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BioMotion Congress
                               Hannover 12 Nov. 2009



                          Biofuels in France
                      from 1st to 2nd generation
                     within a biorefinery strategy


                  Dr. Fabien DAURIAC
                  Chambers of Agriculture of Picardy
                                                          People, Plants, for ever.
                  France - Biomotion partner

IAR - Competitiveness Cluster with a Worldwide Vocation
The French plan of biofuels development


     The French government has decided to go beyond European directives by
      laying down ambitious objectives of incorporation of biofuels into fuels:
             5,75% (in energy value) in 2008, 7% in 2010 and 10% by 2015.

        In order to reach this target, a great industrial plan has been engaged


      Authorisations                             2008               2010
      biodiesel                                   2,282,500 tons    3,232,500 tons
      bioethanol                                     891,800 tons   1,041,800 tons



IAR - Competitiveness Cluster with a Worldwide Vocation
The French plan of biofuels development




IAR - Competitiveness Cluster with a Worldwide Vocation
The new ethanol plants in France
                                    TEREOS                             SOUFFLET
                                      Origny                         Nogent sur Seine
                              240 000 t (sugarbeet)                  160 000 t (wheat)

         Target                                                                          CRISTAL UNION
          2009                                                                             Bazancourt
                                                                                          120 000 t
                 TEREOS                                                             (sugarbeet & glucose)
                 Lillebonne                                                              160 000 t (wheat)
             240 000 t (wheat)
                                                                                         ROQUETTE
                                                                                             Beinheim
                                                                                    160 000 t (wheat)



                                       Target of industrial capacity:
                                                            capacity:
                                                    1.280.000 tons
     AB BIOENERGY
             Lacq                                                                 (Source : SNPAA)
          200 000 t
    (corn & wine alcohol)

                                                                                         4
IAR - Competitiveness Cluster with a Worldwide Vocation
Biomotion tour in the Tereos Plant




IAR - Competitiveness Cluster with a Worldwide Vocation
DUNKERQUE                          COUDEKERQUE          COMPIEGNE 1 et 2
       DUNKERQUE            TOTAL                              DIESTER               DIESTER
        DAUDRUY
       150 kt/an           200 kt/an
                         Biodiesel synthèse
                                                               250 kt/an                 220 kt/an
                                                                                                         Biodiesel plants
                                                                                      LIMAY
                                                                                                        in France in 2010
     GRAND-COURONNE
         DIESTER                                                                    SARP Industrie
        520 kt/an                                                                    80 kt/An

                                                                                         VERDUN
                                                                                          INEOS
                                                                                    230 kt/an
                                                                                                           Industrial capacity
                                                                                CHARNY/MEUSE (55)
                                                                                PROGILOR BOUVART              will exceed
                                                                                         60 kt/an
                                                                                          EMHA
                                                                                                               3 M tons .

   MONTOIR (44)                                                                     NOGENT LE MERIOT
     AIRAS4                                                                             DIESTER
    55 kt/an                                                                              250 kt/an


     MONTOIR                                                                                             Biodiesel in France
     DIESTER
    250 kt/an                                                                   FOS-sur-MER (13)
                                                                                                         is mainly produced
                                                                                  BIOCAR                from rapeseed in the
                                                                                  200 kt/an
                                                                                                            north and from
   La ROCHELLE (17)
     SICA Atlantique
                                                                           SETE 1 et 2
                                                                                                           sunflower in the
      50 kt/an                                                              DIESTER                             south.
                                                                           500 kt/an
     BORDEAUX                                                                                       BOUSSENS
      DIESTER                                 CHALANDRAY (86)
                                              Centre Ouest Céréales                               COGNIS/DIESTER
     250 kt/an                                   120 kt/an                                           120 kt/an
IAR - Competitiveness Cluster with a Worldwide Vocation
GES reduction and Energy balance




IAR - Competitiveness Cluster with a Worldwide Vocation
GES reduction and Energy balance




IAR - Competitiveness Cluster with a Worldwide Vocation
French Competitiveness Cluster
                                      Industries et Agro-Ressources

Picardie and
Champagne
 -Ardenne                             Brussels
                                                            Non-food uses
         regions                                             of biomass
                                 Paris




                                                  a major agricultural area



IAR - Competitiveness Cluster with a Worldwide Vocation
A major Agro-industrial area
                                           Agro-
                                                          200+ companies and 25,000 jobs


               € 3.4 bn
               13,000 staff                                                Structured industrial
                                                            € 2.7 bn       value chains
                                                            3,400 staff    Major industrial actors


                                                                                 Sugar refineries
                          Picardie and                                           Starch refineries
                                                                  € 6 bn
 1.0 bn
 1,300 staff
                          Champagne                               6,000 staff    Malting plants
                           -Ardenne                                              Mills
                                  regions
                                                                                 Oil crush plants
                                                                                 Deshydration

                 € 1.8 bn                                          € 2.5 bn
                 5,500 staff                                       6,000 staff
IAR - Competitiveness Cluster with a Worldwide Vocation
A tight Research network

                    Amiens



                                                                  4 Universities
                                                                  2 Graduate schools
                                                   Laon

                                                                  INERIS research center
                                                                  (Risks, sustainability,   )
                                                          Reims

                                                                  3 INRA centers
                                                                  Agronomy Research Institute
                                                                  3 demonstration
                                                                     platforms


               A 25 year cluster initiative

IAR - Competitiveness Cluster with a Worldwide Vocation
IAR Members
                                                      16 co-ops
                                                         co-
                                    Biomass producers
                                 (agriculture and forestry)
   15                                                     58
                                  Utiliser toutes
          CENTRES
                                les composantes
            DE                  BIOREFINERY
                                        de la
                                                               ENTREPRISES
         RECHERCHE
                                       Plante
   Research and Technology                                        Industries
       Transfer centers        10
                                                                        112 members (Apr. 2009)
                                     ORGANISMES
                                         DE
                                      FORMATION                         20 industrial groups
                                                                        38 SMEs
                          Universities and Engineer schools
IAR - Competitiveness Cluster with a Worldwide Vocation
The biorefinery concept
                                                     Access to biomass
                                                                   Biomass
   Sustainable Development




                                    New industrial needs                          New industrial tools
                                    Renewable carbon
                                                                                Biomass Green Chemistry
                                    Environment friendly
                                                                                        White Biotech
                                          products



                                                    Markets
                                                    Markets
                              BioEnergies            AgroMaterials              BioMolecules              BioIngredients
                               Biofuels, biogaz,    Building, Paper, Textile,         Chemical             Food Ingredients,
                                electricity, heat    Plastics, Packaging         intermediates, glue,      Processing aids,
                                                                                Lubricants, surfactants      nutraceutics



IAR - Competitiveness Cluster with a Worldwide Vocation
Projects examples on the 2nde
generation biofuels… and more

                   • Pyrobio Energy +
                     Fast pyrolysis of vinasse (beet slops)
                     byproducts out of bioethanol sugarbeet
                     production

                   • Futurol
                     Sugar plateform to produce ethanol from the
                     whole plant

                   • L-Succinic acid Demonstration Plant


IAR - Competitiveness Cluster with a Worldwide Vocation
Project example : Pyrobio Energy +


                                  • Fast pyrolysis of vinasse (beet slops)
                                    byproducts out of bioethanol
                                    sugarbeet production

                                  • Phase 1 : development of a Pilot unit




IAR - Competitiveness Cluster with a Worldwide Vocation
Project example : Pyrobio Energy +


     Tereos, a global actor in sugar and ethanol

                                                          How to increase the
                                                          bioethanol process
                                                          energy balance
                                                          by using vinasse as
                                                          an energy source ?


    Sugarbeet Bioethanol unit,
    Origny-Ste-Benoite (02)

    2 Mhl bioethanol

IAR - Competitiveness Cluster with a Worldwide Vocation
Project example : Pyrobio Energy +

      PILOT FOR FAST PYROGASIFICATION OF ORGANIC COMPOUNDS

    The 15 kg/h Pilot Plant


                                                            Heat exchanger


                                        Boiler




     Pyrolysis reactor


                                                    sys m
                                               ting syste
                                     Balls hea
                                      alls
                                                                                    BC 45


             Feedstock : Vinasses



  Drying




                                                                    Washer smokes

                         Specific metallurgy


IAR - Competitiveness Cluster with a Worldwide Vocation
Project example : Pyrobio Energy +


                      RESULTS
                                                          • Tests confirm the feasibility of
                                                            an industrial-scale plant, which
                                                            should achieve results higher
                                                            than initially expected.

                                                          • Phase 2 of the project with
                                                            Tereos (development of an
                                                            industrial-scale unit in order to
                                                            process 5 tons/hour of
                                                            vinasse) seems to be on track.


IAR - Competitiveness Cluster with a Worldwide Vocation
2nd Generation biofuels & Biorefinery




                                                                    FUTUROL
                                                          France’s Second-Generation
                                                           Bioethanol R&D Program




                                                           US DOE

IAR - Competitiveness Cluster with a Worldwide Vocation
FUTUROL Project

 The french 2nd generation bioethanol R&D project
                                                          11 partners
                                                          8 years of duration
                                                          3 levels
                                                            Laboratory
                                                            Pilot
                                                            Prototype
                                                          74 millions € invested
                                                          30 million € grant from OSEO


              Labeled by IAR and supported by OSEO (French innovation agency)
IAR - Competitiveness Cluster with a Worldwide Vocation
FUTUROL : the partners


   11 partners from research, industry and finance
        RESEARCH                                 INDUSTRY   FINANCE




IAR - Competitiveness Cluster with a Worldwide Vocation
FUTUROL : the objectives


      Development and marketing of a complete production
   process for 2nd generation bioethanol from whole plants or
   from lignocellulosic biomass (agricultural and forest residue,
             green urban waste, dedicated plants, etc.)
  A sustainable process in order to obtain the best possible energy
  and greenhouse gas balance and throughout the entire production
  process (field-to-wheel).
  A flexible pilot plant (multi raw materials) in order to avoid a priori
  choices and to be able to take advantage of future development of
  lignocellulosic biomass production.
  A competitive process through innovations and optimization of
  each step (cellulose extraction, hydrolysis and fermentation processes best
  suited to each raw material configuration).
IAR - Competitiveness Cluster with a Worldwide Vocation
FUTUROL : the objectives



                          DEVELOPMENT METHODOLOGY :
                                                                                    COMMERCIAL
                                                            PROTOTYPE
                                   R&D PILOT
                                     PLANT
     LABORATORY

                        ORGANIZATION IN 6 R&D WORKPACKAGES
        LIGNO                    PRE                                                    ENZYMES
    CELLULOSIQUES             TRAITEMENT             HYDROLYSIS      FERMENTATION      PRODUCTION
      RESOURCES

      CO-PRODUCTS
             +                                       + 1 WORKPACKAGE: INTEGRATION
        RECYCLING


IAR - Competitiveness Cluster with a Worldwide Vocation
White Biotech
Industrial demonstration Plant


                                         21 millions € invested

                                         Capacity up to 350 m3

                                        First molecule produced
                                        will be L-Succinic acid
                                        (for Bio amber)


2000 MT/Yr plant began construction in Sept 08,commissioned in Q4 2009


                    PROVIDES IP                                    PROVIDES
                    PORTFOLIO                                     DEMO PLANT
                                           50 / 50 Worldwide JV
IAR - Competitiveness Cluster with a Worldwide Vocation
Succinic acid : a new step
towards integrated biorefinery
       Sugar Refinery                   Wheat Processing Mill        Cellulose Hydrolysis Pilot




             OUTPUT                                OUTPUT                      OUTPUT
             Sucrose                               Glucose                   C5 &C6 sugars


                      Bioethanol plant                                     Succinic acid plant
                                                              CO2



                                                              Diethyl
                                                             succinate
IAR - Competitiveness Cluster with a Worldwide Vocation
IAR - Competitiveness Cluster with a Worldwide Vocation
Industries et Agro-Ressources
                                       International collaborations
                                                                                            Agronomy

Core business




                                                          Sustainable Development
                                                                                    Bio-
                                                                                    Bio-based feedstock
 Agriculture and
 First transformation industry                                                         Logistic & pre-treatment
                                                                                     Biomass
Objectives                                                                            Green
                                                                                     Chemistry
 Cooperation with other clusters,
                                                                                                 Lab
 within the value chain,                                                                     Pilot plant
 towards final users markets.                                                         Industrial demonstration
                                                                                      Biobased products
                                                                                    biofuels, polymers, chemicals, ingredients




IAR - Competitiveness Cluster with a Worldwide Vocation
                                                                                    Markets
The Biomotion team




IAR - Competitiveness Cluster with a Worldwide Vocation
Special thanks to




IAR - Competitiveness Cluster with a Worldwide Vocation

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Biofuels In France - From 1st To 2nd Generation Within A Biorefinery Strategy - Fabien Dauriac

  • 1. BioMotion Congress Hannover 12 Nov. 2009 Biofuels in France from 1st to 2nd generation within a biorefinery strategy Dr. Fabien DAURIAC Chambers of Agriculture of Picardy People, Plants, for ever. France - Biomotion partner IAR - Competitiveness Cluster with a Worldwide Vocation
  • 2. The French plan of biofuels development The French government has decided to go beyond European directives by laying down ambitious objectives of incorporation of biofuels into fuels: 5,75% (in energy value) in 2008, 7% in 2010 and 10% by 2015. In order to reach this target, a great industrial plan has been engaged Authorisations 2008 2010 biodiesel 2,282,500 tons 3,232,500 tons bioethanol 891,800 tons 1,041,800 tons IAR - Competitiveness Cluster with a Worldwide Vocation
  • 3. The French plan of biofuels development IAR - Competitiveness Cluster with a Worldwide Vocation
  • 4. The new ethanol plants in France TEREOS SOUFFLET Origny Nogent sur Seine 240 000 t (sugarbeet) 160 000 t (wheat) Target CRISTAL UNION 2009 Bazancourt 120 000 t TEREOS (sugarbeet & glucose) Lillebonne 160 000 t (wheat) 240 000 t (wheat) ROQUETTE Beinheim 160 000 t (wheat) Target of industrial capacity: capacity: 1.280.000 tons AB BIOENERGY Lacq (Source : SNPAA) 200 000 t (corn & wine alcohol) 4 IAR - Competitiveness Cluster with a Worldwide Vocation
  • 5. Biomotion tour in the Tereos Plant IAR - Competitiveness Cluster with a Worldwide Vocation
  • 6. DUNKERQUE COUDEKERQUE COMPIEGNE 1 et 2 DUNKERQUE TOTAL DIESTER DIESTER DAUDRUY 150 kt/an 200 kt/an Biodiesel synthèse 250 kt/an 220 kt/an Biodiesel plants LIMAY in France in 2010 GRAND-COURONNE DIESTER SARP Industrie 520 kt/an 80 kt/An VERDUN INEOS 230 kt/an Industrial capacity CHARNY/MEUSE (55) PROGILOR BOUVART will exceed 60 kt/an EMHA 3 M tons . MONTOIR (44) NOGENT LE MERIOT AIRAS4 DIESTER 55 kt/an 250 kt/an MONTOIR Biodiesel in France DIESTER 250 kt/an FOS-sur-MER (13) is mainly produced BIOCAR from rapeseed in the 200 kt/an north and from La ROCHELLE (17) SICA Atlantique SETE 1 et 2 sunflower in the 50 kt/an DIESTER south. 500 kt/an BORDEAUX BOUSSENS DIESTER CHALANDRAY (86) Centre Ouest Céréales COGNIS/DIESTER 250 kt/an 120 kt/an 120 kt/an IAR - Competitiveness Cluster with a Worldwide Vocation
  • 7. GES reduction and Energy balance IAR - Competitiveness Cluster with a Worldwide Vocation
  • 8. GES reduction and Energy balance IAR - Competitiveness Cluster with a Worldwide Vocation
  • 9. French Competitiveness Cluster Industries et Agro-Ressources Picardie and Champagne -Ardenne Brussels Non-food uses regions of biomass Paris a major agricultural area IAR - Competitiveness Cluster with a Worldwide Vocation
  • 10. A major Agro-industrial area Agro- 200+ companies and 25,000 jobs € 3.4 bn 13,000 staff Structured industrial € 2.7 bn value chains 3,400 staff Major industrial actors Sugar refineries Picardie and Starch refineries € 6 bn 1.0 bn 1,300 staff Champagne 6,000 staff Malting plants -Ardenne Mills regions Oil crush plants Deshydration € 1.8 bn € 2.5 bn 5,500 staff 6,000 staff IAR - Competitiveness Cluster with a Worldwide Vocation
  • 11. A tight Research network Amiens 4 Universities 2 Graduate schools Laon INERIS research center (Risks, sustainability, ) Reims 3 INRA centers Agronomy Research Institute 3 demonstration platforms A 25 year cluster initiative IAR - Competitiveness Cluster with a Worldwide Vocation
  • 12. IAR Members 16 co-ops co- Biomass producers (agriculture and forestry) 15 58 Utiliser toutes CENTRES les composantes DE BIOREFINERY de la ENTREPRISES RECHERCHE Plante Research and Technology Industries Transfer centers 10 112 members (Apr. 2009) ORGANISMES DE FORMATION 20 industrial groups 38 SMEs Universities and Engineer schools IAR - Competitiveness Cluster with a Worldwide Vocation
  • 13. The biorefinery concept Access to biomass Biomass Sustainable Development New industrial needs New industrial tools Renewable carbon Biomass Green Chemistry Environment friendly White Biotech products Markets Markets BioEnergies AgroMaterials BioMolecules BioIngredients Biofuels, biogaz, Building, Paper, Textile, Chemical Food Ingredients, electricity, heat Plastics, Packaging intermediates, glue, Processing aids, Lubricants, surfactants nutraceutics IAR - Competitiveness Cluster with a Worldwide Vocation
  • 14. Projects examples on the 2nde generation biofuels… and more • Pyrobio Energy + Fast pyrolysis of vinasse (beet slops) byproducts out of bioethanol sugarbeet production • Futurol Sugar plateform to produce ethanol from the whole plant • L-Succinic acid Demonstration Plant IAR - Competitiveness Cluster with a Worldwide Vocation
  • 15. Project example : Pyrobio Energy + • Fast pyrolysis of vinasse (beet slops) byproducts out of bioethanol sugarbeet production • Phase 1 : development of a Pilot unit IAR - Competitiveness Cluster with a Worldwide Vocation
  • 16. Project example : Pyrobio Energy + Tereos, a global actor in sugar and ethanol How to increase the bioethanol process energy balance by using vinasse as an energy source ? Sugarbeet Bioethanol unit, Origny-Ste-Benoite (02) 2 Mhl bioethanol IAR - Competitiveness Cluster with a Worldwide Vocation
  • 17. Project example : Pyrobio Energy + PILOT FOR FAST PYROGASIFICATION OF ORGANIC COMPOUNDS The 15 kg/h Pilot Plant Heat exchanger Boiler Pyrolysis reactor sys m ting syste Balls hea alls BC 45 Feedstock : Vinasses Drying Washer smokes Specific metallurgy IAR - Competitiveness Cluster with a Worldwide Vocation
  • 18. Project example : Pyrobio Energy + RESULTS • Tests confirm the feasibility of an industrial-scale plant, which should achieve results higher than initially expected. • Phase 2 of the project with Tereos (development of an industrial-scale unit in order to process 5 tons/hour of vinasse) seems to be on track. IAR - Competitiveness Cluster with a Worldwide Vocation
  • 19. 2nd Generation biofuels & Biorefinery FUTUROL France’s Second-Generation Bioethanol R&D Program US DOE IAR - Competitiveness Cluster with a Worldwide Vocation
  • 20. FUTUROL Project The french 2nd generation bioethanol R&D project 11 partners 8 years of duration 3 levels Laboratory Pilot Prototype 74 millions € invested 30 million € grant from OSEO Labeled by IAR and supported by OSEO (French innovation agency) IAR - Competitiveness Cluster with a Worldwide Vocation
  • 21. FUTUROL : the partners 11 partners from research, industry and finance RESEARCH INDUSTRY FINANCE IAR - Competitiveness Cluster with a Worldwide Vocation
  • 22. FUTUROL : the objectives Development and marketing of a complete production process for 2nd generation bioethanol from whole plants or from lignocellulosic biomass (agricultural and forest residue, green urban waste, dedicated plants, etc.) A sustainable process in order to obtain the best possible energy and greenhouse gas balance and throughout the entire production process (field-to-wheel). A flexible pilot plant (multi raw materials) in order to avoid a priori choices and to be able to take advantage of future development of lignocellulosic biomass production. A competitive process through innovations and optimization of each step (cellulose extraction, hydrolysis and fermentation processes best suited to each raw material configuration). IAR - Competitiveness Cluster with a Worldwide Vocation
  • 23. FUTUROL : the objectives DEVELOPMENT METHODOLOGY : COMMERCIAL PROTOTYPE R&D PILOT PLANT LABORATORY ORGANIZATION IN 6 R&D WORKPACKAGES LIGNO PRE ENZYMES CELLULOSIQUES TRAITEMENT HYDROLYSIS FERMENTATION PRODUCTION RESOURCES CO-PRODUCTS + + 1 WORKPACKAGE: INTEGRATION RECYCLING IAR - Competitiveness Cluster with a Worldwide Vocation
  • 24. White Biotech Industrial demonstration Plant 21 millions € invested Capacity up to 350 m3 First molecule produced will be L-Succinic acid (for Bio amber) 2000 MT/Yr plant began construction in Sept 08,commissioned in Q4 2009 PROVIDES IP PROVIDES PORTFOLIO DEMO PLANT 50 / 50 Worldwide JV IAR - Competitiveness Cluster with a Worldwide Vocation
  • 25. Succinic acid : a new step towards integrated biorefinery Sugar Refinery Wheat Processing Mill Cellulose Hydrolysis Pilot OUTPUT OUTPUT OUTPUT Sucrose Glucose C5 &C6 sugars Bioethanol plant Succinic acid plant CO2 Diethyl succinate IAR - Competitiveness Cluster with a Worldwide Vocation
  • 26. IAR - Competitiveness Cluster with a Worldwide Vocation
  • 27. Industries et Agro-Ressources International collaborations Agronomy Core business Sustainable Development Bio- Bio-based feedstock Agriculture and First transformation industry Logistic & pre-treatment Biomass Objectives Green Chemistry Cooperation with other clusters, Lab within the value chain, Pilot plant towards final users markets. Industrial demonstration Biobased products biofuels, polymers, chemicals, ingredients IAR - Competitiveness Cluster with a Worldwide Vocation Markets
  • 28. The Biomotion team IAR - Competitiveness Cluster with a Worldwide Vocation
  • 29. Special thanks to IAR - Competitiveness Cluster with a Worldwide Vocation