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 Kenaf (Hibiscus cannabinus L.) is an annual, dicot
herbaceous crop, originally grown in Africa. It is a
fiber-crop used for bio-products such as rope, paper
pulp, textile, or biocomposite.
 Kenaf could be a source of lignocellulosic biomass
for energy production due to its unusual stem
anatomy (Fig. 1).
 Midwest studies on growth and use of kenaf
have been scant; however, kenaf may have
potential as an alternative crop for Iowa and the
Midwest.
Variety trial and pyrolysis
potential on kenaf grown
in Iowa
METHODS
I would like to thank my major
professor, my committee
members, the Department, the lab
and the field research assistants.
Marie Bourguignon 1, Ken J. Moore1, Robert Brown2, Roger Hintz1, Brian Baldwin3,
Kwang H. Kim2.
1 Dept of Agronomy, Iowa State University
2 Bioeconomy Institute, Iowa State University
3 Plant & Soil Sciences, Mississippi State University
BACKGROUND
CONCLUSION
AcknowledgementsOverall:
 Tainung 2 was the most productive variety in Central Iowa from 2004 to 2007.
 There were variations among varieties regarding the lignocellulosic composition, providing choice for intended fiber purposes.
 Depending on the variety and/or the fiber category, the pyrolysis compounds could be produced in different quantity.
 In general, bast and core could be used for fuel or chemical production but further work is needed.
1
2
RESULTS3
4
Objectives:
1) How do kenaf varieties perform in Iowa for yield?
2) How does fiber morphology and quality differ among
varieties and among core and bast fiber?
3) What potential does kenaf (bast or core) have for
producing fuel using fast pyrolysis?
Figure 1: Anatomy of kenaf fibers.
Seven kenaf varieties were grown at the Iowa State
University Agronomy and Agricultural Engineering
Research Farm in Boone County, IA between 2004
and 2007.
 Kenaf can yield 10
to 20 Mg ha-1 in 5 to
7 months with low
input.
 India and China are
the leaders in kenaf
production. In the
U.S., kenaf is mostly
grown in Southern
U.S.
Experimental
design
RCDB, 4 replications
Row spacing 38 cm
Seeding density 247,105 seed.ha-1
N 168 kg.ha-1
Biomass
(2004 – 2007)
Wet/dry weight
Morphology
(2004 – 2005)
Leaf:stem ratio, stem height, diameter,
core:bast ratio
Fiber and ash
(2004 – 2005)
ANKOM procedure for NDF, ADF, ADL
and insoluble ash
Ash composition
(2004 – 2005)
ICP-OES
Micro fast pyrolysis
(2004 – 2005)
Pyrolyzer (30 sec at 500 °C), gas
chromatography and flame ionization
detector.
Statistical analysis ANOVA, 5% level of significance
Table 1: Experimental design, measurements, and statistical analysis.
Figure 2: Average yield per kenaf variety over 2004 – 2007 (letters denote differences between
varieties).
Objective 1: Field performance in Iowa
The crop yield and population were higher in 2005 with 11 Mg ha-1 and
163,000 plants ha-1, respectively.
Yield (Fig. 2) and population varied among varieties but in different
ways.
In general, kenaf yields were slightly lower than what has been shown
in the literature. Also, final population was approximately half of the
initial seeding density.
Figure 4: Cellulose, hemicellulose and lignin concentration in
bast and core of each variety, over 2004 and 2005 (letters
denote differences between varieties). Stars indicate the
dominance of the variety for total ash.
Figure 3: Average stem height (A) and average
core:bast ratio (B) per kenaf variety over 2004 –
2007 (letters denote differences).
Figure 5: Ca, K, Mg and S (DM %) that were significantly
influenced by the variety (letters denote differences
between varieties for each element).
Objective 3: Fast pyrolysis
potential
Kenaf could be also used for
chemical production. The
chemical analysis showed that
there were some “pollutants”
due to ash content (Table 1).
There was a tradeoff between
levoglucosan and
hydroxyacetone.
Pyrolysis product Effect
Yield
(wt %)
acetic acid Y*F 1.95
furfural Y*F*V 0.13
hydroxy acetone Y*F, F*V 0.86
methyl
cyclopentelonone
F, Y*V 0.03
5-HMF Y*F*V 0.33
levoglucosan Y*F*V 1.25
4-ethylphenol Y*F*V 0.01
4-vinylphenol Y*F*V 0.18
2-methoxy-4-
vinylphenol
Y*F*V 0.32
2,6-dimethoxyphenol Y*F*V 0.07
vanillin Y*F 0.02
4-hydroxy-3-
methoxyacetopheno
ne
F 0.02
2,6-dimethoxy-4-(1-
propenyl) phenol
Y*F 0.02
Table 1: List of hemicellulose (gray),
cellulose (white) and lignin (light gray)
pyrolysis products, influenced by year (Y),
fiber category (F) and/or variety (V), and
their yield.
Core
Short and
porous fibers
Bast
Long and
valuable fibers
StemHeight(cm)
0
50
100
150
200
250
300
Dowling
Everglades 41
Everglades 71
Gregg
SF459
Tainung 2
Whitten
Core:BastRatio
0.0
0.5
1.0
1.5
2.0
2.5
A
B
a
bc c c
bc
c
b
a
b c d e e
a
Ca K Mg S
Concentration(mgg-1,DM)
0
1
2
3
4
5
6
7
Dowling
Everglades 41
Gregg
Tainung 2
Whitten
bc
ab a
c
bc
ab
c
ab
bc
a
ab
b
a
b
ab
abc
bc
a
c
ab
Objective 2: Fiber quantity and quality
Plants grown and processed in 2004 had
10% more leaves, were 16% thicker but
had 9% less core than in 2005.
Stem height, core:bast ratio (Fig. 3) and
fiber composition (Fig. 4) presented
diversity among varieties, providing
choice for intended fiber purposes.
On average, the bast contained 9% more
cellulose, 23% less hemicellulose, 41%
less lignin and 18% less insoluble ash but
63% more total ash than the core. Bast
had higher concentration of Ca, Fe, Mg
and S in its ash than in the core. Ca, K,
Mg and S concentrations, however,
depended on the variety (Fig. 5).
BAST
Dowling
Everglades 41
Everglades 71
Gregg
SF459
Tainung 2
W
hitten
Dowling
Everglades 41
Everglades 71
Gregg
SF459
Tainung 2
W
hitten
LignocellulosicConcentration(DM%)
0
20
40
60
80
100
Cellulose
Hemicellulose
Lignin
CORE
a aab acbcc
bc abc abbab
Dowling
Everglades 41
Everglades 71
Gregg
SF459
Tainung 2
Whitten
Yield(Mgha-1)
0
2
4
6
8
10
12
14
ab ab
b
b
b
a
b

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Poster - Variety Trial - Marie Bourguignon

  • 1.  Kenaf (Hibiscus cannabinus L.) is an annual, dicot herbaceous crop, originally grown in Africa. It is a fiber-crop used for bio-products such as rope, paper pulp, textile, or biocomposite.  Kenaf could be a source of lignocellulosic biomass for energy production due to its unusual stem anatomy (Fig. 1).  Midwest studies on growth and use of kenaf have been scant; however, kenaf may have potential as an alternative crop for Iowa and the Midwest. Variety trial and pyrolysis potential on kenaf grown in Iowa METHODS I would like to thank my major professor, my committee members, the Department, the lab and the field research assistants. Marie Bourguignon 1, Ken J. Moore1, Robert Brown2, Roger Hintz1, Brian Baldwin3, Kwang H. Kim2. 1 Dept of Agronomy, Iowa State University 2 Bioeconomy Institute, Iowa State University 3 Plant & Soil Sciences, Mississippi State University BACKGROUND CONCLUSION AcknowledgementsOverall:  Tainung 2 was the most productive variety in Central Iowa from 2004 to 2007.  There were variations among varieties regarding the lignocellulosic composition, providing choice for intended fiber purposes.  Depending on the variety and/or the fiber category, the pyrolysis compounds could be produced in different quantity.  In general, bast and core could be used for fuel or chemical production but further work is needed. 1 2 RESULTS3 4 Objectives: 1) How do kenaf varieties perform in Iowa for yield? 2) How does fiber morphology and quality differ among varieties and among core and bast fiber? 3) What potential does kenaf (bast or core) have for producing fuel using fast pyrolysis? Figure 1: Anatomy of kenaf fibers. Seven kenaf varieties were grown at the Iowa State University Agronomy and Agricultural Engineering Research Farm in Boone County, IA between 2004 and 2007.  Kenaf can yield 10 to 20 Mg ha-1 in 5 to 7 months with low input.  India and China are the leaders in kenaf production. In the U.S., kenaf is mostly grown in Southern U.S. Experimental design RCDB, 4 replications Row spacing 38 cm Seeding density 247,105 seed.ha-1 N 168 kg.ha-1 Biomass (2004 – 2007) Wet/dry weight Morphology (2004 – 2005) Leaf:stem ratio, stem height, diameter, core:bast ratio Fiber and ash (2004 – 2005) ANKOM procedure for NDF, ADF, ADL and insoluble ash Ash composition (2004 – 2005) ICP-OES Micro fast pyrolysis (2004 – 2005) Pyrolyzer (30 sec at 500 °C), gas chromatography and flame ionization detector. Statistical analysis ANOVA, 5% level of significance Table 1: Experimental design, measurements, and statistical analysis. Figure 2: Average yield per kenaf variety over 2004 – 2007 (letters denote differences between varieties). Objective 1: Field performance in Iowa The crop yield and population were higher in 2005 with 11 Mg ha-1 and 163,000 plants ha-1, respectively. Yield (Fig. 2) and population varied among varieties but in different ways. In general, kenaf yields were slightly lower than what has been shown in the literature. Also, final population was approximately half of the initial seeding density. Figure 4: Cellulose, hemicellulose and lignin concentration in bast and core of each variety, over 2004 and 2005 (letters denote differences between varieties). Stars indicate the dominance of the variety for total ash. Figure 3: Average stem height (A) and average core:bast ratio (B) per kenaf variety over 2004 – 2007 (letters denote differences). Figure 5: Ca, K, Mg and S (DM %) that were significantly influenced by the variety (letters denote differences between varieties for each element). Objective 3: Fast pyrolysis potential Kenaf could be also used for chemical production. The chemical analysis showed that there were some “pollutants” due to ash content (Table 1). There was a tradeoff between levoglucosan and hydroxyacetone. Pyrolysis product Effect Yield (wt %) acetic acid Y*F 1.95 furfural Y*F*V 0.13 hydroxy acetone Y*F, F*V 0.86 methyl cyclopentelonone F, Y*V 0.03 5-HMF Y*F*V 0.33 levoglucosan Y*F*V 1.25 4-ethylphenol Y*F*V 0.01 4-vinylphenol Y*F*V 0.18 2-methoxy-4- vinylphenol Y*F*V 0.32 2,6-dimethoxyphenol Y*F*V 0.07 vanillin Y*F 0.02 4-hydroxy-3- methoxyacetopheno ne F 0.02 2,6-dimethoxy-4-(1- propenyl) phenol Y*F 0.02 Table 1: List of hemicellulose (gray), cellulose (white) and lignin (light gray) pyrolysis products, influenced by year (Y), fiber category (F) and/or variety (V), and their yield. Core Short and porous fibers Bast Long and valuable fibers StemHeight(cm) 0 50 100 150 200 250 300 Dowling Everglades 41 Everglades 71 Gregg SF459 Tainung 2 Whitten Core:BastRatio 0.0 0.5 1.0 1.5 2.0 2.5 A B a bc c c bc c b a b c d e e a Ca K Mg S Concentration(mgg-1,DM) 0 1 2 3 4 5 6 7 Dowling Everglades 41 Gregg Tainung 2 Whitten bc ab a c bc ab c ab bc a ab b a b ab abc bc a c ab Objective 2: Fiber quantity and quality Plants grown and processed in 2004 had 10% more leaves, were 16% thicker but had 9% less core than in 2005. Stem height, core:bast ratio (Fig. 3) and fiber composition (Fig. 4) presented diversity among varieties, providing choice for intended fiber purposes. On average, the bast contained 9% more cellulose, 23% less hemicellulose, 41% less lignin and 18% less insoluble ash but 63% more total ash than the core. Bast had higher concentration of Ca, Fe, Mg and S in its ash than in the core. Ca, K, Mg and S concentrations, however, depended on the variety (Fig. 5). BAST Dowling Everglades 41 Everglades 71 Gregg SF459 Tainung 2 W hitten Dowling Everglades 41 Everglades 71 Gregg SF459 Tainung 2 W hitten LignocellulosicConcentration(DM%) 0 20 40 60 80 100 Cellulose Hemicellulose Lignin CORE a aab acbcc bc abc abbab Dowling Everglades 41 Everglades 71 Gregg SF459 Tainung 2 Whitten Yield(Mgha-1) 0 2 4 6 8 10 12 14 ab ab b b b a b