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1
Functional Groups
of
Organic Compounds
Learning goal: Identify, name and draw the structures of the
common functional groups.
2
 Organic compounds are classified according to
the type of functional group(s) present.
 Functional groups composed of an atom or
groups of atoms …
 a structural features
 similar physical properties
 undergo __________ chemical reactions
Functional Groups
3
Very important because they are:
 units by which organic compounds are divided into
classes.
 sites of chemical reactions
 basis for naming organic compounds
Functional Groups
4
 Organic compounds can be represented as
R - <functional group>
Functional Groups
The symbol R represents the rest of the molecule
Useful in simplifying or summarizing equations
5
Classification of Organic
Compounds
 Alkane
 Alkene
 Alkyne
 Aromatic
 Haloalkane
(Alkylhalide)
 Alcohol
 Ether
 Aldehyde
 Ketone
 Carboxylic acid
 Ester
 Amine
 Amide
6
Alkane, Alkene and Alkyne
| |
- C – C - C = C - C ≡
C - | |
Alkane Alkene Alkyne
Functional
Group
Example CH3CH2CH3 CH3CH=CH3 CH3C≡CH
Propane Propene Propyne
7
Haloalkane and Aromatic
– X
X : F, Cl, Br, I
Alkyl halide Benzene Ring
(Haloalkane) (Aromatic)
Functional
Group
Example CH3CH2CH2Cl
1-Chloropropane Ethylbenzene
8
Alcohol and Ether
– O – H – O –
Alcohol Ether
Functional
Group
Example CH3CH2CH2OH CH3CH2-O-CH3
1-Propanol Ethyl methyl ether
9
Aldehyde and Ketone
H
| |
– C = O – C = O
Aldehyde Ketone
Functional
Group
Example CH3CH2C=O CH3 – C – CH3
| ||
H O
Propanal Acetone
10
Carboxylic Acid and Ester
OH O
| ||
– C = O – C – O –
Carboxylic Ester
Acid
Functional
Group
Example CH3CH2C=O CH3 – C – O - CH3
| ||
OH O
Propanoic Acid Methyl Acetate
11
Amine and Amide
H O H
| || |
– N – H – C – N – H
Amine Amide
Functional
Group
Example CH3CH2CH2 CH3CH2 – C – NH2
| ||
NH2 O
1-Propanamine Propanamide
12
Practice
Classify the following organic compounds
according to their functional groups:
CH3 CH2OH
CH3 CH2NHCH3
H3C-O-CH3
 Amine
 Carboxylic acid
 Alcohol
 Ether

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Oc 02-functional-groups-handout-1208704930480189-9 (1)

  • 1. 1 Functional Groups of Organic Compounds Learning goal: Identify, name and draw the structures of the common functional groups.
  • 2. 2  Organic compounds are classified according to the type of functional group(s) present.  Functional groups composed of an atom or groups of atoms …  a structural features  similar physical properties  undergo __________ chemical reactions Functional Groups
  • 3. 3 Very important because they are:  units by which organic compounds are divided into classes.  sites of chemical reactions  basis for naming organic compounds Functional Groups
  • 4. 4  Organic compounds can be represented as R - <functional group> Functional Groups The symbol R represents the rest of the molecule Useful in simplifying or summarizing equations
  • 5. 5 Classification of Organic Compounds  Alkane  Alkene  Alkyne  Aromatic  Haloalkane (Alkylhalide)  Alcohol  Ether  Aldehyde  Ketone  Carboxylic acid  Ester  Amine  Amide
  • 6. 6 Alkane, Alkene and Alkyne | | - C – C - C = C - C ≡ C - | | Alkane Alkene Alkyne Functional Group Example CH3CH2CH3 CH3CH=CH3 CH3C≡CH Propane Propene Propyne
  • 7. 7 Haloalkane and Aromatic – X X : F, Cl, Br, I Alkyl halide Benzene Ring (Haloalkane) (Aromatic) Functional Group Example CH3CH2CH2Cl 1-Chloropropane Ethylbenzene
  • 8. 8 Alcohol and Ether – O – H – O – Alcohol Ether Functional Group Example CH3CH2CH2OH CH3CH2-O-CH3 1-Propanol Ethyl methyl ether
  • 9. 9 Aldehyde and Ketone H | | – C = O – C = O Aldehyde Ketone Functional Group Example CH3CH2C=O CH3 – C – CH3 | || H O Propanal Acetone
  • 10. 10 Carboxylic Acid and Ester OH O | || – C = O – C – O – Carboxylic Ester Acid Functional Group Example CH3CH2C=O CH3 – C – O - CH3 | || OH O Propanoic Acid Methyl Acetate
  • 11. 11 Amine and Amide H O H | || | – N – H – C – N – H Amine Amide Functional Group Example CH3CH2CH2 CH3CH2 – C – NH2 | || NH2 O 1-Propanamine Propanamide
  • 12. 12 Practice Classify the following organic compounds according to their functional groups: CH3 CH2OH CH3 CH2NHCH3 H3C-O-CH3  Amine  Carboxylic acid  Alcohol  Ether