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Dual Phase Steels
    Overview
    Evan Sanders
Dual Phase Steels
● Microstructure
   ○ 75-85 vol% ferrite
   ○ Remainder mixture of martensite, lower bainite,
     retained austenite
   ○ Usually consists of more than 2 phases
● Essentially just a low carbon steel
  thermomechanically processed for better
  formability than ferrite-pearlite steels of
  similar tensile strength
Stress-Strain Behavior
● Characteristically different from HSLA (High
  Strength Low Alloy) or plain carbon steels
  ○ Continuous Stress-Strain curve with no yield point
    elongation
  ○ Work harden rapidly at low strains
  ○ Low yield strength
  ○ High UTS
  ○ Strength-Ductility data falls on separate curve
Development
● Ferrite-Martensite steels developed by
  British Iron and Steel Research Association
  (BISRA, UK) and Inland Steel Corporation
  (ISC, US) in mid 1960s
  ○ Focus was for producing steels with tinplate
  ○ Neither group focused on improved formability
● Development for formability triggered in
  1970s by conflicting demands in automotive
  industry for decreased weight for fuel
  economy and increased weight to meet
  safety standards
  ○ Matsuoka & Yammamori, and Hayami and
Processing Methods
● Before processing, starting steel consists of
  a ferrite matrix with grain boundary iron
  carbides and small islands of pearlite
● 3 types of processing methods to produce
  dual phase steel
   ○ Continuous annealed
   ○ Batch annealed
   ○ As-rolled
Continuous annealed method
● Rapid heating above the critical temperature
● Short time holding at that temperature
● Cooling below the martensitic start
  temperature
● Some processes also include a short time
  tempering above 500 degrees Celsius
● Rate of heating is far less critical than the
  heating temperature
● Faster cooling required for steels with lower
  hardenability
Batch annealed
● Used with high alloy content and high
  hardenability
● Very slow cooling (days)
As-Rolled
● Steel composition chosen such that 80-90%
  of the steel is transformed to ferrite after the
  final roll pass in normal conventional hot
  rolling and before entering the coiler
● Remaining 10-20% does not transform until
  slow cooling in the coiler
● This method possible with steels that
  express certain characteristics in their
  continuous cooling transformation diagrams
Deformation behavior
● Typically stress strain behavior is not
  satisfied for dual phase steels
● 2 proposed methods for changes in
  deformation behavior
   ○ n i(j)=[log(σj)-log(σj-1)]/ [log(εj)-log(εj-1)]
   ○ σ=σo+Bε^m
   ○ Where σ is the true stress, σo us the true yield
     stress, B and m are constants, and j=1 to L, where L
     is the number of segments in the curve
Deformation behavior (cont)
● The shear and volume change
  accompanying the austenite to martensite
  transformation upon cooling from above the
  critical temperature produce numerous free
  mobile dislocations in the surrounding ferrite
  matrix
   ○ Upon application of the load, free dislocations move
     with stresses much less than that required to move
     restrained dislocations as commonly found in ferrite-
     pearlite steels, so dual phase steels yield plastic flow
     at lower stresses of equivalent tensile strength
   ○ Magnitude of work hardening in dual phase steels at
     low strains too large to be explained by dislocation
Deformation behavior (cont)
● Martensite is the principal load bearing
  constituent
   ○ Volume percent of martensite and steel strength are
     linearly related
   ○ Carbon content is also important though, and
     separate linear relationships exist
   ○ Martensite strength can be increased by decreasing
     its particle size
Transformation Mechanisms
● Continuous annealed
  ○ Upon heating the steel above the critical
    temperature,islands of carbon-rich, nonequilibrium
    austenite form at the carbide locations.
     ■ Heating temp determines volume fraction of
       austenite and carbon content that can exist
  ○ Carbon migration
Transformation Mechanisms (cont)
● Batch annealed
  ○ Similar to those observed during continuous
    annealing
    ■ However, grain size and substructure are
       characteristic of slower cooling rates

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Dual phase steels (1)

  • 1. Dual Phase Steels Overview Evan Sanders
  • 2. Dual Phase Steels ● Microstructure ○ 75-85 vol% ferrite ○ Remainder mixture of martensite, lower bainite, retained austenite ○ Usually consists of more than 2 phases ● Essentially just a low carbon steel thermomechanically processed for better formability than ferrite-pearlite steels of similar tensile strength
  • 3.
  • 4. Stress-Strain Behavior ● Characteristically different from HSLA (High Strength Low Alloy) or plain carbon steels ○ Continuous Stress-Strain curve with no yield point elongation ○ Work harden rapidly at low strains ○ Low yield strength ○ High UTS ○ Strength-Ductility data falls on separate curve
  • 5.
  • 6.
  • 7. Development ● Ferrite-Martensite steels developed by British Iron and Steel Research Association (BISRA, UK) and Inland Steel Corporation (ISC, US) in mid 1960s ○ Focus was for producing steels with tinplate ○ Neither group focused on improved formability ● Development for formability triggered in 1970s by conflicting demands in automotive industry for decreased weight for fuel economy and increased weight to meet safety standards ○ Matsuoka & Yammamori, and Hayami and
  • 8. Processing Methods ● Before processing, starting steel consists of a ferrite matrix with grain boundary iron carbides and small islands of pearlite ● 3 types of processing methods to produce dual phase steel ○ Continuous annealed ○ Batch annealed ○ As-rolled
  • 9. Continuous annealed method ● Rapid heating above the critical temperature ● Short time holding at that temperature ● Cooling below the martensitic start temperature ● Some processes also include a short time tempering above 500 degrees Celsius ● Rate of heating is far less critical than the heating temperature ● Faster cooling required for steels with lower hardenability
  • 10.
  • 11. Batch annealed ● Used with high alloy content and high hardenability ● Very slow cooling (days)
  • 12. As-Rolled ● Steel composition chosen such that 80-90% of the steel is transformed to ferrite after the final roll pass in normal conventional hot rolling and before entering the coiler ● Remaining 10-20% does not transform until slow cooling in the coiler ● This method possible with steels that express certain characteristics in their continuous cooling transformation diagrams
  • 13.
  • 14.
  • 15. Deformation behavior ● Typically stress strain behavior is not satisfied for dual phase steels ● 2 proposed methods for changes in deformation behavior ○ n i(j)=[log(σj)-log(σj-1)]/ [log(εj)-log(εj-1)] ○ σ=σo+Bε^m ○ Where σ is the true stress, σo us the true yield stress, B and m are constants, and j=1 to L, where L is the number of segments in the curve
  • 16.
  • 17.
  • 18.
  • 19. Deformation behavior (cont) ● The shear and volume change accompanying the austenite to martensite transformation upon cooling from above the critical temperature produce numerous free mobile dislocations in the surrounding ferrite matrix ○ Upon application of the load, free dislocations move with stresses much less than that required to move restrained dislocations as commonly found in ferrite- pearlite steels, so dual phase steels yield plastic flow at lower stresses of equivalent tensile strength ○ Magnitude of work hardening in dual phase steels at low strains too large to be explained by dislocation
  • 20. Deformation behavior (cont) ● Martensite is the principal load bearing constituent ○ Volume percent of martensite and steel strength are linearly related ○ Carbon content is also important though, and separate linear relationships exist ○ Martensite strength can be increased by decreasing its particle size
  • 21.
  • 22.
  • 23. Transformation Mechanisms ● Continuous annealed ○ Upon heating the steel above the critical temperature,islands of carbon-rich, nonequilibrium austenite form at the carbide locations. ■ Heating temp determines volume fraction of austenite and carbon content that can exist ○ Carbon migration
  • 24. Transformation Mechanisms (cont) ● Batch annealed ○ Similar to those observed during continuous annealing ■ However, grain size and substructure are characteristic of slower cooling rates