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CHAPTER 1:
INTRODUCTION
Instructor: Phan Thi Thu Ha, MSc.
Thai Nguyen University of Technology
Overview
• Definition
• Characteristics
• Classification
- Particle-reinforced composites
- Fiber-reinforced composites
+ Matrix
+ Fibers
- Structural composites
• Some common types of composites:
- Polymer matrix composites
- Metal matrix composites
- Ceramic matrix composites
- Carbon-carbon composites
• Manufacturing techniques
• Applications
Definition
What is a composite?
• A composite material is made by combining 2 or more
distinct materials to give an unique and better
combination of properties.
• Distinct materials:
- Different at the molecular level (chemically
dissimilar) and mechanically separable.
- In bulk form, the constituent materials work
together but remain in their original forms (separated by a
distinct interface)
• Constituents: Matrix and reinforcing phase
Composite Characteristics
Advantages:
• Low density
• High specific stiffness (stiffness-to-density ratio)
• Very high specific strength (strength-to-density ratio).
• Much higher fatigue strength
• High corrosion resistance
• Design flexibility
• Good impact properties
• Noise, vibration, and harshness characteristics are better for
CM than metals
• Data adapted from Marllick
Disadvantages:
• Materials cost
• Manufacturing suitable for high production rates
• Lack of database
• Low temperature resistance
• Low resistance to solvents, environmental stress cracking
• Absorb moisture
Classification of composite types
Large-
particle
Dispersion-
strengthened
Particle-reinforced
Continuous
(aligned)
Aligned Randomly
oriented
Discontinuous
(short)
Fiber-reinforced
Laminates Sandwich
panels
Structural
Composites
Particle-reinforced composites
• Large-particle composites
- Concrete
• Dispersion-strengthened composites
Fiber-reinforced composites
• Are the most important composites
• Design goals:
- Low density;
- High specific strength;
- High specific modulus.
• Constituents: - Fibers and matrix
- Agents, coatings.
Fibers
• Characteristics:
- Principal constituents;
- Occupy the largest volume fraction;
- Share the major portion of the load acting.
• Design considerations:
- fiber type, fiber volume fraction, fiber length, fiber
orientation.
• Some common fiber types:
- Glass fiber, carbon fiber, aramid fiber, boron fiber,
ceramic fiber, etc.
• Tensile stress-strain for reinforcing fibers:
Matrix
• Roles:
- Keep fibers in place;
- Transfer stress between fibers;
- Provide a barrier against an adverse environment
(chemicals, moisture)
- Protect the surface of fibers (by abrasion)
- Minor role in the tensile load-carrying capacity, but major
influence on the compressive, inter-laminar shear, in-
plane shear, buckling, etc.
• Types of matrix:
- Polymer matrix, metal matrix, ceramic matrix
Polymer matrix
• Thermoset vs Thermoplastic
• Thermoset (resins):
- Examples: epoxy, polyester, and vinyl ester
- Used as matrix in continuous or long fiber-reinforced
composites
- Molecules are joined by cross-links  rigid, 3-D network
structure. Once cross-links are formed, it cannot be melted
by heat.
- Long fabrication time.
(curing)
• Thermal plastics:
- Examples: PVC, PS, PP
- Individual molecules are not chemically joined together;
- Held in place by Van der Waals bonds and hydrogen bonds
that can be broken by heat;
- Heat-softened, melted, and reshaped as many times as
desired.
Polymer-matrix Composites (PMC)
Matrix: Polymer resin
Reinforcement: Fibers
• Glass fiber-reinforced polymer composites
• Carbon fiber-reinforced polymer composites
• Aramid fiber-reinforced polymer composites
Glass fiber-reinforced polymer composites
• Glass is popular as a fiber reinforcement because:
- Easily drawn into high-strength fibers;
- Relatively strong  very high specific strength
composites
- Inertness with various plastics
- E-glass, C-glass, S-glass
• High strength but not very stiff and rigid enough for some
applications such as: structure members for airplanes and
bridges
• Limited to services temperatures, below 200C ( t 
polyimide resins)
• Applications: automotive and marine bodies, storage
containers, industrial flooring, etc.
Carbon fiber-reinforced polymer composites
• Carbon characteristics:
- Very high specific moduli and specific strengths (207-
1035 Gpa);
- Retain characteristics at elevated temperatures, high-
temperature oxidation;
- Not affected by moisture, inert with variety of solvents
Metal-matrix composites
• Matrix:
- Ductile material (alloys of Al, Ti, Mg, Cu, etc.)
• Reinforcement:
- Continuous fiber: carbon, silicon carbide (SiC), boron,
Al2O3
- Discontinuous reinforcement: SiC whiskers, chopped fibers
of Al2O3
- Particulates: SiC, Al2O3
• Advantages:
- Higher operating temperatures;
- No flammability;
- Greater resistance
Disadvantages:
- Much more expensive than PMC
- Reactions between matrix and reinforcement at elevated
temperatures  composite degradation  surface coating
or modifying the matrix alloy composition.
• Applications:
- Aerospace industry: Aluminum-alloy metal matrix
composites
Ceramic-matrix composites
Particulates, fibers or whiskers of one ceramic are
embedded into a matrix of another ceramic.
Improve significantly fracture toughness
Fracture toughness is the ability of a material
containing a crack to resist fracture.
• Applications:
- In high-temperature and severe-stress applications :
Components in automobile and aircraft gas turbine engine
Carbon-Carbon composites
• Carbon fiber-reinforced carbon-matrix composites
• Advantages:
- High tensile moduli and tensile strength;
- Retained to temperatures in excess of 2000C;
- Resistance to creep;
- Relatively large fracture toughness;
- Low coefficient of thermal expansion; and high thermal
conductivity
Drawbacks:
- High-temperature oxidation
- Expensive
Manufacturing Techniques
- The hand layup technique
- The industrial manufacturing technique:
+ Compression molding, pultrusion, filament winding,
Resin transfer molding, etc.
+ Curing
+ Prepreg
Applications
• The US composite materials market forecast
The Aerospace Industry
• Automotive industry
- Glass fiber
• Sporting goods industry
• Marine Applications
• Consumer goods
- Short fiber composites
• Construction and civil structures
Quiz 1
1/ What is a composite material? Give 3 examples of
composite materials, show the matrix and reinforcing phase
in these examples.
2/ What are the functions of: Matrix, Fibers, Agents and
coatings in composites
3/ List 5 general characteristics of composite materials?
4/ What are 2 main and important differences between
polymer-matrix composites and metal-matrix composite.

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Ch1 introduction

  • 1. CHAPTER 1: INTRODUCTION Instructor: Phan Thi Thu Ha, MSc. Thai Nguyen University of Technology
  • 2. Overview • Definition • Characteristics • Classification - Particle-reinforced composites - Fiber-reinforced composites + Matrix + Fibers - Structural composites • Some common types of composites: - Polymer matrix composites - Metal matrix composites - Ceramic matrix composites - Carbon-carbon composites • Manufacturing techniques • Applications
  • 3. Definition What is a composite? • A composite material is made by combining 2 or more distinct materials to give an unique and better combination of properties. • Distinct materials: - Different at the molecular level (chemically dissimilar) and mechanically separable. - In bulk form, the constituent materials work together but remain in their original forms (separated by a distinct interface) • Constituents: Matrix and reinforcing phase
  • 4. Composite Characteristics Advantages: • Low density • High specific stiffness (stiffness-to-density ratio) • Very high specific strength (strength-to-density ratio). • Much higher fatigue strength • High corrosion resistance • Design flexibility • Good impact properties • Noise, vibration, and harshness characteristics are better for CM than metals
  • 5. • Data adapted from Marllick
  • 6. Disadvantages: • Materials cost • Manufacturing suitable for high production rates • Lack of database • Low temperature resistance • Low resistance to solvents, environmental stress cracking • Absorb moisture
  • 7. Classification of composite types Large- particle Dispersion- strengthened Particle-reinforced Continuous (aligned) Aligned Randomly oriented Discontinuous (short) Fiber-reinforced Laminates Sandwich panels Structural Composites
  • 8. Particle-reinforced composites • Large-particle composites - Concrete • Dispersion-strengthened composites
  • 9. Fiber-reinforced composites • Are the most important composites • Design goals: - Low density; - High specific strength; - High specific modulus. • Constituents: - Fibers and matrix - Agents, coatings.
  • 10. Fibers • Characteristics: - Principal constituents; - Occupy the largest volume fraction; - Share the major portion of the load acting. • Design considerations: - fiber type, fiber volume fraction, fiber length, fiber orientation. • Some common fiber types: - Glass fiber, carbon fiber, aramid fiber, boron fiber, ceramic fiber, etc.
  • 11. • Tensile stress-strain for reinforcing fibers:
  • 12. Matrix • Roles: - Keep fibers in place; - Transfer stress between fibers; - Provide a barrier against an adverse environment (chemicals, moisture) - Protect the surface of fibers (by abrasion) - Minor role in the tensile load-carrying capacity, but major influence on the compressive, inter-laminar shear, in- plane shear, buckling, etc. • Types of matrix: - Polymer matrix, metal matrix, ceramic matrix
  • 13. Polymer matrix • Thermoset vs Thermoplastic • Thermoset (resins): - Examples: epoxy, polyester, and vinyl ester - Used as matrix in continuous or long fiber-reinforced composites - Molecules are joined by cross-links  rigid, 3-D network structure. Once cross-links are formed, it cannot be melted by heat. - Long fabrication time. (curing)
  • 14. • Thermal plastics: - Examples: PVC, PS, PP - Individual molecules are not chemically joined together; - Held in place by Van der Waals bonds and hydrogen bonds that can be broken by heat; - Heat-softened, melted, and reshaped as many times as desired.
  • 15. Polymer-matrix Composites (PMC) Matrix: Polymer resin Reinforcement: Fibers • Glass fiber-reinforced polymer composites • Carbon fiber-reinforced polymer composites • Aramid fiber-reinforced polymer composites
  • 16. Glass fiber-reinforced polymer composites • Glass is popular as a fiber reinforcement because: - Easily drawn into high-strength fibers; - Relatively strong  very high specific strength composites - Inertness with various plastics - E-glass, C-glass, S-glass • High strength but not very stiff and rigid enough for some applications such as: structure members for airplanes and bridges • Limited to services temperatures, below 200C ( t  polyimide resins) • Applications: automotive and marine bodies, storage containers, industrial flooring, etc.
  • 17. Carbon fiber-reinforced polymer composites • Carbon characteristics: - Very high specific moduli and specific strengths (207- 1035 Gpa); - Retain characteristics at elevated temperatures, high- temperature oxidation; - Not affected by moisture, inert with variety of solvents
  • 18. Metal-matrix composites • Matrix: - Ductile material (alloys of Al, Ti, Mg, Cu, etc.) • Reinforcement: - Continuous fiber: carbon, silicon carbide (SiC), boron, Al2O3 - Discontinuous reinforcement: SiC whiskers, chopped fibers of Al2O3 - Particulates: SiC, Al2O3 • Advantages: - Higher operating temperatures; - No flammability; - Greater resistance
  • 19. Disadvantages: - Much more expensive than PMC - Reactions between matrix and reinforcement at elevated temperatures  composite degradation  surface coating or modifying the matrix alloy composition. • Applications: - Aerospace industry: Aluminum-alloy metal matrix composites
  • 20. Ceramic-matrix composites Particulates, fibers or whiskers of one ceramic are embedded into a matrix of another ceramic. Improve significantly fracture toughness Fracture toughness is the ability of a material containing a crack to resist fracture. • Applications: - In high-temperature and severe-stress applications : Components in automobile and aircraft gas turbine engine
  • 21. Carbon-Carbon composites • Carbon fiber-reinforced carbon-matrix composites • Advantages: - High tensile moduli and tensile strength; - Retained to temperatures in excess of 2000C; - Resistance to creep; - Relatively large fracture toughness; - Low coefficient of thermal expansion; and high thermal conductivity Drawbacks: - High-temperature oxidation - Expensive
  • 23. - The hand layup technique - The industrial manufacturing technique: + Compression molding, pultrusion, filament winding, Resin transfer molding, etc. + Curing + Prepreg
  • 24. Applications • The US composite materials market forecast
  • 26. • Automotive industry - Glass fiber • Sporting goods industry • Marine Applications • Consumer goods - Short fiber composites • Construction and civil structures
  • 27. Quiz 1 1/ What is a composite material? Give 3 examples of composite materials, show the matrix and reinforcing phase in these examples. 2/ What are the functions of: Matrix, Fibers, Agents and coatings in composites 3/ List 5 general characteristics of composite materials? 4/ What are 2 main and important differences between polymer-matrix composites and metal-matrix composite.