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POLYMERISATION
Presented by N . Sindhuja and N . Rishik Kumar
Polymers : combination of monomers
is called polymers.
■ There are two types of polymers
1. Addition polymerisation
2. Condensation polymerisation
Addition polymers:
■ Formation of long chain molecules from lots of small molecules
joining together is addition polymerisation.
■ Catalysts are used for polymerisation.
Characteristics:
■ No bi products are formed.
■ The functionality of monomers is double bond.
■ The mechanism is rapid.
■ It is highly exothermic reaction.
Examples:
■ Process initiated by free radical.
 The free radical attacks double
bond to from new free radical.
Condensation polymerisation:
 Condensation polymers are polymers formed from condensation
reactions between monomers.
 Many natural polymers are condensation polymers.
examples :silk , starch and DNA
Characteristics:
 The monomers must has contains two or more functional groups.
 The reactions catalysed by catalyst.
 The reactions are endothermic.
 There is elimination of biproducts.
Examples:
polyesters polyamides
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