SlideShare ist ein Scribd-Unternehmen logo
1 von 86
21st February, 2018
UNIVERSITY OF LAGOS, AKOKA
LAGOS, NIGERIA
A seminar presentation by group one
FURNACES, FUELS AND FLUXES IN CHEMICAL METALLURGY
DEPARTMENT OF METALLURGICAL AND MATERIALS ENGINEERING
FACULTY OF ENGINEERING
GROUP MEMBERS
 GROUP LEADER
ADESINA JOSHUA
OLUWATIMILEHIN
 MEMBERS
ADESOLA SEGUN EMMANUEL
ODUNOSHO ADEDAMOLA MICHAEL
EJIOFOR IKECHUKWU CHIBUIKEM
INTRODUCTION
The subject of metallurgy is an integral
constituent
that must be given a large space, especially for
industrialization.
In fact, every age the world has seen is defined
by
materials. From the stone age, bronze, iron,
copper
and even IT age
Objective
 This report aims to provide knowledge of
furnaces, integrating the study of blast furnace
into focus, as it is dominantly used in the
extraction of iron;
 Fuel with coal as a case study, and why it is
essential to the blast furnace, as well as fluxes
(lime and dolomite) used during the extraction
process
 The ultimate aim is to provide substantial
knowledge and to state the underlying
principles and operations that serve as the
basis for what make our world imaginable.
Furnace
 A furnace is an equipment used to melt
metals for casting or to heat materials to
change their shape (rolling, forging) or
properties (heat treatment).
 They are appliances capable of heating
materials to such a high temperature that
they melt, which from a chemical
perspective basically means that they
reach the critical threshold temperature
at which they convert from solid to liquid
(Ricketts 1992).
In metallurgy, furnaces are essential devices
that are used to carry out many metallurgical
processes such as;
smelting, heat treatment, and so on.
Furnace can majorly be classified as follows,
based on the mode of energy:
 Fuel-fired
furnaces (oil, gas,
coke, or coal):
 Crucible
 Reverbatory or
hearth
 Rotary
 Converter
Electric furnaces
(Electricity):
 Induction
 Resistance
 Electric arc
Fuel-fired Oil-fired (rotary furnace
Gas-fired (open-hearth furnace)
Coal-fired (blast, rotary and
cupola furnaces)
Electric furnace Type 1 (Electric arc furnace)
Type 2 (Induction furnace)
Type 3 (Resistance furnace)
Classification of furnace
Advantages of electric
furnace over gas furnace
Electric furnaces require far less maintenance than
gas furnaces
Electric furnaces are one of the least expensive
furnaces to purchase and install
Compared to gas furnaces, an electric furnace
does not give off any dangerous emissions that could
potentially cause harm
ADVANTAGES AND DISADVANTAGES OF
ELECTRIC FURNACE OVER GAS
FURNACE
ADVANTAGES
 Electric furnaces require far
less maintenance than gas
furnaces
 Electric furnaces are one of
the least expensive
furnaces to purchase and
install
 Compared to gas furnaces,
an electric furnace does
not give off any dangerous
emissions that could
potentially cause harm
DISADVANTAGES
 An electric furnace costs
more to run than a gas
furnace
 An electric furnace may be
more expensive to repair
than a gas furnace
 Electric furnaces are not
very efficient at heating
large spaces
ADVANTAGES AND DISADVANTAGES OF
OIL-FIRED FURNACE
 The advantage of
heating with oil is that
it may be available
when other forms of
fuel, such as natural or
propane gas, are not.
 Nozzles can clog with dirt
 Oil furnaces need to be
regularly cleaned and the
fuel filters must be changed
 Controlling heat output is
more difficult for oil
furnaces than for gas
furnaces
 Oil furnaces use more
electricity than gas
furnaces
 Most oil furnaces are less
DESIGN AND CONSTRUCTION OF FURNACES
(BLAST FURNACE AS A CASE STUDY)
Why is blast furnace considered a case study?
The blast furnace is the first step in producing steel from
iron oxides. It has an enormous impact on the production of
raw (pig) iron from iron ores (hematite or magnetite),
although other methods for iron production are also in use
but the efficiency of blast furnace supersedes almost all
other iron-making technologies.
Without first extracting iron from its ore, you cannot proceed
to alloying of iron to get steel, which is an important
industrial material.
BLAST FURNACE: OVERVIEW
The basic idea involves the
heating of an iron oxide,
often hematite, Fe2O3, with
carbon.
A jet of air is used to burn
the carbon to form the gas
carbon dioxide then reacts
with more carbon to form
carbon monoxide. Carbon
mono
oxide is then used to reduce
the
iron oxide to iron. Carbon
dioxide is also formed in this
reaction.
A Blast furnace site
DESIGN AND CONSTRUCTION OF FURNACES (BLAST
FURNACE AS A CASE STUDY)
Basic components of a furnace:
 Refractory chamber
 Hearth
 Burners
 Chimney
 Charging and
 discharging doors
 Stockhouse
DESIGN AND CONSTRUCTION OF
FURNACES (BLAST FURNACE AS A CASE
STUDY)
 The design of a modern
blast furnace is generally
based on the concept of a
free standing unit with a
surrounding building,
providing access to the
furnace and support for
the blast furnace gas
system.
 The design of a blast
furnace plays a
fundamental role in its
reliable operation,
metallurgical
performance, sustained
high productivity and long
DESIGN AND CONSTRUCTION OF FURNACES (BLAST FURNACE
AS A CASE STUDY)
EQUIPMENT FOR DESIGNING A BLAST FURNACE EQ
The design of a blast
furnace should involve
equipment which has a
proven reputation for
reliability, durability, and
high performance in
the arduous conditions
of the blast furnace
environment.
EQUIPMENT
 Auxiliary equipment:
 Ore storage yard and bins for
temporary storing of raw
materials
 Belt conveyor or skip-hoist for
transporting raw materials to
the furnace top
 Charging apparatus for
charging the raw materials
into the furnace
 Hot stoves for heating the
blast
 Equipment for dust removal,
and recovering and storing the
gas from the furnace top
 Equipment for liquid products
transfer
DESIGN AND CONSTRUCTION OF FURNACES (BLAST
FURNACE AS A CASE STUDY)
DIFFERENT TEMPERATURE ZONES IN A BLAST FURNACE ZONE
 Dead man zone (Above
1500oC)
 Hearth zone (1500oC)
 Bottom part of the bosh
zone
 Top part of the bosh zone
 Bottom half of the stack
zone
 Top half of the stack zone
DESIGN AND CONSTRUCTION OF FURNACES (BLAST
FURNACE AS A CASE STUDY)
MODEL OF A BLAST FURNACE OPERATION
RAW MATERIALS REQUIRED FOR THE PRODUCTION OF
PIG IRON IN A BLAST FURNACE
In the blast furnace application, the production of iron
historically required three important raw materials:
 iron ore
 coal converted to "coke", and;
 chemical grade limestone
In more modern times additional materials have been used
such
as iron ore pellets and sinter
Iron Ore
 Iron oxides can come to the blast furnace plant in the
form of raw ore, pellets or sinter.
 The raw ore is removed from the earth and sized into
pieces that range from 0.5 to 1.5 inches. This ore is
either Hematite (Fe2O3) or Magnetite (Fe3O4) and the
iron content ranges from 50% to 70%.
 This iron-rich ore can be charged directly into a blast
furnace without any further processing. Iron ore that
contains a lower iron content must be processed or
beneficiated to increase its iron content. An example is
pellet
Coal and Limestone will be discussed in the following
slides
Applications of Furnace
Although the purpose of a blast furnace is to chemically
reduce and physically convert iron oxides into liquid iron
called "hot metal”, the applications of furnaces, generally,
include:
 Heat treatment: annealing, quenching, ageing, etc
 Aerospace Industry: heat treatment of aircraft metals,
preheating of titanium alloy bar before forging
 Automotive Industry: heat treatment of automotive parts
 Application in the Metal Industry: tube, bar, strip, rods,
forgings, casting and so on

The use of fuel cannot be undermined
in our every day life.
Fuel is used in the following areas:
1. Cooking
2. Transportation
3. Manufacturing
4. Heating and cooling buildings
5. Generating electricity to run
appliances.
INTRODUCTION
Introduction
Introduction
FUELS
 A fuel is defined as a substance used to
produce heat or power by combustion
 Any chemical process accompanied by the
evolution of light and heat is called
combustion. It is simply the reaction of
substances with oxygen and converts
chemical energy into heat and light.
 Fuel + Oxygen → Combustion products +
Heat
Characteristics of a Good Fuel
1. A good fuel should ignite easily.
2. It should have a high calorific value, that
is, it should give out a lot of heat.
3. It should be inexpensive and readily
available
4. It should be easy to store and transport
5. It should not produce harmful gases.
Classification of Fuels
Classification of
Fuels
Based on
Physical State
Solid Fuel
(wood, coal)
Liquid Fuel (crude
petroleum, natural
gasoline)
Gaseous Fuel
(natural gas)
Based on
occurrence
Primary or natural
fuels (wood, coal)
Secondary or
prepared fuel
(charcoal, coke)
Solid Fuels
 Solid fuel refers to various forms of
solid material that can be burnt to
release energy, providing heat and
light through the process of
combustion.
 Common examples of solid fuels
include wood, charcoal, coke, coal
 Solid fuels are extensively used in
rocketry as solid propellants.
Wood
 Wood has been used as fuel from ancient times. Due to
large scale of deforestation, wood is no longer used
except in forest areas where wood is available at low
cost.
 Wood when freshly cut contains 25-50% moisture.
Normally it is used in air dried condition with 10-15%
moisture content.
 The calorific value of air dried wood is about 3500-4500
kcal/kg
 When wood burns. The ash content is high. This makes
dry wood a fuel of low calorific value.
 Wood charcoal is obtained by destructive distillation of
wood.
 The major use of wood charcoal is for producing
activated carbon used for adsorption or chemical
reactions.
Coal
Coal is regarded as a fossil fuel produced from the
vegetable debris under conditions of high
temperature and pressure over million of years
Types of coal
Peat The lowest carbon content
Lignite
Brown variety containing 25-
30% carbon and 60% moisture
content
Sub-bituminous
coal
Black variety, 35-45% carbon
Bituminous Coal
Hard black variety, 45-86%
carbon.
Anthracite Coal
The highest ranking coal,
carbon content 86-97%
Uses of Coal
1. As a primary fuel: Coal is used to
produce steam through heat and
combustion, which is again used for
running turbines to generate electricity in
power plants.
2. As a secondary fuel: The product of
burning coal in the absence of air is of
metallurgical importance. The byproducts
plastic, tar and synthetic fibre and also
used for making steel in industries.
Coke
 Coke is obtained when coal is heated
strongly out of contact with air. The
process is called carbonization or
coking
1. Low temperature carbonization:
500⁰C-700⁰C; low temperature coke
or semi coke or soft coke.
2. High temperature carbonization:
900⁰C-1100⁰C; metallurgical coke or
hard coke.
Metallurgical Coke
The properties of coke depend on porosity, reactivity and the
amount of volatile matter retained by coke during carbonization.
Coke is mainly used as a heat source and reducing agent in
metallurgy a good coke in metallurgical process should posses
the following characteristics:
1. Purity: The metallurgical coke should contain lower
percentage of moisture, ash, sulphur and phosphorous.
2. Porosity: The coke should be porous so as to provide
contact between carbon and oxygen
3. Strength: The coke used in metallurgical process should
have high strength so as to withstand the weight of ore, flux
in the furnace.
4. Size: Metallurgical coke should be of medium size.
5. Combustibility: Coke should burn easily. The
combustibility of coke depends on the nature of the coal,
carbonization temperature and reaction temperature.
6. Calorific Value: It should be high
7. Cost: It should be cheap and readily available.
Benefits/disadvantages of solid
fuel
 Benefits
 Solid fuels, compared to liquid fuels or
gaseous fuels, are often cheaper,
easier to extract, more stable to
transport and in many places are more
readily available.
 Coal in particular, is utilized in the
generation of 38.1% of the world’s
electricity because it is less expensive
and more powerful than its liquid and
gas counterparts.
Disadvantages
 Solid fuels are heavier to transport,
require more destructive methods to
extract/burn and often have higher
carbon, nitrate and sulphate
emissions.
 With the exception of sustainable
wood solid fuel is normally considered
non-renewable as it requires
thousands of years to form.
Liquid Fuel
 Liquid fuels are combustible or energy-
generating molecules that can be
harnessed to create mechanical energy,
usually producing kinetic energy; they also
must take the shape of their container. It is
the fumes of liquid fuels that are flammable
instead of the fluid.
 Most liquid fuels in widespread use are
derived from crude oil, also called
petroleum.
 Many liquid fuels play a primary role in
transportation and the economy.
Petroleum
 Most liquid fuels used are currently
produced from petroleum.
 The petroleum or crude oil is never used
as such, it is refined.
 The refining of petroleum is
accomplished by three processes:
1. Fractional distillation
2. Cracking, and
3. Treating
 The three most important liquid fuels
derived are gasoline or petrol, kerosene
and diesel oil.
Natural gas and Liquefied
petroleum gas
 Compressed Natural Gas
Natural gas, composed chiefly of
methane, can be compressed to a liquid
and used as a substitute for other
traditional liquid fuels. Its combustion is
very clean compared to other
hydrocarbon fuels, but the fuel’s low
boiling point requires the fuel to be kept
at high pressure to keep it in liquid
state.
Natural gas and Liquefied
petroleum gas
Liquefied petroleum gas (LPG)
LP gas is a mixture of propane and
butane, both of which are easily
compressible gases under standard
atmospheric conditions. It offers many f
the advantages of compressed natural gas
(CNG), but does not burn as cleaner, is
denser than air and is much more easily
compressed. Commonly used for cooking
and space heating, LP gas and
compressed propane are seeing increased
use in motorized vehicles; propane is the
third most commonly used motor fuel
globally.
Merits and Demerits of Liquid
Fuel
 Merits
Possess higher calorific value per unit
mass than solid fuels.
Easy transportation through pipes.
Less excess furnace space.
No wear and tear on furnace parts such
as those for solid fuels.
For equal heat output, much less space
occupancy and much less weight than
solid fuels.
Combustion without formation of dust,
ash, and clinkers.
Merits and Demerits of Liquid
Fuel
 Demerits
Costlier than solid fuels.
Requirement of costly special storage
tanks.
Associated with a greater risk of fire
hazards, particularly true of highly
inflammable and volatile liquid fuels.
Requirement of efficient burning,
specially designed burners and
spraying systems for efficient burning.
Gaseous Fuel
 Gaseous fuels are obtained either
naturally or by the treatment of solid or
liquid fuel.
 Among the naturally occurring gaseous
fuels, natural gas and liquefied
petroleum gas are most important.
 These gases have high calorific value.
 The calorific value and specific gravity of
a gaseous fuel determine the thermal
output of a heating appliance.
Types of Gaseous Fuels
Gaseou
s Fuel
Manufacture
d or
synthetic
fuel gases
Natural gas
Manufactured Fuel gases
 Manufactured fuel gases are those produced
through an artificial process, usually gasification, at
a location known as a gasworks
 Examples are: Coal gas, producer gas, water gas
 Producer gases as reducing agent in metallurgical
operations
 Coal gas are used as illuminants in cities and
towns. They are also used in metallurgical
operations contributing reducing pressure.
 Water gas is used as a source of hydrogen gas
and an illuminating agent.
Manufactured Fuel Gas
 Coal gas: it is obtained by
carbonization of coal and consists
mainly of hydrogen, carbon monoxide
and various hydrocarbons
 Producer gas: it is obtained by the
partial combustion of coal, coke,
anthracite coal or charcoal in a mixed
air-stream blast
 Water gas: it is a mixture of hydrogen
and carbon monoxide and is made by
passing steam over incandescent
coke.
Natural Gas
 The main constituent is methane. It is usually found
in or near the petroleum field, under the earth’s
surface. Apart from methane it contains small
amounts of other gases such as ethane and
carbon dioxide.
 It is a fuel gas substitute for gasoline (petrol), diesel
or propane.
 It is more environmentally clean alternative to
those fuels and it’s much safer than other fuels in
the event of spill.
 It is made by compressing methane to less than
1% of the volume it occupies at standard
atmospheric pressure.
 Used in domestic fuel and manufacture of
chemicals.
Merits and Demerits of Gaseous
Fuel
 Merits
 The supply of fuel gas and hence the
temperature of furnace is easily and
accurately controlled.
 The high temperature is obtained at a
moderate cost by pre-heating gas and air
with heat of waste gases of combustion.
 They are directly used in internal combustion
engine.
 They do not produce ash or smoke
 They undergo complete combustion with
minimum air supply.
Merits and Demerits of Gaseous
Fuel
 Demerits
They are readily inflammable.
They require large storage capacity.
SELECTION OF FUEL FOR METALLURGICAL
PROCESSES
The principal factors taken into account
in
the selection of a particular type of fuel
are:
 Suitability to process
 Supply position, and
 Cost
OTHER FACTORS THAT DETERMINE FUEL
SELECTION
 The type of heating with respect to
size
 The availability and reliability of supply
of fuels in question
 The efficiency of the heating operation
with the chosen fuel
THE ECONOMIC IMPORTANCE OF A FUEL
DEPENDS UPON
 Its geographical distribution
 The cost involved in its tapping and
transport
 Calorific value of fuel
 Its combustion or burning quality in air
MAJOR SOURCES OF ENERGY (FUEL) IN THE
WORLD
 Coal
 Oil
 Natural gas
 Uranium and Nuclear
 Hydro Power
 Wind
 Solar PV
 Bio-energy and waste
Source: World Energy Council: World Energy Resources,
2013 survey; 23rd edition for the Survey of Energy Resources
WORLD ENERGY CONSUMPTION, 2013 SURVEY
CRUDE OIL RESERVES (R/P
Rate)
COAL RESERVES (R/P Rate)
NATURAL GAS RESERVES
(R/P Rate)
CRUDE OIL vs COAL
 From the reserves and production rate
tables, It is seen that that there is
reduction in the reserves of coal between
1993 and 2011 while crude oil reserves
increase
 However, for the production of steel, the
use of coal as fuel for the blast furnace is
still very much in demand
 According to World Coal
Association(WCA), global steel
production depends on coal. 74% of the
steel produced today uses coal.
COAL
 In 2017, world crude steel production was
1.6 billion tones. WCA CEO, Benjamin
Sporton said, “Despite the headlines the
reality is that coal will continue to play a
significant role in the world’s energy
system. India, Pakistan, Bangladesh and
parts of Southeast Asia will become the
primary engines of future coal demand
growth. Today, coal accounts for 27% of
global primary energy and is the second
most important source of primary
energy.”
APPLICATION OF COAL FOR THE PRODUCTION
OF STEEL
Coal performs three functions, which are:
 Reducing agent
 Source of energy
 Source of carbon
WHY DOES COAL MATTER:
CAN WE MAKE STEEL WITHOUT COAL?
 Currently, natural gas is increasingly
being used as a replacement for oil. To
a certain extent the use of fuel is also
being replaced by electric power
 On the other hand, coal is
indispensable when it comes to the
production of iron, which is further
processed into steel
 Coal cannot be replaced, to any
extent, since it is primarily used as
reducing agent
WHY DOES COAL MATTER:
CAN WE MAKE STEEL WITHOUT COAL?
 A sustainable iron and steel production is
the techno-economic backbone of the
national development of any nation
including in Nigeria
 Coal Action Network Aotearoa (CANA) says
that, “60% of solid energy’s production in
New Zealand is for steel making.”
 The company further says that, “there is no
way of making steel without coal”.
OTHER INDUSTRIAL APPLICATIONS OF COAL
 Electricity generation
 Steel production
 Cement manufacturing
 Liquid fuel
 Chemical by-products—ammonia gas for agricultural
fertilizer, plastics and fibres, phenol and benzenes
 Silicon metals for water repellants, resins silicones
and silanes for cosmetics, hair shampoo, toothpaste
 Carbon fibre—extremely strong but lightweight,
reinforcement material used in construction,
mountain bikes
 Activated carbon—filters for water, air purification,
and in kidney dialysis machine
In fact, iron and steel are so important that a
steel
company in the Republic of South Korea has
this
inscription on its entrance: “A nation that
controls Iron controls the world” – Pohang
Steel Company Ltd
Fluxes
 A flux is derived from Latin “fluxus”
meaning “flow”
 It is a chemical cleaning agent, flowing
agent, or purifying agent.
 Fluxes may have more than one
function at a time. They are used in
both extractive metallurgy and metal
joining.
FLUX
 A metallurgical flux is a substance that is
added to combine with gangue
(unwanted materials) during ore smelting
to form slag that can be separated from
the molten metal
 It is also used with additives in metal
joining process
Classes of Flux
 Acidic Fluxes: These are fluxes that
generally form acids in water and bases.
Examples are silica, alumina, and
phosphorus
 Basic fluxes: are those that would generally
form bases in water. Examples are lime and
magnesia
 Neutral fluxes: are neutral substances
because it can be viewed as the reaction
product of a base and an acid. Examples are
fluorspar, calcium, fluoride
* Alumina can act as a basic or acidic flux.
Classes of Flux
 The degree of acidity or basicity of flux is
often specified to characterize the slag
chemistry for a particular system.
 For example, steelmaking uses slags with
more bases (lime and magnesia) than acids
(silica and alumina).
FLUXES
 The minerals and compounds used as
fluxes depend on five basic things, which
are;
 the process requirements
 availability
 costs
 requirements for recycling of
intermediate products; and
 environmental concerns
Flux Addition Process
 Fluxes are used in metallurgical
processes either in iron-making process
or steelmaking process.
 In ironmaking, the flux is added either by
direct charging or through sinter and
fluxed pellets, while;
 In steelmaking, flux is added as lime or
dolomitic lime that are either charged as
lumps or injected as fines
Flux Addition Process
 Some flux materials are added to repair
smelting and refining vessel refractory
linings.
 The selection of the flux to be added
depends on the type of process and type of
refractory.
 For instance, in copper smelting, an acid
slag practice is used, and silica is added for
repair of refractories in some parts of the
Flux Addition Process
 Since 90% of all metal production is iron
and steel, the major fluxes consumed will
be those used in iron-making and
steelmaking, that is, limestone, dolomite,
lime, fluorspar, or siliceous sources
 However, some small amounts lime and
dolomite are used in nonferrous smelting,
particularly in smelting and refining of
copper and lead ores
Flux Selection
The selection of flux for a particular process
may be dependent on:
 The chemistry of flux to be employed
 Size of flux available
 Geographical location and economics
Limestone and Dolomite
Fluxes
 Limestone is a naturally occurring mineral. The
term limestone is applied to any calcareous
sedimentary rock consisting essentially of
carbonates.
 The ore is widely available geographically all
over the world. Earth’s crust contains more than
4 % of calcium carbonate.
 Limestone is theoretically composed of
exclusively calcium carbonate (CaCO3). When
limestone contains a certain portion of
magnesium, it is called dolomite or dolomitic
limestone (CaCO3.MgCO3).
Limestone and Dolomite
Fluxes
 Generally, limestone and dolomite are
composed of calcium carbonate
(CaCO3), magnesium carbonate
(MgCO3), silica (SiO2), alumina (Al2O3),
iron (Fe), sulfur (S) and other trace
elements.
Limestone and Dolomite
Fluxes
Limestone Dolomite
Physical Properties of Limestone
and Dolomite
 Resistance physical degradation: during
handling and transportation is also important
to minimize the amount of fines formed
 Thermal decrepitation: Thermal decrepitation
and physical degradation are not desirable
because the permeability of the furnace
burden is reduced by the presence of fines.
Experience has shown that fine-grained
stone decrepitates less than coarse-grained
stone in the blast furnace (Gault and Ames,
1960). Resistance of the stone to physical
degradation during handling and
transportation is also important to minimize
the amount of fines formed.
Chemical Reactions of
Limestone and Dolomite
 Limestone and dolomite are calcined or heated to
drive off the carbon dioxide prior to use in
steelmaking.
 Calcination is usually done in rotary kilns at 900 to
1100°C. The reaction proceeds according to:
CaCO3(s) = CaO(s) + CO2(g) for limestone, and
(Mg,Ca)CO3(s) = (Mg,Ca)O(s) + CO2(g) for dolomite,
 Also, the sulfur content of the lime should be low,
and The sulfur level in the calcined lime is controlled
by regulating the oxygen content in the calcining
system exit gas.
REQUIREMENTS FOR FLUORSPAR
 Fluorspar or calcium fluoride (CaF2) is
used as a flux along with lime to
improve the fluidity of slag in
steelmaking and subsequent ladle
metallurgy processing
 The fluorspar can be added as lumps,
gravel-sized material, or as fines
incorporated in briquettes
PROPERTIES OF SLAG
 Melting Point
 Viscosity
 Density
The successful application of a slag in a
metallurgical process depends on the slag
chemistry and properties of the molten slag
which are obtained by selecting the proper
fluxes
Applications/Uses of Flux
 Smelting processes
 Iron and steel making
 External Treatment of Hot Metal
 Oxygen steel making
 Ladle metallurgy
 Continuous casting
PROBLEMS AND FUTURE TRENDS IN FLUXES AS
REGARDS METALLURGY
 The demand for saving energy and
improving the environment, the
consumption of flux for metallurgical
purposes is likely to continue
downward.
 Metal production and flux
consumption will be influenced by
new process technologies, recycling,
and substitution.
PROBLEMS AND FUTURE TRENDS IN FLUXES AS
REGARDS METALLURGY
 Identifiable trends are the use of
composite and lightweight materials in
transportation vehicles, the increased
use of high technology devices and
miniaturization.
 Substitution of plastics, composites,
and light alloys including aluminum
will impact the use of steel and the
attendant flux consumption
CONCLUSION
The above shows the design and construction
of furnaces (blast furnace) for the industrial
production of iron and further purports that
furnaces are essential equipment for both an iron
making and steelmaking processes.
It is also ascertained that the growth of economic
depends largely on the production of steel.
In addition, the steel industry is seen as the
largest
employer of labor due to their work multiplier
effect.
CONCLUSION
 More over, coal is seen as an indispensable
source of energy for the production of iron,
which eventually brings about the
production of steel
 From the research, it is also seen, as of this
moment, that steel cannot be made without
coal
CONCLUSION
 Finally, the existence of steel is largely dependent
on furnaces, fuel and fluxes, and these three
materials must be properly optimized with the
development of new clean energy technologies.
 Reduction in adverse effect of burning coal in the
environment and superior substitute for fluxes can
improve the production of steel and hence, boost
the economic values of steel, especially in
underdeveloped countries like Nigeria
 As a result, this can be seen as a panacea to
stagnancy and retrogression that has battered
Nigeria for decades.

Weitere ähnliche Inhalte

Was ist angesagt? (20)

Electrric arc furnace
Electrric arc furnaceElectrric arc furnace
Electrric arc furnace
 
Steel making
Steel makingSteel making
Steel making
 
Steel Making: Lecture AOD
Steel Making: Lecture AOD Steel Making: Lecture AOD
Steel Making: Lecture AOD
 
Sintering Technology
Sintering   Technology  Sintering   Technology
Sintering Technology
 
Smelting furnaces
Smelting furnacesSmelting furnaces
Smelting furnaces
 
Ultimate Analysis of Coal
Ultimate Analysis of CoalUltimate Analysis of Coal
Ultimate Analysis of Coal
 
Electric Arc furnace
Electric Arc furnaceElectric Arc furnace
Electric Arc furnace
 
Iron making refractories
Iron making refractoriesIron making refractories
Iron making refractories
 
Blast furnace
Blast furnaceBlast furnace
Blast furnace
 
Austempering and Martempering in Metallurgy
Austempering and Martempering in Metallurgy Austempering and Martempering in Metallurgy
Austempering and Martempering in Metallurgy
 
TTT Diagram
TTT  DiagramTTT  Diagram
TTT Diagram
 
Midrex shaft process
Midrex shaft processMidrex shaft process
Midrex shaft process
 
Iron Making Lecture Notes
Iron Making Lecture NotesIron Making Lecture Notes
Iron Making Lecture Notes
 
Steel making process
Steel making processSteel making process
Steel making process
 
Iron making
Iron makingIron making
Iron making
 
Principals of roasting and its types
Principals of roasting and its typesPrincipals of roasting and its types
Principals of roasting and its types
 
Alternative Iron making processess
Alternative Iron making processessAlternative Iron making processess
Alternative Iron making processess
 
Introduction to steel making processes
Introduction to steel making processesIntroduction to steel making processes
Introduction to steel making processes
 
Hydrogen Embrittlement : Causes, Effects, Prevention.
Hydrogen Embrittlement : Causes, Effects, Prevention.Hydrogen Embrittlement : Causes, Effects, Prevention.
Hydrogen Embrittlement : Causes, Effects, Prevention.
 
introduction to Cast Iron
introduction to Cast Ironintroduction to Cast Iron
introduction to Cast Iron
 

Ähnlich wie Furnace, fuels and fluxes

High Speed Infra Red Furnace
High Speed Infra Red FurnaceHigh Speed Infra Red Furnace
High Speed Infra Red FurnaceIJMER
 
iron (2)Iron and steel industry occupational.pptx
iron (2)Iron and steel industry  occupational.pptxiron (2)Iron and steel industry  occupational.pptx
iron (2)Iron and steel industry occupational.pptxmirohiph
 
A VOCATIONAL TRAINNING REPORT_aman
A  VOCATIONAL TRAINNING REPORT_amanA  VOCATIONAL TRAINNING REPORT_aman
A VOCATIONAL TRAINNING REPORT_amanAMAN KESARI
 
Thermal energy management of blast furnace plant
Thermal energy management of blast furnace plantThermal energy management of blast furnace plant
Thermal energy management of blast furnace planteSAT Journals
 
Chapter 7 - Coal.pptx
Chapter 7 - Coal.pptxChapter 7 - Coal.pptx
Chapter 7 - Coal.pptxAkramMusa5
 
Blast furnace fuel.pptxhbgggjjiiikkkkkkkkk
Blast furnace fuel.pptxhbgggjjiiikkkkkkkkkBlast furnace fuel.pptxhbgggjjiiikkkkkkkkk
Blast furnace fuel.pptxhbgggjjiiikkkkkkkkkshesadebmahanta1
 
Iron and Steel Making with allied chemical reactions .pptx
Iron and Steel Making with allied chemical reactions .pptxIron and Steel Making with allied chemical reactions .pptx
Iron and Steel Making with allied chemical reactions .pptx029DevendraKumarSing
 
Metallurgical coke
Metallurgical cokeMetallurgical coke
Metallurgical cokeKhhushbakht
 
METAL MANUFACTURING AND FURNACES
METAL MANUFACTURING AND FURNACESMETAL MANUFACTURING AND FURNACES
METAL MANUFACTURING AND FURNACESNeelRao
 
Ferrosilicon productiion and submerged arc furnace
Ferrosilicon productiion and submerged arc furnaceFerrosilicon productiion and submerged arc furnace
Ferrosilicon productiion and submerged arc furnaceNasser Harby
 
Ferrosilicon productiion and submerged arc furnace (1)
Ferrosilicon productiion and submerged arc furnace (1)Ferrosilicon productiion and submerged arc furnace (1)
Ferrosilicon productiion and submerged arc furnace (1)Nasser Harby
 
Industrial melting furnaces
Industrial melting furnacesIndustrial melting furnaces
Industrial melting furnacesNear East Uni
 
report-pankaj.docx2FIMAL
report-pankaj.docx2FIMALreport-pankaj.docx2FIMAL
report-pankaj.docx2FIMALPankaj Kumar
 
Blast Furnace Iron Making Process with Construction and Chemical Reactions in...
Blast Furnace Iron Making Process with Construction and Chemical Reactions in...Blast Furnace Iron Making Process with Construction and Chemical Reactions in...
Blast Furnace Iron Making Process with Construction and Chemical Reactions in...029DevendraKumarSing
 
Furnaces in primary metal production
Furnaces in primary metal productionFurnaces in primary metal production
Furnaces in primary metal productionStelter & Brinck
 
project report bsl
project report bslproject report bsl
project report bslAKSHAY KUMAR
 
PRODUCTION OF FERRO ALLOY seminar.pptx
PRODUCTION OF FERRO ALLOY seminar.pptxPRODUCTION OF FERRO ALLOY seminar.pptx
PRODUCTION OF FERRO ALLOY seminar.pptxLiveandletLive3
 

Ähnlich wie Furnace, fuels and fluxes (20)

High Speed Infra Red Furnace
High Speed Infra Red FurnaceHigh Speed Infra Red Furnace
High Speed Infra Red Furnace
 
iron (2)Iron and steel industry occupational.pptx
iron (2)Iron and steel industry  occupational.pptxiron (2)Iron and steel industry  occupational.pptx
iron (2)Iron and steel industry occupational.pptx
 
A VOCATIONAL TRAINNING REPORT_aman
A  VOCATIONAL TRAINNING REPORT_amanA  VOCATIONAL TRAINNING REPORT_aman
A VOCATIONAL TRAINNING REPORT_aman
 
Thermal energy management of blast furnace plant
Thermal energy management of blast furnace plantThermal energy management of blast furnace plant
Thermal energy management of blast furnace plant
 
Chapter 7 - Coal.pptx
Chapter 7 - Coal.pptxChapter 7 - Coal.pptx
Chapter 7 - Coal.pptx
 
Blast furnace fuel.pptxhbgggjjiiikkkkkkkkk
Blast furnace fuel.pptxhbgggjjiiikkkkkkkkkBlast furnace fuel.pptxhbgggjjiiikkkkkkkkk
Blast furnace fuel.pptxhbgggjjiiikkkkkkkkk
 
Iron and Steel Making with allied chemical reactions .pptx
Iron and Steel Making with allied chemical reactions .pptxIron and Steel Making with allied chemical reactions .pptx
Iron and Steel Making with allied chemical reactions .pptx
 
Metallurgical coke
Metallurgical cokeMetallurgical coke
Metallurgical coke
 
METAL MANUFACTURING AND FURNACES
METAL MANUFACTURING AND FURNACESMETAL MANUFACTURING AND FURNACES
METAL MANUFACTURING AND FURNACES
 
Arc furnaces eaf
Arc furnaces eafArc furnaces eaf
Arc furnaces eaf
 
Manu
ManuManu
Manu
 
Ferrosilicon productiion and submerged arc furnace
Ferrosilicon productiion and submerged arc furnaceFerrosilicon productiion and submerged arc furnace
Ferrosilicon productiion and submerged arc furnace
 
Ferrosilicon productiion and submerged arc furnace (1)
Ferrosilicon productiion and submerged arc furnace (1)Ferrosilicon productiion and submerged arc furnace (1)
Ferrosilicon productiion and submerged arc furnace (1)
 
Industrial melting furnaces
Industrial melting furnacesIndustrial melting furnaces
Industrial melting furnaces
 
report-pankaj.docx2FIMAL
report-pankaj.docx2FIMALreport-pankaj.docx2FIMAL
report-pankaj.docx2FIMAL
 
Blast Furnace Iron Making Process with Construction and Chemical Reactions in...
Blast Furnace Iron Making Process with Construction and Chemical Reactions in...Blast Furnace Iron Making Process with Construction and Chemical Reactions in...
Blast Furnace Iron Making Process with Construction and Chemical Reactions in...
 
Furnaces in primary metal production
Furnaces in primary metal productionFurnaces in primary metal production
Furnaces in primary metal production
 
project report bsl
project report bslproject report bsl
project report bsl
 
Metal Casting.pptx
Metal Casting.pptxMetal Casting.pptx
Metal Casting.pptx
 
PRODUCTION OF FERRO ALLOY seminar.pptx
PRODUCTION OF FERRO ALLOY seminar.pptxPRODUCTION OF FERRO ALLOY seminar.pptx
PRODUCTION OF FERRO ALLOY seminar.pptx
 

Kürzlich hochgeladen

VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130Suhani Kapoor
 
Porous Ceramics seminar and technical writing
Porous Ceramics seminar and technical writingPorous Ceramics seminar and technical writing
Porous Ceramics seminar and technical writingrakeshbaidya232001
 
Software Development Life Cycle By Team Orange (Dept. of Pharmacy)
Software Development Life Cycle By  Team Orange (Dept. of Pharmacy)Software Development Life Cycle By  Team Orange (Dept. of Pharmacy)
Software Development Life Cycle By Team Orange (Dept. of Pharmacy)Suman Mia
 
(MEERA) Dapodi Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Escorts
(MEERA) Dapodi Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Escorts(MEERA) Dapodi Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Escorts
(MEERA) Dapodi Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Escortsranjana rawat
 
Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...
Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...
Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...Dr.Costas Sachpazis
 
CCS335 _ Neural Networks and Deep Learning Laboratory_Lab Complete Record
CCS335 _ Neural Networks and Deep Learning Laboratory_Lab Complete RecordCCS335 _ Neural Networks and Deep Learning Laboratory_Lab Complete Record
CCS335 _ Neural Networks and Deep Learning Laboratory_Lab Complete RecordAsst.prof M.Gokilavani
 
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur EscortsHigh Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escortsranjana rawat
 
(SHREYA) Chakan Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Esc...
(SHREYA) Chakan Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Esc...(SHREYA) Chakan Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Esc...
(SHREYA) Chakan Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Esc...ranjana rawat
 
The Most Attractive Pune Call Girls Budhwar Peth 8250192130 Will You Miss Thi...
The Most Attractive Pune Call Girls Budhwar Peth 8250192130 Will You Miss Thi...The Most Attractive Pune Call Girls Budhwar Peth 8250192130 Will You Miss Thi...
The Most Attractive Pune Call Girls Budhwar Peth 8250192130 Will You Miss Thi...ranjana rawat
 
UNIT-V FMM.HYDRAULIC TURBINE - Construction and working
UNIT-V FMM.HYDRAULIC TURBINE - Construction and workingUNIT-V FMM.HYDRAULIC TURBINE - Construction and working
UNIT-V FMM.HYDRAULIC TURBINE - Construction and workingrknatarajan
 
HARDNESS, FRACTURE TOUGHNESS AND STRENGTH OF CERAMICS
HARDNESS, FRACTURE TOUGHNESS AND STRENGTH OF CERAMICSHARDNESS, FRACTURE TOUGHNESS AND STRENGTH OF CERAMICS
HARDNESS, FRACTURE TOUGHNESS AND STRENGTH OF CERAMICSRajkumarAkumalla
 
Call Girls Service Nashik Vaishnavi 7001305949 Independent Escort Service Nashik
Call Girls Service Nashik Vaishnavi 7001305949 Independent Escort Service NashikCall Girls Service Nashik Vaishnavi 7001305949 Independent Escort Service Nashik
Call Girls Service Nashik Vaishnavi 7001305949 Independent Escort Service NashikCall Girls in Nagpur High Profile
 
Call Girls Service Nagpur Tanvi Call 7001035870 Meet With Nagpur Escorts
Call Girls Service Nagpur Tanvi Call 7001035870 Meet With Nagpur EscortsCall Girls Service Nagpur Tanvi Call 7001035870 Meet With Nagpur Escorts
Call Girls Service Nagpur Tanvi Call 7001035870 Meet With Nagpur EscortsCall Girls in Nagpur High Profile
 
HARMONY IN THE NATURE AND EXISTENCE - Unit-IV
HARMONY IN THE NATURE AND EXISTENCE - Unit-IVHARMONY IN THE NATURE AND EXISTENCE - Unit-IV
HARMONY IN THE NATURE AND EXISTENCE - Unit-IVRajaP95
 
Processing & Properties of Floor and Wall Tiles.pptx
Processing & Properties of Floor and Wall Tiles.pptxProcessing & Properties of Floor and Wall Tiles.pptx
Processing & Properties of Floor and Wall Tiles.pptxpranjaldaimarysona
 
Introduction to Multiple Access Protocol.pptx
Introduction to Multiple Access Protocol.pptxIntroduction to Multiple Access Protocol.pptx
Introduction to Multiple Access Protocol.pptxupamatechverse
 
Call for Papers - Educational Administration: Theory and Practice, E-ISSN: 21...
Call for Papers - Educational Administration: Theory and Practice, E-ISSN: 21...Call for Papers - Educational Administration: Theory and Practice, E-ISSN: 21...
Call for Papers - Educational Administration: Theory and Practice, E-ISSN: 21...Christo Ananth
 
SPICE PARK APR2024 ( 6,793 SPICE Models )
SPICE PARK APR2024 ( 6,793 SPICE Models )SPICE PARK APR2024 ( 6,793 SPICE Models )
SPICE PARK APR2024 ( 6,793 SPICE Models )Tsuyoshi Horigome
 
Introduction and different types of Ethernet.pptx
Introduction and different types of Ethernet.pptxIntroduction and different types of Ethernet.pptx
Introduction and different types of Ethernet.pptxupamatechverse
 

Kürzlich hochgeladen (20)

VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
 
Porous Ceramics seminar and technical writing
Porous Ceramics seminar and technical writingPorous Ceramics seminar and technical writing
Porous Ceramics seminar and technical writing
 
Software Development Life Cycle By Team Orange (Dept. of Pharmacy)
Software Development Life Cycle By  Team Orange (Dept. of Pharmacy)Software Development Life Cycle By  Team Orange (Dept. of Pharmacy)
Software Development Life Cycle By Team Orange (Dept. of Pharmacy)
 
(MEERA) Dapodi Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Escorts
(MEERA) Dapodi Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Escorts(MEERA) Dapodi Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Escorts
(MEERA) Dapodi Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Escorts
 
Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...
Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...
Structural Analysis and Design of Foundations: A Comprehensive Handbook for S...
 
CCS335 _ Neural Networks and Deep Learning Laboratory_Lab Complete Record
CCS335 _ Neural Networks and Deep Learning Laboratory_Lab Complete RecordCCS335 _ Neural Networks and Deep Learning Laboratory_Lab Complete Record
CCS335 _ Neural Networks and Deep Learning Laboratory_Lab Complete Record
 
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur EscortsHigh Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
 
(SHREYA) Chakan Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Esc...
(SHREYA) Chakan Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Esc...(SHREYA) Chakan Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Esc...
(SHREYA) Chakan Call Girls Just Call 7001035870 [ Cash on Delivery ] Pune Esc...
 
The Most Attractive Pune Call Girls Budhwar Peth 8250192130 Will You Miss Thi...
The Most Attractive Pune Call Girls Budhwar Peth 8250192130 Will You Miss Thi...The Most Attractive Pune Call Girls Budhwar Peth 8250192130 Will You Miss Thi...
The Most Attractive Pune Call Girls Budhwar Peth 8250192130 Will You Miss Thi...
 
UNIT-V FMM.HYDRAULIC TURBINE - Construction and working
UNIT-V FMM.HYDRAULIC TURBINE - Construction and workingUNIT-V FMM.HYDRAULIC TURBINE - Construction and working
UNIT-V FMM.HYDRAULIC TURBINE - Construction and working
 
★ CALL US 9953330565 ( HOT Young Call Girls In Badarpur delhi NCR
★ CALL US 9953330565 ( HOT Young Call Girls In Badarpur delhi NCR★ CALL US 9953330565 ( HOT Young Call Girls In Badarpur delhi NCR
★ CALL US 9953330565 ( HOT Young Call Girls In Badarpur delhi NCR
 
HARDNESS, FRACTURE TOUGHNESS AND STRENGTH OF CERAMICS
HARDNESS, FRACTURE TOUGHNESS AND STRENGTH OF CERAMICSHARDNESS, FRACTURE TOUGHNESS AND STRENGTH OF CERAMICS
HARDNESS, FRACTURE TOUGHNESS AND STRENGTH OF CERAMICS
 
Call Girls Service Nashik Vaishnavi 7001305949 Independent Escort Service Nashik
Call Girls Service Nashik Vaishnavi 7001305949 Independent Escort Service NashikCall Girls Service Nashik Vaishnavi 7001305949 Independent Escort Service Nashik
Call Girls Service Nashik Vaishnavi 7001305949 Independent Escort Service Nashik
 
Call Girls Service Nagpur Tanvi Call 7001035870 Meet With Nagpur Escorts
Call Girls Service Nagpur Tanvi Call 7001035870 Meet With Nagpur EscortsCall Girls Service Nagpur Tanvi Call 7001035870 Meet With Nagpur Escorts
Call Girls Service Nagpur Tanvi Call 7001035870 Meet With Nagpur Escorts
 
HARMONY IN THE NATURE AND EXISTENCE - Unit-IV
HARMONY IN THE NATURE AND EXISTENCE - Unit-IVHARMONY IN THE NATURE AND EXISTENCE - Unit-IV
HARMONY IN THE NATURE AND EXISTENCE - Unit-IV
 
Processing & Properties of Floor and Wall Tiles.pptx
Processing & Properties of Floor and Wall Tiles.pptxProcessing & Properties of Floor and Wall Tiles.pptx
Processing & Properties of Floor and Wall Tiles.pptx
 
Introduction to Multiple Access Protocol.pptx
Introduction to Multiple Access Protocol.pptxIntroduction to Multiple Access Protocol.pptx
Introduction to Multiple Access Protocol.pptx
 
Call for Papers - Educational Administration: Theory and Practice, E-ISSN: 21...
Call for Papers - Educational Administration: Theory and Practice, E-ISSN: 21...Call for Papers - Educational Administration: Theory and Practice, E-ISSN: 21...
Call for Papers - Educational Administration: Theory and Practice, E-ISSN: 21...
 
SPICE PARK APR2024 ( 6,793 SPICE Models )
SPICE PARK APR2024 ( 6,793 SPICE Models )SPICE PARK APR2024 ( 6,793 SPICE Models )
SPICE PARK APR2024 ( 6,793 SPICE Models )
 
Introduction and different types of Ethernet.pptx
Introduction and different types of Ethernet.pptxIntroduction and different types of Ethernet.pptx
Introduction and different types of Ethernet.pptx
 

Furnace, fuels and fluxes

  • 1. 21st February, 2018 UNIVERSITY OF LAGOS, AKOKA LAGOS, NIGERIA A seminar presentation by group one FURNACES, FUELS AND FLUXES IN CHEMICAL METALLURGY DEPARTMENT OF METALLURGICAL AND MATERIALS ENGINEERING FACULTY OF ENGINEERING
  • 2. GROUP MEMBERS  GROUP LEADER ADESINA JOSHUA OLUWATIMILEHIN  MEMBERS ADESOLA SEGUN EMMANUEL ODUNOSHO ADEDAMOLA MICHAEL EJIOFOR IKECHUKWU CHIBUIKEM
  • 3. INTRODUCTION The subject of metallurgy is an integral constituent that must be given a large space, especially for industrialization. In fact, every age the world has seen is defined by materials. From the stone age, bronze, iron, copper and even IT age
  • 4.
  • 5. Objective  This report aims to provide knowledge of furnaces, integrating the study of blast furnace into focus, as it is dominantly used in the extraction of iron;  Fuel with coal as a case study, and why it is essential to the blast furnace, as well as fluxes (lime and dolomite) used during the extraction process  The ultimate aim is to provide substantial knowledge and to state the underlying principles and operations that serve as the basis for what make our world imaginable.
  • 6. Furnace  A furnace is an equipment used to melt metals for casting or to heat materials to change their shape (rolling, forging) or properties (heat treatment).  They are appliances capable of heating materials to such a high temperature that they melt, which from a chemical perspective basically means that they reach the critical threshold temperature at which they convert from solid to liquid (Ricketts 1992).
  • 7. In metallurgy, furnaces are essential devices that are used to carry out many metallurgical processes such as; smelting, heat treatment, and so on. Furnace can majorly be classified as follows, based on the mode of energy:  Fuel-fired furnaces (oil, gas, coke, or coal):  Crucible  Reverbatory or hearth  Rotary  Converter Electric furnaces (Electricity):  Induction  Resistance  Electric arc
  • 8. Fuel-fired Oil-fired (rotary furnace Gas-fired (open-hearth furnace) Coal-fired (blast, rotary and cupola furnaces) Electric furnace Type 1 (Electric arc furnace) Type 2 (Induction furnace) Type 3 (Resistance furnace) Classification of furnace
  • 9. Advantages of electric furnace over gas furnace Electric furnaces require far less maintenance than gas furnaces Electric furnaces are one of the least expensive furnaces to purchase and install Compared to gas furnaces, an electric furnace does not give off any dangerous emissions that could potentially cause harm
  • 10. ADVANTAGES AND DISADVANTAGES OF ELECTRIC FURNACE OVER GAS FURNACE ADVANTAGES  Electric furnaces require far less maintenance than gas furnaces  Electric furnaces are one of the least expensive furnaces to purchase and install  Compared to gas furnaces, an electric furnace does not give off any dangerous emissions that could potentially cause harm DISADVANTAGES  An electric furnace costs more to run than a gas furnace  An electric furnace may be more expensive to repair than a gas furnace  Electric furnaces are not very efficient at heating large spaces
  • 11. ADVANTAGES AND DISADVANTAGES OF OIL-FIRED FURNACE  The advantage of heating with oil is that it may be available when other forms of fuel, such as natural or propane gas, are not.  Nozzles can clog with dirt  Oil furnaces need to be regularly cleaned and the fuel filters must be changed  Controlling heat output is more difficult for oil furnaces than for gas furnaces  Oil furnaces use more electricity than gas furnaces  Most oil furnaces are less
  • 12. DESIGN AND CONSTRUCTION OF FURNACES (BLAST FURNACE AS A CASE STUDY) Why is blast furnace considered a case study? The blast furnace is the first step in producing steel from iron oxides. It has an enormous impact on the production of raw (pig) iron from iron ores (hematite or magnetite), although other methods for iron production are also in use but the efficiency of blast furnace supersedes almost all other iron-making technologies. Without first extracting iron from its ore, you cannot proceed to alloying of iron to get steel, which is an important industrial material.
  • 13. BLAST FURNACE: OVERVIEW The basic idea involves the heating of an iron oxide, often hematite, Fe2O3, with carbon. A jet of air is used to burn the carbon to form the gas carbon dioxide then reacts with more carbon to form carbon monoxide. Carbon mono oxide is then used to reduce the iron oxide to iron. Carbon dioxide is also formed in this reaction.
  • 15. DESIGN AND CONSTRUCTION OF FURNACES (BLAST FURNACE AS A CASE STUDY) Basic components of a furnace:  Refractory chamber  Hearth  Burners  Chimney  Charging and  discharging doors  Stockhouse
  • 16. DESIGN AND CONSTRUCTION OF FURNACES (BLAST FURNACE AS A CASE STUDY)  The design of a modern blast furnace is generally based on the concept of a free standing unit with a surrounding building, providing access to the furnace and support for the blast furnace gas system.  The design of a blast furnace plays a fundamental role in its reliable operation, metallurgical performance, sustained high productivity and long
  • 17. DESIGN AND CONSTRUCTION OF FURNACES (BLAST FURNACE AS A CASE STUDY) EQUIPMENT FOR DESIGNING A BLAST FURNACE EQ The design of a blast furnace should involve equipment which has a proven reputation for reliability, durability, and high performance in the arduous conditions of the blast furnace environment. EQUIPMENT  Auxiliary equipment:  Ore storage yard and bins for temporary storing of raw materials  Belt conveyor or skip-hoist for transporting raw materials to the furnace top  Charging apparatus for charging the raw materials into the furnace  Hot stoves for heating the blast  Equipment for dust removal, and recovering and storing the gas from the furnace top  Equipment for liquid products transfer
  • 18. DESIGN AND CONSTRUCTION OF FURNACES (BLAST FURNACE AS A CASE STUDY) DIFFERENT TEMPERATURE ZONES IN A BLAST FURNACE ZONE  Dead man zone (Above 1500oC)  Hearth zone (1500oC)  Bottom part of the bosh zone  Top part of the bosh zone  Bottom half of the stack zone  Top half of the stack zone
  • 19. DESIGN AND CONSTRUCTION OF FURNACES (BLAST FURNACE AS A CASE STUDY) MODEL OF A BLAST FURNACE OPERATION
  • 20. RAW MATERIALS REQUIRED FOR THE PRODUCTION OF PIG IRON IN A BLAST FURNACE In the blast furnace application, the production of iron historically required three important raw materials:  iron ore  coal converted to "coke", and;  chemical grade limestone In more modern times additional materials have been used such as iron ore pellets and sinter
  • 21. Iron Ore  Iron oxides can come to the blast furnace plant in the form of raw ore, pellets or sinter.  The raw ore is removed from the earth and sized into pieces that range from 0.5 to 1.5 inches. This ore is either Hematite (Fe2O3) or Magnetite (Fe3O4) and the iron content ranges from 50% to 70%.  This iron-rich ore can be charged directly into a blast furnace without any further processing. Iron ore that contains a lower iron content must be processed or beneficiated to increase its iron content. An example is pellet Coal and Limestone will be discussed in the following slides
  • 22. Applications of Furnace Although the purpose of a blast furnace is to chemically reduce and physically convert iron oxides into liquid iron called "hot metal”, the applications of furnaces, generally, include:  Heat treatment: annealing, quenching, ageing, etc  Aerospace Industry: heat treatment of aircraft metals, preheating of titanium alloy bar before forging  Automotive Industry: heat treatment of automotive parts  Application in the Metal Industry: tube, bar, strip, rods, forgings, casting and so on 
  • 23. The use of fuel cannot be undermined in our every day life. Fuel is used in the following areas: 1. Cooking 2. Transportation 3. Manufacturing 4. Heating and cooling buildings 5. Generating electricity to run appliances. INTRODUCTION
  • 26. FUELS  A fuel is defined as a substance used to produce heat or power by combustion  Any chemical process accompanied by the evolution of light and heat is called combustion. It is simply the reaction of substances with oxygen and converts chemical energy into heat and light.  Fuel + Oxygen → Combustion products + Heat
  • 27. Characteristics of a Good Fuel 1. A good fuel should ignite easily. 2. It should have a high calorific value, that is, it should give out a lot of heat. 3. It should be inexpensive and readily available 4. It should be easy to store and transport 5. It should not produce harmful gases.
  • 28. Classification of Fuels Classification of Fuels Based on Physical State Solid Fuel (wood, coal) Liquid Fuel (crude petroleum, natural gasoline) Gaseous Fuel (natural gas) Based on occurrence Primary or natural fuels (wood, coal) Secondary or prepared fuel (charcoal, coke)
  • 29. Solid Fuels  Solid fuel refers to various forms of solid material that can be burnt to release energy, providing heat and light through the process of combustion.  Common examples of solid fuels include wood, charcoal, coke, coal  Solid fuels are extensively used in rocketry as solid propellants.
  • 30. Wood  Wood has been used as fuel from ancient times. Due to large scale of deforestation, wood is no longer used except in forest areas where wood is available at low cost.  Wood when freshly cut contains 25-50% moisture. Normally it is used in air dried condition with 10-15% moisture content.  The calorific value of air dried wood is about 3500-4500 kcal/kg  When wood burns. The ash content is high. This makes dry wood a fuel of low calorific value.  Wood charcoal is obtained by destructive distillation of wood.  The major use of wood charcoal is for producing activated carbon used for adsorption or chemical reactions.
  • 31. Coal Coal is regarded as a fossil fuel produced from the vegetable debris under conditions of high temperature and pressure over million of years Types of coal Peat The lowest carbon content Lignite Brown variety containing 25- 30% carbon and 60% moisture content Sub-bituminous coal Black variety, 35-45% carbon Bituminous Coal Hard black variety, 45-86% carbon. Anthracite Coal The highest ranking coal, carbon content 86-97%
  • 32. Uses of Coal 1. As a primary fuel: Coal is used to produce steam through heat and combustion, which is again used for running turbines to generate electricity in power plants. 2. As a secondary fuel: The product of burning coal in the absence of air is of metallurgical importance. The byproducts plastic, tar and synthetic fibre and also used for making steel in industries.
  • 33. Coke  Coke is obtained when coal is heated strongly out of contact with air. The process is called carbonization or coking 1. Low temperature carbonization: 500⁰C-700⁰C; low temperature coke or semi coke or soft coke. 2. High temperature carbonization: 900⁰C-1100⁰C; metallurgical coke or hard coke.
  • 34. Metallurgical Coke The properties of coke depend on porosity, reactivity and the amount of volatile matter retained by coke during carbonization. Coke is mainly used as a heat source and reducing agent in metallurgy a good coke in metallurgical process should posses the following characteristics: 1. Purity: The metallurgical coke should contain lower percentage of moisture, ash, sulphur and phosphorous. 2. Porosity: The coke should be porous so as to provide contact between carbon and oxygen 3. Strength: The coke used in metallurgical process should have high strength so as to withstand the weight of ore, flux in the furnace. 4. Size: Metallurgical coke should be of medium size. 5. Combustibility: Coke should burn easily. The combustibility of coke depends on the nature of the coal, carbonization temperature and reaction temperature. 6. Calorific Value: It should be high 7. Cost: It should be cheap and readily available.
  • 35. Benefits/disadvantages of solid fuel  Benefits  Solid fuels, compared to liquid fuels or gaseous fuels, are often cheaper, easier to extract, more stable to transport and in many places are more readily available.  Coal in particular, is utilized in the generation of 38.1% of the world’s electricity because it is less expensive and more powerful than its liquid and gas counterparts.
  • 36. Disadvantages  Solid fuels are heavier to transport, require more destructive methods to extract/burn and often have higher carbon, nitrate and sulphate emissions.  With the exception of sustainable wood solid fuel is normally considered non-renewable as it requires thousands of years to form.
  • 37. Liquid Fuel  Liquid fuels are combustible or energy- generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable instead of the fluid.  Most liquid fuels in widespread use are derived from crude oil, also called petroleum.  Many liquid fuels play a primary role in transportation and the economy.
  • 38. Petroleum  Most liquid fuels used are currently produced from petroleum.  The petroleum or crude oil is never used as such, it is refined.  The refining of petroleum is accomplished by three processes: 1. Fractional distillation 2. Cracking, and 3. Treating  The three most important liquid fuels derived are gasoline or petrol, kerosene and diesel oil.
  • 39. Natural gas and Liquefied petroleum gas  Compressed Natural Gas Natural gas, composed chiefly of methane, can be compressed to a liquid and used as a substitute for other traditional liquid fuels. Its combustion is very clean compared to other hydrocarbon fuels, but the fuel’s low boiling point requires the fuel to be kept at high pressure to keep it in liquid state.
  • 40. Natural gas and Liquefied petroleum gas Liquefied petroleum gas (LPG) LP gas is a mixture of propane and butane, both of which are easily compressible gases under standard atmospheric conditions. It offers many f the advantages of compressed natural gas (CNG), but does not burn as cleaner, is denser than air and is much more easily compressed. Commonly used for cooking and space heating, LP gas and compressed propane are seeing increased use in motorized vehicles; propane is the third most commonly used motor fuel globally.
  • 41. Merits and Demerits of Liquid Fuel  Merits Possess higher calorific value per unit mass than solid fuels. Easy transportation through pipes. Less excess furnace space. No wear and tear on furnace parts such as those for solid fuels. For equal heat output, much less space occupancy and much less weight than solid fuels. Combustion without formation of dust, ash, and clinkers.
  • 42. Merits and Demerits of Liquid Fuel  Demerits Costlier than solid fuels. Requirement of costly special storage tanks. Associated with a greater risk of fire hazards, particularly true of highly inflammable and volatile liquid fuels. Requirement of efficient burning, specially designed burners and spraying systems for efficient burning.
  • 43. Gaseous Fuel  Gaseous fuels are obtained either naturally or by the treatment of solid or liquid fuel.  Among the naturally occurring gaseous fuels, natural gas and liquefied petroleum gas are most important.  These gases have high calorific value.  The calorific value and specific gravity of a gaseous fuel determine the thermal output of a heating appliance.
  • 44. Types of Gaseous Fuels Gaseou s Fuel Manufacture d or synthetic fuel gases Natural gas
  • 45. Manufactured Fuel gases  Manufactured fuel gases are those produced through an artificial process, usually gasification, at a location known as a gasworks  Examples are: Coal gas, producer gas, water gas  Producer gases as reducing agent in metallurgical operations  Coal gas are used as illuminants in cities and towns. They are also used in metallurgical operations contributing reducing pressure.  Water gas is used as a source of hydrogen gas and an illuminating agent.
  • 46. Manufactured Fuel Gas  Coal gas: it is obtained by carbonization of coal and consists mainly of hydrogen, carbon monoxide and various hydrocarbons  Producer gas: it is obtained by the partial combustion of coal, coke, anthracite coal or charcoal in a mixed air-stream blast  Water gas: it is a mixture of hydrogen and carbon monoxide and is made by passing steam over incandescent coke.
  • 47. Natural Gas  The main constituent is methane. It is usually found in or near the petroleum field, under the earth’s surface. Apart from methane it contains small amounts of other gases such as ethane and carbon dioxide.  It is a fuel gas substitute for gasoline (petrol), diesel or propane.  It is more environmentally clean alternative to those fuels and it’s much safer than other fuels in the event of spill.  It is made by compressing methane to less than 1% of the volume it occupies at standard atmospheric pressure.  Used in domestic fuel and manufacture of chemicals.
  • 48. Merits and Demerits of Gaseous Fuel  Merits  The supply of fuel gas and hence the temperature of furnace is easily and accurately controlled.  The high temperature is obtained at a moderate cost by pre-heating gas and air with heat of waste gases of combustion.  They are directly used in internal combustion engine.  They do not produce ash or smoke  They undergo complete combustion with minimum air supply.
  • 49. Merits and Demerits of Gaseous Fuel  Demerits They are readily inflammable. They require large storage capacity.
  • 50. SELECTION OF FUEL FOR METALLURGICAL PROCESSES The principal factors taken into account in the selection of a particular type of fuel are:  Suitability to process  Supply position, and  Cost
  • 51. OTHER FACTORS THAT DETERMINE FUEL SELECTION  The type of heating with respect to size  The availability and reliability of supply of fuels in question  The efficiency of the heating operation with the chosen fuel
  • 52. THE ECONOMIC IMPORTANCE OF A FUEL DEPENDS UPON  Its geographical distribution  The cost involved in its tapping and transport  Calorific value of fuel  Its combustion or burning quality in air
  • 53. MAJOR SOURCES OF ENERGY (FUEL) IN THE WORLD  Coal  Oil  Natural gas  Uranium and Nuclear  Hydro Power  Wind  Solar PV  Bio-energy and waste
  • 54. Source: World Energy Council: World Energy Resources, 2013 survey; 23rd edition for the Survey of Energy Resources WORLD ENERGY CONSUMPTION, 2013 SURVEY
  • 55. CRUDE OIL RESERVES (R/P Rate)
  • 58. CRUDE OIL vs COAL  From the reserves and production rate tables, It is seen that that there is reduction in the reserves of coal between 1993 and 2011 while crude oil reserves increase  However, for the production of steel, the use of coal as fuel for the blast furnace is still very much in demand  According to World Coal Association(WCA), global steel production depends on coal. 74% of the steel produced today uses coal.
  • 59. COAL  In 2017, world crude steel production was 1.6 billion tones. WCA CEO, Benjamin Sporton said, “Despite the headlines the reality is that coal will continue to play a significant role in the world’s energy system. India, Pakistan, Bangladesh and parts of Southeast Asia will become the primary engines of future coal demand growth. Today, coal accounts for 27% of global primary energy and is the second most important source of primary energy.”
  • 60. APPLICATION OF COAL FOR THE PRODUCTION OF STEEL Coal performs three functions, which are:  Reducing agent  Source of energy  Source of carbon
  • 61. WHY DOES COAL MATTER: CAN WE MAKE STEEL WITHOUT COAL?  Currently, natural gas is increasingly being used as a replacement for oil. To a certain extent the use of fuel is also being replaced by electric power  On the other hand, coal is indispensable when it comes to the production of iron, which is further processed into steel  Coal cannot be replaced, to any extent, since it is primarily used as reducing agent
  • 62. WHY DOES COAL MATTER: CAN WE MAKE STEEL WITHOUT COAL?  A sustainable iron and steel production is the techno-economic backbone of the national development of any nation including in Nigeria  Coal Action Network Aotearoa (CANA) says that, “60% of solid energy’s production in New Zealand is for steel making.”  The company further says that, “there is no way of making steel without coal”.
  • 63. OTHER INDUSTRIAL APPLICATIONS OF COAL  Electricity generation  Steel production  Cement manufacturing  Liquid fuel  Chemical by-products—ammonia gas for agricultural fertilizer, plastics and fibres, phenol and benzenes  Silicon metals for water repellants, resins silicones and silanes for cosmetics, hair shampoo, toothpaste  Carbon fibre—extremely strong but lightweight, reinforcement material used in construction, mountain bikes  Activated carbon—filters for water, air purification, and in kidney dialysis machine
  • 64. In fact, iron and steel are so important that a steel company in the Republic of South Korea has this inscription on its entrance: “A nation that controls Iron controls the world” – Pohang Steel Company Ltd
  • 65. Fluxes  A flux is derived from Latin “fluxus” meaning “flow”  It is a chemical cleaning agent, flowing agent, or purifying agent.  Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining.
  • 66. FLUX  A metallurgical flux is a substance that is added to combine with gangue (unwanted materials) during ore smelting to form slag that can be separated from the molten metal  It is also used with additives in metal joining process
  • 67. Classes of Flux  Acidic Fluxes: These are fluxes that generally form acids in water and bases. Examples are silica, alumina, and phosphorus  Basic fluxes: are those that would generally form bases in water. Examples are lime and magnesia  Neutral fluxes: are neutral substances because it can be viewed as the reaction product of a base and an acid. Examples are fluorspar, calcium, fluoride * Alumina can act as a basic or acidic flux.
  • 68. Classes of Flux  The degree of acidity or basicity of flux is often specified to characterize the slag chemistry for a particular system.  For example, steelmaking uses slags with more bases (lime and magnesia) than acids (silica and alumina).
  • 69. FLUXES  The minerals and compounds used as fluxes depend on five basic things, which are;  the process requirements  availability  costs  requirements for recycling of intermediate products; and  environmental concerns
  • 70. Flux Addition Process  Fluxes are used in metallurgical processes either in iron-making process or steelmaking process.  In ironmaking, the flux is added either by direct charging or through sinter and fluxed pellets, while;  In steelmaking, flux is added as lime or dolomitic lime that are either charged as lumps or injected as fines
  • 71. Flux Addition Process  Some flux materials are added to repair smelting and refining vessel refractory linings.  The selection of the flux to be added depends on the type of process and type of refractory.  For instance, in copper smelting, an acid slag practice is used, and silica is added for repair of refractories in some parts of the
  • 72. Flux Addition Process  Since 90% of all metal production is iron and steel, the major fluxes consumed will be those used in iron-making and steelmaking, that is, limestone, dolomite, lime, fluorspar, or siliceous sources  However, some small amounts lime and dolomite are used in nonferrous smelting, particularly in smelting and refining of copper and lead ores
  • 73. Flux Selection The selection of flux for a particular process may be dependent on:  The chemistry of flux to be employed  Size of flux available  Geographical location and economics
  • 74. Limestone and Dolomite Fluxes  Limestone is a naturally occurring mineral. The term limestone is applied to any calcareous sedimentary rock consisting essentially of carbonates.  The ore is widely available geographically all over the world. Earth’s crust contains more than 4 % of calcium carbonate.  Limestone is theoretically composed of exclusively calcium carbonate (CaCO3). When limestone contains a certain portion of magnesium, it is called dolomite or dolomitic limestone (CaCO3.MgCO3).
  • 75. Limestone and Dolomite Fluxes  Generally, limestone and dolomite are composed of calcium carbonate (CaCO3), magnesium carbonate (MgCO3), silica (SiO2), alumina (Al2O3), iron (Fe), sulfur (S) and other trace elements.
  • 77. Physical Properties of Limestone and Dolomite  Resistance physical degradation: during handling and transportation is also important to minimize the amount of fines formed  Thermal decrepitation: Thermal decrepitation and physical degradation are not desirable because the permeability of the furnace burden is reduced by the presence of fines. Experience has shown that fine-grained stone decrepitates less than coarse-grained stone in the blast furnace (Gault and Ames, 1960). Resistance of the stone to physical degradation during handling and transportation is also important to minimize the amount of fines formed.
  • 78. Chemical Reactions of Limestone and Dolomite  Limestone and dolomite are calcined or heated to drive off the carbon dioxide prior to use in steelmaking.  Calcination is usually done in rotary kilns at 900 to 1100°C. The reaction proceeds according to: CaCO3(s) = CaO(s) + CO2(g) for limestone, and (Mg,Ca)CO3(s) = (Mg,Ca)O(s) + CO2(g) for dolomite,  Also, the sulfur content of the lime should be low, and The sulfur level in the calcined lime is controlled by regulating the oxygen content in the calcining system exit gas.
  • 79. REQUIREMENTS FOR FLUORSPAR  Fluorspar or calcium fluoride (CaF2) is used as a flux along with lime to improve the fluidity of slag in steelmaking and subsequent ladle metallurgy processing  The fluorspar can be added as lumps, gravel-sized material, or as fines incorporated in briquettes
  • 80. PROPERTIES OF SLAG  Melting Point  Viscosity  Density The successful application of a slag in a metallurgical process depends on the slag chemistry and properties of the molten slag which are obtained by selecting the proper fluxes
  • 81. Applications/Uses of Flux  Smelting processes  Iron and steel making  External Treatment of Hot Metal  Oxygen steel making  Ladle metallurgy  Continuous casting
  • 82. PROBLEMS AND FUTURE TRENDS IN FLUXES AS REGARDS METALLURGY  The demand for saving energy and improving the environment, the consumption of flux for metallurgical purposes is likely to continue downward.  Metal production and flux consumption will be influenced by new process technologies, recycling, and substitution.
  • 83. PROBLEMS AND FUTURE TRENDS IN FLUXES AS REGARDS METALLURGY  Identifiable trends are the use of composite and lightweight materials in transportation vehicles, the increased use of high technology devices and miniaturization.  Substitution of plastics, composites, and light alloys including aluminum will impact the use of steel and the attendant flux consumption
  • 84. CONCLUSION The above shows the design and construction of furnaces (blast furnace) for the industrial production of iron and further purports that furnaces are essential equipment for both an iron making and steelmaking processes. It is also ascertained that the growth of economic depends largely on the production of steel. In addition, the steel industry is seen as the largest employer of labor due to their work multiplier effect.
  • 85. CONCLUSION  More over, coal is seen as an indispensable source of energy for the production of iron, which eventually brings about the production of steel  From the research, it is also seen, as of this moment, that steel cannot be made without coal
  • 86. CONCLUSION  Finally, the existence of steel is largely dependent on furnaces, fuel and fluxes, and these three materials must be properly optimized with the development of new clean energy technologies.  Reduction in adverse effect of burning coal in the environment and superior substitute for fluxes can improve the production of steel and hence, boost the economic values of steel, especially in underdeveloped countries like Nigeria  As a result, this can be seen as a panacea to stagnancy and retrogression that has battered Nigeria for decades.