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IIT JEE - Past papers CHEMISTRY- UNSOLVED PAPER – I990
SECTION – I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
01 Problem Chlorination of toluene in the presence of light and heat followed by treatment with aqueous NaOH gives O-Cresol P-Cresol 2, 4 Dihydroxytoluene Benzoic acid
Problem  02 Amongst the following, the most basic compound is Benzylamine Aniline  Acetanilide P-Nitroaniline
Problem 03 The density of neon will be highest at STP , 2 atm         , 1 atm          , 2 atm
Problem 04 The oxidation number of phosphorus is Ba                  is +3 +2 +1 -1
Problem 05 The embolic from of acetone contains  9 sigma bonds, 1 pi bond and 2 lone pairs 8 sigma bonds, 2 pi bond and 2 lone pairs 10 sigma bonds, 1 pi bond and 1 lone pairs 9 sigma bonds, 2 pi bond and 1 lone pairs
Problem 06 The freezing point of equimolal aqueous solutions will be highest for a .                          (aniline hydrochloride) b. c.                      d.                      (glucose)
Problem 07 Amongst the following elements (whose electronic configurations are given below), the one having the highest ionization energy is    a. b. c. d.
Problem 08 The formation of cyanohydrin from a ketone is an example of Electrophonic addition  Nucleophilic addition  Nucleophilic substitution  Electrophonic substitution
Problem 09 Amongst the following hydroxides, the one which has the lowest value of           at ordinary temperature (about 25 0C) is a. b. c. d.
Problem 10 The rate of diffusion of methane at a given temperature is twice that of gas X. The molecular weight of X is  64.0 32.0 4.0 8.0
SECTION – II Multiple Answer Type ,[object Object],[object Object]
Problem  02 The compounds used as refrigerant are a. b. c. d. e.
Problem 03 When  zeolite,  which  is hydrated sodium  aluminum  silicate, is treated  with hard  water the  sodium  ions are exchanged with  H+ ions b.             Ions c.              ions            Ions e.            ions
Problem 04 The aqueous solutions of the following salts will be colored in the case of  a. b. c. d. e. Potash alum
Problem 05 Of the  following, the metals  that  cannot  be obtained by electrolysis  of the  aqueous  solution  of their  salts  are  Ag Mg Cu Al Cr
SECTION – III Fill in the blanks Read the following statements carefully. Indicate  the subdivision  number  and write  the matter  corresponding  to the  blanks  strictly in  the order they  appear  in the statement
01 Problem The shape of [OH3] + is _______________.
Problem  02 The valence atomic orditals on C in silver acetylide is _____________ hybridized.
Problem 03 The basicity of phosphorous acid                     is _________________.
Problem 04 Phenol is acidic because of resonance stabilization of its conjugate base, namely, _______________.
Problem 05 Fehling’s solution ‘A’ consists of an aqueous solution of copper sulphate, while Fehling’s solution ‘B’ consists of an alkaline solution of ______________.
SECTION – IV True of False This question contains five statements, each of which is either true of false. Indicate your choice of the answer in the answer-book by writing TRUE or FALSE for each statement.
01 Problem The presence of polar bonds in a polyatomic molecule suggests that the molecule has non-zero dipole moment.
Problem  02 2, 3, 4-Thrichloropentane has three asymmetric carbon atoms.
Problem 03 During         1 reaction, the leaving group leaves the molecule before the incoming group is attached to the molecule,
Problem 04 In           - emission from a nucleus the atomic number of the daughter element decreases by one.
Problem 05 The rate of an exothermic reaction increases with increasing temperature.
FOR SOLUTION VISIT WWW.VASISTA.NET
IIT JEE Chemistry   1990

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IIT JEE Chemistry 1990

  • 1. IIT JEE - Past papers CHEMISTRY- UNSOLVED PAPER – I990
  • 2. SECTION – I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
  • 3. 01 Problem Chlorination of toluene in the presence of light and heat followed by treatment with aqueous NaOH gives O-Cresol P-Cresol 2, 4 Dihydroxytoluene Benzoic acid
  • 4. Problem 02 Amongst the following, the most basic compound is Benzylamine Aniline Acetanilide P-Nitroaniline
  • 5. Problem 03 The density of neon will be highest at STP , 2 atm , 1 atm , 2 atm
  • 6. Problem 04 The oxidation number of phosphorus is Ba is +3 +2 +1 -1
  • 7. Problem 05 The embolic from of acetone contains 9 sigma bonds, 1 pi bond and 2 lone pairs 8 sigma bonds, 2 pi bond and 2 lone pairs 10 sigma bonds, 1 pi bond and 1 lone pairs 9 sigma bonds, 2 pi bond and 1 lone pairs
  • 8. Problem 06 The freezing point of equimolal aqueous solutions will be highest for a . (aniline hydrochloride) b. c. d. (glucose)
  • 9. Problem 07 Amongst the following elements (whose electronic configurations are given below), the one having the highest ionization energy is   a. b. c. d.
  • 10. Problem 08 The formation of cyanohydrin from a ketone is an example of Electrophonic addition Nucleophilic addition Nucleophilic substitution Electrophonic substitution
  • 11. Problem 09 Amongst the following hydroxides, the one which has the lowest value of at ordinary temperature (about 25 0C) is a. b. c. d.
  • 12. Problem 10 The rate of diffusion of methane at a given temperature is twice that of gas X. The molecular weight of X is 64.0 32.0 4.0 8.0
  • 13.
  • 14. Problem 02 The compounds used as refrigerant are a. b. c. d. e.
  • 15. Problem 03 When zeolite, which is hydrated sodium aluminum silicate, is treated with hard water the sodium ions are exchanged with H+ ions b. Ions c. ions Ions e. ions
  • 16. Problem 04 The aqueous solutions of the following salts will be colored in the case of  a. b. c. d. e. Potash alum
  • 17. Problem 05 Of the following, the metals that cannot be obtained by electrolysis of the aqueous solution of their salts are Ag Mg Cu Al Cr
  • 18. SECTION – III Fill in the blanks Read the following statements carefully. Indicate the subdivision number and write the matter corresponding to the blanks strictly in the order they appear in the statement
  • 19. 01 Problem The shape of [OH3] + is _______________.
  • 20. Problem 02 The valence atomic orditals on C in silver acetylide is _____________ hybridized.
  • 21. Problem 03 The basicity of phosphorous acid is _________________.
  • 22. Problem 04 Phenol is acidic because of resonance stabilization of its conjugate base, namely, _______________.
  • 23. Problem 05 Fehling’s solution ‘A’ consists of an aqueous solution of copper sulphate, while Fehling’s solution ‘B’ consists of an alkaline solution of ______________.
  • 24. SECTION – IV True of False This question contains five statements, each of which is either true of false. Indicate your choice of the answer in the answer-book by writing TRUE or FALSE for each statement.
  • 25. 01 Problem The presence of polar bonds in a polyatomic molecule suggests that the molecule has non-zero dipole moment.
  • 26. Problem 02 2, 3, 4-Thrichloropentane has three asymmetric carbon atoms.
  • 27. Problem 03 During 1 reaction, the leaving group leaves the molecule before the incoming group is attached to the molecule,
  • 28. Problem 04 In - emission from a nucleus the atomic number of the daughter element decreases by one.
  • 29. Problem 05 The rate of an exothermic reaction increases with increasing temperature.
  • 30. FOR SOLUTION VISIT WWW.VASISTA.NET