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NOVEL DATA ANALYSIS TECHNIQUE
USED TO EVALUATE NOX AND
CO2 CONTINUOUS EMISSIONS DATA
AWMA 106th Annual Conference, June 27, 2013
Sergio A. Guerra - Wenck Associates, Inc.
Dennis D. Lane, Norman A. Slade, Ray E. Carter, Edward Peltier, Glen Marotz University of Kansas
BACKGROUND
• Society depends heavily on diesel engines
• Diesel engines are more durable and fuel efficient than

gasoline ones
• At full load diesel engine use ~70% of the fuel a
comparable gasoline engine consumes (Lloyd et al., 2001)
• Off-road diesel vehicles not well studied
BACKGROUND- Off-road Emissions
OBJECTIVES
1.Collect real-world NOx and CO2 emission profiles from an

off-road diesel vehicle
2.Evaluate NOx and CO2 emission profiles for a diesel offroad vehicle running on diesel, B20 and ULSD fuels to
determine potential emission reductions
3.Evaluate the effect that temporal factors exert on NOx and
CO2 emission profiles
Methodology - Test Vehicle
• 2002 Terex CMI Trashmaster 3-90E.
• Cummins Model QSK-19, 525-hp diesel engine.
• Operated from ~ 7 AM to 5:30 PM M-F
• Average fuel use of over 200 gallons per day.
PEMS
Portable Emission Monitoring Systems
1.Increasingly more common
2.Affordable
3.Small size and ease of installation
4.Increasingly more accurate
Sampling System
• Simple, Portable, On-vehicle,

Testing (SPOT) system.
• Capable of measuring at 1Hz:
• NOx and O2 emissions
• Exhaust mass flow
• Relative humidity
• Ambient temperature
• Engine speed
• Calculated CO2
• Composed of:
• main console
• alternator sensor
• battery connections
• exhaust probe
Sampling Site
Sanitary landfill
Analysis of PEMS Data
•Autocorrelation
• Frequent successive observations tend to be positively

correlated
• Issue in PEMS generated data
•Binning Approach Frey et al. (2002) and EPA (2002 C,D)
• Driving modes are defined to segregate data
• Produces discontinuous time series to reduce
autocorrelation
• Each “bin” is analyzed separately
Analysis of PEMS Data
•Averaging Approach EPA 2002D, Rubino et al. (2007), Weiss

et al. (2011 AB),
• Can be used to “smooth” data
• It will miss peaks and valleys that may be driving emissions
• Good way to compare test cycles to field observations
RESULTS

NOx
ANALYSIS
RESULTS

FUEL
ANALYSIS
CO2
ANALYSIS
RESULTS- General Trends
Day
08/29/2005
08/30/2005
08/31/2005
09/01/2005
09/12/2005
09/13/2005
09/14/2005
09/15/2005

Fuel
type
Diesel
Diesel
Diesel
Diesel
B20
B20
ULSD
ULSD

Start
End time
time
7:07 AM 5:10 PM
7:10 AM 5:57 PM
7:08 AM 5:21 PM
7:08 AM 4:29 PM
7:07 AM 5:10 PM
7:21 AM 5:11 PM
7:22 AM 5:02 PM
7:21 AM 5:00 PM

Total
time
10:03
10:47
10:13
9:21
10:03
9:50
9:40
9:39

Total data
points
36158
38873
36738
32383
35704
32287
33441
30906
RESULTS- General Trends
RESULTS- General Trends
RESULTS- General Trends
RESULTS- General Trends
Statistical Analysis
•General Linear Model (GLM) with Engine Speed as a covariate

term. Evaluated the following questions:
1.Are there statistically significant differences in NOx and CO2
concentrations from a diesel compactor running on no. 2 diesel,
ULSD and B20 fuel types?
2.Are there statistically significant differences in NOx and CO2
concentrations due to temporal factors?
RESULTS- Tested Fuel Type factor on NOx Concentrations

Factor

DF

F

P-value

Engine
Speed

1

655115.01

0.000

Fuel Type

2

610.58

0.000

2

781.41

0.000

Fuel type*
Engine
Speed

N

276485
IV. RESULTS- Initial Partial Autocorrelation Test
RESULTS- Time to Independence Method
•Swihart, R. K., and N. A. Slade. (1985). “Testing for independence of

observations in animal movements.” Ecology 66: 1176-1184.
• Developed a procedure for determining the time interval at which
autocorrelation becomes negligible by using location data of a radiotagged adult female cotton rat
• Study showed that if a fixed interval separates successive observations
in an autocorrelated data set, the dependency can be removed by
using observations separated by several intervals
•Method was adapted to emission data and different intervals were
evaluated
•Interval of 800 seconds per observation was selected to produce quasiindependent observations
RESULTS- GLM for Reduced Data Set

Factor

N

Fuel Type
Fuel type * Engine
Speed

346

F

P-value

1

Engine Speed

DF

824.72

0.000

2

0.52

0.595

2

0.44

0.645
RESULTS- Partial Autocorrelation Test
RESULTS- Fuel Analysis
Pollutant
NOx

CO2

Factor

N

Engine Speed
Fuel Type
346
Fuel Type* Engine Speed
Engine Speed
Fuel Type
346
Fuel Type* Engine Speed

DF
1
2
2
1
2
2

PDifference
value Significant?
824.72 0.000
YES
0.52 0.595
NO
0.44 0.645
NO
1454.71 0.000
YES
0.95 0.389
NO
0.34 0.714
NO
F
RESULTS- Temporal Analysis
Pollutant
NOx

CO2

Factor
Engine Speed
Day
Day* Engine Speed
Engine Speed
Day
Day* Engine Speed

N
346

346

DF
1
7
7
1
2
2

PDifference
value Significant?
921.77 0.000
YES
0.28 0.960
NO
0.51 0.823
NO
1555.83 0.000
YES
0.38 0.914
NO
0.25 0.972
NO
F
CONCLUSIONS
1.Raise awareness about autocorrelation and spurious

statistical significance in continuous emission data
2.Development of a data handling technique to deal with
autocorrelation in continuous data
3.Finding that NOx and CO2 emissions are unaffected from
the use of ULSD and B20 fuel
QUESTIONS…

Sergio A. Guerra, PhD
Environmental Engineer
Phone: (651) 395-5225
sguerra@wenck.com
www.sergioaguerra.com

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NOVEL DATA ANALYSIS TECHNIQUE USED TO EVALUATE NOX AND CO2 CONTINUOUS EMISSIONS DATA

  • 1. NOVEL DATA ANALYSIS TECHNIQUE USED TO EVALUATE NOX AND CO2 CONTINUOUS EMISSIONS DATA AWMA 106th Annual Conference, June 27, 2013 Sergio A. Guerra - Wenck Associates, Inc. Dennis D. Lane, Norman A. Slade, Ray E. Carter, Edward Peltier, Glen Marotz University of Kansas
  • 2. BACKGROUND • Society depends heavily on diesel engines • Diesel engines are more durable and fuel efficient than gasoline ones • At full load diesel engine use ~70% of the fuel a comparable gasoline engine consumes (Lloyd et al., 2001) • Off-road diesel vehicles not well studied
  • 4. OBJECTIVES 1.Collect real-world NOx and CO2 emission profiles from an off-road diesel vehicle 2.Evaluate NOx and CO2 emission profiles for a diesel offroad vehicle running on diesel, B20 and ULSD fuels to determine potential emission reductions 3.Evaluate the effect that temporal factors exert on NOx and CO2 emission profiles
  • 5. Methodology - Test Vehicle • 2002 Terex CMI Trashmaster 3-90E. • Cummins Model QSK-19, 525-hp diesel engine. • Operated from ~ 7 AM to 5:30 PM M-F • Average fuel use of over 200 gallons per day.
  • 6. PEMS Portable Emission Monitoring Systems 1.Increasingly more common 2.Affordable 3.Small size and ease of installation 4.Increasingly more accurate
  • 7. Sampling System • Simple, Portable, On-vehicle, Testing (SPOT) system. • Capable of measuring at 1Hz: • NOx and O2 emissions • Exhaust mass flow • Relative humidity • Ambient temperature • Engine speed • Calculated CO2 • Composed of: • main console • alternator sensor • battery connections • exhaust probe
  • 9. Analysis of PEMS Data •Autocorrelation • Frequent successive observations tend to be positively correlated • Issue in PEMS generated data •Binning Approach Frey et al. (2002) and EPA (2002 C,D) • Driving modes are defined to segregate data • Produces discontinuous time series to reduce autocorrelation • Each “bin” is analyzed separately
  • 10. Analysis of PEMS Data •Averaging Approach EPA 2002D, Rubino et al. (2007), Weiss et al. (2011 AB), • Can be used to “smooth” data • It will miss peaks and valleys that may be driving emissions • Good way to compare test cycles to field observations
  • 12. RESULTS- General Trends Day 08/29/2005 08/30/2005 08/31/2005 09/01/2005 09/12/2005 09/13/2005 09/14/2005 09/15/2005 Fuel type Diesel Diesel Diesel Diesel B20 B20 ULSD ULSD Start End time time 7:07 AM 5:10 PM 7:10 AM 5:57 PM 7:08 AM 5:21 PM 7:08 AM 4:29 PM 7:07 AM 5:10 PM 7:21 AM 5:11 PM 7:22 AM 5:02 PM 7:21 AM 5:00 PM Total time 10:03 10:47 10:13 9:21 10:03 9:50 9:40 9:39 Total data points 36158 38873 36738 32383 35704 32287 33441 30906
  • 17. Statistical Analysis •General Linear Model (GLM) with Engine Speed as a covariate term. Evaluated the following questions: 1.Are there statistically significant differences in NOx and CO2 concentrations from a diesel compactor running on no. 2 diesel, ULSD and B20 fuel types? 2.Are there statistically significant differences in NOx and CO2 concentrations due to temporal factors?
  • 18. RESULTS- Tested Fuel Type factor on NOx Concentrations Factor DF F P-value Engine Speed 1 655115.01 0.000 Fuel Type 2 610.58 0.000 2 781.41 0.000 Fuel type* Engine Speed N 276485
  • 19. IV. RESULTS- Initial Partial Autocorrelation Test
  • 20. RESULTS- Time to Independence Method •Swihart, R. K., and N. A. Slade. (1985). “Testing for independence of observations in animal movements.” Ecology 66: 1176-1184. • Developed a procedure for determining the time interval at which autocorrelation becomes negligible by using location data of a radiotagged adult female cotton rat • Study showed that if a fixed interval separates successive observations in an autocorrelated data set, the dependency can be removed by using observations separated by several intervals •Method was adapted to emission data and different intervals were evaluated •Interval of 800 seconds per observation was selected to produce quasiindependent observations
  • 21. RESULTS- GLM for Reduced Data Set Factor N Fuel Type Fuel type * Engine Speed 346 F P-value 1 Engine Speed DF 824.72 0.000 2 0.52 0.595 2 0.44 0.645
  • 23. RESULTS- Fuel Analysis Pollutant NOx CO2 Factor N Engine Speed Fuel Type 346 Fuel Type* Engine Speed Engine Speed Fuel Type 346 Fuel Type* Engine Speed DF 1 2 2 1 2 2 PDifference value Significant? 824.72 0.000 YES 0.52 0.595 NO 0.44 0.645 NO 1454.71 0.000 YES 0.95 0.389 NO 0.34 0.714 NO F
  • 24. RESULTS- Temporal Analysis Pollutant NOx CO2 Factor Engine Speed Day Day* Engine Speed Engine Speed Day Day* Engine Speed N 346 346 DF 1 7 7 1 2 2 PDifference value Significant? 921.77 0.000 YES 0.28 0.960 NO 0.51 0.823 NO 1555.83 0.000 YES 0.38 0.914 NO 0.25 0.972 NO F
  • 25. CONCLUSIONS 1.Raise awareness about autocorrelation and spurious statistical significance in continuous emission data 2.Development of a data handling technique to deal with autocorrelation in continuous data 3.Finding that NOx and CO2 emissions are unaffected from the use of ULSD and B20 fuel
  • 26. QUESTIONS… Sergio A. Guerra, PhD Environmental Engineer Phone: (651) 395-5225 sguerra@wenck.com www.sergioaguerra.com