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Plastics &
Environmental
Impacts



Ecozuri Inc. promotes reusable shopping bags made from 100% recycled plastics. To
learn more about our products and offerings, please visit www.ecozuri.com

                                   www.ecozuri.com
Part One: Plastics 101




Ecozuri Inc. promotes reusable shopping bags made from 100% recycled plastics. To
learn more about our products and offerings, please visit www.ecozuri.com

                                   www.ecozuri.com
----- PLASTIC 101------

     Definition:
     Any of various complex organic compounds produced by polymerization, capable of being molded, extruded, cast into
     various shapes and films, or drawn into filaments, and then used as textile fibers.

     History:
     Alexander Parkes unveiled the first man-made plastic at the 1862 Great International Exhibition in London. This material --
     which was dubbed Parkesine, now called celluloid -- was an organic material derived from cellulose that, once heated, could
     be molded but retained its shape when cooled.

     In 1907, chemist Leo Hendrik Baekland, while striving to produce a synthetic varnish, stumbled upon the formula for a new
     synthetic polymer originating from coal tar. He subsequently named the new substance "Bakelite." Bakelite, once formed,
     could not be melted. Because of its properties as an electrical insulator, Bakelite was used in the production of high-tech
     objects including cameras and telephones. It was also used in the production of ashtrays, and as a substitute for jade,
     marble, and amber. By 1909, Baekland had coined "plastics" as the term to describe this completely new category of
     materials.

     The first patent for polyvinyl chloride (PVC), a substance now used widely in vinyl siding and water pipes, was registered in
     1914. Cellophane was also discovered during this period.

     Plastics did not really take off until after the First World War with the use of petroleum, a substance easier to process than
     coal into raw materials. Plastics served as substitutes for wood, glass, and metal during the hardship times of World War's I
     & II. After World War II, newer plastics, such as polyurethane, polyester, silicones, polypropylene, and polycarbonate joined
     polymethyl methacrylate and polystyrene and PVC in widespread applications. Many more would follow and, by the 1960s,
     plastics were within everyone's reach due to their inexpensive cost. Plastics had thus come to be considered “common,” a
     symbol of our consumer society.

     Since the 1970s, we have witnessed the advent of 'high-tech' plastics used in demanding fields such as health and
     technology. New types and forms of plastics, with new or improved performance characteristics, continue to be developed.


Source: American Chemical Council, Literature research
                                                             www.ecozuri.com
----- PLASTIC 101------

     Types:                                                                                           Characteristics
     Plastics are divided into three distinct groups: thermoplastics , thermosets and bio-plastics.
                                                                                                      • Can be very resistant to
     Thermoplastics soften when heated and harden on cooling. More than 80 percent of                   chemicals
     plastics are thermoplastics, examples of which include:                                          • Can be both thermal
       • High density polyethylene (HDPE) - used for bottles for detergents, food products and          and electrical
         toys                                                                                           insulators
       • Low density polyethylene (LDPE) - for products such as (bin liners, and flexible             • Are generally very light
         containers                                                                                     in weight with varying
       • Polyethylene terephthalate (PET) - used in bottles, carpets & food packaging                   degrees of strength
       • Polypropylene (PP) - used in yogurt and margarine pots, automotive parts, fibers, and        • Can be processed in
         milk crates                                                                                    various ways to
       • Polyvinyl chloride (PVC) - is made from oil and salt and is used for window frames,            produce thin fibers or
         flooring, wallpaper, bottles, and medical products                                             very intricate parts
                                                                                                      • Are materials with a
     Thermosets are hardened by a curing process and cannot be re-melted or re-molded.                  seemingly limitless
     Examples of thermosets include:                                                                    range of characteristics
       • Polyurethane (PU) - used in coatings, finishes, mattresses, vehicle seating, and building    • Are usually made from
         insulation                                                                                     petroleum, but not
       • Epoxy - adhesives, boats, sporting equipment, electrical and automotive components             always
       • Phenolics - used in ovens and circuit boards
       • Unsaturated polyesters – used for windmills, car body parts, and boats

     Bio-plastics, which are bio-degradable, are developed from plant materials and bacteria.
     There are three techniques used to produce bio-plastics:
       • Converting plant sugars into plastic
       • Producing plastics inside micro-organisms
       • Growing plastics in corn and other crops



Source: American Chemical Council, Literature research       www.ecozuri.com
----- PLASTIC INDUSTRY OVERVIEW----

                                            Plastics                                     Plastics
                                                                                         materials




                                                                                                       Downstream using industries
                                            materials
                                            and resins             Plastic               and product
                                            NAICS                  products              wholesaling




                                                                                                                                     End users, including consumers,
                                                                                         NAICS
         Upstream goods and services




                                            325211
                                                                     Gov’t docu-         424610




                                                                                                                                     business and government
                                                                     mented
                                                                     plastics
                                            Plastics                 products
                                            machinery                NAICS
                                            NAICS                    3261&
                                            3332201                  325991




                                                                                                                                     agencies
                                                                     Captive
                                            Molds for                plastic
                                            plastics                 products
                                            NAICS
                                            33351105

                                                                                                               U.S. Plastics industry:
                                           Plastic manufacturing industry plus                                 $374B shipment in
                                           captive plastics products                                           2007

                                            Plastics industry

                                       Full impact of plastics
Source: SPI
                                                                              www.ecozuri.com
----- PLASTIC USAGE ----
          Total sales & captive use of selected thermoplastic resins* by major market, 2003-2007
          (millions of pounds, dry weight basis)
                                                                                                                                            CAGR
                                                                                                                                            (2003-2007)
                         80,270                   86,101                83,231                 83,970                   82,354              0.5%




                                                                                                                                            6.5%


                                                                                                                                            -0.3%


                                                                                                                                            -0.4%




                                                                                                                                            1.9%




      * Include LDPE, LLDPE, HDPE, PP, Nylon, PVC, PS, Engineering Resins, ABS, SAN, Other Styrene Butadiene Latexes, Styrene Butadiene Latexes
Source: American Chemical Council                                   www.ecozuri.com
----- PLASTIC INDUSTRY OVERVIEW----

                                            Plastics                                     Plastics
                                                                                         materials




                                                                                                       Downstream using industries
                                            materials
                                            and resins             Plastic               and product
                                            NAICS                  products              wholesaling




                                                                                                                                     End users, including consumers,
                                                                                         NAICS
         Upstream goods and services




                                            325211
                                                                     Gov’t docu-         424610




                                                                                                                                     business and government
                                                                     mented
                                                                     plastics
                                            Plastics                 products
                                            machinery                NAICS
                                            NAICS                    3261&
                                            3332201                  325991




                                                                                                                                     agencies
                                                                     Captive
                                            Molds for                plastic
                                            plastics                 products
                                            NAICS
                                            33351105

                                                                                                               U.S. Plastics industry:
                                           Plastic manufacturing industry plus                                 $374B shipment in
                                           captive plastics products                                           2007

                                            Plastics industry

                                       Full impact of plastics
Source: SPI
                                                                              www.ecozuri.com
----- PLASTIC LIFE CYCLE-----
                                                (Part 1: Resin production, product manufacturing stage)
                                                                                                                        Environmental
                                                                                                                        concerns

                                Biogeochemically              Manufacturing
       Cracking                 manipulated




                                                                               Extrusion
Petroleum                                                                                   Example products: Plastic
                                                                                            films and bags

Natural gas                 Monomers         Polymers

Coal




                                                                               Injection
                                                                               molding
                                                                                            Example products: Yogurt
                                                         Additives                          containers, closures


  Energy issues                    Pollution and toxic
  Plastics consume 4%              materials




                                                                               molding
  of the world’s oil               Industrial practices in                                  Example products: Soft drink




                                                                                Blow
  stock as feedstock.              plastic manufacture can                                  bottles
  Although, in many                lead to polluting
  cases, the use of                effluents. The exposure
  plastics actually saves          to toxic intermediates
  more oil than                    used can be hazardous.                      Rotational
  alternatives,                    Significant process                          molding     Example products: Toys or
  opportunities for                improvements are
  energy preservation              employed to avoid the                                    kayaks
  do exit.                         above.


                                                             www.ecozuri.com
----- PLASTIC LIFE CYCLE-----
                                                   (Part 2: Waste, landfill , incineration and recycle stage)
                                                                                                                                Environmental
                                                                                                                                concerns

Discarding   Processing


                                  Mechanical recycling              Recycled plastic
                                  (collection, sorting,             flakes for new end
Consumer          Recycling
                                  reclamation)                      product
plastic
waste

                                  Feedstock recycling               Monomers for new
                                  (heating,                         polymers
                                  gasification,
                                  chemical)
                                                                    Plastic waste in               Capacity issues
                                   Land filling                                                    Majority of the plastic waste ends up
                                                                    landfill
Industrial                                                                                         in landfill, where they take more than
plastic                                                                                            1,000 years to decompose.
waste
                  Not recycling




                                                                                                   Oceans and wild life
                                                                                                   Over a billion seabirds and mammals
                                                                                                   die annually from ingestion of
                                                                                                   plastics
                                                                                                   Toxic emission
                                                                    Reduced volume
                                   Incineration                                                    Burning plastic releases dioxin, a
                                                                    waste in landfill              cancer-causing chemical



                                                             www.ecozuri.com
----- PLASTIC POLLUTION----




HAWAII

                              Canada
                              Canada       England UK
                                           England,
                                           England                Sweden
                                                                  Sweden
 United States


                                                                                   Japan
                                                                                    Japan



Hawaii




                                                                                               China


                                                                 Philippines




Litter left by tourists
 Venezuela                Antarctica      Tanzania bag
                                          Floating plastic
                                                                 Philippines New Zealand Beach cleanup
Venezuela                 Antarctica                                         New Zealand
                                          Tanzania
                                               www.ecozuri.com
----- PLASTIC POLLUTION – WIDELIFE ----




          www.ecozuri.com
----- PLASTIC POLLUTION – CITY ----




         www.ecozuri.com
----- PLASTIC POLLUTION – OCEAN ----




         www.ecozuri.com
----- PLASTIC USAGE ----
          Total sales & captive use of selected thermoplastic resins* by major market, 2003-2007
          (millions of pounds, dry weight basis)
                                                                                                                                            CAGR
                                                                                                                                            (2003-2007)
                         80,270                   86,101                83,231                 83,970                   82,354              0.5%




                                                                                                                                            6.5%


                                                                                                                                            -0.3%


                                                                                                                                            -0.4%




                                                                                                                                            1.9%




      * Include LDPE, LLDPE, HDPE, PP, Nylon, PVC, PS, Engineering Resins, ABS, SAN, Other Styrene Butadiene Latexes, Styrene Butadiene Latexes
Source: American Chemical Council                                   www.ecozuri.com
----- PLASTIC SALES VOLUME BY TYPE ----
          Total sales & captive use of selected thermoplastic resins* by resin type, 2006-2007
          (millions of pounds, dry weight basis)




                                                                                                                                             92,347




                                                                                                                                             94,350


 CAGR
 (2003-2007)                 4.0%                   4.6%                  -1.8%          2.5%                                                2.2%




(1) Except Phenolic resins, (2) Sales & Captive Use Data Include Imports, (3) Canadian production and sales data included, (4) Canadian and Mexican production
and sales data included, (5) Includes: engineering resins, polyurethanes (TDI, MDI and polyols), unsaturated (thermoset) polyester, and other resins.
Source: American Chemical Council                                      www.ecozuri.com
Part Two: Plastic Bags




Ecozuri Inc. promotes reusable shopping bags made from 100% recycled plastics. To
learn more about our products and offerings, please visit www.ecozuri.com

                                   www.ecozuri.com
----- PLASTIC BAG 101 ---

Definition:
Bags that are made out of "film", or thin flexible sheets of plastic. Plastic film is typically defined as any plastic less than 10
mm thick. The majority of plastic films are made from polyethylene resin and are readily recyclable if the material is clean, dry,
and not pigmented black.

History:

1957 The first baggies and sandwich bags on rolls are introduced.
1958 Poly dry cleaning bags compete with traditional brown paper.
1966 Between 25 and 30 percent of packaging for bread is plastic.
1966 Plastic produce bags on rolls are introduced in grocery stores.
1969 The New York City Sanitation Department's "New York City Experiment" demonstrates that using plastic bags for
refuse curbside pickup is cleaner, safer, and quieter than metal trash can pick-up. This began a shift to plastic can liners
among consumers.
1974/75 Retailing giants such as Sears, J.C. Penney, Montgomery Ward, Jordan Marsh, Allied, Federated, and Hills make the
switch to plastic merchandise bags.
1973 The first commercial system for manufacturing plastic grocery bags becomes operational
1977 The plastic grocery bag is introduced to the supermarket industry as an alternative to paper sacks.
1982 Kroger and Safeway start to replace traditional craft sacks with polyethylene "t-shirt" bags.
1990 The first blue bag recycling program begins with curbside collection.
1990 Consumer plastic bag recycling begins through a supermarket collection-site network.
1992 Nearly half of U.S. supermarkets have recycling available for plastic bags.
1994 Denmark creates first plastic bag tax.
1996 Over 80% grocery bags used are plastic.
2002 Ireland introduces the worlds first consumer paid plastic bag tax.




                                                       www.ecozuri.com
----- PLASTIC BAG 101------

Types:

  Resin type             Characteristics                  Usages                          Examples

                                                          Bags (e.g., thicker
                                                          newspaper bags, bread
                         Films with high clarity,
  LDPE - Low Density                                      bags)
                         moderate stretch &
  Polyethylene                                            Bubble wrap (may also
                         strength characteristics
                                                          contain nylon


                                                          Bags (e.g. clear, thin
                                                          newspaper bags)
                         films have moderate clarity,
  LLDPE - Linear Low                                      Dry cleaning film
                         slightly tacky feel to the
  Density Polyethylene
                         touch


                                                          Consumer paper packaging
                                                          (i.e. toilet paper, paper
                         films have moderate clarity,
  MDPE - Medium                                           towel)
                         poor stretch and strength
  Density Polyethylene
                         characteristics


                         films have some opacity,         Most grocery bags
  HDPE - High Density    crinkle to the touch, low        T-shirt bags
  Polyethylene           stretch, can tear easily, high   Bags with sealed air for
                         strength                         packaging (e.g., air cushion)


                                                     www.ecozuri.com
----- THE ALTERNATIVES FOR PLASTIC BAGS----

       Paper bags                            Biodegradable bags                 Reusable bags




       • Degradable in well-run             • Light and convenient like        • Reduce energy usage, landfill,
         landfill                             plastic bags                       and pollution due to its
       • Hold more stuff                    • Biodegradable in certain           reusable nature
       • Higher percentage of                 conditions
Pros




         recycling (10% -15% versus
         1%-3% for plastics)

       • Consume forests                    • Highly confusing definition of   • If the bags are not reused a
       • Take 4 times as much energy          bio-plastics. Many bio-based       sufficient number of times,
         as needed to produce                 products are not necessarily       more energies are wasted as
       • Generate 70% more air                biodegradable                      most reusable bags are made
         pollution and 50 times more        • Many biodegradable bags            from materials that require
Cons




         water pollution in production        require special processing and     more energy to produce
       • Take 90% more energy to              facilities. There are limited    • Difficult to remember as it
         recycle when recycling rate is       collection and processing          requires living habit changes
         low                                  platforms                        • Inconvenient since most
       • 7 times heavier than plastic       • When mingled with traditional      products are bulky to carry
         to transport                         plastics, this causes
       • Take up more space in landfill       contamination and make the
                                              product unrecyclable


          NOT THE RIGHT ANSWER              NOT AS GOOD AN ANSWER AS             THE RIGHT ANSWER – BUT
                                                    IT SOUNDS                    NEED INDIVIDUAL EFFORTS

         Source: Literature research              www.ecozuri.com
----- THE ENVIRONMENTAL IMPACTS OF PLASTIC BAGS ----
                                     Energy                 The energy used to make one high-density polyethylene (HDPE) plastic bag is 0.48 megajoules (MJ).
                                     consumptions           To give this figure perspective, a car driving one kilometre is the equivalent of manufacturing 8.7
                                                            plastic bags (Australian Bureau of Statistics, 2004).
Production and distribution




                                     Health                 Toxic emissions are produced during the extraction of materials for the production of plastic grocery
                                     impacts                bags. The manufacturing and transportation of such materials contribute to acid rain, smog, and
                                                            numerous other harmful effects.

                                     Air and Water          Without enhanced processes, the manufacturing of two plastic bags produces 1.1 kg of atmospheric
                                     Pollution              pollution, which contributes to acid rain and smog, and 0.1 g of waterborne waste, which has the
                                                            capability of disrupting associated ecosystems, such as waterways and the life that they support.
                                                            Following manufacturing, the plastic grocery bags are subsequently shipped all over the world.
                                                            Container ships used to transport these bags to each consumer country use fuels which produce high
                                                            levels of pollutants, such as sulfur.

                                     Land Pollution         Lightweight plastic grocery bags are additionally harmful due to their propensity to be carried away
                                                            on a breeze and become attached to tree branches, fill roadside ditches, or end up in public
                                                            waterways, rivers, or oceans. In one instance, Cape Town, South Africa, had more than 3000 plastic
                                                            grocery bags that covered each kilometer of road.

                                     Impact on              Most distressing, over a billion seabirds and mammals die annually from ingestion of plastics (Baker,
                                     wildlife               2002). In Newfoundland, 100,000 marine mammals are killed each year by ingesting plastic (Brown,
                                                            2003). However, the impact of plastic bags does not end with the death of one animal. When a bird
Disposal




                                                            or mammal dies in such a manner and subsequently decomposes, the plastic bag will again be
                                                            released into the environment to be ingested by another animal.

                                     Marine                 The North Pacific Tropical Gyre, also known as the Garbage Patch, is seven million tons of floating
                                     Pollution              plastic waste spanning an area twice the size of Texas. There is six times as much plastic in the gyre
                                                            than there is plankton. Plankton is the area’s most abundant food source. Animals mistake this waste
                                                            for food, dying either from plastic poisoning or blockage of their digestive system. This plastic absorbs,
                                                            transports, and releases hydrophobic pollutants (PCB,DDE,DDT) not only harming the oceans food
                                                            chain, but us as well.    www.ecozuri.com
                              Source: Literature research
----- PLASTIC SHOPPING BAG LIFE CYCLE-----
                                                                                                                                                                                                                                              Only 2% recycled, still
                                                           Production                                                                                                    Distribution              Destination                Disposal
                                                                                                                                                                                                                                              a very expensive
                                                                                                                                                                                                                                              process
             of natural gas or oil
             Use large amount




                                                                                                                                                                                                   500-1,000 bags
             to produce and



                                                                                                                                                                         Supermarket                                          Home recycled         Recycling
                                                                                                                                                                                                   used per
                                                                                                                                                                                                   household per
             transport




                                                                                                                                                                                                   year


                                                                                                       Up to 3-4 trillion a year worldwide, 100 billion in US alone
                                                                                                                                                                                                   Average usage
                                                                                                                                                                                                   time: 12 minutes                            96% goes to Landfill
                                                                                                                                                                        Other foods or                                                         Take >1,000 yrs to
                                                                                                                                                                            liquid                                                             breakdown
                                                                                                                                                                                                        Home                  Home garbage
  Natural gas or oil extraction




                                                            Ethylene Polymerization
                                  Ethylene manufacturing




                                                                                      Bag production




                                                                                                                                                                           General                                                                    Landfill
                                                                                                                                                                       merchandise and                                Reuse                      disposal/waste
                                                                                                                                                                          apparels                                                                  treatment
                                                                                                                                                                                                            Maximally 1-2 times

                                                                                                                                                                                                                                                   Pollute land
                                                                                                                                                                           Fast food                                              Garbage          and oceans
                                                                                                                                                                       convenient stores
                                                                                                                                                                       & service stations
                                                                                                                                                                                                     Public areas
                                                                                                                                                                                                                                                      Litter


                                                                                                                                                                         Other retails                                             Litter


Source: Nolan-ITU, Literature research
                                                                                                                                                                                            www.ecozuri.com
Part Two: Plastic Bottles




Ecozuri Inc. promotes reusable shopping bags made from 100% recycled plastics. To
learn more about our products and offerings, please visit www.ecozuri.com

                                   www.ecozuri.com
----- PLASTIC BOTTLE 101 ---

Definition:
A plastic bottle is a container constructed of plastic with a neck that is narrower than its body and an opening at the top. The
mouth of the bottle is normally sealed with a plastic bottle cap. Plastic bottles are typically used to store liquids such as water,
soft drinks, cooking oil, medicine, shampoo, milk, and ink.

History:
Plastic bottles were first used commercially in 1947, but remained relatively expensive until the early 1960's when high-
density polyethylene was introduced. They quickly became popular with both manufacturers and customers due to their
lightweight nature, and relatively low production costs compared with glass bottles . The food industry has almost
completely replaced glass in many cases with plastic bottles, but wine and beer are still commonly sold in glass bottles.

Types

 Materials                 Characteristics                                                Usage
 High-density              Naturally translucent and flexible. The addition of color      Shampoo and detergent bottles, milk
 polyethylene (HDPE)       will make HDPE bottles opaque although not glossy.             jugs, cosmetics, motor oil
 Low Density               Less chemically resistant than HDPE, but is more
                                                                                          For squeeze application
 Polyethylene (LDPE)       translucent
 Polyethylene              Very good alcohol and essential oil barrier properties,
                                                                                          Carbonated beverage bottles
 Terephthalate (PET)       generally good chemical resistance
 Polyvinyl Chloride        Naturally clear, have extremely good resistance to oils,       Salad oil, mineral oil, and vinegar,
 (PVC)                     and have very low oxygen transmission                          shampoos, and cosmetic products
 Polypropylene (PP)
                           Excellent moisture barrier, stability at high temperatures     Hot fill products such as pancake syrup

                                                                                          Dry products including vitamins,
 Polystyrene (PS)          Excellent clarity and stiffness at an economical cost
                                                                                          petroleum jellies, and spices
                                                        www.ecozuri.com
----- THE INCONVENIENT FACTS OF BOTTLED WATER -----

         US bottled water market (1997 – 2008)
         Million gallon/ billion bottles

       - 18 million barrels of crude oil are requires to produce the 900,000 tons of plastics
         (PET) that bottle the water
       - Only 24% of the plastic bottles are recycled – 76% end up as either garbage or liter
       - The total amount of energy required to make the bottle, fill the bottle with water,
         transport, refrigerate the bottled water, and recover, recycle, or throw away the
         empty bottle is equivalent, on average, to filling a plastic bottle ¼ full with oil.                    31 billion
                                                                                                                  bottles


                                                                15 billion
                                                                 bottles

                               6 billion
         3 billion             bottles
         bottles




Source: NY State Department of Environmental Conservation, Beverage Marketing Corporation, Literature Research
                                                                www.ecozuri.com
----- PET BOTTLE LIFE CYCLE -----


   Natural gas and
   petroleum are                                                                  The bottled water
   converted into             PET pellets are              A beverage              is distributed to             A consumer buys
     polyethylene              melted and                 company fills              gas stations,               the water, drinks
    terephalate, a              blown into                and caps the            vending machines,                 it and then
       chemical                bottle molds                  bottles               grocery and big                  chooses to
      compound                                                                        box stores
    known as PET


                                                                                                                                 Toss the bottle
                                                                    … or tossing the bottle in a recycling bin
                                                                                                                                 into the trash…
                                                                                                                                 (76%)



                                    At a mill, the plastic is
                                                                                                                    In the US, 76% of
                                   ground into shreds and              At recycling centers, the
                                                                                                                     plastic bottles –
                                    melted. Used RPET is                  bottles are sorted,
                                                                                                                     about 7.1 billion
                                    typically recycled into             washed, and stacked,
                                                                                                                     pounds of them,
                                    other products, often                then finally crushed,
                                                                                                                  wound up burned in
                                   polyester fleece jackets,            baled and sold (for 38-
                                                                                                                 incinerators or buried
                                      carpets, or plastic                66 cents per pound)
                                                                                                                   in landfills in 2006
                                            decking




Sources: The American Chemical Counsel, The Boston Globe Magazine
                                                                www.ecozuri.com
center




Sources: CWC, WRAP
                                                                                      bottles
                                                                                                                   bottles




                                                                                     recycled




                                                       Drop-off
                                                       recycling
                                                                                     Curbside
                                                                                                                  returned




                          Buy-back
                                                                                                                Redemption
                                                                                                                programs for




                                                                                   collections of
                                                                      Debale


                              Sorting (manual or automated to separate PVC and color bottles)


                                                                       Grind


                                                     Air classification to remove labels


                                               Scrubber to remove drink residue, glue and dirt

                               Float/sink or hydrocyclone classification to remove cap and ring
                                                    made from HDPE or PP




        www.ecozuri.com
                                                      Metal detector to remove metal


                                                      Other decontamination process


                                                  Clean flake packer, storage and shipping

                                                                    Repelletizing
                                                                                                                                  ----- PET BOTTLE RECYCLING PROCESS -----




                                   Fiber
                                                       resins
                                                                           Strapping
                                                                                                                    Packaging




                                                     Engineered




                                applications
                                                     applications
                                                                                                                   applications




                                                                                                applications
                                                                                               Sheet and film
----- US PET BOTTLE RECYCLING STATISTICS -----
             Gross recycle statistics for US PET bottles
             (mmlbs, %)




                                                                                      24.6%
                    31.7% 27.1% 24.8% 23.7% 22.3% 22.1% 19.9% 19.6% 21.6% 23.1% 23.5%




Sources: NAPCOR
                                               www.ecozuri.com
----- RYCYCLED PET MARKET STATISTICS -----
             Market for US post consumer PET bottles
             (mmlbs)




                                                                        Top buyers:
                                                                        China
                                                                        Canada




Sources: NAPCOR
                                        www.ecozuri.com
----- RECYCLED PET UTILIZATION TREND -----
              RPET PRODUCT CATEGORIES IN US MARKET
              (mmlbs)




Sources: NAPCOR
                                     www.ecozuri.com
“Zuri” means “good and beautiful” in Swahili, a
beautiful language spoken in East Africa. Ecozuri, Inc.
offers environmentally conscious, habit changing
products to help people embrace an more eco-
friendly lifestyle. We also contribute up to 10% of our
revenue to support education for children living in
poverty in rural Africa.


                      “Ecozuri” is a registered trademark of California based Ecozuri Inc. The
                      company promotes Ecozuri line of reusable bags made from 100% recycled
                      plastics and offers green custom-made promotional products OEM services
                      for corporate clients.

                      To learn about Ecozuri’s products and offerings, please visit
                      www. ecozuri.com or email info@ecozuri.com


                                       www.ecozuri.com

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Plastics and environment_by_ecozuri.com

  • 1. Plastics & Environmental Impacts Ecozuri Inc. promotes reusable shopping bags made from 100% recycled plastics. To learn more about our products and offerings, please visit www.ecozuri.com www.ecozuri.com
  • 2. Part One: Plastics 101 Ecozuri Inc. promotes reusable shopping bags made from 100% recycled plastics. To learn more about our products and offerings, please visit www.ecozuri.com www.ecozuri.com
  • 3. ----- PLASTIC 101------ Definition: Any of various complex organic compounds produced by polymerization, capable of being molded, extruded, cast into various shapes and films, or drawn into filaments, and then used as textile fibers. History: Alexander Parkes unveiled the first man-made plastic at the 1862 Great International Exhibition in London. This material -- which was dubbed Parkesine, now called celluloid -- was an organic material derived from cellulose that, once heated, could be molded but retained its shape when cooled. In 1907, chemist Leo Hendrik Baekland, while striving to produce a synthetic varnish, stumbled upon the formula for a new synthetic polymer originating from coal tar. He subsequently named the new substance "Bakelite." Bakelite, once formed, could not be melted. Because of its properties as an electrical insulator, Bakelite was used in the production of high-tech objects including cameras and telephones. It was also used in the production of ashtrays, and as a substitute for jade, marble, and amber. By 1909, Baekland had coined "plastics" as the term to describe this completely new category of materials. The first patent for polyvinyl chloride (PVC), a substance now used widely in vinyl siding and water pipes, was registered in 1914. Cellophane was also discovered during this period. Plastics did not really take off until after the First World War with the use of petroleum, a substance easier to process than coal into raw materials. Plastics served as substitutes for wood, glass, and metal during the hardship times of World War's I & II. After World War II, newer plastics, such as polyurethane, polyester, silicones, polypropylene, and polycarbonate joined polymethyl methacrylate and polystyrene and PVC in widespread applications. Many more would follow and, by the 1960s, plastics were within everyone's reach due to their inexpensive cost. Plastics had thus come to be considered “common,” a symbol of our consumer society. Since the 1970s, we have witnessed the advent of 'high-tech' plastics used in demanding fields such as health and technology. New types and forms of plastics, with new or improved performance characteristics, continue to be developed. Source: American Chemical Council, Literature research www.ecozuri.com
  • 4. ----- PLASTIC 101------ Types: Characteristics Plastics are divided into three distinct groups: thermoplastics , thermosets and bio-plastics. • Can be very resistant to Thermoplastics soften when heated and harden on cooling. More than 80 percent of chemicals plastics are thermoplastics, examples of which include: • Can be both thermal • High density polyethylene (HDPE) - used for bottles for detergents, food products and and electrical toys insulators • Low density polyethylene (LDPE) - for products such as (bin liners, and flexible • Are generally very light containers in weight with varying • Polyethylene terephthalate (PET) - used in bottles, carpets & food packaging degrees of strength • Polypropylene (PP) - used in yogurt and margarine pots, automotive parts, fibers, and • Can be processed in milk crates various ways to • Polyvinyl chloride (PVC) - is made from oil and salt and is used for window frames, produce thin fibers or flooring, wallpaper, bottles, and medical products very intricate parts • Are materials with a Thermosets are hardened by a curing process and cannot be re-melted or re-molded. seemingly limitless Examples of thermosets include: range of characteristics • Polyurethane (PU) - used in coatings, finishes, mattresses, vehicle seating, and building • Are usually made from insulation petroleum, but not • Epoxy - adhesives, boats, sporting equipment, electrical and automotive components always • Phenolics - used in ovens and circuit boards • Unsaturated polyesters – used for windmills, car body parts, and boats Bio-plastics, which are bio-degradable, are developed from plant materials and bacteria. There are three techniques used to produce bio-plastics: • Converting plant sugars into plastic • Producing plastics inside micro-organisms • Growing plastics in corn and other crops Source: American Chemical Council, Literature research www.ecozuri.com
  • 5. ----- PLASTIC INDUSTRY OVERVIEW---- Plastics Plastics materials Downstream using industries materials and resins Plastic and product NAICS products wholesaling End users, including consumers, NAICS Upstream goods and services 325211 Gov’t docu- 424610 business and government mented plastics Plastics products machinery NAICS NAICS 3261& 3332201 325991 agencies Captive Molds for plastic plastics products NAICS 33351105 U.S. Plastics industry: Plastic manufacturing industry plus $374B shipment in captive plastics products 2007 Plastics industry Full impact of plastics Source: SPI www.ecozuri.com
  • 6. ----- PLASTIC USAGE ---- Total sales & captive use of selected thermoplastic resins* by major market, 2003-2007 (millions of pounds, dry weight basis) CAGR (2003-2007) 80,270 86,101 83,231 83,970 82,354 0.5% 6.5% -0.3% -0.4% 1.9% * Include LDPE, LLDPE, HDPE, PP, Nylon, PVC, PS, Engineering Resins, ABS, SAN, Other Styrene Butadiene Latexes, Styrene Butadiene Latexes Source: American Chemical Council www.ecozuri.com
  • 7. ----- PLASTIC INDUSTRY OVERVIEW---- Plastics Plastics materials Downstream using industries materials and resins Plastic and product NAICS products wholesaling End users, including consumers, NAICS Upstream goods and services 325211 Gov’t docu- 424610 business and government mented plastics Plastics products machinery NAICS NAICS 3261& 3332201 325991 agencies Captive Molds for plastic plastics products NAICS 33351105 U.S. Plastics industry: Plastic manufacturing industry plus $374B shipment in captive plastics products 2007 Plastics industry Full impact of plastics Source: SPI www.ecozuri.com
  • 8. ----- PLASTIC LIFE CYCLE----- (Part 1: Resin production, product manufacturing stage) Environmental concerns Biogeochemically Manufacturing Cracking manipulated Extrusion Petroleum Example products: Plastic films and bags Natural gas Monomers Polymers Coal Injection molding Example products: Yogurt Additives containers, closures Energy issues Pollution and toxic Plastics consume 4% materials molding of the world’s oil Industrial practices in Example products: Soft drink Blow stock as feedstock. plastic manufacture can bottles Although, in many lead to polluting cases, the use of effluents. The exposure plastics actually saves to toxic intermediates more oil than used can be hazardous. Rotational alternatives, Significant process molding Example products: Toys or opportunities for improvements are energy preservation employed to avoid the kayaks do exit. above. www.ecozuri.com
  • 9. ----- PLASTIC LIFE CYCLE----- (Part 2: Waste, landfill , incineration and recycle stage) Environmental concerns Discarding Processing Mechanical recycling Recycled plastic (collection, sorting, flakes for new end Consumer Recycling reclamation) product plastic waste Feedstock recycling Monomers for new (heating, polymers gasification, chemical) Plastic waste in Capacity issues Land filling Majority of the plastic waste ends up landfill Industrial in landfill, where they take more than plastic 1,000 years to decompose. waste Not recycling Oceans and wild life Over a billion seabirds and mammals die annually from ingestion of plastics Toxic emission Reduced volume Incineration Burning plastic releases dioxin, a waste in landfill cancer-causing chemical www.ecozuri.com
  • 10. ----- PLASTIC POLLUTION---- HAWAII Canada Canada England UK England, England Sweden Sweden United States Japan Japan Hawaii China Philippines Litter left by tourists Venezuela Antarctica Tanzania bag Floating plastic Philippines New Zealand Beach cleanup Venezuela Antarctica New Zealand Tanzania www.ecozuri.com
  • 11. ----- PLASTIC POLLUTION – WIDELIFE ---- www.ecozuri.com
  • 12. ----- PLASTIC POLLUTION – CITY ---- www.ecozuri.com
  • 13. ----- PLASTIC POLLUTION – OCEAN ---- www.ecozuri.com
  • 14. ----- PLASTIC USAGE ---- Total sales & captive use of selected thermoplastic resins* by major market, 2003-2007 (millions of pounds, dry weight basis) CAGR (2003-2007) 80,270 86,101 83,231 83,970 82,354 0.5% 6.5% -0.3% -0.4% 1.9% * Include LDPE, LLDPE, HDPE, PP, Nylon, PVC, PS, Engineering Resins, ABS, SAN, Other Styrene Butadiene Latexes, Styrene Butadiene Latexes Source: American Chemical Council www.ecozuri.com
  • 15. ----- PLASTIC SALES VOLUME BY TYPE ---- Total sales & captive use of selected thermoplastic resins* by resin type, 2006-2007 (millions of pounds, dry weight basis) 92,347 94,350 CAGR (2003-2007) 4.0% 4.6% -1.8% 2.5% 2.2% (1) Except Phenolic resins, (2) Sales & Captive Use Data Include Imports, (3) Canadian production and sales data included, (4) Canadian and Mexican production and sales data included, (5) Includes: engineering resins, polyurethanes (TDI, MDI and polyols), unsaturated (thermoset) polyester, and other resins. Source: American Chemical Council www.ecozuri.com
  • 16. Part Two: Plastic Bags Ecozuri Inc. promotes reusable shopping bags made from 100% recycled plastics. To learn more about our products and offerings, please visit www.ecozuri.com www.ecozuri.com
  • 17. ----- PLASTIC BAG 101 --- Definition: Bags that are made out of "film", or thin flexible sheets of plastic. Plastic film is typically defined as any plastic less than 10 mm thick. The majority of plastic films are made from polyethylene resin and are readily recyclable if the material is clean, dry, and not pigmented black. History: 1957 The first baggies and sandwich bags on rolls are introduced. 1958 Poly dry cleaning bags compete with traditional brown paper. 1966 Between 25 and 30 percent of packaging for bread is plastic. 1966 Plastic produce bags on rolls are introduced in grocery stores. 1969 The New York City Sanitation Department's "New York City Experiment" demonstrates that using plastic bags for refuse curbside pickup is cleaner, safer, and quieter than metal trash can pick-up. This began a shift to plastic can liners among consumers. 1974/75 Retailing giants such as Sears, J.C. Penney, Montgomery Ward, Jordan Marsh, Allied, Federated, and Hills make the switch to plastic merchandise bags. 1973 The first commercial system for manufacturing plastic grocery bags becomes operational 1977 The plastic grocery bag is introduced to the supermarket industry as an alternative to paper sacks. 1982 Kroger and Safeway start to replace traditional craft sacks with polyethylene "t-shirt" bags. 1990 The first blue bag recycling program begins with curbside collection. 1990 Consumer plastic bag recycling begins through a supermarket collection-site network. 1992 Nearly half of U.S. supermarkets have recycling available for plastic bags. 1994 Denmark creates first plastic bag tax. 1996 Over 80% grocery bags used are plastic. 2002 Ireland introduces the worlds first consumer paid plastic bag tax. www.ecozuri.com
  • 18. ----- PLASTIC BAG 101------ Types: Resin type Characteristics Usages Examples Bags (e.g., thicker newspaper bags, bread Films with high clarity, LDPE - Low Density bags) moderate stretch & Polyethylene Bubble wrap (may also strength characteristics contain nylon Bags (e.g. clear, thin newspaper bags) films have moderate clarity, LLDPE - Linear Low Dry cleaning film slightly tacky feel to the Density Polyethylene touch Consumer paper packaging (i.e. toilet paper, paper films have moderate clarity, MDPE - Medium towel) poor stretch and strength Density Polyethylene characteristics films have some opacity, Most grocery bags HDPE - High Density crinkle to the touch, low T-shirt bags Polyethylene stretch, can tear easily, high Bags with sealed air for strength packaging (e.g., air cushion) www.ecozuri.com
  • 19. ----- THE ALTERNATIVES FOR PLASTIC BAGS---- Paper bags Biodegradable bags Reusable bags • Degradable in well-run • Light and convenient like • Reduce energy usage, landfill, landfill plastic bags and pollution due to its • Hold more stuff • Biodegradable in certain reusable nature • Higher percentage of conditions Pros recycling (10% -15% versus 1%-3% for plastics) • Consume forests • Highly confusing definition of • If the bags are not reused a • Take 4 times as much energy bio-plastics. Many bio-based sufficient number of times, as needed to produce products are not necessarily more energies are wasted as • Generate 70% more air biodegradable most reusable bags are made pollution and 50 times more • Many biodegradable bags from materials that require Cons water pollution in production require special processing and more energy to produce • Take 90% more energy to facilities. There are limited • Difficult to remember as it recycle when recycling rate is collection and processing requires living habit changes low platforms • Inconvenient since most • 7 times heavier than plastic • When mingled with traditional products are bulky to carry to transport plastics, this causes • Take up more space in landfill contamination and make the product unrecyclable NOT THE RIGHT ANSWER NOT AS GOOD AN ANSWER AS THE RIGHT ANSWER – BUT IT SOUNDS NEED INDIVIDUAL EFFORTS Source: Literature research www.ecozuri.com
  • 20. ----- THE ENVIRONMENTAL IMPACTS OF PLASTIC BAGS ---- Energy The energy used to make one high-density polyethylene (HDPE) plastic bag is 0.48 megajoules (MJ). consumptions To give this figure perspective, a car driving one kilometre is the equivalent of manufacturing 8.7 plastic bags (Australian Bureau of Statistics, 2004). Production and distribution Health Toxic emissions are produced during the extraction of materials for the production of plastic grocery impacts bags. The manufacturing and transportation of such materials contribute to acid rain, smog, and numerous other harmful effects. Air and Water Without enhanced processes, the manufacturing of two plastic bags produces 1.1 kg of atmospheric Pollution pollution, which contributes to acid rain and smog, and 0.1 g of waterborne waste, which has the capability of disrupting associated ecosystems, such as waterways and the life that they support. Following manufacturing, the plastic grocery bags are subsequently shipped all over the world. Container ships used to transport these bags to each consumer country use fuels which produce high levels of pollutants, such as sulfur. Land Pollution Lightweight plastic grocery bags are additionally harmful due to their propensity to be carried away on a breeze and become attached to tree branches, fill roadside ditches, or end up in public waterways, rivers, or oceans. In one instance, Cape Town, South Africa, had more than 3000 plastic grocery bags that covered each kilometer of road. Impact on Most distressing, over a billion seabirds and mammals die annually from ingestion of plastics (Baker, wildlife 2002). In Newfoundland, 100,000 marine mammals are killed each year by ingesting plastic (Brown, 2003). However, the impact of plastic bags does not end with the death of one animal. When a bird Disposal or mammal dies in such a manner and subsequently decomposes, the plastic bag will again be released into the environment to be ingested by another animal. Marine The North Pacific Tropical Gyre, also known as the Garbage Patch, is seven million tons of floating Pollution plastic waste spanning an area twice the size of Texas. There is six times as much plastic in the gyre than there is plankton. Plankton is the area’s most abundant food source. Animals mistake this waste for food, dying either from plastic poisoning or blockage of their digestive system. This plastic absorbs, transports, and releases hydrophobic pollutants (PCB,DDE,DDT) not only harming the oceans food chain, but us as well. www.ecozuri.com Source: Literature research
  • 21. ----- PLASTIC SHOPPING BAG LIFE CYCLE----- Only 2% recycled, still Production Distribution Destination Disposal a very expensive process of natural gas or oil Use large amount 500-1,000 bags to produce and Supermarket Home recycled Recycling used per household per transport year Up to 3-4 trillion a year worldwide, 100 billion in US alone Average usage time: 12 minutes 96% goes to Landfill Other foods or Take >1,000 yrs to liquid breakdown Home Home garbage Natural gas or oil extraction Ethylene Polymerization Ethylene manufacturing Bag production General Landfill merchandise and Reuse disposal/waste apparels treatment Maximally 1-2 times Pollute land Fast food Garbage and oceans convenient stores & service stations Public areas Litter Other retails Litter Source: Nolan-ITU, Literature research www.ecozuri.com
  • 22. Part Two: Plastic Bottles Ecozuri Inc. promotes reusable shopping bags made from 100% recycled plastics. To learn more about our products and offerings, please visit www.ecozuri.com www.ecozuri.com
  • 23. ----- PLASTIC BOTTLE 101 --- Definition: A plastic bottle is a container constructed of plastic with a neck that is narrower than its body and an opening at the top. The mouth of the bottle is normally sealed with a plastic bottle cap. Plastic bottles are typically used to store liquids such as water, soft drinks, cooking oil, medicine, shampoo, milk, and ink. History: Plastic bottles were first used commercially in 1947, but remained relatively expensive until the early 1960's when high- density polyethylene was introduced. They quickly became popular with both manufacturers and customers due to their lightweight nature, and relatively low production costs compared with glass bottles . The food industry has almost completely replaced glass in many cases with plastic bottles, but wine and beer are still commonly sold in glass bottles. Types Materials Characteristics Usage High-density Naturally translucent and flexible. The addition of color Shampoo and detergent bottles, milk polyethylene (HDPE) will make HDPE bottles opaque although not glossy. jugs, cosmetics, motor oil Low Density Less chemically resistant than HDPE, but is more For squeeze application Polyethylene (LDPE) translucent Polyethylene Very good alcohol and essential oil barrier properties, Carbonated beverage bottles Terephthalate (PET) generally good chemical resistance Polyvinyl Chloride Naturally clear, have extremely good resistance to oils, Salad oil, mineral oil, and vinegar, (PVC) and have very low oxygen transmission shampoos, and cosmetic products Polypropylene (PP) Excellent moisture barrier, stability at high temperatures Hot fill products such as pancake syrup Dry products including vitamins, Polystyrene (PS) Excellent clarity and stiffness at an economical cost petroleum jellies, and spices www.ecozuri.com
  • 24. ----- THE INCONVENIENT FACTS OF BOTTLED WATER ----- US bottled water market (1997 – 2008) Million gallon/ billion bottles - 18 million barrels of crude oil are requires to produce the 900,000 tons of plastics (PET) that bottle the water - Only 24% of the plastic bottles are recycled – 76% end up as either garbage or liter - The total amount of energy required to make the bottle, fill the bottle with water, transport, refrigerate the bottled water, and recover, recycle, or throw away the empty bottle is equivalent, on average, to filling a plastic bottle ¼ full with oil. 31 billion bottles 15 billion bottles 6 billion 3 billion bottles bottles Source: NY State Department of Environmental Conservation, Beverage Marketing Corporation, Literature Research www.ecozuri.com
  • 25. ----- PET BOTTLE LIFE CYCLE ----- Natural gas and petroleum are The bottled water converted into PET pellets are A beverage is distributed to A consumer buys polyethylene melted and company fills gas stations, the water, drinks terephalate, a blown into and caps the vending machines, it and then chemical bottle molds bottles grocery and big chooses to compound box stores known as PET Toss the bottle … or tossing the bottle in a recycling bin into the trash… (76%) At a mill, the plastic is In the US, 76% of ground into shreds and At recycling centers, the plastic bottles – melted. Used RPET is bottles are sorted, about 7.1 billion typically recycled into washed, and stacked, pounds of them, other products, often then finally crushed, wound up burned in polyester fleece jackets, baled and sold (for 38- incinerators or buried carpets, or plastic 66 cents per pound) in landfills in 2006 decking Sources: The American Chemical Counsel, The Boston Globe Magazine www.ecozuri.com
  • 26. center Sources: CWC, WRAP bottles bottles recycled Drop-off recycling Curbside returned Buy-back Redemption programs for collections of Debale Sorting (manual or automated to separate PVC and color bottles) Grind Air classification to remove labels Scrubber to remove drink residue, glue and dirt Float/sink or hydrocyclone classification to remove cap and ring made from HDPE or PP www.ecozuri.com Metal detector to remove metal Other decontamination process Clean flake packer, storage and shipping Repelletizing ----- PET BOTTLE RECYCLING PROCESS ----- Fiber resins Strapping Packaging Engineered applications applications applications applications Sheet and film
  • 27. ----- US PET BOTTLE RECYCLING STATISTICS ----- Gross recycle statistics for US PET bottles (mmlbs, %) 24.6% 31.7% 27.1% 24.8% 23.7% 22.3% 22.1% 19.9% 19.6% 21.6% 23.1% 23.5% Sources: NAPCOR www.ecozuri.com
  • 28. ----- RYCYCLED PET MARKET STATISTICS ----- Market for US post consumer PET bottles (mmlbs) Top buyers: China Canada Sources: NAPCOR www.ecozuri.com
  • 29. ----- RECYCLED PET UTILIZATION TREND ----- RPET PRODUCT CATEGORIES IN US MARKET (mmlbs) Sources: NAPCOR www.ecozuri.com
  • 30. “Zuri” means “good and beautiful” in Swahili, a beautiful language spoken in East Africa. Ecozuri, Inc. offers environmentally conscious, habit changing products to help people embrace an more eco- friendly lifestyle. We also contribute up to 10% of our revenue to support education for children living in poverty in rural Africa. “Ecozuri” is a registered trademark of California based Ecozuri Inc. The company promotes Ecozuri line of reusable bags made from 100% recycled plastics and offers green custom-made promotional products OEM services for corporate clients. To learn about Ecozuri’s products and offerings, please visit www. ecozuri.com or email info@ecozuri.com www.ecozuri.com