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Explaining the trend in melting points
Explaining the trend in melting points
  The melting points of the
  elements decrease down
  group 1.
Explaining the trend in melting points
  The melting points of the                     Melting
  elements decrease down            Element
                                                point (K)
  group 1.
                                    Lithium       454
 A metal’s melting point depends
 on the strength of its metallic    Sodium        371
 bonds. This decreases down the
                                    Potassium     336
 group because the atomic radius
 increases, resulting in a weaker   Rubidium      312
 attraction between the nucleus
                                    Caesium       302
 and delocalized electrons.
Explaining the trend in melting points
  The melting points of the                        Melting
  elements decrease down            Element
                                                   point (K)
  group 1.
                                    Lithium           454
 A metal’s melting point depends
 on the strength of its metallic    Sodium            371
 bonds. This decreases down the
                                    Potassium         336
 group because the atomic radius
 increases, resulting in a weaker   Rubidium          312
 attraction between the nucleus
                                    Caesium           302
 and delocalized electrons.

                                              large radius
                                              weak attraction
Small radius
Strong attraction
Trend in Mp of halogens?
 The halogens are the elements in Group 7 of the
 periodic table.
Trend in Mp of halogens?
 The halogens are the elements in Group 7 of the
 periodic table.
Trend in Mp of halogens?
 The halogens are the elements in Group 7 of the
 periodic table.




 The name halogen comes from the Greek
 words for salt-making.
Trends in boiling point
  Halogen molecules increase in size down the group. This
  leads to greater van der Waals forces between molecules,
  increasing the energy needed to separate the molecules
  and therefore higher melting and boiling points.
Trends in boiling point
  Halogen molecules increase in size down the group. This
  leads to greater van der Waals forces between molecules,
  increasing the energy needed to separate the molecules
  and therefore higher melting and boiling points.




           fluorine
atomic radius = 42 × 10-12 m
   boiling point = -118 °C
Trends in boiling point
  Halogen molecules increase in size down the group. This
  leads to greater van der Waals forces between molecules,
  increasing the energy needed to separate the molecules
  and therefore higher melting and boiling points.




           fluorine                       iodine
atomic radius = 42 × 10-12 m   atomic radius = 115 × 10-12 m
   boiling point = -118 °C        boiling point = 184 °C
Trends in boiling point
  Halogen molecules increase in size down the group. This
  leads to greater van der Waals forces between molecules,
  increasing the energy needed to separate the molecules
  and therefore higher melting and boiling points.



                        van der
                      Waals forces




           fluorine                       iodine
atomic radius = 42 × 10-12 m   atomic radius = 115 × 10-12 m
   boiling point = -118 °C        boiling point = 184 °C

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IB 3.2.2.5

  • 1. Explaining the trend in melting points
  • 2. Explaining the trend in melting points The melting points of the elements decrease down group 1.
  • 3. Explaining the trend in melting points The melting points of the Melting elements decrease down Element point (K) group 1. Lithium 454 A metal’s melting point depends on the strength of its metallic Sodium 371 bonds. This decreases down the Potassium 336 group because the atomic radius increases, resulting in a weaker Rubidium 312 attraction between the nucleus Caesium 302 and delocalized electrons.
  • 4. Explaining the trend in melting points The melting points of the Melting elements decrease down Element point (K) group 1. Lithium 454 A metal’s melting point depends on the strength of its metallic Sodium 371 bonds. This decreases down the Potassium 336 group because the atomic radius increases, resulting in a weaker Rubidium 312 attraction between the nucleus Caesium 302 and delocalized electrons. large radius weak attraction Small radius Strong attraction
  • 5. Trend in Mp of halogens? The halogens are the elements in Group 7 of the periodic table.
  • 6. Trend in Mp of halogens? The halogens are the elements in Group 7 of the periodic table.
  • 7. Trend in Mp of halogens? The halogens are the elements in Group 7 of the periodic table. The name halogen comes from the Greek words for salt-making.
  • 8. Trends in boiling point Halogen molecules increase in size down the group. This leads to greater van der Waals forces between molecules, increasing the energy needed to separate the molecules and therefore higher melting and boiling points.
  • 9. Trends in boiling point Halogen molecules increase in size down the group. This leads to greater van der Waals forces between molecules, increasing the energy needed to separate the molecules and therefore higher melting and boiling points. fluorine atomic radius = 42 × 10-12 m boiling point = -118 °C
  • 10. Trends in boiling point Halogen molecules increase in size down the group. This leads to greater van der Waals forces between molecules, increasing the energy needed to separate the molecules and therefore higher melting and boiling points. fluorine iodine atomic radius = 42 × 10-12 m atomic radius = 115 × 10-12 m boiling point = -118 °C boiling point = 184 °C
  • 11. Trends in boiling point Halogen molecules increase in size down the group. This leads to greater van der Waals forces between molecules, increasing the energy needed to separate the molecules and therefore higher melting and boiling points. van der Waals forces fluorine iodine atomic radius = 42 × 10-12 m atomic radius = 115 × 10-12 m boiling point = -118 °C boiling point = 184 °C