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ARTICLES
                                                                                       PUBLISHED ONLINE: 24 JULY 2011 | DOI: 10.1038/NGEO1212




Non-mare silicic volcanism on the lunar farside at
Compton–Belkovich
Bradley L. Jolliff1 *, Sandra A. Wiseman2 , Samuel J. Lawrence3 , Thanh N. Tran3 , Mark S. Robinson3 ,
Hiroyuki Sato3 , B. Ray Hawke4 , Frank Scholten5 , Jürgen Oberst5 , Harald Hiesinger6 ,
Carolyn H. van der Bogert6 , Benjamin T. Greenhagen7 , Timothy D. Glotch8 and David A. Paige9

Non-basaltic volcanism is rare on the Moon. The best known examples occur on the lunar nearside in the compositionally
evolved Procellarum KREEP terrane. However, there is an isolated thorium-rich area—the Compton–Belkovich thorium
anomaly—on the lunar farside for which the origin is enigmatic. Here we use images from the Lunar Reconnaissance Orbiter
Cameras, digital terrain models and spectral data from the Diviner lunar radiometer to assess the morphology and composition
of this region. We identify a central feature, 25 by 35 km across, that is characterized by elevated topography and relatively high
reflectance. The topography includes a series of domes that range from less than 1 km to more than 6 km across, some with
steeply sloping sides. We interpret these as volcanic domes formed from viscous lava. We also observe arcuate to irregular
circular depressions, which we suggest result from collapse associated with volcanism. We find that the volcanic feature is
also enriched in silica or alkali-feldspar, indicative of compositionally evolved, rhyolitic volcanic materials. We suggest that the
Compton–Belkovich thorium anomaly represents a rare occurrence of non-basaltic volcanism on the lunar farside. We conclude
that compositionally evolved volcanism did occur far removed from the Procellarum KREEP terrane.


                                                                              LRO imaging and topography of the CBF

T
       he Compton–Belkovich thorium anomaly (CBTA), centred
       at 61.1◦ N, 99.5◦ E, was identified as an isolated thorium             WAC images delineate the high-reflectance terrain covering an area
       ‘hotspot’ in data obtained by the Lunar Prospector gamma-              of about 25 × 35 km from 98.5◦ to 101.0◦ E and 60.7◦ to 61.6◦ N
ray spectrometer (LP–GRS; Fig. 1; refs 1–3). The site has a                   (Fig. 2a). Within the high-reflectance terrain, reflectance is 20–40%
high, focused concentration of thorium (Th) and is isolated in                higher on average than the surroundings in visible wavelengths (see
an area of Th-poor terrain on the lunar farside. It is nestled                Supplementary Information). The limited, contiguous extent of
between two ancient impact craters, Compton (162 km diameter)                 high-reflectance material indicates localization of the CBF; no large,
and Belkovich (214 km diameter). Gillis and co-workers4 , using               contiguous patches of similarly reflective material occur beyond
Clementine visible images, noted that the centre of the CBTA                  the main reflectance anomaly. A NAC-derived digital terrain model
corresponds to an area of relatively high reflectance, about 30 km            (DTM; ref. 6) shows locally elevated topography within the central
across. The elevated reflectance is readily apparent in Lunar                 region (Fig. 2c), including irregular depressions.
Reconnaissance Orbiter Camera (LROC) Wide Angle Camera                           Topographic information derived from the WAC DTM (ref. 7;
(WAC) images5 (for example, Fig. 2a). The compositional anomaly               100 m per pixel scale) and LOLA data8 show that the CBF
in LP–GRS data is asymmetric and ‘smeared’ to the east, beyond                corresponds to an area of elevated topography (Fig. 3a,b). The
the extent of the more highly reflective terrain (compare Figs 1              central part of the topographic feature rises 400–600 m above
and 2). The Th anomaly covers a greater area than the high-                   the surrounding terrain, less on the west, where the CBF abuts
reflectance terrain on which it is centred, but this results from             mountains of the Belkovich crater rim, and greater to the east
the broad spatial response function of the LP–GRS (ref. 2) and                (Fig. 3a). The local elevation is approximately 2–3 km below the
is not a true representation of the areal extent of the Compton–              global mean surface elevation of 1,737.4 km. The site occurs in low
Belkovich feature. Here, we investigate the high-reflectance feature          terrain associated with the Humboldtianum basin, just inside its
(hereafter CBF) located at the centre of the CBTA—with images                 outer ring4 . However, in this area the outer ring was obliterated
acquired by the WAC (100 m per pixel) and by the Narrow                       by Compton, Belkovich, and other large, post-Humboldtianum
Angle Cameras (NACs) (0.5 to 1.5 m per pixel), with digital                   impact events. The elevated topography (dashed outline in Fig. 2a)
terrain data derived from NAC and WAC geometric stereo                        corresponds approximately, but not exactly, to the high-reflectance
images, and with data acquired by the Diviner Lunar Radiometer                terrain. High-reflectance material extends ∼5 km to the east-
Experiment on LRO.                                                            southeast of the boundary of the CBF elevated topography.




1 Department  of Earth and Planetary Sciences and the McDonnell Center for the Space Sciences, Washington University, One Brookings Drive, St Louis,
Missouri 63130, USA, 2 Department of Geological Sciences, Brown University, Providence, Rhode Island 02912, USA, 3 School of Earth and Space
Exploration, Box 871404, Arizona State University, Tempe, Arizona 85287, USA, 4 Hawaii Institute of Geophysics and Planetology, University of Hawaii,
Honolulu, Hawaii 96822, USA, 5 German Aerospace Center (DLR), Institute of Planetary Research, Rutherfordstr. 2, D-12489 Berlin, Germany, 6 Institut für
Planetologie, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Str. 10, 48149 Muenster, Germany, 7 Jet Propulsion Laboratory, 4800 Oak
Grove Drive, M/S 183-301, Pasadena, California 91109, USA, 8 Department of Geosciences, Stony Brook University, Stony Brook, New York 11794, USA,
9 Department of Earth and Space Sciences, University of California, Los Angeles, California 90095, USA. *e-mail: blj@wustl.edu.



NATURE GEOSCIENCE | ADVANCE ONLINE PUBLICATION | www.nature.com/naturegeoscience                                                                           1
                                                        © 2011 Macmillan Publishers Limited. All rights reserved.
ARTICLES                                                                                      NATURE GEOSCIENCE DOI: 10.1038/NGEO1212

                                                                                lavas, which typically have slopes of <7◦ (ref. 10). Small domes such
                                                           N. Pole              as these are found on Earth, associated with silicic (for example,
                     70° N
                       °                                                        rhyolitic) volcanism.
                                                                                    In addition to light-toned materials, numerous scarp-bounded
     Hayn                                                                       irregular depressions occur in the CBF (Fig. 2b,d). Some of the
                             Belkovich                                          irregular depressions form arcuate patterns (for example, Fig. 2c),
                                                                                although the central depression is not circular, and impact craters
                                                                                disrupt the boundary of the depression. In the irregular-shaped,
                                                                                central depressed area of the CBF, vertical relief on some of the
                                                                                scarps bounding collapse structures is ∼50–100 m.
                                                                     Th (ppm)       Bright material extends some 7 km to the E-SE beyond the
                                                                     9          region of elevated topography. Dispersal of bright material could
            60° N
                                                                                be caused by impact cratering, and 7 km is a reasonable length scale
                                                                                for mixing from small impacts11 . Another possibility is dispersal by
                                                                     7          pyroclastic eruption. The centre of a circle that fits the outline of
 Humboldtianum                                                                  this extension of bright material would be located in the depressed
                                                                     5          area labelled ‘3’ in Fig. 2b, possibly a source vent. However, the high
                                                                                viscosity of this silicic magma may have favoured effusive eruption
                                                                                over pyroclastic eruption.
                    200 km                                           3
                                             Compton                            Possible rock types of the CBF
    50° N
                                                                     1
                                                                                Using LP–GRS FeO and Th data, we investigate possible rock
                                                                                types that may be exposed in the CBF. Taking the low-altitude,
              90° E                 100° E             110° E
                                                                                two-degree binned data, a plot of FeO versus Th for the feature
                                                                                and surrounding regions shows the anomaly extending to about
Figure 1 | Compton–Belkovich thorium anomaly. The location of the CBTA          3 ppm Th at about 5 wt.% FeO (refs 4,12; Fig. 5). The gamma-ray
is northeast of Humboldtianum basin and just beyond the Moon’s eastern          response function is broad (integrating the signal over a radius
limb (LP–GRS 0.5◦ , ∼15 km resolution Th data1,2 as deconvolved by              ∼80 km, with a full-width half-maximum of 48 km for 30-km-
Lawrence et al.3 , overlain on WAC 400 m per pixel base). The highest           altitude data2 ) such that the observed signal probably corresponds
measured Th intensity corresponds to a concentration at this resolution of      to a higher Th concentration and more focused areal extent than
∼10 ppm at the centre of the Th hotspot.                                        indicated by the first-reported data, as described by Lawrence
                                                                                and colleagues2,3 . Lawrence et al.2 modelled the CBTA as a highly
Domes and irregular depressions                                                 localized source of high-Th material and concluded that the
The elevated terrain is highest on the western and eastern flanks,              concentration of Th in the source materials at the centre of the
reaching −1,800 m elevation, about 300–400 m above the central                  CBTA could be as high as 40–55 ppm.
region (Fig. 3c, profile b–b ). In the north, at the edge of the                    In Fig. 5, the LP–GRS data project toward high Th along vectors
high-reflectance terrain and CBF topographic feature, is an isolated            pointing to the compositions of two lunar rock types that are
massif over 6 km across at its base and nearly a kilometre high from            rare in the lunar sample collection: (1) granite or its fine-grained
base to summit. Its morphology suggests that it is volcanic in origin;          equivalent, felsite (rhyolite), and (2) the more mafic alkali norite
its upper slopes range from 20 to 26◦ and it has a summit plateau               or alkali gabbro (monzogabbro). These rock types are known only
with a broad, central depression (Fig. 4).                                      as small rocks and clasts in breccia, mainly in Apollo 12, 14, and
    Just north-northeast of the CBF central depression, a north–                15 samples13–18 . A pristine granitic rock fragment from Apollo 12
south-oriented elongate rock body occurs with moderate relief                   regolith19,20 has the highest Th concentration measured so far in
(7◦ –22◦ slopes and 200 m above the base elevation, Fig. 2b). This              a lunar rock, 61 ppm, and an FeO concentration of 5 wt.%. Other
feature, 2.5 km in length and ∼2 km wide at its base, is probably               lunar granites, however, have similarly enriched Th concentrations,
also a volcanic construct (see also Fig. 4, ‘middle dome’), but                 typically in the 40–60 ppm range. The more mafic alkali-suite
smaller than the massif (‘big dome’) to the north. Small channel-               rocks also have elevated Th, but lower concentrations, for example,
like features suggest flows and erosion occurred on its west side.              10–40 ppm (refs 17,21). Alkali anorthosite could also be associated
Clusters of 1–5 m boulders are concentrated in several locations                with these rocks, but typically has lower Th concentrations (Fig. 5).
along its crest and flanks.                                                     On the basis of compositions, silica- and feldspar-rich rocks would
    In and around the central area of the irregular depression marked           contribute to the high reflectance of the anomaly, especially granite
‘1’ in Fig. 2b,c, small domes are also observed (for example, Fig. 2d).         or its extrusive equivalent, rhyolite.
A half dozen small domes occur in the central area—all with similar                 Data from the LRO Diviner Lunar Radiometer22 contribute
size (∼500 m across), but different morphologies, including some                another piece to the puzzle. The spectral signature measured by
elongate forms and some that are subtle, low-relief bulges. Most                Diviner’s three ∼8-µm channels is consistent with highly polymer-
have a prominent clustering of boulders at their summits and on                 ized mineralogy such as silica and/or alkali feldspar23,24 . Quartz and
their flanks (for example, Fig. 2e). The boulders are typically one             K-feldspar are the two main mineralogical components of lunar
to several metres in size, but some are as large as 10 m. Such                  granite, and no other common lunar minerals (olivine, pyroxene,
clustering of boulders on domes has been noted in other locations,              anorthitic plagioclase, ilmenite, spinel) would create a similar
such as the Marius Hills9 . The boulders suggest weathering of                  signature in the Diviner data. An overlay of Diviner modelled
coherent rock as the domes degraded over time, with the largest                 Christiansen feature (CF) position in the 7.1–8.6 µm region (Fig. 6),
boulders having been excavated by small impacts. In the example                 which correlates inversely with silicate polymerization, shows a
shown in Fig. 2d, the dome is ∼500 m in diameter at the base and                close correspondence between low CF modelled wavelength and the
∼100 m high. The shape of the dome and its flank slopes, ∼20◦ ,                 area of high reflectance. The CF modelled data demonstrate a better
indicate a more viscous lava composition (silicic) than expected                areal correspondence with the high-reflectance feature than with
for volcanic constructs associated with low-viscosity mare basalt               the topographic expression of the CBF. This observation supports

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                                                         © 2011 Macmillan Publishers Limited. All rights reserved.
NATURE GEOSCIENCE DOI: 10.1038/NGEO1212                                                                                               ARTICLES
a                                                                                b                                                       c
              62° N


                                                                                                           Area of e
                         Area of c

                                        Area of b

                                                                                                     1



              61° N

                                                                                                                                                          1
                                                                                                                             3


      98° E           99° E           100° E          101° E         102° E
                                                                                         Area of d



                                     15 km                                                                                                    Area of d
              60° N


d                                        e                                                  2
                                                                                                                                               2
                                                    Dome
                         Irregular
                         depression                                    Crater

      Small dome



                                                                                                                                              Elevation (m)
          2 km                                             500 m                                                                         ¬2,600¬2,400¬2,200¬2,000




Figure 2 | Geomorphology of the CBF. a, Portion of WAC image showing high-reflectance terrain. Dashed outline denotes the topographically elevated
area (Fig. 3). b, NAC mosaic showing the central region of the CBF and location of features discussed in text. Arrows indicate arcuate escarpments; double
arrow locates the elongate rock body referred to in the text and Fig. 4 as ‘middle dome.’ Numbers 1 and 2 locate corresponding areas on parts b and c, 1, 2,
and 3 correspond to irregular depressions (see text). c, Digital terrain model of the area noted in part a. d, Arcuate escarpment along the western side of
the central depression. e, Small dome.

the possibility that silicic materials may have been distributed                     intrusion, possibly of KREEP-basalt or some similarly evolved
by pyroclastic eruption beyond the boundary of the topographic                       composition, derived from melting deep in the crust, led to the local
expression of the CBF, such as along its southeastern margin.                        inflation or uplift of CBF topography, forming a low ‘dome’ some
                                                                                     30 km across and ∼1 km high. As this lava solidified, it differentiated
Origin of the CBF                                                                    to produce more silicic residual melt and Th enrichment. Effusive
Potential origins of the CBF include: (1) deposition as secondary                    eruptions produced elevated topography on the west and east sides
ejecta, either from nearby (for example, Humboldtianum or                            of the CBF, and broad, low flow features. Late eruptives produced
Belkovich), or from far to the west (for example, as ejecta from the                 domes with slopes up to 26◦ and a range of sizes. As these positive
Imbrium impact event), or (2) exposure of a near-surface, isolated,                  relief volcanic features formed, other parts of the CBF collapsed,
alkali-intrusive/extrusive complex with high Th, but relatively low                  forming irregular-shaped calderas near the CBF centre. A small
FeO, such as granite or alkali anorthosite2,4 . The CBF bears no                     amount of late pyroclastic volcanism may have spread eruptive
relationship to ejecta deposits and compositions of nearby large                     materials over a region extending to the southeast, some 7 km
craters, nor is it co-located with obvious secondary craters, so                     beyond the edge of the topographic feature.
a local impact-related origin is unlikely. Origin as an Imbrium                          The occurrence and preservation of small domes and other vol-
ejecta deposit is unlikely because the inferred composition differs                  canic constructs suggest the CBF had not yet formed during the pe-
from other Imbrium ejecta, for example, Apollo 14 high-K KREEP                       riod of heavy impact bombardment. Ejecta deposits from Belkovich
rocks21 . Moreover, the CBF and surrounding terrain lack elongation                  and Compton craters, which are Nectarian and Lower Imbrian,
or ‘sculpture’ that would indicate an Imbrium source. Although                       respectively25 , do not overprint the CBF, so the feature must post-
located just east of the Belkovich crater rim, the CBF does not appear               date formation of these craters. Crater densities on several relatively
to be related to Belkovich rim deposits. The CBF is located along                    flat areas within the CBF are conspicuously low, and preliminary
the extrapolated second ring of Humboldtianum basin; however,                        crater counts suggest extraordinarily young ages, that is, Coperni-
ring-related topography is absent in this region.                                    can; however, these apparently young surfaces need to be studied
   The data presented here are consistent with the CBF being an                      carefully to determine whether other characteristics, such as phys-
exposure of a near-surface, volcanic complex, including a central                    ical properties or specific surface characteristics, might affect small
region that may be an irregularly shaped, collapsed caldera or set                   crater densities. Nonetheless, the good state of preservation of the
of vents. Accordingly, we infer that an initial hypabyssal (shallow)                 CBF indicates that it has been little modified by impact processes.

NATURE GEOSCIENCE | ADVANCE ONLINE PUBLICATION | www.nature.com/naturegeoscience                                                                               3
                                                               © 2011 Macmillan Publishers Limited. All rights reserved.
ARTICLES                                                                                                         NATURE GEOSCIENCE DOI: 10.1038/NGEO1212

    a                                                                                                                                                              Perspective
                                                                                                                                        Big dome
                                                                                    N                                                                                    views
                                           a




              b                                                            b'
                                                                                                                                             Middle dome



                                                                                                                    2.5 km



                                           a'

                                                                                                                                                                       m
                                                                                                                                                                 600
                  ¬2,900       ¬2,600              ¬2,300     ¬2,000       ¬1,700
                                                Elevation (m)
    b         ¬1,900
              ¬2,000
              ¬2,100    a                                                                    a'
              ¬2,200
        (m)




                                                                                                                                               Little dome
              ¬2,300
              ¬2,400
              ¬2,500
              ¬2,600
                    0      2   4       6        8    10   12     14 16   18 20 22 24 26
                                                               (km)
              ¬1,700                                                                                        Elevation (m)
              ¬1,800 b                                                                             ¬2,840 ¬2,540 ¬2,240 ¬1,940 ¬1,640          500 m
                                                                                        b'
              ¬1,900
              ¬2,000
        (m)




              ¬2,100
              ¬2,200
              ¬2,300                                                                              Figure 4 | Domes in the CBF. Positive relief features in the CBF inferred to
              ¬2,400                                                                              be volcanic in origin.
                    0 2        4   6       8        10 12 14 16 18 20 22 24 26 28 30
                                                           (km)
                                                                                                  extreme fractional crystallization of a KREEP-rich magma body
Figure 3 | Topography of the CBF. a, WAC DTM (200 m per pixel, draped                             with upward enrichment of silicic late-stage residual melt, or large-
over WAC orthophoto, 100 m per pixel). b, Elevation profiles for sections                          scale gravity separation of silicic melt from a magma that reached
a–a and b–b generated from the WAC DTM.                                                           the field of silicate-liquid immiscibility during crystallization21,27,28 ,
                                                                                                  producing conjugate mafic and felsic fractions, as occurs in some
    On the basis of composition and morphologic features, we                                      terrestrial mafic intrusives, such as the Skaergaard complex29
infer that the CBF represents a shallow, KREEP-rich (or similarly                                 in western Greenland.
evolved) alkaline-silicic intrusive and volcanic complex. In the                                      Volcanism involving Th enrichment occurred in several loca-
surrounding region, there is no evidence that any of the large impact                             tions on the lunar nearside within the Procellarum KREEP terrane,
craters excavated similar rock bodies, thus the magma source must                                 for example, Hansteen Alpha30 , the Gruithuisen domes31,32 , and
have been deep in the crust, because there is no mechanism other                                  the Lassell massif24,33 , and in several isolated locations on the
than impact to heat shallow crustal rocks. It is unlikely, however,                               lunar farside, for example, the Dewar region2,34 . However, no other
that a high-viscosity silicic magma would rise through a significant                              locations on the farside have such a prominent compositional
thickness of crust. A KREEP-basalt magma, derived from a more                                     signature, felsic mineralogy, and exposure as the CBF. The CBF
mafic intrusive or from a pocket of KREEP deep in the crust,                                      is unusual because it is an example of non-mare volcanism, and
however, could have intruded to shallow depth, perhaps ponding                                    it differs in its expression at the lunar surface, that is, a broad
within the upper megaregolith layer, where extended differentiation                               area of elevated topography with a range of volcanic features,
produced late-stage, silicic residual melt that erupted to the surface.                           including irregular depressions interpreted to be collapse features,
We postulate a relatively young intrusion (post Imbrium and per-                                  small domes that can only be seen for the first time in the LROC
haps much younger) and a deep source, because old, large impacts                                  NAC images, intermediate-sized domical volcanic features, and
in the region, ranging from nearby 40 to 50 km diameter craters, to                               large volcanic constructs, the size of which approach the size of some
the large Compton and Belkovich craters, to Humboldtianum basin                                   of the Gruithuisen and Mairan domes35 .
(650 km), do not appear to have tapped into or excavated enriched                                     Further questions are raised by the occurrence of the CBF. For
target rocks of KREEP-basalt or alkali-suite affinities.                                          example, how is this feature related to other nonmare volcanic
    The CBF lies distant, about 900 km to the east, from the                                      features such as the Gruithuisen domes, and why does the CBF
Procellarum KREEP terrane26 , where compositionally evolved rocks                                 occur in such geographic isolation? Chevrel et al.31 pointed out
are more common. This relative isolation indicates that within the                                that because the Gruithuisen domes are embayed by mare basalt,
lunar crust, and even well beyond the Procellarum KREEP terrane,                                  the full expression of the volcanism that produced them could
mechanisms existed to produce compositionally and petrologically                                  be more extensive. The CBF is not embayed by mare basalts, so
evolved lithologies late in crustal magmatic history, but that such                               the full extent of volcanism there is revealed. If the CBF formed
occurrences are rare. Silicic magmas on the Moon require either                                   relatively late in lunar magmatic evolution, what was the source

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                                                                          © 2011 Macmillan Publishers Limited. All rights reserved.
NATURE GEOSCIENCE DOI: 10.1038/NGEO1212                                                                                                                                  ARTICLES
                     5.0                                                                                      Humboldtianum basin. In this regard, the CBF may be similar to
                                 Felsite/granite
                     4.5                                                                                      the Gruithuisen volcanic complex, which is located along the second
                                                   Alkali norite, gabbro                                      ring of Imbrium basin31 . Chemical fractionation in the near-surface
                     4.0
                           Alkali anorthosite                                                                 setting would then have permitted generation and further rise and
                     3.5
  Th (ppm), LP–GRS




                                                              KREEP basalt                                    extrusion of silicic magma, despite high viscosity, because it would
                     3.0                                                                                      have had only a short vertical distance to migrate.
                     2.5                                                                                         Much remains to be learned about the Compton–Belkovich
                                                                                                              volcanic complex and how it relates to other occurrences of
                     2.0
                                                                                                              nonmare volcanism on the Moon. New, high-resolution imaging,
                     1.5                                                                                      determination of morphologies, and mineralogical remote sensing,
                     1.0       Feldspathic                                                 Mare basalt
                                                                                                              which is possible with LRO and other recent mission results,
                                highlands
                     0.5                                                                                      reveal new insights to the Moon’s past history and the extent
                                                                                                              of its geologic activity and variety, and pose new questions that
                      0
                           0        3        4          5       6      7               8          9      10   could be addressed by renewed exploration of Earth’s nearest and
                                                        FeO (wt%), LP–GRS                                     geologically complex neighbour.

Figure 5 | Compositions of the CBTA and surrounding region. LP–GRS Th                                         Methods
versus FeO for the region 80◦ –120◦ E and 50◦ –65◦ N. Low altitude, 2◦                                        LROC Images were processed using the Integrated Software for Imagers
                                                                                                              and Spectrometers (ISIS) produced by the US Geological Survey
binned data1,2,8 . Vectors point to compositions of relevant lunar rock                                       (http://isis.astrogeology.usgs.gov/TechnicalInfo/index.html) and Envi for
types6,12–15,17 . The LP–GRS data in the Compton–Belkovich region are                                         post-processing display and processing of Digital Topographic Models (DTM). The
consistent with granite (rhyolite) or a mixture of granite and alkali                                         LROC WAC image of Fig. 2 is M108555211CE, 566 nm, 66◦ incidence angle, and
anorthosite, norite and/or gabbro with well-mixed feldspathic highlands                                       69◦ phase angle. The DTM in Fig. 2, part c was derived from overlap of NAC pairs
and basalt derived from nearby mare surfaces via impact processes.                                            M108569083 and M108575940. The DTM used for Fig. 4 was derived from overlap
                                                                                                              of NAC pairs M139244929 and M139238146.

                                                                                                              NAC DTMs. Procedures used to generate digital topographic models (DTMs)
   62° N                           99° E                100° E               101° E                           from NAC images are described by Tran and colleagues38 .

                                                                                                              WAC DTM. Procedures used to generate the digital topographic model (DTM)
                                    CBF high reflectance                                                      from WAC images are described by Scholten and colleagues39 .

                                                                                                              LRO Diviner Lunar Radiometer. Diviner-calibrated radiance data were binned
                                                                                                              at 64 pixels per degree and then converted to emissivity. The CF position was
                                                                                                              determined by fitting a parabola to the emissivity of the three 8-µm region
                                                                                                              channels. CF positions that occur shorter than Diviner’s 8-µm region channels’
                                                                                                              range were assigned values of 7.0 µm. For additional details, the reader is referred
                                                                                                              to Greenhagen et al.23 and Glotch and colleagues24 .

                                                                                                              Received 24 March 2011; accepted 22 June 2011; published online
    61° N                                                                                                     24 July 2011
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                                                                                       © 2011 Macmillan Publishers Limited. All rights reserved.
ARTICLES                                                                                                   NATURE GEOSCIENCE DOI: 10.1038/NGEO1212

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Non mare silicic volcanism on the lunar farside at compton–belkovich

  • 1. ARTICLES PUBLISHED ONLINE: 24 JULY 2011 | DOI: 10.1038/NGEO1212 Non-mare silicic volcanism on the lunar farside at Compton–Belkovich Bradley L. Jolliff1 *, Sandra A. Wiseman2 , Samuel J. Lawrence3 , Thanh N. Tran3 , Mark S. Robinson3 , Hiroyuki Sato3 , B. Ray Hawke4 , Frank Scholten5 , Jürgen Oberst5 , Harald Hiesinger6 , Carolyn H. van der Bogert6 , Benjamin T. Greenhagen7 , Timothy D. Glotch8 and David A. Paige9 Non-basaltic volcanism is rare on the Moon. The best known examples occur on the lunar nearside in the compositionally evolved Procellarum KREEP terrane. However, there is an isolated thorium-rich area—the Compton–Belkovich thorium anomaly—on the lunar farside for which the origin is enigmatic. Here we use images from the Lunar Reconnaissance Orbiter Cameras, digital terrain models and spectral data from the Diviner lunar radiometer to assess the morphology and composition of this region. We identify a central feature, 25 by 35 km across, that is characterized by elevated topography and relatively high reflectance. The topography includes a series of domes that range from less than 1 km to more than 6 km across, some with steeply sloping sides. We interpret these as volcanic domes formed from viscous lava. We also observe arcuate to irregular circular depressions, which we suggest result from collapse associated with volcanism. We find that the volcanic feature is also enriched in silica or alkali-feldspar, indicative of compositionally evolved, rhyolitic volcanic materials. We suggest that the Compton–Belkovich thorium anomaly represents a rare occurrence of non-basaltic volcanism on the lunar farside. We conclude that compositionally evolved volcanism did occur far removed from the Procellarum KREEP terrane. LRO imaging and topography of the CBF T he Compton–Belkovich thorium anomaly (CBTA), centred at 61.1◦ N, 99.5◦ E, was identified as an isolated thorium WAC images delineate the high-reflectance terrain covering an area ‘hotspot’ in data obtained by the Lunar Prospector gamma- of about 25 × 35 km from 98.5◦ to 101.0◦ E and 60.7◦ to 61.6◦ N ray spectrometer (LP–GRS; Fig. 1; refs 1–3). The site has a (Fig. 2a). Within the high-reflectance terrain, reflectance is 20–40% high, focused concentration of thorium (Th) and is isolated in higher on average than the surroundings in visible wavelengths (see an area of Th-poor terrain on the lunar farside. It is nestled Supplementary Information). The limited, contiguous extent of between two ancient impact craters, Compton (162 km diameter) high-reflectance material indicates localization of the CBF; no large, and Belkovich (214 km diameter). Gillis and co-workers4 , using contiguous patches of similarly reflective material occur beyond Clementine visible images, noted that the centre of the CBTA the main reflectance anomaly. A NAC-derived digital terrain model corresponds to an area of relatively high reflectance, about 30 km (DTM; ref. 6) shows locally elevated topography within the central across. The elevated reflectance is readily apparent in Lunar region (Fig. 2c), including irregular depressions. Reconnaissance Orbiter Camera (LROC) Wide Angle Camera Topographic information derived from the WAC DTM (ref. 7; (WAC) images5 (for example, Fig. 2a). The compositional anomaly 100 m per pixel scale) and LOLA data8 show that the CBF in LP–GRS data is asymmetric and ‘smeared’ to the east, beyond corresponds to an area of elevated topography (Fig. 3a,b). The the extent of the more highly reflective terrain (compare Figs 1 central part of the topographic feature rises 400–600 m above and 2). The Th anomaly covers a greater area than the high- the surrounding terrain, less on the west, where the CBF abuts reflectance terrain on which it is centred, but this results from mountains of the Belkovich crater rim, and greater to the east the broad spatial response function of the LP–GRS (ref. 2) and (Fig. 3a). The local elevation is approximately 2–3 km below the is not a true representation of the areal extent of the Compton– global mean surface elevation of 1,737.4 km. The site occurs in low Belkovich feature. Here, we investigate the high-reflectance feature terrain associated with the Humboldtianum basin, just inside its (hereafter CBF) located at the centre of the CBTA—with images outer ring4 . However, in this area the outer ring was obliterated acquired by the WAC (100 m per pixel) and by the Narrow by Compton, Belkovich, and other large, post-Humboldtianum Angle Cameras (NACs) (0.5 to 1.5 m per pixel), with digital impact events. The elevated topography (dashed outline in Fig. 2a) terrain data derived from NAC and WAC geometric stereo corresponds approximately, but not exactly, to the high-reflectance images, and with data acquired by the Diviner Lunar Radiometer terrain. High-reflectance material extends ∼5 km to the east- Experiment on LRO. southeast of the boundary of the CBF elevated topography. 1 Department of Earth and Planetary Sciences and the McDonnell Center for the Space Sciences, Washington University, One Brookings Drive, St Louis, Missouri 63130, USA, 2 Department of Geological Sciences, Brown University, Providence, Rhode Island 02912, USA, 3 School of Earth and Space Exploration, Box 871404, Arizona State University, Tempe, Arizona 85287, USA, 4 Hawaii Institute of Geophysics and Planetology, University of Hawaii, Honolulu, Hawaii 96822, USA, 5 German Aerospace Center (DLR), Institute of Planetary Research, Rutherfordstr. 2, D-12489 Berlin, Germany, 6 Institut für Planetologie, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Str. 10, 48149 Muenster, Germany, 7 Jet Propulsion Laboratory, 4800 Oak Grove Drive, M/S 183-301, Pasadena, California 91109, USA, 8 Department of Geosciences, Stony Brook University, Stony Brook, New York 11794, USA, 9 Department of Earth and Space Sciences, University of California, Los Angeles, California 90095, USA. *e-mail: blj@wustl.edu. NATURE GEOSCIENCE | ADVANCE ONLINE PUBLICATION | www.nature.com/naturegeoscience 1 © 2011 Macmillan Publishers Limited. All rights reserved.
  • 2. ARTICLES NATURE GEOSCIENCE DOI: 10.1038/NGEO1212 lavas, which typically have slopes of <7◦ (ref. 10). Small domes such N. Pole as these are found on Earth, associated with silicic (for example, 70° N ° rhyolitic) volcanism. In addition to light-toned materials, numerous scarp-bounded Hayn irregular depressions occur in the CBF (Fig. 2b,d). Some of the Belkovich irregular depressions form arcuate patterns (for example, Fig. 2c), although the central depression is not circular, and impact craters disrupt the boundary of the depression. In the irregular-shaped, central depressed area of the CBF, vertical relief on some of the scarps bounding collapse structures is ∼50–100 m. Th (ppm) Bright material extends some 7 km to the E-SE beyond the 9 region of elevated topography. Dispersal of bright material could 60° N be caused by impact cratering, and 7 km is a reasonable length scale for mixing from small impacts11 . Another possibility is dispersal by 7 pyroclastic eruption. The centre of a circle that fits the outline of Humboldtianum this extension of bright material would be located in the depressed 5 area labelled ‘3’ in Fig. 2b, possibly a source vent. However, the high viscosity of this silicic magma may have favoured effusive eruption over pyroclastic eruption. 200 km 3 Compton Possible rock types of the CBF 50° N 1 Using LP–GRS FeO and Th data, we investigate possible rock types that may be exposed in the CBF. Taking the low-altitude, 90° E 100° E 110° E two-degree binned data, a plot of FeO versus Th for the feature and surrounding regions shows the anomaly extending to about Figure 1 | Compton–Belkovich thorium anomaly. The location of the CBTA 3 ppm Th at about 5 wt.% FeO (refs 4,12; Fig. 5). The gamma-ray is northeast of Humboldtianum basin and just beyond the Moon’s eastern response function is broad (integrating the signal over a radius limb (LP–GRS 0.5◦ , ∼15 km resolution Th data1,2 as deconvolved by ∼80 km, with a full-width half-maximum of 48 km for 30-km- Lawrence et al.3 , overlain on WAC 400 m per pixel base). The highest altitude data2 ) such that the observed signal probably corresponds measured Th intensity corresponds to a concentration at this resolution of to a higher Th concentration and more focused areal extent than ∼10 ppm at the centre of the Th hotspot. indicated by the first-reported data, as described by Lawrence and colleagues2,3 . Lawrence et al.2 modelled the CBTA as a highly Domes and irregular depressions localized source of high-Th material and concluded that the The elevated terrain is highest on the western and eastern flanks, concentration of Th in the source materials at the centre of the reaching −1,800 m elevation, about 300–400 m above the central CBTA could be as high as 40–55 ppm. region (Fig. 3c, profile b–b ). In the north, at the edge of the In Fig. 5, the LP–GRS data project toward high Th along vectors high-reflectance terrain and CBF topographic feature, is an isolated pointing to the compositions of two lunar rock types that are massif over 6 km across at its base and nearly a kilometre high from rare in the lunar sample collection: (1) granite or its fine-grained base to summit. Its morphology suggests that it is volcanic in origin; equivalent, felsite (rhyolite), and (2) the more mafic alkali norite its upper slopes range from 20 to 26◦ and it has a summit plateau or alkali gabbro (monzogabbro). These rock types are known only with a broad, central depression (Fig. 4). as small rocks and clasts in breccia, mainly in Apollo 12, 14, and Just north-northeast of the CBF central depression, a north– 15 samples13–18 . A pristine granitic rock fragment from Apollo 12 south-oriented elongate rock body occurs with moderate relief regolith19,20 has the highest Th concentration measured so far in (7◦ –22◦ slopes and 200 m above the base elevation, Fig. 2b). This a lunar rock, 61 ppm, and an FeO concentration of 5 wt.%. Other feature, 2.5 km in length and ∼2 km wide at its base, is probably lunar granites, however, have similarly enriched Th concentrations, also a volcanic construct (see also Fig. 4, ‘middle dome’), but typically in the 40–60 ppm range. The more mafic alkali-suite smaller than the massif (‘big dome’) to the north. Small channel- rocks also have elevated Th, but lower concentrations, for example, like features suggest flows and erosion occurred on its west side. 10–40 ppm (refs 17,21). Alkali anorthosite could also be associated Clusters of 1–5 m boulders are concentrated in several locations with these rocks, but typically has lower Th concentrations (Fig. 5). along its crest and flanks. On the basis of compositions, silica- and feldspar-rich rocks would In and around the central area of the irregular depression marked contribute to the high reflectance of the anomaly, especially granite ‘1’ in Fig. 2b,c, small domes are also observed (for example, Fig. 2d). or its extrusive equivalent, rhyolite. A half dozen small domes occur in the central area—all with similar Data from the LRO Diviner Lunar Radiometer22 contribute size (∼500 m across), but different morphologies, including some another piece to the puzzle. The spectral signature measured by elongate forms and some that are subtle, low-relief bulges. Most Diviner’s three ∼8-µm channels is consistent with highly polymer- have a prominent clustering of boulders at their summits and on ized mineralogy such as silica and/or alkali feldspar23,24 . Quartz and their flanks (for example, Fig. 2e). The boulders are typically one K-feldspar are the two main mineralogical components of lunar to several metres in size, but some are as large as 10 m. Such granite, and no other common lunar minerals (olivine, pyroxene, clustering of boulders on domes has been noted in other locations, anorthitic plagioclase, ilmenite, spinel) would create a similar such as the Marius Hills9 . The boulders suggest weathering of signature in the Diviner data. An overlay of Diviner modelled coherent rock as the domes degraded over time, with the largest Christiansen feature (CF) position in the 7.1–8.6 µm region (Fig. 6), boulders having been excavated by small impacts. In the example which correlates inversely with silicate polymerization, shows a shown in Fig. 2d, the dome is ∼500 m in diameter at the base and close correspondence between low CF modelled wavelength and the ∼100 m high. The shape of the dome and its flank slopes, ∼20◦ , area of high reflectance. The CF modelled data demonstrate a better indicate a more viscous lava composition (silicic) than expected areal correspondence with the high-reflectance feature than with for volcanic constructs associated with low-viscosity mare basalt the topographic expression of the CBF. This observation supports 2 NATURE GEOSCIENCE | ADVANCE ONLINE PUBLICATION | www.nature.com/naturegeoscience © 2011 Macmillan Publishers Limited. All rights reserved.
  • 3. NATURE GEOSCIENCE DOI: 10.1038/NGEO1212 ARTICLES a b c 62° N Area of e Area of c Area of b 1 61° N 1 3 98° E 99° E 100° E 101° E 102° E Area of d 15 km Area of d 60° N d e 2 2 Dome Irregular depression Crater Small dome Elevation (m) 2 km 500 m ¬2,600¬2,400¬2,200¬2,000 Figure 2 | Geomorphology of the CBF. a, Portion of WAC image showing high-reflectance terrain. Dashed outline denotes the topographically elevated area (Fig. 3). b, NAC mosaic showing the central region of the CBF and location of features discussed in text. Arrows indicate arcuate escarpments; double arrow locates the elongate rock body referred to in the text and Fig. 4 as ‘middle dome.’ Numbers 1 and 2 locate corresponding areas on parts b and c, 1, 2, and 3 correspond to irregular depressions (see text). c, Digital terrain model of the area noted in part a. d, Arcuate escarpment along the western side of the central depression. e, Small dome. the possibility that silicic materials may have been distributed intrusion, possibly of KREEP-basalt or some similarly evolved by pyroclastic eruption beyond the boundary of the topographic composition, derived from melting deep in the crust, led to the local expression of the CBF, such as along its southeastern margin. inflation or uplift of CBF topography, forming a low ‘dome’ some 30 km across and ∼1 km high. As this lava solidified, it differentiated Origin of the CBF to produce more silicic residual melt and Th enrichment. Effusive Potential origins of the CBF include: (1) deposition as secondary eruptions produced elevated topography on the west and east sides ejecta, either from nearby (for example, Humboldtianum or of the CBF, and broad, low flow features. Late eruptives produced Belkovich), or from far to the west (for example, as ejecta from the domes with slopes up to 26◦ and a range of sizes. As these positive Imbrium impact event), or (2) exposure of a near-surface, isolated, relief volcanic features formed, other parts of the CBF collapsed, alkali-intrusive/extrusive complex with high Th, but relatively low forming irregular-shaped calderas near the CBF centre. A small FeO, such as granite or alkali anorthosite2,4 . The CBF bears no amount of late pyroclastic volcanism may have spread eruptive relationship to ejecta deposits and compositions of nearby large materials over a region extending to the southeast, some 7 km craters, nor is it co-located with obvious secondary craters, so beyond the edge of the topographic feature. a local impact-related origin is unlikely. Origin as an Imbrium The occurrence and preservation of small domes and other vol- ejecta deposit is unlikely because the inferred composition differs canic constructs suggest the CBF had not yet formed during the pe- from other Imbrium ejecta, for example, Apollo 14 high-K KREEP riod of heavy impact bombardment. Ejecta deposits from Belkovich rocks21 . Moreover, the CBF and surrounding terrain lack elongation and Compton craters, which are Nectarian and Lower Imbrian, or ‘sculpture’ that would indicate an Imbrium source. Although respectively25 , do not overprint the CBF, so the feature must post- located just east of the Belkovich crater rim, the CBF does not appear date formation of these craters. Crater densities on several relatively to be related to Belkovich rim deposits. The CBF is located along flat areas within the CBF are conspicuously low, and preliminary the extrapolated second ring of Humboldtianum basin; however, crater counts suggest extraordinarily young ages, that is, Coperni- ring-related topography is absent in this region. can; however, these apparently young surfaces need to be studied The data presented here are consistent with the CBF being an carefully to determine whether other characteristics, such as phys- exposure of a near-surface, volcanic complex, including a central ical properties or specific surface characteristics, might affect small region that may be an irregularly shaped, collapsed caldera or set crater densities. Nonetheless, the good state of preservation of the of vents. Accordingly, we infer that an initial hypabyssal (shallow) CBF indicates that it has been little modified by impact processes. NATURE GEOSCIENCE | ADVANCE ONLINE PUBLICATION | www.nature.com/naturegeoscience 3 © 2011 Macmillan Publishers Limited. All rights reserved.
  • 4. ARTICLES NATURE GEOSCIENCE DOI: 10.1038/NGEO1212 a Perspective Big dome N views a b b' Middle dome 2.5 km a' m 600 ¬2,900 ¬2,600 ¬2,300 ¬2,000 ¬1,700 Elevation (m) b ¬1,900 ¬2,000 ¬2,100 a a' ¬2,200 (m) Little dome ¬2,300 ¬2,400 ¬2,500 ¬2,600 0 2 4 6 8 10 12 14 16 18 20 22 24 26 (km) ¬1,700 Elevation (m) ¬1,800 b ¬2,840 ¬2,540 ¬2,240 ¬1,940 ¬1,640 500 m b' ¬1,900 ¬2,000 (m) ¬2,100 ¬2,200 ¬2,300 Figure 4 | Domes in the CBF. Positive relief features in the CBF inferred to ¬2,400 be volcanic in origin. 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 (km) extreme fractional crystallization of a KREEP-rich magma body Figure 3 | Topography of the CBF. a, WAC DTM (200 m per pixel, draped with upward enrichment of silicic late-stage residual melt, or large- over WAC orthophoto, 100 m per pixel). b, Elevation profiles for sections scale gravity separation of silicic melt from a magma that reached a–a and b–b generated from the WAC DTM. the field of silicate-liquid immiscibility during crystallization21,27,28 , producing conjugate mafic and felsic fractions, as occurs in some On the basis of composition and morphologic features, we terrestrial mafic intrusives, such as the Skaergaard complex29 infer that the CBF represents a shallow, KREEP-rich (or similarly in western Greenland. evolved) alkaline-silicic intrusive and volcanic complex. In the Volcanism involving Th enrichment occurred in several loca- surrounding region, there is no evidence that any of the large impact tions on the lunar nearside within the Procellarum KREEP terrane, craters excavated similar rock bodies, thus the magma source must for example, Hansteen Alpha30 , the Gruithuisen domes31,32 , and have been deep in the crust, because there is no mechanism other the Lassell massif24,33 , and in several isolated locations on the than impact to heat shallow crustal rocks. It is unlikely, however, lunar farside, for example, the Dewar region2,34 . However, no other that a high-viscosity silicic magma would rise through a significant locations on the farside have such a prominent compositional thickness of crust. A KREEP-basalt magma, derived from a more signature, felsic mineralogy, and exposure as the CBF. The CBF mafic intrusive or from a pocket of KREEP deep in the crust, is unusual because it is an example of non-mare volcanism, and however, could have intruded to shallow depth, perhaps ponding it differs in its expression at the lunar surface, that is, a broad within the upper megaregolith layer, where extended differentiation area of elevated topography with a range of volcanic features, produced late-stage, silicic residual melt that erupted to the surface. including irregular depressions interpreted to be collapse features, We postulate a relatively young intrusion (post Imbrium and per- small domes that can only be seen for the first time in the LROC haps much younger) and a deep source, because old, large impacts NAC images, intermediate-sized domical volcanic features, and in the region, ranging from nearby 40 to 50 km diameter craters, to large volcanic constructs, the size of which approach the size of some the large Compton and Belkovich craters, to Humboldtianum basin of the Gruithuisen and Mairan domes35 . (650 km), do not appear to have tapped into or excavated enriched Further questions are raised by the occurrence of the CBF. For target rocks of KREEP-basalt or alkali-suite affinities. example, how is this feature related to other nonmare volcanic The CBF lies distant, about 900 km to the east, from the features such as the Gruithuisen domes, and why does the CBF Procellarum KREEP terrane26 , where compositionally evolved rocks occur in such geographic isolation? Chevrel et al.31 pointed out are more common. This relative isolation indicates that within the that because the Gruithuisen domes are embayed by mare basalt, lunar crust, and even well beyond the Procellarum KREEP terrane, the full expression of the volcanism that produced them could mechanisms existed to produce compositionally and petrologically be more extensive. The CBF is not embayed by mare basalts, so evolved lithologies late in crustal magmatic history, but that such the full extent of volcanism there is revealed. If the CBF formed occurrences are rare. Silicic magmas on the Moon require either relatively late in lunar magmatic evolution, what was the source 4 NATURE GEOSCIENCE | ADVANCE ONLINE PUBLICATION | www.nature.com/naturegeoscience © 2011 Macmillan Publishers Limited. All rights reserved.
  • 5. NATURE GEOSCIENCE DOI: 10.1038/NGEO1212 ARTICLES 5.0 Humboldtianum basin. In this regard, the CBF may be similar to Felsite/granite 4.5 the Gruithuisen volcanic complex, which is located along the second Alkali norite, gabbro ring of Imbrium basin31 . Chemical fractionation in the near-surface 4.0 Alkali anorthosite setting would then have permitted generation and further rise and 3.5 Th (ppm), LP–GRS KREEP basalt extrusion of silicic magma, despite high viscosity, because it would 3.0 have had only a short vertical distance to migrate. 2.5 Much remains to be learned about the Compton–Belkovich volcanic complex and how it relates to other occurrences of 2.0 nonmare volcanism on the Moon. New, high-resolution imaging, 1.5 determination of morphologies, and mineralogical remote sensing, 1.0 Feldspathic Mare basalt which is possible with LRO and other recent mission results, highlands 0.5 reveal new insights to the Moon’s past history and the extent of its geologic activity and variety, and pose new questions that 0 0 3 4 5 6 7 8 9 10 could be addressed by renewed exploration of Earth’s nearest and FeO (wt%), LP–GRS geologically complex neighbour. Figure 5 | Compositions of the CBTA and surrounding region. LP–GRS Th Methods versus FeO for the region 80◦ –120◦ E and 50◦ –65◦ N. Low altitude, 2◦ LROC Images were processed using the Integrated Software for Imagers and Spectrometers (ISIS) produced by the US Geological Survey binned data1,2,8 . Vectors point to compositions of relevant lunar rock (http://isis.astrogeology.usgs.gov/TechnicalInfo/index.html) and Envi for types6,12–15,17 . The LP–GRS data in the Compton–Belkovich region are post-processing display and processing of Digital Topographic Models (DTM). The consistent with granite (rhyolite) or a mixture of granite and alkali LROC WAC image of Fig. 2 is M108555211CE, 566 nm, 66◦ incidence angle, and anorthosite, norite and/or gabbro with well-mixed feldspathic highlands 69◦ phase angle. The DTM in Fig. 2, part c was derived from overlap of NAC pairs and basalt derived from nearby mare surfaces via impact processes. M108569083 and M108575940. The DTM used for Fig. 4 was derived from overlap of NAC pairs M139244929 and M139238146. NAC DTMs. Procedures used to generate digital topographic models (DTMs) 62° N 99° E 100° E 101° E from NAC images are described by Tran and colleagues38 . WAC DTM. Procedures used to generate the digital topographic model (DTM) CBF high reflectance from WAC images are described by Scholten and colleagues39 . LRO Diviner Lunar Radiometer. Diviner-calibrated radiance data were binned at 64 pixels per degree and then converted to emissivity. The CF position was determined by fitting a parabola to the emissivity of the three 8-µm region channels. CF positions that occur shorter than Diviner’s 8-µm region channels’ range were assigned values of 7.0 µm. For additional details, the reader is referred to Greenhagen et al.23 and Glotch and colleagues24 . Received 24 March 2011; accepted 22 June 2011; published online 61° N 24 July 2011 References 1. Lawrence, D. J. et al. High resolution measurements of absolute thorium abundance on the lunar surface. Geophys. Res. Lett. 26, 2681–2683 (1999). 2. Lawrence, D. J. et al. Small-area thorium features on the lunar surface. J. Geophys. Res. 108, JE002050 (2003). 3. Lawrence, D. J. et al. Global spatial deconvolution of Lunar Prospector Th abundances. Geophys. Res. Lett. 34, L03201 (2007). 7.1 7.4 7.7 8.0 8.3 8.6 4. Gillis, J. J., Jolliff, B. L., Lawrence, D. J., Lawson, S. 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Global silicate mineralogy of the Moon from the NASA ESMD and SMD for support of the LRO mission. The authors thank N. Petro for Diviner lunar radiometer. Science 329, 1507–1509 (2010). comments, which led to significant improvements in the manuscript. 24. Glotch, T. D. et al. Identification of highly silicic features on the Moon. Science 329, 1510–1513 (2010). 25. Wilhelms, D. E. in The geologic history of the Moon Vol. 1348 (US Geol. Surv. Author contributions Prof. Paper, United States Government Printing Office, 1987). B.L.J. drafted the initial manuscript. S.A.W. processed WAC images and DTMs, and 26. Jolliff, B. L., Gillis, J. J., Haskin, L., Korotev, R. L. & Wieczorek, M. A. assisted with NAC image processing. S.J.L. worked with B.L.J. on the topic of lunar red Major lunar crustal terranes: Surface expressions and crust-mantle origins. spots and volcanic domes. M.S.R is the principal investigator of the LRO Cameras, was J. Geophys. 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All of the authors 29. McBirney, A. R. & Nakamura, Y. Immiscibility in late-stage magmas of the contributed to assessment and discussion of the results. Skaergaard intrusion. Carnegie Inst. Wash. Yearb. 73, 348–352 (1974). 30. Hawke, B. R. et al. Hansteen Alpha: A volcanic construct in the lunar highlands. Additional information J. Geophys. Res. 108, E002013 (2003). The authors declare no competing financial interests. Supplementary information 31. Chevrel, S. D., Pinet, P. C. & Head, J. W. III Gruithuisen domes region: A accompanies this paper on www.nature.com/naturegeoscience. Reprints and permissions candidate for an extended nonmare volcanism unit on the Moon. information is available online at http://www.nature.com/reprints. Correspondence and J. Geophys. Res. 104, 16515–16529 (1999). requests for materials should be addressed to B.L.J 6 NATURE GEOSCIENCE | ADVANCE ONLINE PUBLICATION | www.nature.com/naturegeoscience © 2011 Macmillan Publishers Limited. All rights reserved.