.05 to 0.75mm
Case hardness: 850VHN
Nitrogen is more effective in increasing hardenability as compared to carbon
Nitrogen content depend upon ammonia and temperature
Advantages:
Surface hardenability, wear resistance and corossion resistance better than
carburising
Disadvantage:
Longer times than carburising
16. Nitriding
Applicable to alloy steels containing nitride forming elements like Al, Cr, Mo,
V and W
Process carried out @ 550ᵒ C; hence no phase transformation
Proper heat treatment necessary before nitriding
All machining and grinding operations to be completed before nitriding
Area not to be nitrided to be covered by depositing tin by electrolysis
Two types:
Liquid nitriding: Same reactions as that of liquid carburising except only N
diffusion because of low temperatures
Gas nitriding: Anhydrous ammonia gas is passed which dissociates into nascent
nitrogen and hydrogen
2NH3 2 N + 3H2
Nitriding of alloy steels: Fe4N (White layer) + alloy nitrides (dark). Hence
YES
Nitriding of plain carbon steels: Only white layer. Hence NO
Treatment time depends upon case depth and size; usually 21hrs to 100hrs
Nitriding time of 100hrs for case depth of 0.5mm @ 550ᵒ C
Case hardness: 900-1100VHN
Achieved properties: Good wear resistance, hot hardness, corossion resistance
17. Nitriding
Applications: Precision gears, boring bars, forming rolls for paper and rubber,
forming dies, camshafts, crankshafts, cylinder liners
Advantages:
No post heat treatment; hence minimum distortions
High fatigue life
Better corrosion resistance than carburised and hardened components
Excellent bearing properties (Non metallic nature of nitrides, less coefficient of
friction)
High hardeness than carburised and hardened components
High hot hardness
Disadvantages:
Applicable only to alloy steels containing nitriding elements
Thin case depth
White layer
No heat treatment can be done after nitriding
19. Plasma nitriding
Also known as ion nitriding process
What is plasma??
introduction to plasma.mp4
Component acts as cathode
Process:
Apply high DC voltage 500-1000V
Electrically heated in the range of 370 to 650ᵒ C
Gas mixture of N2 and H2 supplied at 1-10 torr
Current flows and forms ionised gas
Nitrogen ions bombard on the surface of component
Part of energy heats the component and allows diffusion
of nitrogen and other part cleans the surface by
displacing secondary electrons
Bombarded ions clean the surface, heat the component
and diffuse the nitrogen
Glow envelops the component and nitrding starts
Component cooled in atmosphere of nitrogen
Anode is kept cooled by surrounding water around it
Ion (Plasma) Nitriding process at Ionitech Ltd.mp4
Plasma nitriding process
[Source: T. V. Rajan, C. P.
Sharma and Ashok Sharma,
2013]
20. Plasma nitriding
Case depth depend upon current,
temperature and time of holding
Advantages:
Complex shapes, components of different
size can be nitrided
Excellent dimensional stability
Steels sensitive to tempering can be
nitrided at low temperatures
Very slow white layer formation
Accurate control
Improved fatigue properties
Cold worked steels can be plasma
nitrided to get high wear resistance
Disadvantages:
Equipment is complex, skilled labor
required for proper control
High equipment cost
Different size and shape part cannot be
plasma nitrided together
Deep surfaces cannot be nitrided
Besides these limitations, process is very
attractive
View of components during plasma
nitriding process
21. Boronizing
Applied to carbon and tool steels
Medium: Pack or gas
Pack process:
Components packed in heat resistant boxes with mixture of granules or paste of
boron carbide or other boron compounds with addition of activators and
dilutents
Heated in the range of 900-1000ᵒ C
Boron diffuses and layers of FeB @ outer suface and Fe2B @ interior are
formed
FeB phase is hard and brittle; hence not desirable. High temperature, long
treatment time and high alloys favor formation of FeB
Case hardness: 1500-2100 VHN
Case depth: 0.012-0.15 mm
Boronizing time of 6hours for case depth of 0.15mm @900ᵒ C
To optimize the performance hardening and tempering can be carried out after
boronising
22. Boronizing
Advantages:
Increases resistance of low alloy steels to sulphuric, phosphoric, and hydrochloric acid
Increases resistance of austenitic stainless steel to hydrochloric acid
Selective hardening is possible
Can be polished to high finish
Can be applied to irregular shapes
Increases tool and mold life by improving resistance to abrasive, sliding and adhesive
wear
Low coefficient of friction
Disadvantages:
Distortions due to high temperature
Poor fatigue and corossion resistance
Applications:
Due to high hot hardness and wear resistance: Hot forging dies, wire drawing dies,
extrusion dies, straightening rolls, ingot molds etc
Nozzles, plungers, gears, shafts and rollers
Oil and gas components like valve components, valve fittings, metal seals, coal/oil
burner nozzles
Turbine components, pump impellors, ball valves and seats, shaft protection sleeve, and
23. Chromizing
Applied to carbon and tool steels
Medium: Pack or gas
Pack process:
Components packed with fine chromium powder and additives
Composition of chromizing mixture: 60% Cr, < 0.1%C, 0.2% ammonium
iodide, 39% kaolin powder
Heated in the range of 900-1020ᵒ C
Chromium carbide formed due to diffusion of chromium
Case hardness: 1500 VHN
Chromising time of 12hours for case depth of 0.02-0.04mm @ 900-1020ᵒ C
Types:
Hard chromising: For steels with minimum % C = 0.35, hard, corossion and
wear resistant chromium layer will be formed
Soft chromising: For steels with % C < 0.35, chromium carbide layer cannot be
formed. Chromium diffusion layer with 200micrometer and 35%Cr. Excellent
corossion and oxidation resistance while maintaining ductility
24. Toyota diffusion process
Developed by Toyota Central Research and Development Laboratories to
develop hard and wear resistant surface for large automotive press tools
Used for die steels, tool steels, high strength steels
Process:
Component kept in a medium containing salt bath of proprietary composition
based on borax (sodium tetraborate)
Carbide forming elements like vanadium and niobium are added in the form of
ferro-alloys.
Heated at about 1050ᵒ C
Carbide forming elements are diffused into the steel
Quenched and tempered
Case hardness: 3000VHN
Carbide layer of 5-12micrometers @ 1000ᵒ C
Advantages:
Extremely high hardness, impact resistance and wear resistance
High seizure resistance and low lubricant requirement
High peel strength
Applications: Press tools, shafts, screws, bushes, blades, taps, pins and plugs
26. Flame hardening
Applicable to steels with %C = 0.3 to 0.6
Process:
Heating above upper critical temperature (here A3) by oxyacetylene flame
Cooling by spraying of jet of water or immersion in water
Reheating in furnace or oil bath @ 180 to 200ᵒ C for stress releiving
Hardness in flame hardened steel is due to lower bainite or martensite structure
Flame Hardening of Crane Wheel.mp4
Case depth: 3mm
Overheating to be avoided
High heating rate to avoid oxidation and decarburisation
Less distortions
Selective areas can be hardened
Different methods of flame hardening:
Spot or stationary: Shaft ends, large gears etc
Progressive: Guideways, flat surfaces etc
Spinning: Shafts, wheels, pulleys etc
Combination of progressive and spinning: Piston rods, Rolls etc
Applications: Crankshaft, axle, large gear, cam, bending roller etc
27. Flame hardening
Progressive flame hardening
[Source: T. V. Rajan, C. P. Sharma
and Ashok Sharma, 2013]
Progressive spin hardening
[Source: T. V. Rajan, C. P. Sharma
and Ashok Sharma, 2013]
28. Flame hardening
Depth of hardening depends upon:
Distance between gas flames and the component surface
Gas pressures and ratio
Rate of travel of flame head or component
Type volume and application of quench
29. Induction hardening
Applicable to steels with %C = 0.4 to 0.5 and some alloy steels
Process:
Heating done by electromagnetic induction
Electromagnetic Induction.mp4
Within a short period of 2 to 5 minutes, the temperature of surface layer comes to
above upper critical temperature
Quenched by jet of cold water
Low temperature tempering @ 160 to 200ᵒ C
Induction Hardening.mp4
INDUCTION HARDENING.mp4.mp4
Induction hardening king pin.mp4
Sometimes self tempering may also occur
Skin effect: Depth of hardened layer is inversely proportional to square root of
frequency of induced current
In addition to the direct heating of the skin by induced current, there is also some
heating of the core due to conduction of heat. Hence overall depth of hardness is
increased
Case depth: 0.5 to 6mm
Applications: Crankshaft, camshaft, gears, crankpins, axles, boring bars, brake
drums, etc
30. Induction hardening
Advantages:
Orignal toughness and ductility remain
unaffected
Fast heating and no holding leads to
increase in production rates
No scaling and decarburisation
Less distortion because of heating of
only required surface
Easy control over the depth of
hardening by control of frequency of
supply voltage and/or time of holding
Cleanliness of working conditions
Only a light final grinding or lapping
operation may be required after
hardening
Disadvantages:
Irregular shaped parts are not suitable
for induction hardening
Not economical for small scale
production
Induction hardening process
[Source: T. V. Rajan, C. P. Sharma
and Ashok Sharma, 2013]
31. Laser beam hardening
Lens used to reduce the intensity
Laser beam of 1kW can produce circular spot of diameter 0.25 to 0.50mm
Process:
Heating the zone to be hardened in the austenitizing range
Holding to ensure adequate diffusion of carbon
Self quenching
Microstructure: Laser heat treated steel consists of bainite + ferrite at the surface of
heated spot and pearlite + ferrite in the interior
Relationship between depth of hardening and power,
Where
Y = case depth (mm)
P = Laser power (W)
Db = Incident beam diameter (mm)
V = traverse speed (mm/s)
Laser Hardening of Tool Steel.mp4
MATEX laser hardening technology.mp4
Hardening of steel axles using lasers.mp4
Case depth: 0.75mm
32. Laser beam hardening
Independent process variables:
Incident laser beam power
Diameter of incident laser beam
Absorptivity of laser beam by surface
Transverse speed across the surface
Dependent process variables:
Depth of hardness
Geometry of heat affected zone
Microstructure and metallurgical properties of laser heat treated material
Efficiency depends on absorption of light energy by work-piece
Colloidal graphite, manganese phosphate, zinc phosphate and black paint are
some of the commonly used absorbent coating to avoid melting and key
formation
33. Laser beam hardening
Advantages:
High production rates
Effect of heat on surrounding surface is less
Less time than induction and flame hardening
Localized treatment is possible
No external quenching is needed; necessary only for small parts
No contamination
Process can be controlled by computer
Difficult to harden areas can be hardened
No final machining needed subsequent to hardening
34. Electron beam hardening
Used to harden the components which cannot be hardened by induction
hardening
Application: Automotive transmission clutch
Work piece kept in vacuum at 0.06 bar pressure
Electron beam focused on work piece to heat the surface
In the beginning, energy input is kept high
With time, power input is reduced as the component gets heated up, to avoid
melting
Computer is used to control voltage, current, beam, dwell time and focus
Case depth: 0.75mm