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Introduction to Organic Chemistry
Contents ,[object Object],[object Object],[object Object],[object Object],[object Object]
Nomenclature and Isomerism ,[object Object],[object Object],[object Object],Hex- Pent- But- Pro- Eth- Meth- Prefix  6 5 4 3 2 1 Number of C atoms
Nomenclature -oate Esters -oic C n H  2n CO 2 H Carboxylic Acids C=O -one Ketones -al Aldehyde – OH  -ol C n H 2n+1  OH Alcohols – Cl or –Br  chloro -, bromo-  etc Haloalkanes C=C -ene C n H 2n Alkenes C –H  -ane C n H  2n+2 Alkanes Functional group Name General Formula Homologous Series – C  O H – C  O O–C  – C  O OH
Isomerisation ,[object Object],Butane  2-Methyl propane ,[object Object],[object Object],[object Object],[object Object],[object Object],CH 3  –CH 2  –CH 2  –CH 3   CH 3  –CH –CH 3 CH 3
Petroleum and Alkanes ,[object Object],[object Object],[object Object]
Petroleum ,[object Object],[object Object],[object Object],[object Object],[object Object]
Combustion ,[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Alkenes and Epoxyethane ,[object Object],[object Object],[object Object],[object Object]
Reactions of Alkenes +H 2  catalyst Heat & pressure +Br 2 +HCl +steam & catalyst n Catalyst & heat Remember in the presence of alkenes bromine water decolourises H  H – C –C – H  H Br  Br – C –C – H  Cl – C –C – H  OH – C –C – alkane C=C
Epoxyethane ,[object Object],[object Object],[object Object],O CH 2 CH 2
Haloalkanes ,[object Object],[object Object],[object Object],C Br : CN -  -  + The carbon atom of the CN -  ion donates a pair of electrons to the haloalkane and the C –Br breaks with loss of a bromide ion. A new C –CN bond is formed.
Elimination  ,[object Object],[object Object],[object Object]
Alcohols Primary  Secondary  Tertiary Alcohols are classified according to the number of carbon atoms bonded to the carbon atom adjacent to the OH group. C OH C C C C OH H H C C OH H C C
Manufacture of Alcohols ,[object Object],[object Object],[object Object]
Reactions of Alcohols ,[object Object],[object Object],[object Object],[object Object]
Summary ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

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Introductiontoorganicchemistry 090518040648 Phpapp02

  • 2.
  • 3.
  • 4. Nomenclature -oate Esters -oic C n H 2n CO 2 H Carboxylic Acids C=O -one Ketones -al Aldehyde – OH -ol C n H 2n+1 OH Alcohols – Cl or –Br chloro -, bromo- etc Haloalkanes C=C -ene C n H 2n Alkenes C –H -ane C n H 2n+2 Alkanes Functional group Name General Formula Homologous Series – C O H – C O O–C – C O OH
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11. Reactions of Alkenes +H 2 catalyst Heat & pressure +Br 2 +HCl +steam & catalyst n Catalyst & heat Remember in the presence of alkenes bromine water decolourises H H – C –C – H H Br Br – C –C – H Cl – C –C – H OH – C –C – alkane C=C
  • 12.
  • 13.
  • 14.
  • 15. Alcohols Primary Secondary Tertiary Alcohols are classified according to the number of carbon atoms bonded to the carbon atom adjacent to the OH group. C OH C C C C OH H H C C OH H C C
  • 16.
  • 17.
  • 18.