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The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
	
	
	
WORKING	TOWARDS	A	SECOND	LIFE	FOR		
CRITICAL	RAW	MATERIALS	IN	GERMANY	
	
	
Each	year	millions	of	tonnes	of	waste	electrical	and	electronic	equipment	(WEEE)	is	
generated	in	the	EU,	but	only	30%	is	reported	as	properly	collected	and	recycled.		The	
Critical	Raw	Materials	(CRM)	Closed	Loop	Recovery	Project	aims	to	increase	the	
recovery	of	target	materials	by	5%	by	2020	and	by	20%	by	2030.		
	
With	this	in	mind	the	project	has	invested	in	trials	exploring	novel	ways	of	boosting	the	
collection	and	recovery	of	CRMs	from	household	WEEE.			
	
Held	across	the	UK,	Italy,	Germany	and	the	Czech	Republic,	the	collection	trials	
mechanisms	included	retailer	take-back	schemes;	re-use	containers	at	household	waste	
recycling	centres,	business	collections,	university	drop-off	hubs,	school	collections	and	
other	collection	events.			
	
PROMOTING	RECOVERY	IN	GERMANY	
RecyclingBörse	(also	known	as	‘AKR’),	based	in	North	Rhine-Westphalia	in	Germany,	
collects	and	re-markets	used	products	in	its	own	second-hand	shops	across	the	region	
and	also	runs	a	certified	WEEE	recycling	facility.		
	
AKR	is	an	independent	and	not-for-profit	organisation,	with	a	mission	to	promote	re-
use.		It	also	has	the	capability	to	test	and	evaluate	collected	WEEE	items	according	to	
technical	and	market	criteria.
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
METHODOLOGY	
	
This	trial	was	focussed	on	the	recovery	of	tantalum	(Ta),	commonly	used	in	the	
electronics	industry	for	capacitors	and	high	power	resistors,	and	neodymium	(Nd),	
commonly	used	as	an	alloy	within	magnets	and	within	everyday	household	items,	such	
PCs,	laptops	and	smartphones.	
	
	
	
	
	
	
Notes:	
Tantalum	Recovery
Input	materials:	
capcacitors	and	printed	
circuit	boards	(PCBs)
Activity	undertaken	by	
TUHH	(Hamburg	
University	of	
Technology)	with	
support	by	Faunhofer	
Project	Group	IWKS
Removing	Ta	capacitors	
from	PCBs	by	EHF	
(electrohydraulic	
fragmentation)	
Bio-leaching	processes	
used	to	recover	Ta	from	
capacitors
Neodymium	
Recovery
Input	materials:	magnets
Activity	undertaken	by	
Fraunhofer	Project	Group	
IWKS		
Hydrogen	decrepitation	
process	used	to	separate
rare	earth	permanent	
magnets	from	metal	
plates	
Rapid	quenching	(melt-
spinning)	process	used	to	
form	rare	earth	flakes
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
The	bio-leaching	trials	for	Ta	are	classed	as	very	early-stage,	as	it	is	a	metal	which	cannot	be	
leached	even	by	aqua	regia,	and	there	is	almost	no	existing	literature	for	Ta	bio-leaching.		As	the	
bio-leaching	process	does	not	require	or	produce	highly	toxic	or	highly	corrosive	chemicals,	the	
downstream	processes,	including	the	metal-removing	from	liquid	phase	and	waste	water	treatment,	
would	cause	much	lower	environmental	impacts.		
	
LINK	BETWEEN	COLLECTION	AND	RECOVERY	TRIALS	
The	below	table	demonstrates	the	overall	recovery	potential	of	Ta	and	Nd	based	on	the	
collection	and	recovery	trials.		The	trial	activities	listed	are	described	within	the	AKR	
collection	case	study.1	Note:	The	recovery	trials	were	focused	on	good	accessibility	and	
identifiability	of	Ta	and	Nd	containing	components.	Therefore,	only	the	number	of	PCs	and	
laptops	are	taken	into	consideration.		
	
	
TRIAL	RESULTS	
1
http://www.criticalrawmaterialrecovery.eu/three-ways-to-get-great-weee-recycling-results		
NUMBER	OF	COLLECTED	ITEMS	WITH	PRINCIPAL	TANTALUM	
AND	NEODYMIUM	POTENTIAL	
WEEE	Item	
Collection	Trial	Activity	
	
		
Re-use	
Olympics	
Schools	
	
Re-Bag	
	
Re-Box	
	
Total	
	
Recovery	
Potential	
PC		 32	 Zero	 Zero	 32	 Ta,	Nd	
Laptop		 4	 Zero	 Zero	 4	 Ta,	Nd	
Mobile	phone		 36	 20	 1	 57	 Ta,	Nd	
Smartphone		 30	 3	 Zero	 33	 Ta,	Nd	
Tablet		 11	 3	 Zero	 14	 Ta
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
	
• The	recovery	potential	per	unit	(laptop	or	PC),	depending	on	the	length	of	the	
leaching	process,	is	promising.		This	is	especially	the	case,	given	that	the	industry	
standard	for	extraction	of	Ta	in	the	current	treatment	of	PCBs	in	a	smelter	route	is	
zero.		
	
Length	of	leaching	process	 Leaching	ratio	 Tantalum	recovery	potential	
70	days	 13.74%	 0.0011g	
15	days	 5.31%	 0.0004g	
	
Table	2:		Ta	recovery	potential	per	unit	(PC	or	laptop).		
	
• The	recovery	potential	of	Nd	from	magnets	is	also	positive.		For	a	single	Hard	Disk	
Drive	(HDD)	with	a	10.1g	magnet	of	the	Voice	Coil	Motor	(VCM),	0.65g	of	Nd	is	
recoverable.		The	recovered	amount	of	Nd	during	the	trial	also	determined	the	
technical	recovery	potential	of	magnet	flakes	that	are	directly	usable	in	a	magnet	
production.		Since	there	is	no	practical	process	existing	in	Europe,	this	figure	is	an	
important	footnote	that	could	stimulate	further	technological	advances	towards	the	
removal	of	VCM	magnets	from	HDDs.		
	
	
LESSONS	LEARNT	
	
Commercial	
	
• With	regard	to	the	recovery	of	Nd	from	HDDs,	there	is	currently	no	recycling	
process	implemented	in	Europe	for	magnet	recycling/recovery.		Thus,	the	
commercial	viability	can	be	evaluated	only	roughly	by	comparison	with	the	
estimated	costs	of	the	production	and	pricing	of	magnets	imported	from	China.		
Currently,	the	assumed	price	of	magnets	from	China	is	about	60€/kg.		Based	on	
indicative	assessments	of	the	recovery	trials	for	this	project,	the	cost	of	producing	
1kg	magnet	material	from	used	magnets	from	HDDs	is	about	15€,	with	current	
price	levels	of	95€/kg	for	virgin	Nd	oxide.
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
• The	current	lack	of	economically	viable	recycling	processes	highlights	the	
importance	of	keeping	collection	costs	low	to	improve	the	overall	economic	
viability	of	the	process.	
	
• The	analysis	of	the	trials	showed	that	even	though	the	operational	costs	of	bio-
leaching	are	considerably	higher	than	the	cost	of	traditional	recovery	processes	and	
conventional	mining,	more	metal	can	be	extracted	using	bio-leaching,	especially	
from	low-grade	material	(e.g.	copper).		Conventional	mining	can	extract	60%	to	
65%	from	an	ore/material,	whereas	90%	to	95%	can	be	extracted	using	bio-
leaching.		The	same	results	are	expected	for	Ta	and	other	CRMs.	
	
Recovery	Process	
	
• The	recovered	material	can	be	directly	used	for	new	magnet	processing,	without	
further	purification	of	melting	processes	(as	it	is	already	a	ready-to-use	form).		
• Manual	dismantling	took	time	and	effort.		It	would	be	useful	(and	possible)	to	
develop	an	automatic	dismantling	system	for	HDDs.		
• The	 recovered	 amount	 of	 Nd	 during	 the	 trial	 determined	 the	 technical	
recovery	 potential	 of	 magnet	 flakes	 that	 are	 directly	 usable	 in	 magnet	
production.	 	 This	 is	 an	 important	 development,	 as	 there	 aren’t	 any	 practical	
processes	existing	in	Europe.	
• Further	(future)	work	would	be	useful	in	a	number	of	areas:	
- To	 investigate	 the	 potential	 of	 setting-up	 economically	 feasible	 magnet	
production	in	Europe	by	incorporating	significant	flows	of	secondary	magnets	
from	sources	such	as	HDDs	and	electric	motors.	
- To	 develop	 an	 economically	 viable	 dismantling	 process	 to	 remove	 the	 VCM	
magnets	from	HDDs.		
	
BUSINESS	BENEFITS	
• This	 trial	 supports	 a	 2017	 recommendation	 by	 the	 German	 Environment	 Agency
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
(UBA).		Namely,	that	future	treatment	regulations	should	include	a	Ta	requirement	
that	magnets	from	HDDs	should	be	separated	and	added	to	a	recovery	process.		
• The	Ta	recovery	by	bio-leaching	shows	a	high	potential	for	new	innovative	research,	
especially	considering	that	there	appears	to	be	no	existing	literature	on	this	specific	
problem.		
• Bio-leaching	 (compared	 to	 conventional	 acid	 leaching)	 has	 a	 low	 environmental	
impact	 and	 avoids	 the	 use	 of	 hazardous	 substances.	 	 This	 therefore	 suggests	
opportunities	 to	 implement	 this	 technology	 in	 new	 markets,	 or	 for	 use	 by	
organisations	that	have	restrictions	in	handling	hazardous	liquids.		
• This	CRM	Recovery	Project	trial	has	tested	and	demonstrated	a	number	of	repeatable,	
lab-scale	(but	scalable)	processes	for	the	recovery	of	CRMs	from	WEEE	items.	
	
• The	 trial	 has	 also	 successfully	 demonstrated	 the	 important	 link	 between	 WEEE	
collection	and	CRM	recovery,	which	can	serve	to	increase	the	latter.	
	
• The	learnings	and	outcomes	of	this	trial	have	provided	valuable	input	into	the	EU-
wide	policy	and	infrastructure	recommendations	that	will	be	published	shortly,	and	
which	could	be	applied	in	a	commercial	setting	to	increase	the	recovery	of	CRM-rich	
components	from	data-bearing	devices.

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Critical Raw Materials - Working towards a second life for Critical Raw Materials in Germany

  • 1. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. WORKING TOWARDS A SECOND LIFE FOR CRITICAL RAW MATERIALS IN GERMANY Each year millions of tonnes of waste electrical and electronic equipment (WEEE) is generated in the EU, but only 30% is reported as properly collected and recycled. The Critical Raw Materials (CRM) Closed Loop Recovery Project aims to increase the recovery of target materials by 5% by 2020 and by 20% by 2030. With this in mind the project has invested in trials exploring novel ways of boosting the collection and recovery of CRMs from household WEEE. Held across the UK, Italy, Germany and the Czech Republic, the collection trials mechanisms included retailer take-back schemes; re-use containers at household waste recycling centres, business collections, university drop-off hubs, school collections and other collection events. PROMOTING RECOVERY IN GERMANY RecyclingBörse (also known as ‘AKR’), based in North Rhine-Westphalia in Germany, collects and re-markets used products in its own second-hand shops across the region and also runs a certified WEEE recycling facility. AKR is an independent and not-for-profit organisation, with a mission to promote re- use. It also has the capability to test and evaluate collected WEEE items according to technical and market criteria.
  • 2. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. METHODOLOGY This trial was focussed on the recovery of tantalum (Ta), commonly used in the electronics industry for capacitors and high power resistors, and neodymium (Nd), commonly used as an alloy within magnets and within everyday household items, such PCs, laptops and smartphones. Notes: Tantalum Recovery Input materials: capcacitors and printed circuit boards (PCBs) Activity undertaken by TUHH (Hamburg University of Technology) with support by Faunhofer Project Group IWKS Removing Ta capacitors from PCBs by EHF (electrohydraulic fragmentation) Bio-leaching processes used to recover Ta from capacitors Neodymium Recovery Input materials: magnets Activity undertaken by Fraunhofer Project Group IWKS Hydrogen decrepitation process used to separate rare earth permanent magnets from metal plates Rapid quenching (melt- spinning) process used to form rare earth flakes
  • 3. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. The bio-leaching trials for Ta are classed as very early-stage, as it is a metal which cannot be leached even by aqua regia, and there is almost no existing literature for Ta bio-leaching. As the bio-leaching process does not require or produce highly toxic or highly corrosive chemicals, the downstream processes, including the metal-removing from liquid phase and waste water treatment, would cause much lower environmental impacts. LINK BETWEEN COLLECTION AND RECOVERY TRIALS The below table demonstrates the overall recovery potential of Ta and Nd based on the collection and recovery trials. The trial activities listed are described within the AKR collection case study.1 Note: The recovery trials were focused on good accessibility and identifiability of Ta and Nd containing components. Therefore, only the number of PCs and laptops are taken into consideration. TRIAL RESULTS 1 http://www.criticalrawmaterialrecovery.eu/three-ways-to-get-great-weee-recycling-results NUMBER OF COLLECTED ITEMS WITH PRINCIPAL TANTALUM AND NEODYMIUM POTENTIAL WEEE Item Collection Trial Activity Re-use Olympics Schools Re-Bag Re-Box Total Recovery Potential PC 32 Zero Zero 32 Ta, Nd Laptop 4 Zero Zero 4 Ta, Nd Mobile phone 36 20 1 57 Ta, Nd Smartphone 30 3 Zero 33 Ta, Nd Tablet 11 3 Zero 14 Ta
  • 4. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. • The recovery potential per unit (laptop or PC), depending on the length of the leaching process, is promising. This is especially the case, given that the industry standard for extraction of Ta in the current treatment of PCBs in a smelter route is zero. Length of leaching process Leaching ratio Tantalum recovery potential 70 days 13.74% 0.0011g 15 days 5.31% 0.0004g Table 2: Ta recovery potential per unit (PC or laptop). • The recovery potential of Nd from magnets is also positive. For a single Hard Disk Drive (HDD) with a 10.1g magnet of the Voice Coil Motor (VCM), 0.65g of Nd is recoverable. The recovered amount of Nd during the trial also determined the technical recovery potential of magnet flakes that are directly usable in a magnet production. Since there is no practical process existing in Europe, this figure is an important footnote that could stimulate further technological advances towards the removal of VCM magnets from HDDs. LESSONS LEARNT Commercial • With regard to the recovery of Nd from HDDs, there is currently no recycling process implemented in Europe for magnet recycling/recovery. Thus, the commercial viability can be evaluated only roughly by comparison with the estimated costs of the production and pricing of magnets imported from China. Currently, the assumed price of magnets from China is about 60€/kg. Based on indicative assessments of the recovery trials for this project, the cost of producing 1kg magnet material from used magnets from HDDs is about 15€, with current price levels of 95€/kg for virgin Nd oxide.
  • 5. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. • The current lack of economically viable recycling processes highlights the importance of keeping collection costs low to improve the overall economic viability of the process. • The analysis of the trials showed that even though the operational costs of bio- leaching are considerably higher than the cost of traditional recovery processes and conventional mining, more metal can be extracted using bio-leaching, especially from low-grade material (e.g. copper). Conventional mining can extract 60% to 65% from an ore/material, whereas 90% to 95% can be extracted using bio- leaching. The same results are expected for Ta and other CRMs. Recovery Process • The recovered material can be directly used for new magnet processing, without further purification of melting processes (as it is already a ready-to-use form). • Manual dismantling took time and effort. It would be useful (and possible) to develop an automatic dismantling system for HDDs. • The recovered amount of Nd during the trial determined the technical recovery potential of magnet flakes that are directly usable in magnet production. This is an important development, as there aren’t any practical processes existing in Europe. • Further (future) work would be useful in a number of areas: - To investigate the potential of setting-up economically feasible magnet production in Europe by incorporating significant flows of secondary magnets from sources such as HDDs and electric motors. - To develop an economically viable dismantling process to remove the VCM magnets from HDDs. BUSINESS BENEFITS • This trial supports a 2017 recommendation by the German Environment Agency
  • 6. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. (UBA). Namely, that future treatment regulations should include a Ta requirement that magnets from HDDs should be separated and added to a recovery process. • The Ta recovery by bio-leaching shows a high potential for new innovative research, especially considering that there appears to be no existing literature on this specific problem. • Bio-leaching (compared to conventional acid leaching) has a low environmental impact and avoids the use of hazardous substances. This therefore suggests opportunities to implement this technology in new markets, or for use by organisations that have restrictions in handling hazardous liquids. • This CRM Recovery Project trial has tested and demonstrated a number of repeatable, lab-scale (but scalable) processes for the recovery of CRMs from WEEE items. • The trial has also successfully demonstrated the important link between WEEE collection and CRM recovery, which can serve to increase the latter. • The learnings and outcomes of this trial have provided valuable input into the EU- wide policy and infrastructure recommendations that will be published shortly, and which could be applied in a commercial setting to increase the recovery of CRM-rich components from data-bearing devices.