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CUSTOMER BULLETIN 04-10
                  A COMPARISON OF ISO-C1® and HT-300
                    POLYISOCYANURATE INSULATION


PURPOSE
This Customer Bulletin is part of a series of white papers aimed at providing our clients,
engineers, contractors, fabricators, and friends with objective information on competitive
products. Marketing literature on the internet and in printed media address the physical and
performance characteristics of competing polyisocyanurate rigid foam insulations fabricated
from bunstock. As is often the case, some literature can be misleading and/or in some cases
there may not be sufficient information to credibly compare products. This Customer Bulletin
provides factual, clarifying information which should allow for an objective comparison of
Dyplast’s ISO-C1® with HiTherm’s HT-300 (each 2 lb/ft3 density).


TO-THE-POINT SUMMARY COMPARISON
    Dyplast ISO-C1 (nominal 2 lb/ft3)                     HiTherm HT-300 (nominal 2 lb/ft3)
    Manufactured in U.S.                                  Manufactured outside the U.S.
    Blowing agent: pentane (various isomers)              Blowing agent: HCFC (banned in U.S.1)
    Blowing agent GWP: ~10                                Blowing agent GWP: ~700
    Blowing agent ODP: 0.0                                Blowing agent ODP: 0.11
    Physical Properties independently verified Physical Properties                     apparently   not
    and audited by certified independent independently verified2
    laboratories
    Flame spread: 25 up to 4 in. (FM rating)              Flame spread: 25 ≤ 2.5 in.
    Smoke developed: 130 up to 4 in. (FM Smoke developed: 50 3 ≤ 2.5 in.
    rating)
    K-factor: 0.176 aged                                  K-factor: 0.165 aged
    Water vapor permeability: 2.33 perm-in                Water vapor permeability: 4.0 perm-in



1
  Manufacture of polyiso bunstock using HCFCs is banned in the United States and other developed
countries as of January 1, 2005
2
    Could not be verified by literature/internet search
3
 Not verifiable since no independent lab testing was declared, yet not inconceivable given use of the
banned blowing agent HCFC


Customer Bulletin 04-10                                                                        April 2010
Dimensional stability (length)4: <1.0%            Dimensional stability (length)4: 2.3%
    Dimensional stability (volume)4: <2.0%            Dimensional stability (volume)4: 3.8%
    Closed cell content: >95%                         Closed cell content: >90%
    Compressive strength (parallel to rise): 26 Compressive strength (parallel to rise): 30
    lb/in2                                      lb/in2
    Fabricated in U.S.                                Fabricated in U.S.


POLYISOCYANURATE BACKGROUND
Polyisocyanurate (polyiso or “PIR”) rigid foam is often misidentified as a polyurethane foam
(PUR) when, in fact, it is based on a significant modification to standard polyurethane chemistry.
Polyiso foams have a higher ratio of polyisocyanates to polyols (a higher “index”) than do
polyurethane foams. The nature of this high-index foam imparts many advantageous properties
to the foam including dimensional stability, thermal stability, solvent resistance, and superior
flame resistance. Thus PIR has become the insulation of choice for insulation in applications
under 300F, with performance far exceeding extruded polystyrene, expanded polystyrene,
fiberglass, cellular glass, mineral wools, and so forth.
Yet worldwide efforts to mitigate indisputable global ozone layer damage have motivated the
industry to move toward environmentally friendly chemicals in the production of PIR - - even at
the expense of slight reduction in performance.


ENVIRONMENTAL
Ozone Depletion
Ground-level ozone of course contributes to SMOG, which in turn can have adverse effects on
respiratory ailments, as well as reduction in visibility and so forth. Yet a decrease in ozone
concentrations in the upper atmosphere allows damaging ultraviolet radiation (UV) to penetrate
the atmosphere, and can cause cancer in humans and/or cell mutations in plants and animals. It
is this latter problem that motivated major movements by countries around the world (including
the international treaty referred to as the Montreal Protocol) to strive to reduce Ozone Depletion
Potential (ODP). One element of their efforts has been to require a logically beneficial transition
away from chemicals that contribute to ozone depletion high in the atmosphere - - namely CFCs
and HCFCs.
Yet as is often the case, to mitigate undue economic hardship on “developing” countries the
Treaty allows countries such as Mexico, the Caribbean, certain Central/South American
countries, and others to continue use of certain HCFCs until 2040! (after which time it will be a
violation). The problem for the United States arises from a loophole in enforcement that allows,
for instance, a manufacturer of an HCFC-containing insulation product in a developing country
to legally ship it into a developing country (e.g. the U.S.). The ultimate impact on the
environment is the same - - ozone-depleting gases are released. Although strict penalties apply


4
    At 158°F, for 7 days at reported 97% relative humidity for ISO-C1, and 100% humidity for HT-300


Customer Bulletin 04-10                                                                        April 2010
to smuggling CFC and HCFC into the U.S. (http://www.epa.gov/Ozone/enforce/blackmkt.html),
the importation of a product manufactured with the same CFCs/HCFCs is immune to such
penalties.
Greenhouse Gases/Global Warming
Although “Global Warming” is still being debated on the fringes of the population, the existence
of “Greenhouse Gases” is not. Fortunately, the Montreal Protocol’s restrictions on CFCs and
HCFCs also result in a significant reduction in greenhouse gases, that in turn reduce the
likelihood that the average global temperature will increase.


INDEPENDENT TESTING OF PHYSICAL PROPERTIES
Clients and end-users of insulation products have the right to absolute confidence that the
representations of insulation manufacturers/suppliers are accurate. Third party, independent
verification of physical properties is only the first step to ensure credible, objective data is
published (subsequent audit and re-test is the second). In fact, a single test at an independent
lab verifies only that a single batch of product produced a given set of results.
Dyplast not only uses third party independent verification of all ISO-C1 physical properties, but
additionally funds an audit process whereby the independent laboratory randomly visits the
manufacturing facility to monitor how the product is produced - - verifying that the chemistry and
process are consistent with the conditions of the prior tests. In this respect, Dyplast’s ISO-
C1/2.0 product is both tested and has received FM Approval, is listed5 at UL, approved by ICC,
and is tested and audited by RADCO6.
Literature and internet searches for comparable verification of HT-300 physical properties were
unsuccessful.


FLAME AND SMOKE
The unfortunate fact is that when manufacturers in developing countries phased out CFC/HCFC
pollutants as blowing agents in polyiso bunstock, the flame spread index (FSI) and smoke
developed index (SDI) of their products deteriorated. In the past, polyiso bunstock foams
manufactured with CFC blowing agents often achieved 25FSI and 50SDI up to 4 inch product
thickness. With HCFC blowing agents manufacturers had a difficult time achieving 25/50 at 2
inches. Today, manufacturers in developed countries have generally turned to hydro-carbon
blowing agents; and at this stage there is no bunstock manufacturer in any developed country
that credibly advertises 25/50 - - at any thickness. Dyplast may be one of the few that continues
its aggressive R&D efforts to meet this challenging objective.


5
  Underwriters Laboratories, the world’s largest, not-for-profit product safety testing and certification
organization with global name recognition and acceptance. Founded in 1894 in the US, it permits the use
of its listing mark (the UL mark) as its stamp of approval on goods and materials after standardized and
stringent testing. Thereafter its inspectors regularly visit the producer to audit compliance with its
certification requirements.
6
  RADCO is a nationally recognized testing laboratory, listing and quality control inspection agency
headquartered in Long Beach, California, with branch offices across the U.S.


Customer Bulletin 04-10                                                                      April 2010
[Note: The 25/50 market is discovering phenolic foam insulation as the insulation-of-choice due
to its incredibly high insulating value compared to the alternatives of cellular glass and
fiberglass, each of which have additional drawbacks. Dyplast supplies phenolic insulation
meeting 25/50.]


THERMAL PERFORMANCE
Correspondingly to the above relationship between flame/smoke and blowing agent chemistry,
manufacturers in developed countries have observed a deterioration in thermal resistance
(higher K-factors) when using more environmentally-friendly hydrocarbon blowing agents (as
compared to now-banned CFCs and HCFCs). The good news is that polyisocyanurate
insulation continues to provide the highest thermal performance per cost compared to any
commercially available insulation.
Credible verification of HT-300’s K-factor could not be found so it is difficult to dispute the aged
K-factor of 0.165 listed on HT-300 datasheets. Dyplast’s ISO-C1 aged K-factor is higher, yet
compares favorably at 0.176, which is the best of all the current pentane blown foams on the
market. Dyplast’s K-factor has been confirmed by independent tests and audits.


WATER VAPOR PERMEABILITY
Water vapor permeability is one of the most important physical properties, particularly for pipe
insulation. Insulation systems inherently have a “vapor drive” where the second law of
thermodynamics dictates that water-vapor/moisture flows from the wetter/warmer side to
dryer/cooler side. In a chilled water or cryogenic application, for example, the water vapor will
collect and/or freeze on the pipe, valves, and equipment, potentially reducing operability of
moving components and dramatically corrupting the thermal performance of the insulation
system. Indeed a “low-perm” vapor retarder is often wrapped over the insulation material as part
of an insulation system to improve the overall permeability of the system. Yet vapor retarders
have low resistance to punctures and tears, and can often fail in situations where mechanical
abuse is a threat (e.g. stepping on the insulated pipe). The bottom line! When there is a choice
between comparable insulations, the best choice is the insulation with the lower water vapor
permeability. Dyplast’s ISO-C1 has a water vapor permeability of 2.33, while HT-300’s is 72%
higher at 4.0.


DIMENSIONAL STABILITY
Dimensional stability is a measurement of a material’s change in dimensions—length, width,
thickness — over time in response to various environmental exposure conditions such as
temperature and humidity. Sometimes manufacturers provide a “volume” measurement as an
indication of the 3-dimensional changes. Dimensional stability varies with the type of material
and the specific chemical/physical makeup. Since the ASTM D-2126 test is a material test only,
it is not intended to address that material’s performance as part of an overall insulation system.
All insulations have some dimensional instability; insulation system designs and quality
installation can mitigate or eliminate its effect on thermal performance. Yet very poor
dimensional stability can cause swelling, expansion, shrinkage and buckling of a system's
insulation. These actions, in turn, can eventually lead to thermal bridges, vapor

Customer Bulletin 04-10                                                                  April 2010
retarder/jacketing breaches, and unpredictable insulation performance. Another bottom line! - - -
when there is a choice between comparable insulations, the best choice is the insulation with
the best (i.e. lower) dimensional stability.
The following are the dimensional stability measurements of ISO-C1 versus HT-300, measured
per ASTM D-2126:

    Dimensional Stability, % Change                          ISO-C1                         HT-3007
    -40° F (-40°C), 7 Days
    Length                                                   <0.1%                        Not available
    Volume                                                   <0.1%                        Not available
    -20° F (-30°C), 7 Days
    Length                                      Can be inferred by interpolation             0.1%
    Volume                                      Can be inferred by interpolation             1.3%
    158°F (70° C), 97-100% R.H., 7 Days
    Length                                                   <1.0%                           2.3%
    Volume                                                   <2.0%                           3.8%
    212°F (100° C), 7 Days
    Length                                                   <0.1%                           1.0%
    Volume                                                   <1.0%                           2.3%

WATER ABSORPTION
Water absorption is a very important physical property since water materially degrades the
thermal efficiency of insulation. Dyplast has excellent water absorption characteristics of 0.24%
as measured by ASTM C-272. For comparison, this is well below the 0.3%8 for extruded
polystyrene, and 2.0%9 for ~2 lb/ft3 density expanded polystyrene. It is not possible to compare
ISO-C1 with HT-300 since the water absorption of HT-300 is measured using ASTM D-2842,
which determines water absorption by measuring the change in buoyant force (lbs/ft2) resulting
from immersion under a 2 inch head of water for 96 hours.




7
    Technical Datasheet for HT-300 (http://www.pirsupply.com/ht-300tech-data.pdf)
8
    Extruded Polystyrene Foam Insulation data (http://www.xpsa.com/tech/standards.html)
9
      EPS    Molders    Association   data    (http://www.epsmolders.org/PDF_FILES/C578%20Chart.pdf)



Customer Bulletin 04-10                                                                        April 2010

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Customer Bulletin 0410 A Comparison of ISO-C1 and HT-300

  • 1. CUSTOMER BULLETIN 04-10 A COMPARISON OF ISO-C1® and HT-300 POLYISOCYANURATE INSULATION PURPOSE This Customer Bulletin is part of a series of white papers aimed at providing our clients, engineers, contractors, fabricators, and friends with objective information on competitive products. Marketing literature on the internet and in printed media address the physical and performance characteristics of competing polyisocyanurate rigid foam insulations fabricated from bunstock. As is often the case, some literature can be misleading and/or in some cases there may not be sufficient information to credibly compare products. This Customer Bulletin provides factual, clarifying information which should allow for an objective comparison of Dyplast’s ISO-C1® with HiTherm’s HT-300 (each 2 lb/ft3 density). TO-THE-POINT SUMMARY COMPARISON Dyplast ISO-C1 (nominal 2 lb/ft3) HiTherm HT-300 (nominal 2 lb/ft3) Manufactured in U.S. Manufactured outside the U.S. Blowing agent: pentane (various isomers) Blowing agent: HCFC (banned in U.S.1) Blowing agent GWP: ~10 Blowing agent GWP: ~700 Blowing agent ODP: 0.0 Blowing agent ODP: 0.11 Physical Properties independently verified Physical Properties apparently not and audited by certified independent independently verified2 laboratories Flame spread: 25 up to 4 in. (FM rating) Flame spread: 25 ≤ 2.5 in. Smoke developed: 130 up to 4 in. (FM Smoke developed: 50 3 ≤ 2.5 in. rating) K-factor: 0.176 aged K-factor: 0.165 aged Water vapor permeability: 2.33 perm-in Water vapor permeability: 4.0 perm-in 1 Manufacture of polyiso bunstock using HCFCs is banned in the United States and other developed countries as of January 1, 2005 2 Could not be verified by literature/internet search 3 Not verifiable since no independent lab testing was declared, yet not inconceivable given use of the banned blowing agent HCFC Customer Bulletin 04-10 April 2010
  • 2. Dimensional stability (length)4: <1.0% Dimensional stability (length)4: 2.3% Dimensional stability (volume)4: <2.0% Dimensional stability (volume)4: 3.8% Closed cell content: >95% Closed cell content: >90% Compressive strength (parallel to rise): 26 Compressive strength (parallel to rise): 30 lb/in2 lb/in2 Fabricated in U.S. Fabricated in U.S. POLYISOCYANURATE BACKGROUND Polyisocyanurate (polyiso or “PIR”) rigid foam is often misidentified as a polyurethane foam (PUR) when, in fact, it is based on a significant modification to standard polyurethane chemistry. Polyiso foams have a higher ratio of polyisocyanates to polyols (a higher “index”) than do polyurethane foams. The nature of this high-index foam imparts many advantageous properties to the foam including dimensional stability, thermal stability, solvent resistance, and superior flame resistance. Thus PIR has become the insulation of choice for insulation in applications under 300F, with performance far exceeding extruded polystyrene, expanded polystyrene, fiberglass, cellular glass, mineral wools, and so forth. Yet worldwide efforts to mitigate indisputable global ozone layer damage have motivated the industry to move toward environmentally friendly chemicals in the production of PIR - - even at the expense of slight reduction in performance. ENVIRONMENTAL Ozone Depletion Ground-level ozone of course contributes to SMOG, which in turn can have adverse effects on respiratory ailments, as well as reduction in visibility and so forth. Yet a decrease in ozone concentrations in the upper atmosphere allows damaging ultraviolet radiation (UV) to penetrate the atmosphere, and can cause cancer in humans and/or cell mutations in plants and animals. It is this latter problem that motivated major movements by countries around the world (including the international treaty referred to as the Montreal Protocol) to strive to reduce Ozone Depletion Potential (ODP). One element of their efforts has been to require a logically beneficial transition away from chemicals that contribute to ozone depletion high in the atmosphere - - namely CFCs and HCFCs. Yet as is often the case, to mitigate undue economic hardship on “developing” countries the Treaty allows countries such as Mexico, the Caribbean, certain Central/South American countries, and others to continue use of certain HCFCs until 2040! (after which time it will be a violation). The problem for the United States arises from a loophole in enforcement that allows, for instance, a manufacturer of an HCFC-containing insulation product in a developing country to legally ship it into a developing country (e.g. the U.S.). The ultimate impact on the environment is the same - - ozone-depleting gases are released. Although strict penalties apply 4 At 158°F, for 7 days at reported 97% relative humidity for ISO-C1, and 100% humidity for HT-300 Customer Bulletin 04-10 April 2010
  • 3. to smuggling CFC and HCFC into the U.S. (http://www.epa.gov/Ozone/enforce/blackmkt.html), the importation of a product manufactured with the same CFCs/HCFCs is immune to such penalties. Greenhouse Gases/Global Warming Although “Global Warming” is still being debated on the fringes of the population, the existence of “Greenhouse Gases” is not. Fortunately, the Montreal Protocol’s restrictions on CFCs and HCFCs also result in a significant reduction in greenhouse gases, that in turn reduce the likelihood that the average global temperature will increase. INDEPENDENT TESTING OF PHYSICAL PROPERTIES Clients and end-users of insulation products have the right to absolute confidence that the representations of insulation manufacturers/suppliers are accurate. Third party, independent verification of physical properties is only the first step to ensure credible, objective data is published (subsequent audit and re-test is the second). In fact, a single test at an independent lab verifies only that a single batch of product produced a given set of results. Dyplast not only uses third party independent verification of all ISO-C1 physical properties, but additionally funds an audit process whereby the independent laboratory randomly visits the manufacturing facility to monitor how the product is produced - - verifying that the chemistry and process are consistent with the conditions of the prior tests. In this respect, Dyplast’s ISO- C1/2.0 product is both tested and has received FM Approval, is listed5 at UL, approved by ICC, and is tested and audited by RADCO6. Literature and internet searches for comparable verification of HT-300 physical properties were unsuccessful. FLAME AND SMOKE The unfortunate fact is that when manufacturers in developing countries phased out CFC/HCFC pollutants as blowing agents in polyiso bunstock, the flame spread index (FSI) and smoke developed index (SDI) of their products deteriorated. In the past, polyiso bunstock foams manufactured with CFC blowing agents often achieved 25FSI and 50SDI up to 4 inch product thickness. With HCFC blowing agents manufacturers had a difficult time achieving 25/50 at 2 inches. Today, manufacturers in developed countries have generally turned to hydro-carbon blowing agents; and at this stage there is no bunstock manufacturer in any developed country that credibly advertises 25/50 - - at any thickness. Dyplast may be one of the few that continues its aggressive R&D efforts to meet this challenging objective. 5 Underwriters Laboratories, the world’s largest, not-for-profit product safety testing and certification organization with global name recognition and acceptance. Founded in 1894 in the US, it permits the use of its listing mark (the UL mark) as its stamp of approval on goods and materials after standardized and stringent testing. Thereafter its inspectors regularly visit the producer to audit compliance with its certification requirements. 6 RADCO is a nationally recognized testing laboratory, listing and quality control inspection agency headquartered in Long Beach, California, with branch offices across the U.S. Customer Bulletin 04-10 April 2010
  • 4. [Note: The 25/50 market is discovering phenolic foam insulation as the insulation-of-choice due to its incredibly high insulating value compared to the alternatives of cellular glass and fiberglass, each of which have additional drawbacks. Dyplast supplies phenolic insulation meeting 25/50.] THERMAL PERFORMANCE Correspondingly to the above relationship between flame/smoke and blowing agent chemistry, manufacturers in developed countries have observed a deterioration in thermal resistance (higher K-factors) when using more environmentally-friendly hydrocarbon blowing agents (as compared to now-banned CFCs and HCFCs). The good news is that polyisocyanurate insulation continues to provide the highest thermal performance per cost compared to any commercially available insulation. Credible verification of HT-300’s K-factor could not be found so it is difficult to dispute the aged K-factor of 0.165 listed on HT-300 datasheets. Dyplast’s ISO-C1 aged K-factor is higher, yet compares favorably at 0.176, which is the best of all the current pentane blown foams on the market. Dyplast’s K-factor has been confirmed by independent tests and audits. WATER VAPOR PERMEABILITY Water vapor permeability is one of the most important physical properties, particularly for pipe insulation. Insulation systems inherently have a “vapor drive” where the second law of thermodynamics dictates that water-vapor/moisture flows from the wetter/warmer side to dryer/cooler side. In a chilled water or cryogenic application, for example, the water vapor will collect and/or freeze on the pipe, valves, and equipment, potentially reducing operability of moving components and dramatically corrupting the thermal performance of the insulation system. Indeed a “low-perm” vapor retarder is often wrapped over the insulation material as part of an insulation system to improve the overall permeability of the system. Yet vapor retarders have low resistance to punctures and tears, and can often fail in situations where mechanical abuse is a threat (e.g. stepping on the insulated pipe). The bottom line! When there is a choice between comparable insulations, the best choice is the insulation with the lower water vapor permeability. Dyplast’s ISO-C1 has a water vapor permeability of 2.33, while HT-300’s is 72% higher at 4.0. DIMENSIONAL STABILITY Dimensional stability is a measurement of a material’s change in dimensions—length, width, thickness — over time in response to various environmental exposure conditions such as temperature and humidity. Sometimes manufacturers provide a “volume” measurement as an indication of the 3-dimensional changes. Dimensional stability varies with the type of material and the specific chemical/physical makeup. Since the ASTM D-2126 test is a material test only, it is not intended to address that material’s performance as part of an overall insulation system. All insulations have some dimensional instability; insulation system designs and quality installation can mitigate or eliminate its effect on thermal performance. Yet very poor dimensional stability can cause swelling, expansion, shrinkage and buckling of a system's insulation. These actions, in turn, can eventually lead to thermal bridges, vapor Customer Bulletin 04-10 April 2010
  • 5. retarder/jacketing breaches, and unpredictable insulation performance. Another bottom line! - - - when there is a choice between comparable insulations, the best choice is the insulation with the best (i.e. lower) dimensional stability. The following are the dimensional stability measurements of ISO-C1 versus HT-300, measured per ASTM D-2126: Dimensional Stability, % Change ISO-C1 HT-3007 -40° F (-40°C), 7 Days Length <0.1% Not available Volume <0.1% Not available -20° F (-30°C), 7 Days Length Can be inferred by interpolation 0.1% Volume Can be inferred by interpolation 1.3% 158°F (70° C), 97-100% R.H., 7 Days Length <1.0% 2.3% Volume <2.0% 3.8% 212°F (100° C), 7 Days Length <0.1% 1.0% Volume <1.0% 2.3% WATER ABSORPTION Water absorption is a very important physical property since water materially degrades the thermal efficiency of insulation. Dyplast has excellent water absorption characteristics of 0.24% as measured by ASTM C-272. For comparison, this is well below the 0.3%8 for extruded polystyrene, and 2.0%9 for ~2 lb/ft3 density expanded polystyrene. It is not possible to compare ISO-C1 with HT-300 since the water absorption of HT-300 is measured using ASTM D-2842, which determines water absorption by measuring the change in buoyant force (lbs/ft2) resulting from immersion under a 2 inch head of water for 96 hours. 7 Technical Datasheet for HT-300 (http://www.pirsupply.com/ht-300tech-data.pdf) 8 Extruded Polystyrene Foam Insulation data (http://www.xpsa.com/tech/standards.html) 9 EPS Molders Association data (http://www.epsmolders.org/PDF_FILES/C578%20Chart.pdf) Customer Bulletin 04-10 April 2010