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Explaining the trend in ionic radii
Explaining the trend in ionic radii
Both group 1 and group7 ions increase in size as you go
down the group.
Explaining the trend in ionic radii
Both group 1 and group7 ions increase in size as you go
down the group.
This is because as you go down a group the outer level gets
further from the nucleus.




 However it is important to distinguish between cations (+ve)
 and anions (-ve).
Explaining the trend in ionic radii
Both group 1 and group7 ions increase in size as you go
down the group.
This is because as you go down a group the outer level gets
further from the nucleus.
Explaining the trend in ionic radii
Both group 1 and group7 ions increase in size as you go
down the group.
This is because as you go down a group the outer level gets
further from the nucleus.




 However it is important to distinguish between cations (+ve)
 and anions (-ve).
Cation ionic radii
When cations (+ve) are formed they lose electrons
Cation ionic radii
When cations (+ve) are formed they lose electrons
Therefore the electron:proton ratio is less. This makes the
force of attraction between the protons and outer electrons
slightly larger
Cation ionic radii
When cations (+ve) are formed they lose electrons
Therefore the electron:proton ratio is less. This makes the
force of attraction between the protons and outer electrons
slightly larger

This makes cations smaller than their parent atoms
Cation ionic radii
When cations (+ve) are formed they lose electrons
Therefore the electron:proton ratio is less. This makes the
force of attraction between the protons and outer electrons
slightly larger

This makes cations smaller than their parent atoms

              Atomic
Element
              radius
               (nm)
lithium        0.152
Sodium         0.186
potassium      0.231
Rubidium       0.244
Cation ionic radii
When cations (+ve) are formed they lose electrons
Therefore the electron:proton ratio is less. This makes the
force of attraction between the protons and outer electrons
slightly larger

This makes cations smaller than their parent atoms

              Atomic                                 ionic
Element                               Ion
              radius                                radius
               (nm)                                  (nm)

lithium        0.152             Lithium ion        0.068

Sodium         0.186             Sodium ion         0.098

potassium      0.231             Potassium ion      0.133

Rubidium       0.244             Rubidium ion       0.176
Anion ionic radii
Anion ionic radii
When Anions (-ve) are formed they gain electrons
Therefore the electron:proton ratio is more. This makes the
force of attraction between the protons and outer electrons
slightly smaller
Anion ionic radii
When Anions (-ve) are formed they gain electrons
Therefore the electron:proton ratio is more. This makes the
force of attraction between the protons and outer electrons
slightly smaller

This makes Anions larger than their parent atoms
Anion ionic radii
When Anions (-ve) are formed they gain electrons
Therefore the electron:proton ratio is more. This makes the
force of attraction between the protons and outer electrons
slightly smaller

This makes Anions larger than their parent atoms

              Atomic
Element
              radius
               (nm)
Fluorine       0.064
Chlorine       0.099
Bromine        0.114
Iodine         0.133
Anion ionic radii
When Anions (-ve) are formed they gain electrons
Therefore the electron:proton ratio is more. This makes the
force of attraction between the protons and outer electrons
slightly smaller

This makes Anions larger than their parent atoms

              Atomic                                ionic
Element                               Ion
              radius                               radius
               (nm)                                 (nm)

Fluorine       0.064             fluoride ion      0.133

Chlorine       0.099             chloride ion      0.181

Bromine        0.114             bromide ion       0.196

Iodine         0.133             iodide ion        0.219

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IB3.2.2.2

  • 1. Explaining the trend in ionic radii
  • 2. Explaining the trend in ionic radii Both group 1 and group7 ions increase in size as you go down the group.
  • 3. Explaining the trend in ionic radii Both group 1 and group7 ions increase in size as you go down the group. This is because as you go down a group the outer level gets further from the nucleus. However it is important to distinguish between cations (+ve) and anions (-ve).
  • 4. Explaining the trend in ionic radii Both group 1 and group7 ions increase in size as you go down the group. This is because as you go down a group the outer level gets further from the nucleus.
  • 5. Explaining the trend in ionic radii Both group 1 and group7 ions increase in size as you go down the group. This is because as you go down a group the outer level gets further from the nucleus. However it is important to distinguish between cations (+ve) and anions (-ve).
  • 6. Cation ionic radii When cations (+ve) are formed they lose electrons
  • 7. Cation ionic radii When cations (+ve) are formed they lose electrons Therefore the electron:proton ratio is less. This makes the force of attraction between the protons and outer electrons slightly larger
  • 8. Cation ionic radii When cations (+ve) are formed they lose electrons Therefore the electron:proton ratio is less. This makes the force of attraction between the protons and outer electrons slightly larger This makes cations smaller than their parent atoms
  • 9. Cation ionic radii When cations (+ve) are formed they lose electrons Therefore the electron:proton ratio is less. This makes the force of attraction between the protons and outer electrons slightly larger This makes cations smaller than their parent atoms Atomic Element radius (nm) lithium 0.152 Sodium 0.186 potassium 0.231 Rubidium 0.244
  • 10. Cation ionic radii When cations (+ve) are formed they lose electrons Therefore the electron:proton ratio is less. This makes the force of attraction between the protons and outer electrons slightly larger This makes cations smaller than their parent atoms Atomic ionic Element Ion radius radius (nm) (nm) lithium 0.152 Lithium ion 0.068 Sodium 0.186 Sodium ion 0.098 potassium 0.231 Potassium ion 0.133 Rubidium 0.244 Rubidium ion 0.176
  • 12. Anion ionic radii When Anions (-ve) are formed they gain electrons Therefore the electron:proton ratio is more. This makes the force of attraction between the protons and outer electrons slightly smaller
  • 13. Anion ionic radii When Anions (-ve) are formed they gain electrons Therefore the electron:proton ratio is more. This makes the force of attraction between the protons and outer electrons slightly smaller This makes Anions larger than their parent atoms
  • 14. Anion ionic radii When Anions (-ve) are formed they gain electrons Therefore the electron:proton ratio is more. This makes the force of attraction between the protons and outer electrons slightly smaller This makes Anions larger than their parent atoms Atomic Element radius (nm) Fluorine 0.064 Chlorine 0.099 Bromine 0.114 Iodine 0.133
  • 15. Anion ionic radii When Anions (-ve) are formed they gain electrons Therefore the electron:proton ratio is more. This makes the force of attraction between the protons and outer electrons slightly smaller This makes Anions larger than their parent atoms Atomic ionic Element Ion radius radius (nm) (nm) Fluorine 0.064 fluoride ion 0.133 Chlorine 0.099 chloride ion 0.181 Bromine 0.114 bromide ion 0.196 Iodine 0.133 iodide ion 0.219