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PT. HYPROWIRA ADHITAMA
JL. Raya Kebayoran Lama 17D
Jakarta
Telp. 021 5361105
Fax. 021 5361517
www.hyprowira.com
1. Overview varnish
   2. Varnish and its consequences
3. Formation: Precursors and Varnish
             4. Measurement
          5. Varnish removal
How many of you have not experienced the
   following due to varnish?
  1)   Darkened color of lube oil
  2)   Increased temperatures due to cooler coatings
  3)   Plugged oil filters
  4)   Sluggish operations / sticking control valves
  5)   Accelerated rises in acid levels
  6)   Expensive system flushes and clean-out


                                       Reff: Analyst Inc   .
Thin, insoluble film deposit that forms on surfaces inside the turbine lube
system (pipes, tank, bearings heat exchanger, servo-valves, etc)

Comprised of a wide range of oil additive and thermo-oxidative
breakdown, high molecular weight compounds. Varnish precursors are
the result of breakdown from mainly:
◦ Oxidation: water, air and metallic contamination from wear
◦ Thermal stress from extreme temperatures in cases of:
        static discharge
        Micro dieseling: adiabatic compression of air bubbles


The chemical compositions of varnish precursor vary depending on the
turbine type, operating conditions and the oil type. Varnish precursors are
>75% soft particles, <1 micron

Varnish precursors are polar, and their solvency is temperature dependent
◦ Over time migrate from the oil to machine surfaces - depending on system and
  oil conditions.
Reff: Pall Corp.
                                       Varnish Precursors         +
                                                                + -- +
                                                                -
                                                Varnish
Compressor/Turbine Shaft



                                         Main bearings ( roller or journal)
                      Cooler
                Main filter                                        Solenoid valve
                   Main
                   pump
                          3500 psi Control oil filter

                                                                         To Hydraulic control
  Lube Oil Reservoir                                                     circuit
                                                                          little/no flow at turning
                                             Control oil circuit




 Hydraulic circuit:
 High VPR impact
Lube circuit Low                                                     Reff: Analyst Inc   .
VPR impact                       Inlet Vane Control         Fail open valve                  Gas valve
Contamination of critical GT control hydraulic components
◦ Fuel control valves
◦ Safety fail open valves
◦ Vane control valves

Inability to control operation, high maintenance cost for
◦ Replacement of contaminated valves
◦ Cost of chemical clean and flush

Fail to start condition: Loss of flexibility

Trip during operation: Loss of production

Downtime and lost production represent a large share of the
costs associated with poor varnish control in GT installations

                                                 Reff: Pall Corp.
Reff: Pall Corp.
All turbine oils create varnish precursors under normal operating
conditions.

The rate of generation is higher under severe / unusual operating
conditions.
◦   Oxidation
◦   Additive depletion
◦   Filter related electrostatic discharge
◦   Micro-dieseling, adiabatic compression

Recent increase in varnish related problems is attributed to:
◦   Higher operating temperatures
◦   Smaller reservoirs
◦   More peaking and cyclic service
◦   Highly refined base-stocks (Group II - lower solvency for varnish)
◦   Finer filtration resulting in electrostatic discharge

The solvency of varnish in oil is temperature dependent
◦ Transition point 54 - 57 °C
◦ Temperature falls below 54 - 57 °C in the hydraulic section
                                                              Reff: Pall Corp.
Oil has limited solvency for varnish
◦ Majority of the varnish in a turbine lube system
  is in the form of deposits
◦ Small portion of the total is suspended in the oil
◦ As the oil is cleaned up, it dissolves more
  varnish
◦ Lube system is clean when all removable
  varnish deposit is gone
Varnish deposits cause
◦ Restriction and sticking of servo valves
◦ The cost of valve replacement due to varnish is
  ~$30,000 + turbine down time costs


                                        Reff: Pall Corp.
Inside filter housing




                        Contaminated trip relay piston




                                       Reff: Pall Corp.
Pencil Filter, contaminated with varnish deposits

                                                    Servo valve spool: heavily contaminated




                                                              Reff: Pall Corp.
Have You Seen This?




  Varnish formation on a turbine bearing
                                           Reff: Analyst Inc   .
Shuttle Valve




   Plugged Filters



Compressor Gears




   Gas Turbine
       Bearing


                     Reff: Analyst Inc   .
Oil test for visc., TAN, RPVOT, metals, foam, etc will not
indicate varnish potential
Varnish forming potential of oil can be measured by:
◦   FTIR - nitration procedure
◦   Gravimetric analysis (Toluene soluble)
◦   Ultracentrifuge (~17,500 RPM for 30 minutes)
◦   0.2 – 2.0 um Particle Count (Modified ASTM D312) OR
Color patch - Quantitative Spectrophotometer Analysis (QSATM) –
Analysts Inc)
◦   Most commonly used – Draft stage ASTM procedure
◦   Measures discoloration / stain on patch
◦   Proprietary calculations determines varnish potential rating (VPR)
◦   Significant variation in VPR values between labs
◦   VPR of <35 normal - no action
◦   VPR of 38-58 - active monitoring
◦   VPR 60-79 - abnormal
◦   VPR >79 - critical - immediate action

                                                      Reff: Pall Corp.
Reff: Pall Corp.
Measurement of varnish potential does not indicate the actual
amount of varnish deposited on the surfaces of components
It measures varnish precursors in the oil

A system can be considered “varnish free” when varnish deposits
have disappeared, not necessarily when varnish potential is down.
Removal of varnish precursors from the oil displaces the solvency
equilibrium in the oil, forcing deposit to “redissolve” in the fluid,
then removed by varnish removal units. To be free of varnish,
varnish precursor measurements must be consistently low for an
extended period.

Actual clean up time depends on
◦ Efficiency of varnish precursor removal
◦ Amount of deposits already present in the system
◦ Solvency behavior of varnish in the system (site dependent –
  machine dependent – oil dependent…)


                                                   Reff: Pall Corp.
The electrostatic method (EST)
 Kidney-loop mode, off the main tank
 Oil is subjected to electrical field causing
 varnish particles to:
  ◦   charge / agglomerate to larger particles
  ◦   captured by filter mat or
  ◦   attach to charged, disposable surface
  ◦   As the oil is cleaned up, it lifts varnish deposits into the oil
      phase, cleaning the surfaces




                                                          Reff: Pall Corp.
Chemical cleaning/flushing

◦ Lube system flushing with chemicals / solvents
◦ Softens and removes insoluble materials and the flushing
  action suspends and helps remove the material by fine filters
◦ Several hours to several days
◦ System is flushed with appropriate flush fluid to remove
  residual chemicals
◦ Intensive & costly process.
◦ Allows quicker removal of deposits.
◦ Continuous monitoring and turbine shut down
◦ Cost of flushing: $50,000 to $60,000.




                                                Reff: Pall Corp.
The adsorption method:
◦ Utilizes large surface area, high void volume
◦ Low fluxes allow proper residence time for adsorption
◦ Electro-chemical affinity of the filter media for varnish
  particles is a KPI
                                             Particles captured by adsorption, eg
                                             varnish precursors
                                             Particles captured by direct
                                             interception, eg wear metals




                                             Reff: Pall Corp.

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Varnish in turbine lube

  • 1. PT. HYPROWIRA ADHITAMA JL. Raya Kebayoran Lama 17D Jakarta Telp. 021 5361105 Fax. 021 5361517 www.hyprowira.com
  • 2. 1. Overview varnish 2. Varnish and its consequences 3. Formation: Precursors and Varnish 4. Measurement 5. Varnish removal
  • 3. How many of you have not experienced the following due to varnish? 1) Darkened color of lube oil 2) Increased temperatures due to cooler coatings 3) Plugged oil filters 4) Sluggish operations / sticking control valves 5) Accelerated rises in acid levels 6) Expensive system flushes and clean-out Reff: Analyst Inc .
  • 4. Thin, insoluble film deposit that forms on surfaces inside the turbine lube system (pipes, tank, bearings heat exchanger, servo-valves, etc) Comprised of a wide range of oil additive and thermo-oxidative breakdown, high molecular weight compounds. Varnish precursors are the result of breakdown from mainly: ◦ Oxidation: water, air and metallic contamination from wear ◦ Thermal stress from extreme temperatures in cases of: static discharge Micro dieseling: adiabatic compression of air bubbles The chemical compositions of varnish precursor vary depending on the turbine type, operating conditions and the oil type. Varnish precursors are >75% soft particles, <1 micron Varnish precursors are polar, and their solvency is temperature dependent ◦ Over time migrate from the oil to machine surfaces - depending on system and oil conditions. Reff: Pall Corp. Varnish Precursors + + -- + - Varnish
  • 5. Compressor/Turbine Shaft Main bearings ( roller or journal) Cooler Main filter Solenoid valve Main pump 3500 psi Control oil filter To Hydraulic control Lube Oil Reservoir circuit little/no flow at turning Control oil circuit Hydraulic circuit: High VPR impact Lube circuit Low Reff: Analyst Inc . VPR impact Inlet Vane Control Fail open valve Gas valve
  • 6. Contamination of critical GT control hydraulic components ◦ Fuel control valves ◦ Safety fail open valves ◦ Vane control valves Inability to control operation, high maintenance cost for ◦ Replacement of contaminated valves ◦ Cost of chemical clean and flush Fail to start condition: Loss of flexibility Trip during operation: Loss of production Downtime and lost production represent a large share of the costs associated with poor varnish control in GT installations Reff: Pall Corp.
  • 8. All turbine oils create varnish precursors under normal operating conditions. The rate of generation is higher under severe / unusual operating conditions. ◦ Oxidation ◦ Additive depletion ◦ Filter related electrostatic discharge ◦ Micro-dieseling, adiabatic compression Recent increase in varnish related problems is attributed to: ◦ Higher operating temperatures ◦ Smaller reservoirs ◦ More peaking and cyclic service ◦ Highly refined base-stocks (Group II - lower solvency for varnish) ◦ Finer filtration resulting in electrostatic discharge The solvency of varnish in oil is temperature dependent ◦ Transition point 54 - 57 °C ◦ Temperature falls below 54 - 57 °C in the hydraulic section Reff: Pall Corp.
  • 9. Oil has limited solvency for varnish ◦ Majority of the varnish in a turbine lube system is in the form of deposits ◦ Small portion of the total is suspended in the oil ◦ As the oil is cleaned up, it dissolves more varnish ◦ Lube system is clean when all removable varnish deposit is gone Varnish deposits cause ◦ Restriction and sticking of servo valves ◦ The cost of valve replacement due to varnish is ~$30,000 + turbine down time costs Reff: Pall Corp.
  • 10. Inside filter housing Contaminated trip relay piston Reff: Pall Corp.
  • 11. Pencil Filter, contaminated with varnish deposits Servo valve spool: heavily contaminated Reff: Pall Corp.
  • 12.
  • 13. Have You Seen This? Varnish formation on a turbine bearing Reff: Analyst Inc .
  • 14. Shuttle Valve Plugged Filters Compressor Gears Gas Turbine Bearing Reff: Analyst Inc .
  • 15. Oil test for visc., TAN, RPVOT, metals, foam, etc will not indicate varnish potential Varnish forming potential of oil can be measured by: ◦ FTIR - nitration procedure ◦ Gravimetric analysis (Toluene soluble) ◦ Ultracentrifuge (~17,500 RPM for 30 minutes) ◦ 0.2 – 2.0 um Particle Count (Modified ASTM D312) OR Color patch - Quantitative Spectrophotometer Analysis (QSATM) – Analysts Inc) ◦ Most commonly used – Draft stage ASTM procedure ◦ Measures discoloration / stain on patch ◦ Proprietary calculations determines varnish potential rating (VPR) ◦ Significant variation in VPR values between labs ◦ VPR of <35 normal - no action ◦ VPR of 38-58 - active monitoring ◦ VPR 60-79 - abnormal ◦ VPR >79 - critical - immediate action Reff: Pall Corp.
  • 17.
  • 18. Measurement of varnish potential does not indicate the actual amount of varnish deposited on the surfaces of components It measures varnish precursors in the oil A system can be considered “varnish free” when varnish deposits have disappeared, not necessarily when varnish potential is down. Removal of varnish precursors from the oil displaces the solvency equilibrium in the oil, forcing deposit to “redissolve” in the fluid, then removed by varnish removal units. To be free of varnish, varnish precursor measurements must be consistently low for an extended period. Actual clean up time depends on ◦ Efficiency of varnish precursor removal ◦ Amount of deposits already present in the system ◦ Solvency behavior of varnish in the system (site dependent – machine dependent – oil dependent…) Reff: Pall Corp.
  • 19. The electrostatic method (EST) Kidney-loop mode, off the main tank Oil is subjected to electrical field causing varnish particles to: ◦ charge / agglomerate to larger particles ◦ captured by filter mat or ◦ attach to charged, disposable surface ◦ As the oil is cleaned up, it lifts varnish deposits into the oil phase, cleaning the surfaces Reff: Pall Corp.
  • 20. Chemical cleaning/flushing ◦ Lube system flushing with chemicals / solvents ◦ Softens and removes insoluble materials and the flushing action suspends and helps remove the material by fine filters ◦ Several hours to several days ◦ System is flushed with appropriate flush fluid to remove residual chemicals ◦ Intensive & costly process. ◦ Allows quicker removal of deposits. ◦ Continuous monitoring and turbine shut down ◦ Cost of flushing: $50,000 to $60,000. Reff: Pall Corp.
  • 21. The adsorption method: ◦ Utilizes large surface area, high void volume ◦ Low fluxes allow proper residence time for adsorption ◦ Electro-chemical affinity of the filter media for varnish particles is a KPI Particles captured by adsorption, eg varnish precursors Particles captured by direct interception, eg wear metals Reff: Pall Corp.