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Structure of Solids Chapter  7
contents ,[object Object],[object Object],[object Object],[object Object],[object Object]
molecular structures ,[object Object],[object Object],molecular compounds ,[object Object],only the weak forces between the molecules break when water boils in a kettle
[object Object],[object Object],[object Object],[object Object],[object Object],molecular structures molecular compounds sugar water fuels fire extinguishers and aerosols medical products chemicals in foods
giant molecular structures ,[object Object],giant molecular compounds diamond each carbon atom is bonded to four others at the corners silicon silicon dioxide
giant molecular structures ,[object Object],[object Object],[object Object],[object Object],physical properties
giant molecular structures ,[object Object],diamond diamond-tipped rock drill ,[object Object],[object Object]
giant molecular structures graphite weak forces between layers, thus, layers can slide over each other easily arrangement of carbon atoms in one flat layer layers of carbon atoms in graphite ,[object Object]
ionic structures ,[object Object],[object Object],ionic compounds C l -  ion Na +  ion Na +  ion C l -   ion ball-and-stick model of sodium chloride shows how ions are arranged inside the crystal how ions are packed together
ionic structures ,[object Object],[object Object],physical properties molten NaC l in molten state, ions are free to move ,[object Object],[object Object],[object Object]
Metallic Bonding In a metal, the outer electrons are shared among all the atoms in the solid. Each atom gives up its outer electrons and becomes slightly positively charged. The negatively charged electrons hold the metal atoms together. Since the electrons are free to move, they lead to good thermal and electrical conductivity.  The phrase used is: “a lattice of positive ions in a sea of negative electrons”
metallic structures ,[object Object],[object Object],metals ,[object Object],metal atoms arrangement of atoms in a metal positive metal ions in a ‘sea of electrons’ positive metal ions free electrons
metallic structures ,[object Object],[object Object],[object Object],[object Object],metals
metallic structures ,[object Object],metals conducting electricity through Cu wire + - positive ions in fixed positions electron flow free electrons move towards + terminal of battery
metallic structures ,[object Object],strong metallic bonds strong ionic bonds strong covalent bonds very weak forces Bonds between the Particles high high high low Boiling Point insoluble soluble insoluble insoluble Solubility in Water conducts when solid and when molten conducts when molten, but not when solid does not conduct in any state does not conduct in any state Electrical Conductivity diamond, silicon dioxide atoms Giant molecular (macro-molecular) sodium chloride, magnesium oxide positive and negative ions Ionic magnesium, iron, copper, sodium positive ions in a sea of electrons Metallic Examples Particles in the Solid methane, iodine, water small covalent molecules Molecular Structure
elements non-metals molecular structure metallic structure atoms positive ions in small numbers of atoms in large numbers of atoms have do not conduct electricity form are joined together by covalent bonds ionic structure giant covalent structure have diamond, silicon dioxide, graphite have H 2 ,  C l 2 , I 2 , H 2 O, CO 2 , CH 4 conduct electricity metals are joined together by metallic bonds in large numbers of atoms Na, Cu, Fe, A l , Mg consist of consist of negative ions form NaC l , MgC l 2 , MgO have loss of electrons gain of electrons ionic bonds in large numbers of ions are joined together by consist of contains

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Structures of solids and other types of bonding

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  • 11. Metallic Bonding In a metal, the outer electrons are shared among all the atoms in the solid. Each atom gives up its outer electrons and becomes slightly positively charged. The negatively charged electrons hold the metal atoms together. Since the electrons are free to move, they lead to good thermal and electrical conductivity. The phrase used is: “a lattice of positive ions in a sea of negative electrons”
  • 12.
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  • 16. elements non-metals molecular structure metallic structure atoms positive ions in small numbers of atoms in large numbers of atoms have do not conduct electricity form are joined together by covalent bonds ionic structure giant covalent structure have diamond, silicon dioxide, graphite have H 2 , C l 2 , I 2 , H 2 O, CO 2 , CH 4 conduct electricity metals are joined together by metallic bonds in large numbers of atoms Na, Cu, Fe, A l , Mg consist of consist of negative ions form NaC l , MgC l 2 , MgO have loss of electrons gain of electrons ionic bonds in large numbers of ions are joined together by consist of contains