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International Journal of Civil EngineeringOF CIVIL ENGINEERING AND
  INTERNATIONAL JOURNAL and Technology (IJCIET), ISSN 0976 – 6308
  (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME
                              TECHNOLOGY (IJCIET)
ISSN 0976 – 6308 (Print)
ISSN 0976 – 6316(Online)
Volume 3, Issue 2, July- December (2012), pp. 353-368
                                                                        IJCIET
© IAEME: www.iaeme.com/ijciet.asp
Journal Impact Factor (2012): 3.1861 (Calculated by GISI)               IAEME
www.jifactor.com



           PROPERTIES OF MATERIALS USED IN SELF COMPACTING
                           CONCRETE (SCC)

       N. Krishna Murthy1, A.V. Narasimha Rao 2, I .V . Ramana Reddy 3, M. Vijaya sekhar Reddy 4,
                                          P. Ramesh 5
       1
         Engineering Department , Yogi Vemana University, Kadapa, & Research Scholar of
                      S.V.Univers,Tirupati, India, e-mail: krishpurna@yahoo.co.in
             2
                Professor ,Department of Civil Engineering, S.V. University, Tirupati, India
              3
                Professor,Department of Civil Engineering, S.V. University, Tirupati, India
                    4
                      HOD,Department of Civil Engineering, SKIT,srikalahasti , India
      5
        Asst. Professor, Department of Civil Engineering, SVEC, A.Rangampeta,Tirupati, India


  ABSTRACT

  Self-compacting concrete (SCC) can be defined as a fresh concrete which
  possesses superior flowability under maintained stability (i.e. no segregation) thus
  allowing self-compaction that is, material consolidation without addition of energy.
  Self-compacting concrete is a fluid mixture suitable for placing in structures with
  congested reinforcement without vibration and it helps in achieving higher quality
  of surface finishes. However utilization of high reactive Metakaolin and Flyash as
  an admixtures as an effective pozzolan which causes great improvement in the pore
  structure. The relative proportions of key components are considered by volume
  rather than by mass. self compacting concrete (SCC) mix design with 29% of coarse
  aggregate, replacement of cement with Metakaolin and class F flyash, combinations
  of both and controlled SCC mix with 0.36 water/cementitious ratio(by weight) and
  388 litre/m3 of cement paste volume. Crushed granite stones of size 16mm and
  12.5mm are used with a blending 60:40 by percentage weight of total coarse
  aggregate. Self-compacting concrete compactibility is affected by the characteristics
  of materials and the mix proportions; it becomes necessary to evolve a procedure for
  mix design of SCC. The properties of different constituent materials used in this
  investigation and it’s standard tests procedures for acceptance characteristics of self-
  compacting concrete such as slump flow, V-funnel and L-Box are presented.

  KEYWORDS: Self Compacting Concrete, Metakaolin, Flyash , Properties.

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International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME


I.    INTRODUCTION

       Self-compacting concrete (SCC) was first developed in Japan in 1988 in
order to achieve durable concrete structures by improving quality in the
construction process. It was also found to offer economic, social and
environmental benefits over traditional vibrated concrete construction. Research
and development work into SCC in Europe began in Sweden in the 1990s and now
nearly all the countries in Europe conduct some form of research and development
into the material. Once the fully compliant SCC is supplied to the point of
application then the final operation of casting requires very little skill or manpower
compared with traditional concrete to produce uniformly dense concrete. Because
of vibration being unnecessary, the noise is reduced and the risk of developing
problems due to the use of vibrating equipment is reduced. Fewer operatives are
required, but more time is needed to test the concrete before placing. In addition to
the benefits described above, SCC is also able to provide a more consistent and
superior finished product for the client, with less defects. Another advantage is that
less skilled labour is required in order for it to be placed, finished and made good
after casting. As the shortage of skilled site labour in construction continues to
increase in the UK and many other countries, this is an additional advantage of the
material which will become increasingly important.

       Research and development of SCC is being conducted by private companies
(mainly product development),by universities (mainly pure research into the
material’s properties), by national bodies and working groups (mainly the
production of national guidelines and specifications) and at European level (Brite-
EuRam and RILEM projects on test methods and                  the casting of SCC,
respectively). There are several organizations that collect the work in this
area.Institute, (PCI, 2003) and European Research Project Report, (Schutter,
2005) are good examples. Symposiums and workshops on this topic were given
by these organizations and several test methods on the flowability of SCC have
been popularized since then. has revolutionized concrete placement.
SCC, was first introduced in the late 1980’s by Japanese researchers is
highly     workable The use of self-consolidating concrete (SCC) has grown
tremendously since its inception in the 1980s.Different from a conventional
concrete, SCC is characterized by its high flowability at the fresh state. Among
the existing test methods, slump flow test, using the traditional slump cone, is the
most common testing method for flowability (or filling ability). During the test,
the final slump flow diameter and T50 (time needed for concrete to reach a spread
diameter of 50 cm are recorded. The U-Box, L-Box are used for the evaluation of
passing ability. These fresh properties are governed by the rheological properties
of the material and some studied have been conducted in the lab to investigate the
L-box test Segregation resistance is another important issue for SCC. Surface
settlement test and the penetration test are two methods to evaluate the resistance
to segregation of SCC in the field. The objective of this paper is to study a set


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of test method and performance based specifications for the workability of
structural SCC that can be used for casting highly restricted or congested
sections. Proven combinations of test methods to assess filling capacity and
stability are proposed and should be of interest to engineers and contractors using
SCC.

The three properties that characterise a concrete as self-compacting Concrete are
Flowing ability—the ability to completely fill all areas and corners of the
formwork into which it is placed

    Passing ability—the ability to pass through congested reinforcement without
separation of the constituents or blocking
Resistance to segregation— the ability to retain the coarse components of the mix
in suspension in order to maintain a homogeneous material.

                               Table 1 :Guidelines for SCC
      Sl.        Description of      EFNARC         NORVEY         SWEDEN       GERMANY
      No.          country
       1     Slump Flow (mm)           550-800       600-750            NA         >750
       2     V Funnel(Sec)               2-5           NA               NA          NA
       3     L- Box( h2/h1)             0.8 -1         NA          0.8-0.85         NA
       4     U- Box(h2-h1)          0-30(mm)           NA               NA          NA
       5     Orimet Test(Second)         0-5           NA               NA          NA
       6     GTM-Stability (%)          0-15           NA               NA          NA
       7     Aggregate Size (mm)        12-20         < 16             < 16        < 16

These properties must all be satisfied in order to design an adequate SCC, together
with other requirements including those for hardened performance.

II. EXPERIMENTAL PROGRAM
    2.1 SCC Mix Target Typical acceptance criteria and target for SCC are shown
in Table 8.

      Table 2. Typical Acceptance Criteria and Target for Self Compacting Concrete

                                                      Unit               SCC Mix Target
                   Property        Test Method                      Minimum       Maximum
                                  Slump Flow by
             Filling ability       Abrams Cone          mm             650           800
                               T50cm Slump Flow         Sec             2             5
                               V-Funnel                 Sec             6            12

            Passing ability     L-Box               h2/h1(mm/mm)       0.8           1.0
              Segregation         V-Funnel atT5min.     Sec             6            12
                resistance




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                                                     July-

 2.2 Properties Of SCC




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International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
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2.3 Mixing Procedure for self compacting Concrete For SCC, it is generally
necessary to use superplasticizers in order to obtain high mobility. Adding a large
volume of powdered material or viscosity modifying admixture can eliminate
segregation. The powdered materials that can be added are fly ash ,Metakaolin,
silica fume, lime stone powder, glass filler and quartzite filler. Okamura and
Ozawa have proposed a mix proportioning system for SCC .

      In this system, the coarse aggregate and fine aggregate contents are fixed
and self-compactibility is to be achieved by adjusting the water /powder ratio and
super plasticizer dosage.     In addition, the test results for acceptance
characteristics for self-compacting concrete such as slump flow, V-funnel and L-
Box are presented.

III Selection of Materials and Mix Proportions

        SCC can be made from any of the constituent materials that are normally
considered for structural concrete . In designing the SCC mix, it is most useful to consider
the relative proportions of the key components by volume rather than by mass.

       Worldwide, there is a wide range of mix proportions that can produce successful
SCC. Typical range of proportions and quantities in order to obtain SCC are given below:
These Guidelines are not intended to provide specific advice on mix design but Table 8.2
gives an indication of the typical range of constituents in SCC by weight and by volume.
These proportions are in no way restrictive and many SCC mixes will fall outside this
range for one or more constituents.


3.1 Characteristics Of Test Methods

            Table 3: Characteristic test methods for self compacting concrete
                     Characteristi               Test         Measured value
                     c                           method
              Flowability/filling     Slump-flow             total spread
              ability                 Kajima box             visual filling
                                      T500                   flow time
                                      V-funnel               flow time
              Viscosity/              O-funnel               flow time
              flowability             Orimet                 flow time
                                      L-box                  passing ratio
                                      U-box                  height difference
              Passing ability         J-ring                 step height, total flow
                                      Kajima box             visual passing ability
                                      penetration            depth
              Segregation             sieve segregation      percent laitance
              resistance
                                      settlement column      segregation ratio




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                   Table 4 Mix proportion of a typical ranges of SCC

                                    Typical range by          Typical range by volume
                   Constituent
                                     mass (kg/m)3                    (liters/m)3
                Powder                      380 - 600
                 Paste                                              300 - 380
                 Water                   150 - 210                  150 - 210
            Coarse aggregate            750 - 1000                  270 - 360
                                  Content balances the volume of the other
          Fine aggregate (sand)   constituents, typically 48 – 55% of total aggregate
                                  weight.
          Water/Powder ratio by                                         0.85 – 1.10
                Volume



                  Table 5 , Mix proportion of a NVC and typical ranges of SCC

            Constituent                  NVC (C40, 75 mm             SCC (Domone, 2006b; The
                                         slump)                      Concrete Society and BRE,
    Coarse aggregate/concrete(%) by vol. 42                          28.0 – 38.6
    Water/powder (by wt.)                0.55                        0.26 – 0.48
    Paste/concrete (%) by vol.           32                          30.4 – 41.5
    Powder content (kg/m 3)              375                         385 – 635
    Sand/mortar (%) by vol.              44                          38.1 – 52.9

III. MATERIALS USED

 3.1 . Fine Aggregate Natural river sand is used as fine aggregate. The
bulk specific gravity in oven dry condition and water absorption of the
sand are 2.6 and 1% respectively. The gradation of the sand was
determined by sieve analysis as per IS-383(1970) and presented in the
Table 6. Fineness modulus of sand is 2.65.
                      Table 6. Sieve Analysis of Fine Aggregate

                                              Cumulative Percent Passing
    Sieve No.
                           Fine Aggregate                      IS: 383-1970 – Zone II Requirement
         10mm                         100                                       100
         4.75mm                       100                                      90-100
         2.36mm                        94                                      75-100
         1.18mm                        74                                      55-90
         600µm                         46                                      35-59
         300µm                         14                                       8-30
        150µm                          3                                        0-10



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2.2.4. Coarse Aggregate
Crushed granite stones of size 16mm and 12.5mm are used as coarse aggregate.
The bulk specific gravity in oven dry condition and water absorption of the
coarse aggregate are 2.66 and 0.3% respectively. The gradation of the coarse
aggregate was determined by sieve analysis as per IS-383(1970) [4] and
presented in the Table7 and Table 8,Fineness modulus of coarse aggregate is 6.67.


               Table 7. Sieve Analysis of 16 mm Coarse Aggregate
                                                 Cumulative Percent Passing
                    IS Sieve Size        16 mm passing        IS: 383-1970 Limits
                      20 mm                   100                     100
                      16 mm                   99                      85-100
                     12.5 mm                 57.77                    N/A
                      10 mm                  18.89                    0-30
                     4.75 mm                   1                       0-5
                     2.36mm                    --                     ----


                   Table 8. Sieve Analysis of 12.5 mm Coarse Aggregate
                                                Cumulative Percent Passing
                    IS Sieve Size        12.5 mm passing     IS: 383-1970 Limits
                      16 mm                  100                       100
                     12.5mm                   94                      85-100
                     10 mm                   36.5                      0-45
                     4.75 mm                 8.76                      0-10
                     2.36 mm                  2.4                      NA

Dry-rodded unit weight (DRUW) and void ratio of coarse aggregate with
relative blending by percentage weight as per IS: 2386 (Part III)-1963 [6] is
shown in Table 6 and Figure 1.

Table 9. Dry-rodded unit weight and Void Ratio of a given coarse aggregate blending

           Coarse Aggregate Blending
             by Percentage Weight      DRUW (kg/m3)         Void Ratio
              ( 16 mm and 12.5 mm)
                     100:0                 1596               0.378
                     80:20                 1642               0.374
                     70:30                 1647               0.376
                     67:33                 1659               0.386
                     60:40                 1608               0.395
                     40:60                 1568               0.399
                     20:80                 1559                0.40
                     0:100                 1533                0.41




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3.2   Water Potable water for casting and curing of the SCC mixes

            Table 10. Chemical Composition and Physical Properties of Cement

                          Test Result                             Requirement as per IS:12269-1989
           Chemical Composition
              Lime Saturation Factor                         Not less than 0.60 & not more than 1.02
      CaO-0.7SO3/2.8SiO2+1.2Al2 O3+0.65Fe2O3        0.89
             Ratio of Alumina/Iron Oxide            1.00                    Min. 0.66
               Insoluble Residue(%)                 1.31                  Not more Than 3.0%
                  % Magnesium oxide(MgO)            1.40                  Not more Than 6.0%
                                                                        Max. 3.0% when C3 A>5.0
            % Sulphuric Anhydride (SO3)             1.91                Max. 2.5% when C3 A<5.0
                   Loss of Ignition(%)              1.29                Not more Than 5.0%
                    Alkalies(%)                      0.60               ---------
                                                      0.01               Not more Than 0.1%
                  Chlorides(%)
                % Silica(SiO2)                      19.79
                                3                    5.67
                % Alumina(Al2O )
                                  3                  4.68
                % Iron Oxide(Fe2O )
                % Lime(CaO)                         61.81
                 C3 A                                 5.5
       Temperature During Testing(0C)                  27                      27 +/-2
                                            Physical Properties
                  Specific gravity                  3.15
                             2                      275                       Min.225
                  Fineness (m /Kg)
                  Soundness                                                     2
               Lechatlier Expansion(mm)             1.50            Max. 10mm
                 Auto clave Expansion (%)           0.04            Max. 0.8%
             Setting time(minutes)
                     Initial                        180           Min. 30 min Max. 600 min
                      Final                         230
              Compressive strength
                       3 Days                        32                        > 23 N/mm2
                       7 Days                        43                        > 33 N/mm2
                      28 days                        55                        > 43 N/mm2


3.3 Additive or Mineral Admixture

Metakaolin manufactured from pure raw material to strict quality standards. Metakaolin is
a high quality pozzolanic material, which blended with Portland cement in order to
improve the strength and durability of concrete and mortars. Metakaolin removes
chemically reactive calcium hydroxide from the hardened cement paste. It reduces the
porosity of hardened concrete. Metakaolin densified and reduces the thickness of the
interfacial zone, this improving the adhesion between the hardened cement paste and
particulars of sand or aggregate. Metakaolin procured from 20 Microns company
Vadodara, Gujarat, India. As per IS-456(2000) , cement is replaced by weight of
material. The specific gravity of Metakaolin is 2.5 .


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3.3.1 Reactivity of Different Pozzolanic Materials

            Table 11 : Reactivity of Different Pozzolanic Materials
                       Material             Pozzolanic Reactivity
                                            mg Ca(OH)2 per g
              Blast furnace slag                            40
              Calcined paper waste                         300
              Microsilica, silica fume                     427
              Calcined bauxite                             534
              Pulverised fuel ash                          875
              High Reactive Metakaolin                    1050

3.3.2   METAKAOLIN

      Metakaolin manufactured from pure raw material to strict quality standards.
Metakaolin is a high quality pozzolanic material, which blended with Portland
cement in order to improve the strength and durability of concrete and mortars.
Metakaolin removes chemically reactive calcium hydroxide from the hardened
cement paste. It reduces the porosity of hardened concrete. Metakaolin densified
and reduces the thickness of the interfacial zone, this improving the adhesion
between the hardened cement paste and particulars of sand or aggregate.
3.3.3 Properties of Metakaolin

      Metakaolin grades of Calcined clays are reactive allumino silicate pozzolan
formed by calcining very pure hydrous China clay. Chemically Metakaolin
combines with Calcium Silicate and Calcium processed to remove uncreative
impurities producing almost 100 percent reactive material. The particle size of
Metakaolin is significantly smaller than cement particles. I S: 456-2000
recommend use of Metacioline as mineral admixture.

      Metakaolin is a thermally structure, ultrafine pozzolan which replace
industrial by-products such as silica fume / micro silica. Commercial use of
Metakaolin has already in several countries worldwide. Metakaolin removes
chemically reactive calcium hydroxide from the hardened cement paste.
Metakaolin reduces the porosity of hardened concrete. Metakaolin densifies
reduces the thickness of the interfacial zone, this improving the adhesion between
the hardened cement paste and particles of sand or aggregate. Blending with
Portland cement Metakaolin improves the properties of concrete and cement
products considerably by:

      Increasing compressive and flexural strength, providing resistance to
chemical attack, reducing permeability substantially, preventing Alkali-Silica
Reaction, reducing efflorescence & Shrinkage and Protecting corrosion




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International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
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3.3.4 Physical and Chemical Properties of Metakaolin
         Physical Properties of                          Chemical Properties
         Metakaolin                                          of Metakaolin
                                               1.5
             Average particle size, µm                         SiO2 + Al2O3 + Fe2O3   96.88%
                                               0.5
            Residue 325 mesh (% max)                                  CaO             0.39%
             B.E.T. Surface area m2/gm         15                     MgO             0.08%
        Pozzolan Reactivity mg Ca(OH)2 / gm 1050                      TiO2            1.35%
                  Specific Gravity             2.5                    Na2O            0.56%
               Bulk Density (gm/ltr.)      300+ or -30                K 2O            0.06%
                     Brightness             80+ or –2                 Li2O              Nil
                                           off-white
                                            powder
                   Physical foam                                      L.O.I           0.68%

3.3.4     Pozzolanic Reactivity of Metakaolin

      Metakaolin is a lime-hungry pozzolan that reacts with free calcium
hydroxide    to   form    stable,   insoluble,      strength-adding,   cementitious
compounds.When Metakaolin – HRM(AS2) reacts with calcium hydroxide(CH), a
cement hydration byproducts, a pozzolanic reaction takes place whereby new
cementitious compounds,(C2ASH8) and (CSH), are formed. These newly formed
compounds will contribute cementitious strength and enhanced durability
properties to the system in place of the otherwise weak and soluble calcium
hydroxide.
                       Cement Hydration Process
      OPC + H2O -----------------------------------------------> CSH + CH
                       Pozzolanic Reaction Process

                                             H 2O
             AS2 + CH        -----------------------------------------------> C2ASH8 + CSH

       Unlike other commercially available pozzolanic materials, Metakaolin is a
quality controlled, manufactured material. It is not a by-product of unrelated
industrial process. Metakaolin has been engineered and optimized to contain a
minimum of impurities and to react efficiently with cement’s hydration byproduct-
calcium hydroxide. Table summarizes the relative reactivities of six different
pozzolans, including High Reactive Metakaolin-HRM.

3.3.5 Fly Ash
Flyash ,known also as pulverized –fuel ash,is the ash precipitated electro-statically from
the exhaust fumes of coal-fired power stations, and is the most common artificial
pozzolana .Flyash is the most commonly used pozzolana with cement. . Class F fly ash
from Rayalaseema Thermal Power Plant (RTPP), Muddanur, A.P, India is used as an
additives according to ASTM C 618 cement is replaced by weight of material. The
specific gravity of fly ash is 2.12


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      Table 13. Chemical and Physical Properties of Class F Fly Ash
                                                                   ASTM C 618 Class F Fly Ash
                   Particulars
       Chemical Composition
                 % Silica(SiO 2)                       65.6
      % Alumina(Al2O3)                                 28.0
      % Iron Oxide(Fe2O3)                               3.0       SiO2+ Al2O3+ Fe2O3>70
      % Lime(CaO)                                       1.0
      % Magnesia(MgO)
                                                        1.0
      % Titanium Oxide (TiO2)                           0.5
      % Sulphur Trioxide (SO3)                          0.2
      Loss on Ignition                                 0.29
      Physical Properties
      Specific gravity                                 2.12
      Fineness (m2/Kg)                                 360         Min.225 m2/kg

3.3.6 Chemical Admixtures

Sika Viscocrete 10R3 is used as high range water reducer (HRWR) SP cum
retarder is used . The properties of the chemical admixtures as obtained from the
manufacturer are presented in the Table 14

Table 14. Properties of Chemical Admixtures Confirming to EN 934-2 Table11.1/11.2 and
SIA 162(1989)
                                                                            Solid    Quantity(%)By
   Chemical         Specific   Appearance
                                                          Relative Density Content   cementitious
   Admixture        Gravity    /Colour        Ph                                                   Chemical Base
                                                                           (%)         weight
Sika Visocrete-        1.10    Light brown ≈ Above 6    ≈1.09 kg/lit           40      0.6 - 2        Aqueous
10 R3                             liquid                .(at+300c)                                   solution of
 High Performance                                                                                     Modified
Super-Plasticiser                                                                                  Polycarboxylate
cum
retarder(HRWRA)



IV     EXPERIMENTAL INVESTIGATIONS
4.1. SCC Mix Design

Several methods exist for the mix design of SCC. The general purpose mix design
method was first developed by Okamura and Ozawa (1995). In this study, the key
proportions for the mixes are done by volume. The detailed steps for mix design
are described as follows:
1. Assume air content as 2% (20 litres) of concrete volume.
2. Determine the dry-rodded unit weight (DRUW) of coarse aggregate for a
given coarse aggregate blending.
3. Using DRUW, calculate the coarse aggregate content by volume (28 – 35%) of
mix volume.


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     4. Adopt fine aggregate volume of 40 to 50% of the mortar volume.
     5. Maintain paste volume of 388 litre/m3 of the concrete volume. 6. Keep water/
     cementitious ratio by weight (w/cm) as 0.36.
     7. Calculate the binder (cementitious material) content by weight.
     8. Replace cement with Metakaolin,fly ash and combinations of both by weight of
     cementitious material.
     9. Optimize the dosages of super plasticizer (SP) and viscosity modifying agent
     for the given w/cm (0.36) using mortar tests by mini slump cone test.
     10. Perform SCC tests.

     4.2    Percentage of Mix Proportions.

     Mix types with percentage relative proportions and mix proportions of constituent
     materials are shown in Table 9 and Table 10.

     Table 16. Designed Mix Proportions
Sl.    Designation of    Total Cement Metakao        Flyash F.A       C.A    Water S.P.   S.P       W/P
No.    Mix Proportion    Binder      3     lin            3      3        3      3 (%)        3     ratio
                                (Kg/m )             (Kg/m ) (Kg/m ) (Kg/m ) (Kg/m )     (Kg/m )
                              3                 3
                        (Kg/m )         (Kg/m )
 1           MK5         533.00 506.35   26.65        -----   836   771.84   191.88   0.9   4.797   0.36
 2           MK10        530.00 477.00   53.00        -----   836   771.84   190.80   0.9   4.770   0.36
 3           MK15        527.00 447.95   79.05        -----   836   771.84   189.72   0.9   4.743   0.36
 4           MK20        523.50 418.80 105.00         -----   836   771.84   188.46   0.9   4.712   0.36
 5           FA10        524.50 472.00    -----      52.45    836   771.84   188.82   0.9   4.721   0.36
 6           FA20        513.50 410.80    -----     102.70    836   771.84   184.86   0.9   4.622   0.36
 7           FA30        502.00 351.75    -----     150.75    836   771.84   180.90   0.9   4.523   0.36
 8         MK5+FA30      499.50 324.68   25.00      149.85    836   771.84   179.82   0.9   4.500   0.36
 9         MK10+FA20     507.50 355.25   50.75      101.50    836   771.84   182.70   0.9   4.570   0.36
10         MK15+FA10     504.00 378.00   75.60      50.40     836   771.84   181.44   0.9   4.536   0.36
11           SCC         536.00 536.00    -----       -----   836   771.84   192.96   0.9   4.824   0.36


     V . Testing Fresh Properties of SCC
     5.1. Slump Flow Test.
     The slump flow test is used to assess the horizontal free flow of SCC in the absence of
     obstructions. The test also indicates resistance to segregation. On lifting the slump
     cone, filled with concrete the average diameter spread of the concrete is measured. It
     indicates the filling ability of the concrete. Slump flow test apparatus is shown in Figure
     3(a). Slump cone has 20 cm bottom diameter, 10 cm top diameter and 30 cm in height. In
     this test, the slump cone mould is placed exactly on the 20 cm diameter graduated circle
     marked on the glass plate, filled with concrete and lifted upwards. The subsequent
     diameter of the concrete spread is measured in two perpendicular directions and the
     average of the diameters is reported as the spread of the concrete.
     T50cm is the time measured from lifting the cone to the concrete reaching a diameter of
     50 cm. The measured T50cm indicates the deformation rate or viscosity of the concrete.
     The slump flow is used to assess the horizontal free flow and the filling ability of SCC in
     the absence of obstructions. It is recommended to maintain slump flow value as 650 to 800
     mm. This test is used along with slump flow test to assess the flowability of SCC.

                                                     364
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME

5.2 . V-Funnel Test

 The flowability of the fresh concrete can be tested with the V-funnel test,
whereby the flow time is measured. The funnel is filled with about 12 litres
of concrete and the time taken for it to flow through the apparatus is
measured. Shorter flow time indicate greater flowability. V-Funnel test
apparatus dimensions are shown in Figure 3(b). In this test, trap door is
closed at the bottom of V-Funnel and V-Funnel is completely filled with
fresh concrete. V-Funnel time is the time measured from opening the trap
door and complete emptying the funnel. Again, the V-Funnel is filled with
concrete, kept for 5 minutes and trap door is opened. V-Funnel time is
measured again and this indicates V-Funnel time at T5min. This test is used
to determine the filling ability, flowability and segregation resistance of
SCC.

5.3 L-Box Test

This is a widely used test, suitable for laboratory and site use. It assesses
filling and passing ability of SCC and serious lack of stability (segregation)
can be detected visually. The vertical section of the L- Box is filled with
concrete, and then the gate is lifted to let the concrete flow into the
horizontal section. Blocking ratio (i.e. is ratio of the height of the concrete at
the end of the horizontal section (h2) to height of concrete at beginning of
horizontal section (h1)) is determined.
L-Box test apparatus dimensions are shown in Figure In this test, fresh
concrete is filled in the vertical section of L-Box and the gate is lifted to let
the concrete to flow into the horizontal section. The height of the concrete
at the end of horizontal section represents h2 (mm) at the vertical section
represents h1 (mm). The ratio h2/h1 represents blocking ratio .This test
assesses the flow of the concrete in presence of reinforcement obstructions.

5.4. Determination of Consistence Retention

Consistence retention is also an important fresh property of SCC in view of
workability. It refers to the period of duration during which SCC retains its
properties, which is important for transportation and placing. Consistence
retention was evaluated by measuring the slump flow spread and T50cm of
successful SCC mixes at 60 minutes after adding water. The SCC mix was
remixed for one minute before each test.




                                        365
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME

VI.   CONCLUSIONS

    Based on the findings of this study, the following conclusions may be drawn:
1. Establishment of standard mix design procedure and appropriate testing
methods is essential for wide spread use of SCC . Most of Indian researchers have
followed European guidelines for testing SCC. Other countries are adopting these
guiedelines with slight modifications as per local conditions.
2. Both coarse aggregate maximum size and coarse aggregate volume are
influenced in obtaining the successful SCC mixes.
3.As the replacements of Metakaolin, Flyash and combinations of both MK and
FA compared with controlled concrete SCC, totally there are eleven type of mix
designs                                     such                                  as
MK5,MK10,MK15,MK20;FA10,FA20,FA30;(MK5+FA30),(MK10+FA20),(MK1
5+FA10) and Controlled mix SCC
4 As per the mix designs and trial mixes addition of MK increases the demand of
HRWRA in SCC Mixes. Replacement of cement by 20%MKin SCC the super
plasticizer cum retarder demands may be increased.
5. As per the mix designs and trial mixes addition of FA decreases the demand of
HRWRA in SCC Mixes. Replacement of cement by 30% FA in SCC the super
plasticizer cum retarder demands may be decreased.
6. The utilization of by-product mineral admixtures is the best alternative for now
a days since it not only makes the concrete       accomplish the proper performance
but also reduce the concrete cost and environmental problems. Incorporating such
materials further enhances the fresh properties of SCC concrete.

REFERENCES

[1].Krishna Murthy.N., NarasimhaRao.A.V., Ramana Reddy,I.V. and Vijaya
sekhar Reddy M.., Mix Design procedure for Self-Compacting Concrete, IOSR
Journal of Engineering(IOSRJEN, Volume 2,Issue 9,(September2012)P.P 33-41.
[2].IS: 3812-2003, Specifications for Pulverized fuel ash, Bureau of Indian
Standards, New Delhi, India.
[3] IS: 8112-1989, Specifications for 43 grade Portland cement, Bureau of Indian
Standards, New Delhi, India.
[4]IS: 383-1970, Specifications for Coarse and Fine aggregates from Natural
sources for Concrete, Bureau of Indian Standards, New Delhi, India.
[5].American Concrete Institute. “Self-Consolidating Concrete”, ACI 237R-07.
[6].American Concrete Institute. “Specifications for Structural Concrete”, ACI
301.
[7].American Society for Testing and Materials. “Standard specification for coal
fly ash and raw or calcined natural pozzolan for use in concrete”, ASTM C 618
(2003).
[8].American Society for Testing and Materials. “Standard specification for coal
fly ash and raw or calcined natural pozzolan for use concrete”, ASTM C 618
(2003).


                                        366
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME

 [9].Bureau of Indian Standards. “Methods of test for aggregates for
concrete. Specific gravity,
Density, Voids, Absorption and Bulking”, IS-2386 (Part III, 1963).
[10].Bureau of Indian Standards. “Plain and reinforced concrete code for practice”,
IS-456 (2000), New Delhi. [4]. Bureau of Indian             Standards. “Methods of
test for aggregates for concrete. Specific gravity, Density, Voids, Absorption and
Bulking”, IS-2386 (Part III, 1963).
[11].Domone PLJ. 2006b. “Self-compacting concrete: An analysis of 11 years of
case studies”. Cement and Concrete Composites 28(2):197-208.
[12].EFNARC (European Federation of national trade associations representing
producers and applicators of specialist building products), Specification and
Guidelines for self- compacting concrete, February 2002, Hampshire, U.K.
[13].EFNARC. “Specification and guidelines for self-compacting concrete.
European Federation of Producers and Applicators of          Specialist Products for
Structures”, 2002.
[14].RILEM TC 174 SCC. “Self compacting concrete State-of-the-art report of
RILEM technical committee 174-SCC”. Skarendahl A,              Petersson O, editors,
RILEM Publications S.A.R.L., France, 2000.
[15].Ghazi F Kheder, Rand S Al Jaidiri. 2010. “New Method for Proportioning
Self-Consolidating Concrete Based on Compressive           Strength Requirements”.
ACI Materials 107(5):490-497.
[16].Goodier C. 2001. “Self-Compacting Concrete”. European Network of
Building Research Institutes (ENBRI). 17:6
[17].Khayat KH. 1998. Viscosity-enhancing admixtures for cement-based
materials - An overview. Cement and Concrete Composites, No.20, 2-3: 171-188
 [18].Newman J, Choo BS. Advanced concrete technology concrete
properties. Elsevier Butterworth Heinemann, 2003.
 [19].Okamura H, Ozawa K. 1995. “Mix design for self-compacting concrete”.
Concrete Library of Japanese Society of Civil Engineers 25(6):107-120.
[20].Okamura H, Ouchi M. 1999. “Self-compacting concrete development, present
use and future”.In:The 1st International RILEM Symposium on Self-Compacting
Concrete. Skarendahl A, Petersson O, editors, RILEM Publications. S.A.R.L,
France. 3-14.
[21].Ozawa K, Maekawa K, Kunishima M, Okamura H. 1989. “Development of
high performance concrete based on the durability design of concrete structures”.
445-450.
[22].Nagamoto N., Ozawa K., Mixture properties of Self-Compacting, High-
Performance Concrete,         Proceedings, Third CANMET/ACI International
Conferences on Design and Materials and Recent Advances in Concrete
Technology, SP- 172, V.             M. Malhotra, American Concrete Institute,
Farmington Hills, Mich. 1997, p. 623-637.
[23].Khayat K.H., Ghezal A., Utility of Statistical models in Proportioning Self-
Compacting Concrete, Proceedings, RILEM
[24].International symposium on Self-Compacting Concrete, Stockholm, 1999, p.
345-359.


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International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME

[25].Okamura H., Ozawa K., Mix Design for Self-Compacting Concrete, Concrete
Library of Japanese Society of Civil Engineers, June 25, 1995, p. 107-120.
[26].Nagataki S., Fujiwara H., Self-Compacting property of Highly-Flowable
concrete, Second Conference on advances in Concrete Technology, ACI SP-
154,V.M. Malhotra, American Concrete Institute, June 1995, p. 301-304.
[27] Khayat K.H., Manai K., Lesbetons autonivlants : proprietes,
charcterisation et applications , colloque sur les betons autonivlants, Universite de
Sherbroke, Canada, November 1996, p. 8.
 [28]. Ghazi F Kheder, Rand S Al Jaidiri. 2010. “New Method for Proportioning
Self-Consolidating Concrete Based on Compressive Strength Requirements”. ACI
Materials 107(5):490-497.
 [29].Petersson O., Billberg P., Van B.K., A model for Self-Compacting Concrete,
Proceedings of Production Methods and Workability of Concrete,1996, E & FN
Span, London, p. 483- 492.
 [30]Okamura H, Ozawa K. 1995. “Mix design for self-compacting concrete”.
Concrete Library of Japanese Society of Civil Engineers 25(6):107-120.
[31].Okamura H. 1997. “Self-compacting high-performance concrete”. Concrete
International 19(7):50-54.
[32].Okamura H, Ouchi M. 1999. “Self-compacting concrete development,
present use and future”. In: The 1st International RILEM Symposium on Self-
Compacting Concrete. Skarendahl A, Petersson O, editors, RILEM Publications.
S.A.R.L, France. 3-14.
[33]. Okamura H, Ouchi M. 2003b. “Self-compacting concrete”. Journal of
Advanced Concrete Technology 1(1):5-15.
[34]. Ozawa K, Maekawa K, Kunishima M, Okamura H. 1989. “Development of
high performance concrete based on the durability design of concrete structures”.
445-450.
[35]. Skarendahl, A. and Petersson, O. (eds.), “Self-compacting concrete”, State-
of-the-art report of RILEM Technical Committee 174-SCC, RILEM Publications,
2000.
[36]. The Concrete Society, BRE. 2005. “Technical report No.62 self-
compacting concrete: a review”. Day RTU, Holton IX, editors, Camberley, UK,
Concrete Society, Surrey GU17 9AB, UK.




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Properties of materials used in self

  • 1. International Journal of Civil EngineeringOF CIVIL ENGINEERING AND INTERNATIONAL JOURNAL and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME TECHNOLOGY (IJCIET) ISSN 0976 – 6308 (Print) ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), pp. 353-368 IJCIET © IAEME: www.iaeme.com/ijciet.asp Journal Impact Factor (2012): 3.1861 (Calculated by GISI) IAEME www.jifactor.com PROPERTIES OF MATERIALS USED IN SELF COMPACTING CONCRETE (SCC) N. Krishna Murthy1, A.V. Narasimha Rao 2, I .V . Ramana Reddy 3, M. Vijaya sekhar Reddy 4, P. Ramesh 5 1 Engineering Department , Yogi Vemana University, Kadapa, & Research Scholar of S.V.Univers,Tirupati, India, e-mail: krishpurna@yahoo.co.in 2 Professor ,Department of Civil Engineering, S.V. University, Tirupati, India 3 Professor,Department of Civil Engineering, S.V. University, Tirupati, India 4 HOD,Department of Civil Engineering, SKIT,srikalahasti , India 5 Asst. Professor, Department of Civil Engineering, SVEC, A.Rangampeta,Tirupati, India ABSTRACT Self-compacting concrete (SCC) can be defined as a fresh concrete which possesses superior flowability under maintained stability (i.e. no segregation) thus allowing self-compaction that is, material consolidation without addition of energy. Self-compacting concrete is a fluid mixture suitable for placing in structures with congested reinforcement without vibration and it helps in achieving higher quality of surface finishes. However utilization of high reactive Metakaolin and Flyash as an admixtures as an effective pozzolan which causes great improvement in the pore structure. The relative proportions of key components are considered by volume rather than by mass. self compacting concrete (SCC) mix design with 29% of coarse aggregate, replacement of cement with Metakaolin and class F flyash, combinations of both and controlled SCC mix with 0.36 water/cementitious ratio(by weight) and 388 litre/m3 of cement paste volume. Crushed granite stones of size 16mm and 12.5mm are used with a blending 60:40 by percentage weight of total coarse aggregate. Self-compacting concrete compactibility is affected by the characteristics of materials and the mix proportions; it becomes necessary to evolve a procedure for mix design of SCC. The properties of different constituent materials used in this investigation and it’s standard tests procedures for acceptance characteristics of self- compacting concrete such as slump flow, V-funnel and L-Box are presented. KEYWORDS: Self Compacting Concrete, Metakaolin, Flyash , Properties. 353
  • 2. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME I. INTRODUCTION Self-compacting concrete (SCC) was first developed in Japan in 1988 in order to achieve durable concrete structures by improving quality in the construction process. It was also found to offer economic, social and environmental benefits over traditional vibrated concrete construction. Research and development work into SCC in Europe began in Sweden in the 1990s and now nearly all the countries in Europe conduct some form of research and development into the material. Once the fully compliant SCC is supplied to the point of application then the final operation of casting requires very little skill or manpower compared with traditional concrete to produce uniformly dense concrete. Because of vibration being unnecessary, the noise is reduced and the risk of developing problems due to the use of vibrating equipment is reduced. Fewer operatives are required, but more time is needed to test the concrete before placing. In addition to the benefits described above, SCC is also able to provide a more consistent and superior finished product for the client, with less defects. Another advantage is that less skilled labour is required in order for it to be placed, finished and made good after casting. As the shortage of skilled site labour in construction continues to increase in the UK and many other countries, this is an additional advantage of the material which will become increasingly important. Research and development of SCC is being conducted by private companies (mainly product development),by universities (mainly pure research into the material’s properties), by national bodies and working groups (mainly the production of national guidelines and specifications) and at European level (Brite- EuRam and RILEM projects on test methods and the casting of SCC, respectively). There are several organizations that collect the work in this area.Institute, (PCI, 2003) and European Research Project Report, (Schutter, 2005) are good examples. Symposiums and workshops on this topic were given by these organizations and several test methods on the flowability of SCC have been popularized since then. has revolutionized concrete placement. SCC, was first introduced in the late 1980’s by Japanese researchers is highly workable The use of self-consolidating concrete (SCC) has grown tremendously since its inception in the 1980s.Different from a conventional concrete, SCC is characterized by its high flowability at the fresh state. Among the existing test methods, slump flow test, using the traditional slump cone, is the most common testing method for flowability (or filling ability). During the test, the final slump flow diameter and T50 (time needed for concrete to reach a spread diameter of 50 cm are recorded. The U-Box, L-Box are used for the evaluation of passing ability. These fresh properties are governed by the rheological properties of the material and some studied have been conducted in the lab to investigate the L-box test Segregation resistance is another important issue for SCC. Surface settlement test and the penetration test are two methods to evaluate the resistance to segregation of SCC in the field. The objective of this paper is to study a set 354
  • 3. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME of test method and performance based specifications for the workability of structural SCC that can be used for casting highly restricted or congested sections. Proven combinations of test methods to assess filling capacity and stability are proposed and should be of interest to engineers and contractors using SCC. The three properties that characterise a concrete as self-compacting Concrete are Flowing ability—the ability to completely fill all areas and corners of the formwork into which it is placed Passing ability—the ability to pass through congested reinforcement without separation of the constituents or blocking Resistance to segregation— the ability to retain the coarse components of the mix in suspension in order to maintain a homogeneous material. Table 1 :Guidelines for SCC Sl. Description of EFNARC NORVEY SWEDEN GERMANY No. country 1 Slump Flow (mm) 550-800 600-750 NA >750 2 V Funnel(Sec) 2-5 NA NA NA 3 L- Box( h2/h1) 0.8 -1 NA 0.8-0.85 NA 4 U- Box(h2-h1) 0-30(mm) NA NA NA 5 Orimet Test(Second) 0-5 NA NA NA 6 GTM-Stability (%) 0-15 NA NA NA 7 Aggregate Size (mm) 12-20 < 16 < 16 < 16 These properties must all be satisfied in order to design an adequate SCC, together with other requirements including those for hardened performance. II. EXPERIMENTAL PROGRAM 2.1 SCC Mix Target Typical acceptance criteria and target for SCC are shown in Table 8. Table 2. Typical Acceptance Criteria and Target for Self Compacting Concrete Unit SCC Mix Target Property Test Method Minimum Maximum Slump Flow by Filling ability Abrams Cone mm 650 800 T50cm Slump Flow Sec 2 5 V-Funnel Sec 6 12 Passing ability L-Box h2/h1(mm/mm) 0.8 1.0 Segregation V-Funnel atT5min. Sec 6 12 resistance 355
  • 4. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July December (2012), © IAEME July- 2.2 Properties Of SCC 356
  • 5. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME 2.3 Mixing Procedure for self compacting Concrete For SCC, it is generally necessary to use superplasticizers in order to obtain high mobility. Adding a large volume of powdered material or viscosity modifying admixture can eliminate segregation. The powdered materials that can be added are fly ash ,Metakaolin, silica fume, lime stone powder, glass filler and quartzite filler. Okamura and Ozawa have proposed a mix proportioning system for SCC . In this system, the coarse aggregate and fine aggregate contents are fixed and self-compactibility is to be achieved by adjusting the water /powder ratio and super plasticizer dosage. In addition, the test results for acceptance characteristics for self-compacting concrete such as slump flow, V-funnel and L- Box are presented. III Selection of Materials and Mix Proportions SCC can be made from any of the constituent materials that are normally considered for structural concrete . In designing the SCC mix, it is most useful to consider the relative proportions of the key components by volume rather than by mass. Worldwide, there is a wide range of mix proportions that can produce successful SCC. Typical range of proportions and quantities in order to obtain SCC are given below: These Guidelines are not intended to provide specific advice on mix design but Table 8.2 gives an indication of the typical range of constituents in SCC by weight and by volume. These proportions are in no way restrictive and many SCC mixes will fall outside this range for one or more constituents. 3.1 Characteristics Of Test Methods Table 3: Characteristic test methods for self compacting concrete Characteristi Test Measured value c method Flowability/filling Slump-flow total spread ability Kajima box visual filling T500 flow time V-funnel flow time Viscosity/ O-funnel flow time flowability Orimet flow time L-box passing ratio U-box height difference Passing ability J-ring step height, total flow Kajima box visual passing ability penetration depth Segregation sieve segregation percent laitance resistance settlement column segregation ratio 357
  • 6. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME Table 4 Mix proportion of a typical ranges of SCC Typical range by Typical range by volume Constituent mass (kg/m)3 (liters/m)3 Powder 380 - 600 Paste 300 - 380 Water 150 - 210 150 - 210 Coarse aggregate 750 - 1000 270 - 360 Content balances the volume of the other Fine aggregate (sand) constituents, typically 48 – 55% of total aggregate weight. Water/Powder ratio by 0.85 – 1.10 Volume Table 5 , Mix proportion of a NVC and typical ranges of SCC Constituent NVC (C40, 75 mm SCC (Domone, 2006b; The slump) Concrete Society and BRE, Coarse aggregate/concrete(%) by vol. 42 28.0 – 38.6 Water/powder (by wt.) 0.55 0.26 – 0.48 Paste/concrete (%) by vol. 32 30.4 – 41.5 Powder content (kg/m 3) 375 385 – 635 Sand/mortar (%) by vol. 44 38.1 – 52.9 III. MATERIALS USED 3.1 . Fine Aggregate Natural river sand is used as fine aggregate. The bulk specific gravity in oven dry condition and water absorption of the sand are 2.6 and 1% respectively. The gradation of the sand was determined by sieve analysis as per IS-383(1970) and presented in the Table 6. Fineness modulus of sand is 2.65. Table 6. Sieve Analysis of Fine Aggregate Cumulative Percent Passing Sieve No. Fine Aggregate IS: 383-1970 – Zone II Requirement 10mm 100 100 4.75mm 100 90-100 2.36mm 94 75-100 1.18mm 74 55-90 600µm 46 35-59 300µm 14 8-30 150µm 3 0-10 358
  • 7. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME 2.2.4. Coarse Aggregate Crushed granite stones of size 16mm and 12.5mm are used as coarse aggregate. The bulk specific gravity in oven dry condition and water absorption of the coarse aggregate are 2.66 and 0.3% respectively. The gradation of the coarse aggregate was determined by sieve analysis as per IS-383(1970) [4] and presented in the Table7 and Table 8,Fineness modulus of coarse aggregate is 6.67. Table 7. Sieve Analysis of 16 mm Coarse Aggregate Cumulative Percent Passing IS Sieve Size 16 mm passing IS: 383-1970 Limits 20 mm 100 100 16 mm 99 85-100 12.5 mm 57.77 N/A 10 mm 18.89 0-30 4.75 mm 1 0-5 2.36mm -- ---- Table 8. Sieve Analysis of 12.5 mm Coarse Aggregate Cumulative Percent Passing IS Sieve Size 12.5 mm passing IS: 383-1970 Limits 16 mm 100 100 12.5mm 94 85-100 10 mm 36.5 0-45 4.75 mm 8.76 0-10 2.36 mm 2.4 NA Dry-rodded unit weight (DRUW) and void ratio of coarse aggregate with relative blending by percentage weight as per IS: 2386 (Part III)-1963 [6] is shown in Table 6 and Figure 1. Table 9. Dry-rodded unit weight and Void Ratio of a given coarse aggregate blending Coarse Aggregate Blending by Percentage Weight DRUW (kg/m3) Void Ratio ( 16 mm and 12.5 mm) 100:0 1596 0.378 80:20 1642 0.374 70:30 1647 0.376 67:33 1659 0.386 60:40 1608 0.395 40:60 1568 0.399 20:80 1559 0.40 0:100 1533 0.41 359
  • 8. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME 3.2 Water Potable water for casting and curing of the SCC mixes Table 10. Chemical Composition and Physical Properties of Cement Test Result Requirement as per IS:12269-1989 Chemical Composition Lime Saturation Factor Not less than 0.60 & not more than 1.02 CaO-0.7SO3/2.8SiO2+1.2Al2 O3+0.65Fe2O3 0.89 Ratio of Alumina/Iron Oxide 1.00 Min. 0.66 Insoluble Residue(%) 1.31 Not more Than 3.0% % Magnesium oxide(MgO) 1.40 Not more Than 6.0% Max. 3.0% when C3 A>5.0 % Sulphuric Anhydride (SO3) 1.91 Max. 2.5% when C3 A<5.0 Loss of Ignition(%) 1.29 Not more Than 5.0% Alkalies(%) 0.60 --------- 0.01 Not more Than 0.1% Chlorides(%) % Silica(SiO2) 19.79 3 5.67 % Alumina(Al2O ) 3 4.68 % Iron Oxide(Fe2O ) % Lime(CaO) 61.81 C3 A 5.5 Temperature During Testing(0C) 27 27 +/-2 Physical Properties Specific gravity 3.15 2 275 Min.225 Fineness (m /Kg) Soundness 2 Lechatlier Expansion(mm) 1.50 Max. 10mm Auto clave Expansion (%) 0.04 Max. 0.8% Setting time(minutes) Initial 180 Min. 30 min Max. 600 min Final 230 Compressive strength 3 Days 32 > 23 N/mm2 7 Days 43 > 33 N/mm2 28 days 55 > 43 N/mm2 3.3 Additive or Mineral Admixture Metakaolin manufactured from pure raw material to strict quality standards. Metakaolin is a high quality pozzolanic material, which blended with Portland cement in order to improve the strength and durability of concrete and mortars. Metakaolin removes chemically reactive calcium hydroxide from the hardened cement paste. It reduces the porosity of hardened concrete. Metakaolin densified and reduces the thickness of the interfacial zone, this improving the adhesion between the hardened cement paste and particulars of sand or aggregate. Metakaolin procured from 20 Microns company Vadodara, Gujarat, India. As per IS-456(2000) , cement is replaced by weight of material. The specific gravity of Metakaolin is 2.5 . 360
  • 9. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME 3.3.1 Reactivity of Different Pozzolanic Materials Table 11 : Reactivity of Different Pozzolanic Materials Material Pozzolanic Reactivity mg Ca(OH)2 per g Blast furnace slag 40 Calcined paper waste 300 Microsilica, silica fume 427 Calcined bauxite 534 Pulverised fuel ash 875 High Reactive Metakaolin 1050 3.3.2 METAKAOLIN Metakaolin manufactured from pure raw material to strict quality standards. Metakaolin is a high quality pozzolanic material, which blended with Portland cement in order to improve the strength and durability of concrete and mortars. Metakaolin removes chemically reactive calcium hydroxide from the hardened cement paste. It reduces the porosity of hardened concrete. Metakaolin densified and reduces the thickness of the interfacial zone, this improving the adhesion between the hardened cement paste and particulars of sand or aggregate. 3.3.3 Properties of Metakaolin Metakaolin grades of Calcined clays are reactive allumino silicate pozzolan formed by calcining very pure hydrous China clay. Chemically Metakaolin combines with Calcium Silicate and Calcium processed to remove uncreative impurities producing almost 100 percent reactive material. The particle size of Metakaolin is significantly smaller than cement particles. I S: 456-2000 recommend use of Metacioline as mineral admixture. Metakaolin is a thermally structure, ultrafine pozzolan which replace industrial by-products such as silica fume / micro silica. Commercial use of Metakaolin has already in several countries worldwide. Metakaolin removes chemically reactive calcium hydroxide from the hardened cement paste. Metakaolin reduces the porosity of hardened concrete. Metakaolin densifies reduces the thickness of the interfacial zone, this improving the adhesion between the hardened cement paste and particles of sand or aggregate. Blending with Portland cement Metakaolin improves the properties of concrete and cement products considerably by: Increasing compressive and flexural strength, providing resistance to chemical attack, reducing permeability substantially, preventing Alkali-Silica Reaction, reducing efflorescence & Shrinkage and Protecting corrosion 361
  • 10. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME 3.3.4 Physical and Chemical Properties of Metakaolin Physical Properties of Chemical Properties Metakaolin of Metakaolin 1.5 Average particle size, µm SiO2 + Al2O3 + Fe2O3 96.88% 0.5 Residue 325 mesh (% max) CaO 0.39% B.E.T. Surface area m2/gm 15 MgO 0.08% Pozzolan Reactivity mg Ca(OH)2 / gm 1050 TiO2 1.35% Specific Gravity 2.5 Na2O 0.56% Bulk Density (gm/ltr.) 300+ or -30 K 2O 0.06% Brightness 80+ or –2 Li2O Nil off-white powder Physical foam L.O.I 0.68% 3.3.4 Pozzolanic Reactivity of Metakaolin Metakaolin is a lime-hungry pozzolan that reacts with free calcium hydroxide to form stable, insoluble, strength-adding, cementitious compounds.When Metakaolin – HRM(AS2) reacts with calcium hydroxide(CH), a cement hydration byproducts, a pozzolanic reaction takes place whereby new cementitious compounds,(C2ASH8) and (CSH), are formed. These newly formed compounds will contribute cementitious strength and enhanced durability properties to the system in place of the otherwise weak and soluble calcium hydroxide. Cement Hydration Process OPC + H2O -----------------------------------------------> CSH + CH Pozzolanic Reaction Process H 2O AS2 + CH -----------------------------------------------> C2ASH8 + CSH Unlike other commercially available pozzolanic materials, Metakaolin is a quality controlled, manufactured material. It is not a by-product of unrelated industrial process. Metakaolin has been engineered and optimized to contain a minimum of impurities and to react efficiently with cement’s hydration byproduct- calcium hydroxide. Table summarizes the relative reactivities of six different pozzolans, including High Reactive Metakaolin-HRM. 3.3.5 Fly Ash Flyash ,known also as pulverized –fuel ash,is the ash precipitated electro-statically from the exhaust fumes of coal-fired power stations, and is the most common artificial pozzolana .Flyash is the most commonly used pozzolana with cement. . Class F fly ash from Rayalaseema Thermal Power Plant (RTPP), Muddanur, A.P, India is used as an additives according to ASTM C 618 cement is replaced by weight of material. The specific gravity of fly ash is 2.12 362
  • 11. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME Table 13. Chemical and Physical Properties of Class F Fly Ash ASTM C 618 Class F Fly Ash Particulars Chemical Composition % Silica(SiO 2) 65.6 % Alumina(Al2O3) 28.0 % Iron Oxide(Fe2O3) 3.0 SiO2+ Al2O3+ Fe2O3>70 % Lime(CaO) 1.0 % Magnesia(MgO) 1.0 % Titanium Oxide (TiO2) 0.5 % Sulphur Trioxide (SO3) 0.2 Loss on Ignition 0.29 Physical Properties Specific gravity 2.12 Fineness (m2/Kg) 360 Min.225 m2/kg 3.3.6 Chemical Admixtures Sika Viscocrete 10R3 is used as high range water reducer (HRWR) SP cum retarder is used . The properties of the chemical admixtures as obtained from the manufacturer are presented in the Table 14 Table 14. Properties of Chemical Admixtures Confirming to EN 934-2 Table11.1/11.2 and SIA 162(1989) Solid Quantity(%)By Chemical Specific Appearance Relative Density Content cementitious Admixture Gravity /Colour Ph Chemical Base (%) weight Sika Visocrete- 1.10 Light brown ≈ Above 6 ≈1.09 kg/lit 40 0.6 - 2 Aqueous 10 R3 liquid .(at+300c) solution of High Performance Modified Super-Plasticiser Polycarboxylate cum retarder(HRWRA) IV EXPERIMENTAL INVESTIGATIONS 4.1. SCC Mix Design Several methods exist for the mix design of SCC. The general purpose mix design method was first developed by Okamura and Ozawa (1995). In this study, the key proportions for the mixes are done by volume. The detailed steps for mix design are described as follows: 1. Assume air content as 2% (20 litres) of concrete volume. 2. Determine the dry-rodded unit weight (DRUW) of coarse aggregate for a given coarse aggregate blending. 3. Using DRUW, calculate the coarse aggregate content by volume (28 – 35%) of mix volume. 363
  • 12. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME 4. Adopt fine aggregate volume of 40 to 50% of the mortar volume. 5. Maintain paste volume of 388 litre/m3 of the concrete volume. 6. Keep water/ cementitious ratio by weight (w/cm) as 0.36. 7. Calculate the binder (cementitious material) content by weight. 8. Replace cement with Metakaolin,fly ash and combinations of both by weight of cementitious material. 9. Optimize the dosages of super plasticizer (SP) and viscosity modifying agent for the given w/cm (0.36) using mortar tests by mini slump cone test. 10. Perform SCC tests. 4.2 Percentage of Mix Proportions. Mix types with percentage relative proportions and mix proportions of constituent materials are shown in Table 9 and Table 10. Table 16. Designed Mix Proportions Sl. Designation of Total Cement Metakao Flyash F.A C.A Water S.P. S.P W/P No. Mix Proportion Binder 3 lin 3 3 3 3 (%) 3 ratio (Kg/m ) (Kg/m ) (Kg/m ) (Kg/m ) (Kg/m ) (Kg/m ) 3 3 (Kg/m ) (Kg/m ) 1 MK5 533.00 506.35 26.65 ----- 836 771.84 191.88 0.9 4.797 0.36 2 MK10 530.00 477.00 53.00 ----- 836 771.84 190.80 0.9 4.770 0.36 3 MK15 527.00 447.95 79.05 ----- 836 771.84 189.72 0.9 4.743 0.36 4 MK20 523.50 418.80 105.00 ----- 836 771.84 188.46 0.9 4.712 0.36 5 FA10 524.50 472.00 ----- 52.45 836 771.84 188.82 0.9 4.721 0.36 6 FA20 513.50 410.80 ----- 102.70 836 771.84 184.86 0.9 4.622 0.36 7 FA30 502.00 351.75 ----- 150.75 836 771.84 180.90 0.9 4.523 0.36 8 MK5+FA30 499.50 324.68 25.00 149.85 836 771.84 179.82 0.9 4.500 0.36 9 MK10+FA20 507.50 355.25 50.75 101.50 836 771.84 182.70 0.9 4.570 0.36 10 MK15+FA10 504.00 378.00 75.60 50.40 836 771.84 181.44 0.9 4.536 0.36 11 SCC 536.00 536.00 ----- ----- 836 771.84 192.96 0.9 4.824 0.36 V . Testing Fresh Properties of SCC 5.1. Slump Flow Test. The slump flow test is used to assess the horizontal free flow of SCC in the absence of obstructions. The test also indicates resistance to segregation. On lifting the slump cone, filled with concrete the average diameter spread of the concrete is measured. It indicates the filling ability of the concrete. Slump flow test apparatus is shown in Figure 3(a). Slump cone has 20 cm bottom diameter, 10 cm top diameter and 30 cm in height. In this test, the slump cone mould is placed exactly on the 20 cm diameter graduated circle marked on the glass plate, filled with concrete and lifted upwards. The subsequent diameter of the concrete spread is measured in two perpendicular directions and the average of the diameters is reported as the spread of the concrete. T50cm is the time measured from lifting the cone to the concrete reaching a diameter of 50 cm. The measured T50cm indicates the deformation rate or viscosity of the concrete. The slump flow is used to assess the horizontal free flow and the filling ability of SCC in the absence of obstructions. It is recommended to maintain slump flow value as 650 to 800 mm. This test is used along with slump flow test to assess the flowability of SCC. 364
  • 13. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME 5.2 . V-Funnel Test The flowability of the fresh concrete can be tested with the V-funnel test, whereby the flow time is measured. The funnel is filled with about 12 litres of concrete and the time taken for it to flow through the apparatus is measured. Shorter flow time indicate greater flowability. V-Funnel test apparatus dimensions are shown in Figure 3(b). In this test, trap door is closed at the bottom of V-Funnel and V-Funnel is completely filled with fresh concrete. V-Funnel time is the time measured from opening the trap door and complete emptying the funnel. Again, the V-Funnel is filled with concrete, kept for 5 minutes and trap door is opened. V-Funnel time is measured again and this indicates V-Funnel time at T5min. This test is used to determine the filling ability, flowability and segregation resistance of SCC. 5.3 L-Box Test This is a widely used test, suitable for laboratory and site use. It assesses filling and passing ability of SCC and serious lack of stability (segregation) can be detected visually. The vertical section of the L- Box is filled with concrete, and then the gate is lifted to let the concrete flow into the horizontal section. Blocking ratio (i.e. is ratio of the height of the concrete at the end of the horizontal section (h2) to height of concrete at beginning of horizontal section (h1)) is determined. L-Box test apparatus dimensions are shown in Figure In this test, fresh concrete is filled in the vertical section of L-Box and the gate is lifted to let the concrete to flow into the horizontal section. The height of the concrete at the end of horizontal section represents h2 (mm) at the vertical section represents h1 (mm). The ratio h2/h1 represents blocking ratio .This test assesses the flow of the concrete in presence of reinforcement obstructions. 5.4. Determination of Consistence Retention Consistence retention is also an important fresh property of SCC in view of workability. It refers to the period of duration during which SCC retains its properties, which is important for transportation and placing. Consistence retention was evaluated by measuring the slump flow spread and T50cm of successful SCC mixes at 60 minutes after adding water. The SCC mix was remixed for one minute before each test. 365
  • 14. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME VI. CONCLUSIONS Based on the findings of this study, the following conclusions may be drawn: 1. Establishment of standard mix design procedure and appropriate testing methods is essential for wide spread use of SCC . Most of Indian researchers have followed European guidelines for testing SCC. Other countries are adopting these guiedelines with slight modifications as per local conditions. 2. Both coarse aggregate maximum size and coarse aggregate volume are influenced in obtaining the successful SCC mixes. 3.As the replacements of Metakaolin, Flyash and combinations of both MK and FA compared with controlled concrete SCC, totally there are eleven type of mix designs such as MK5,MK10,MK15,MK20;FA10,FA20,FA30;(MK5+FA30),(MK10+FA20),(MK1 5+FA10) and Controlled mix SCC 4 As per the mix designs and trial mixes addition of MK increases the demand of HRWRA in SCC Mixes. Replacement of cement by 20%MKin SCC the super plasticizer cum retarder demands may be increased. 5. As per the mix designs and trial mixes addition of FA decreases the demand of HRWRA in SCC Mixes. Replacement of cement by 30% FA in SCC the super plasticizer cum retarder demands may be decreased. 6. The utilization of by-product mineral admixtures is the best alternative for now a days since it not only makes the concrete accomplish the proper performance but also reduce the concrete cost and environmental problems. Incorporating such materials further enhances the fresh properties of SCC concrete. REFERENCES [1].Krishna Murthy.N., NarasimhaRao.A.V., Ramana Reddy,I.V. and Vijaya sekhar Reddy M.., Mix Design procedure for Self-Compacting Concrete, IOSR Journal of Engineering(IOSRJEN, Volume 2,Issue 9,(September2012)P.P 33-41. [2].IS: 3812-2003, Specifications for Pulverized fuel ash, Bureau of Indian Standards, New Delhi, India. [3] IS: 8112-1989, Specifications for 43 grade Portland cement, Bureau of Indian Standards, New Delhi, India. [4]IS: 383-1970, Specifications for Coarse and Fine aggregates from Natural sources for Concrete, Bureau of Indian Standards, New Delhi, India. [5].American Concrete Institute. “Self-Consolidating Concrete”, ACI 237R-07. [6].American Concrete Institute. “Specifications for Structural Concrete”, ACI 301. [7].American Society for Testing and Materials. “Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete”, ASTM C 618 (2003). [8].American Society for Testing and Materials. “Standard specification for coal fly ash and raw or calcined natural pozzolan for use concrete”, ASTM C 618 (2003). 366
  • 15. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME [9].Bureau of Indian Standards. “Methods of test for aggregates for concrete. Specific gravity, Density, Voids, Absorption and Bulking”, IS-2386 (Part III, 1963). [10].Bureau of Indian Standards. “Plain and reinforced concrete code for practice”, IS-456 (2000), New Delhi. [4]. Bureau of Indian Standards. “Methods of test for aggregates for concrete. Specific gravity, Density, Voids, Absorption and Bulking”, IS-2386 (Part III, 1963). [11].Domone PLJ. 2006b. “Self-compacting concrete: An analysis of 11 years of case studies”. Cement and Concrete Composites 28(2):197-208. [12].EFNARC (European Federation of national trade associations representing producers and applicators of specialist building products), Specification and Guidelines for self- compacting concrete, February 2002, Hampshire, U.K. [13].EFNARC. “Specification and guidelines for self-compacting concrete. European Federation of Producers and Applicators of Specialist Products for Structures”, 2002. [14].RILEM TC 174 SCC. “Self compacting concrete State-of-the-art report of RILEM technical committee 174-SCC”. Skarendahl A, Petersson O, editors, RILEM Publications S.A.R.L., France, 2000. [15].Ghazi F Kheder, Rand S Al Jaidiri. 2010. “New Method for Proportioning Self-Consolidating Concrete Based on Compressive Strength Requirements”. ACI Materials 107(5):490-497. [16].Goodier C. 2001. “Self-Compacting Concrete”. European Network of Building Research Institutes (ENBRI). 17:6 [17].Khayat KH. 1998. Viscosity-enhancing admixtures for cement-based materials - An overview. Cement and Concrete Composites, No.20, 2-3: 171-188 [18].Newman J, Choo BS. Advanced concrete technology concrete properties. Elsevier Butterworth Heinemann, 2003. [19].Okamura H, Ozawa K. 1995. “Mix design for self-compacting concrete”. Concrete Library of Japanese Society of Civil Engineers 25(6):107-120. [20].Okamura H, Ouchi M. 1999. “Self-compacting concrete development, present use and future”.In:The 1st International RILEM Symposium on Self-Compacting Concrete. Skarendahl A, Petersson O, editors, RILEM Publications. S.A.R.L, France. 3-14. [21].Ozawa K, Maekawa K, Kunishima M, Okamura H. 1989. “Development of high performance concrete based on the durability design of concrete structures”. 445-450. [22].Nagamoto N., Ozawa K., Mixture properties of Self-Compacting, High- Performance Concrete, Proceedings, Third CANMET/ACI International Conferences on Design and Materials and Recent Advances in Concrete Technology, SP- 172, V. M. Malhotra, American Concrete Institute, Farmington Hills, Mich. 1997, p. 623-637. [23].Khayat K.H., Ghezal A., Utility of Statistical models in Proportioning Self- Compacting Concrete, Proceedings, RILEM [24].International symposium on Self-Compacting Concrete, Stockholm, 1999, p. 345-359. 367
  • 16. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 3, Issue 2, July- December (2012), © IAEME [25].Okamura H., Ozawa K., Mix Design for Self-Compacting Concrete, Concrete Library of Japanese Society of Civil Engineers, June 25, 1995, p. 107-120. [26].Nagataki S., Fujiwara H., Self-Compacting property of Highly-Flowable concrete, Second Conference on advances in Concrete Technology, ACI SP- 154,V.M. Malhotra, American Concrete Institute, June 1995, p. 301-304. [27] Khayat K.H., Manai K., Lesbetons autonivlants : proprietes, charcterisation et applications , colloque sur les betons autonivlants, Universite de Sherbroke, Canada, November 1996, p. 8. [28]. Ghazi F Kheder, Rand S Al Jaidiri. 2010. “New Method for Proportioning Self-Consolidating Concrete Based on Compressive Strength Requirements”. ACI Materials 107(5):490-497. [29].Petersson O., Billberg P., Van B.K., A model for Self-Compacting Concrete, Proceedings of Production Methods and Workability of Concrete,1996, E & FN Span, London, p. 483- 492. [30]Okamura H, Ozawa K. 1995. “Mix design for self-compacting concrete”. Concrete Library of Japanese Society of Civil Engineers 25(6):107-120. [31].Okamura H. 1997. “Self-compacting high-performance concrete”. Concrete International 19(7):50-54. [32].Okamura H, Ouchi M. 1999. “Self-compacting concrete development, present use and future”. In: The 1st International RILEM Symposium on Self- Compacting Concrete. Skarendahl A, Petersson O, editors, RILEM Publications. S.A.R.L, France. 3-14. [33]. Okamura H, Ouchi M. 2003b. “Self-compacting concrete”. Journal of Advanced Concrete Technology 1(1):5-15. [34]. Ozawa K, Maekawa K, Kunishima M, Okamura H. 1989. “Development of high performance concrete based on the durability design of concrete structures”. 445-450. [35]. Skarendahl, A. and Petersson, O. (eds.), “Self-compacting concrete”, State- of-the-art report of RILEM Technical Committee 174-SCC, RILEM Publications, 2000. [36]. The Concrete Society, BRE. 2005. “Technical report No.62 self- compacting concrete: a review”. Day RTU, Holton IX, editors, Camberley, UK, Concrete Society, Surrey GU17 9AB, UK. 368