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Rates Of Reaction Flow Of Learning
Meaning Of Rate Of Reaction MEASUREMENT OF RATES OF REACTION: ,[object Object],reactant against time ,[object Object]
Calculate the rate of reaction at the specific time from the graph.EXPLANATION FOR THE RATE OF REACTION BASED ON COLLISION THEORY: ,[object Object]
 Concentration
 Temperature
 Catalyst     -The meaning of Collision Theory. -To explain how each factor increases
[object Object]
Experiment On Effect Of Concentration
Experiment On Effect Of Temperature
Experiment On Effect Of CatalystIs proven by
How KFC can cook Fried chicken in quickly?
Application of The Rate Of reaction In daily Activities
Observable changes in quantity that use to determine rate of reaction Meaning rate of reaction Unit for rate of reaction Avarage rate of reaction Measurement  Rate Of Reaction Rate Of reaction at specific time Factors that affect rate of reaction Rate Of Reaction
Rate  Speed =  total Distance/Total time K.L J.B
Speed= Speed= = = =     100km/h =     300km/h
Reaction Types 2 1 Chemical Bonds are made / broken  Change in oxidation states  Plasma Li +1 P+1 P+1
Chemical properties/ changes/ reactions (i.e., reactivity, combustibility).  development of a gas, formation of precipitate, and change in color). Reactivity Combustibility Gas formation  Precipitate Color change
Hydrogen-VERY reactive. Helium-Non-reactive.
The speeds of reactions are very varied ,[object Object]
The weathering of rocks is an extremely very slow reaction. weathering of rocks
The fermentation of sugar to alcohol is quite slow but you can see the carbon dioxide bubbles forming in the 'froth' in a laboratory experiment or beer making in industry!  Bubble gas
[object Object]
Combustion reactions e.g. when a fuel burns in air or oxygen, is a very fast reaction.,[object Object]
evidence of Chemical Change: development of a gas  formation of precipitate  change in color
Meaning  Of Rate Of Reactions The rate of reaction is a measurement of the change in the quantity of reactant or product against  time:  Rate Of Reaction= Change in quantity of reactant / product   Time taken Student ans: Changes of reactant or product against time (0 Mark)
Meaning Of Rate Of Reaction A rate of reaction is high if the reaction occurs fast within a short period of time.. A rate of reaction is low if the reaction occurs slowly within a long period of time.. A rate of reaction is inversely proportional to time:     Rate of reaction 	  α                  1                                                       time taken
Meaning  Of Rate Of Reactions The Higher rate of reaction the shorter time taken to complete the reaction The lower rate of reaction the longer time taken to complete reaction granule powder 5 minute  1 minute  Which is the higher rate of reaction?
CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g)
CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g)
Observable changes The change in amount of reactant / product that can be measured  : ,[object Object]
Increase  in total amount of mass / concentration of the product of reaction per unit of time
Total volume of the gas released.
Formation of precipitate.,[object Object]
Increase  in total amount of mass / concentration of the product of reaction per unit of time
Total volume of the gas released. CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) Deliverytube Conical flask burette water Must shade!
Formation of precipitate. Na2SO3+2HCl->NaCl+S+SO2+H20 PERCIPITATE stopwatch
Precipitatethe formation of insoluble ionic compounds. Does NOT dissolve in water.
Example:Study the reaction:  Between calcium carbonate and excess  1  mol dm-3 hydrochloride acid.CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g)
CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g)
Observable changes CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) stopwatch
Observable changes CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) Hydrometer
Observable changes CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) Hydrometer
Observable changes CaCO3 (s) + 2HCl (aq) -> CaCl2(aq) + H2O + CO2 (g) Displacement Of water
Remember !!! CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) ,[object Object]
Quantities of product will increases against time,[object Object]
Introduction to the Rate of Reaction A reaction between small pieces of excess calcium carbonate with 80 cm3 hydrochloric  acid 0.05M is conducted a laboratory to study the rate of reaction at interval time. The volume of gas released is recorded in the table below.
40 40 30 30 27.00cm3 37.00cm3 Volume : 37-27=10 cm3
(a) Draw an apparatus to shows how this experiment  can be conducted at laboratory. Must label the diagram!
x x
√ √
√ √
(b) Write a balance chemical equation for this reaction. CaCO3 (s) + 2HCl (aq) -> CaCl2(aq) + H2O + CO2 (g)
(c) CaCO3  + 2HCl  -> CaCl2  + H2O + CO2 CaCO3  + 2H++2Cl-  -> Ca2++2Cl-  + H2O + CO2 CaCO3  + 2H++  -> Ca2++ H2O + CO2 Remember !!! Only separate soluble salt  Don’t separate covalentand insoluble salt
(d) Carbon dioxide gas
(e) A reaction between small pieces of excess calcium carbonate with 80 cm3hydrochloric  acid 0.05M is conducted a laboratory to study the rate of reaction at interval time. Number of mole in the solution will use : MV Mol, n   = 1000 0.05(80) = 1000 = 0.004 mol
(f) CaCO3  + 2HCl  -> CaCl2  + H2O + CO2 From the chemical equation : Mole Ratios: 2 mol HCl   :  1 mol CO2 0.004 mol HCl : 0.004 mol HCl × 1 mol CO2 2 mol HCl = 0.002 mol CO2 Volume of gas Co2 at room condition = 0.002×24  0.048 dm3 =
(g) Because some of carbon dioxide gas can escape to surrounding during the experiment.
(h)
Volume of CO2, cm3 Connect  the point without using ruler! Not all the point is connected Time , s
Volume of CO2 cm3 Cannot like this graph Straight line It’s must be smooth graph Time  s
(i) Average Rate Of reaction The average rate of reaction in the first 90 seconds. = The total volume of gas released in the first 90 seconds 		Time taken 33.5÷90=0.372 cm3s-1 unit =          Not cm3 per second
i(ii) The average rate of reaction in the whole experiment. = The total volume of gas released in the whole experiment 		                Time taken 47.5÷180= 0.264cm3s-1 =
(h) Volume of gas against time y x α How to fit your scale in graph? For y: use ratio 5: 10   Check it’s enough by  5÷10=0.5 Maximum volume 47.5÷0.5=95 small boxes  How about x:? 30÷10=3 Maximum 240÷3=80small boxes
Analysis  of Data Rate of reaction at t second   = gradient AB       =  p/q cm3 s-1 Total volume of Hydrogen gas/cm3 Tangent is a line that touch just 1 point of graph in order to calculate  gradient B Tangent  p A q Cannot take directly at x t Time  (second)

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Rates of reaction

  • 1. Rates Of Reaction Flow Of Learning
  • 2.
  • 3.
  • 6. Catalyst -The meaning of Collision Theory. -To explain how each factor increases
  • 7.
  • 8. Experiment On Effect Of Concentration
  • 9. Experiment On Effect Of Temperature
  • 10. Experiment On Effect Of CatalystIs proven by
  • 11. How KFC can cook Fried chicken in quickly?
  • 12. Application of The Rate Of reaction In daily Activities
  • 13. Observable changes in quantity that use to determine rate of reaction Meaning rate of reaction Unit for rate of reaction Avarage rate of reaction Measurement Rate Of Reaction Rate Of reaction at specific time Factors that affect rate of reaction Rate Of Reaction
  • 14. Rate Speed = total Distance/Total time K.L J.B
  • 15. Speed= Speed= = = = 100km/h = 300km/h
  • 16. Reaction Types 2 1 Chemical Bonds are made / broken Change in oxidation states Plasma Li +1 P+1 P+1
  • 17. Chemical properties/ changes/ reactions (i.e., reactivity, combustibility). development of a gas, formation of precipitate, and change in color). Reactivity Combustibility Gas formation Precipitate Color change
  • 19.
  • 20. The weathering of rocks is an extremely very slow reaction. weathering of rocks
  • 21. The fermentation of sugar to alcohol is quite slow but you can see the carbon dioxide bubbles forming in the 'froth' in a laboratory experiment or beer making in industry! Bubble gas
  • 22.
  • 23.
  • 24. evidence of Chemical Change: development of a gas formation of precipitate change in color
  • 25. Meaning Of Rate Of Reactions The rate of reaction is a measurement of the change in the quantity of reactant or product against time: Rate Of Reaction= Change in quantity of reactant / product Time taken Student ans: Changes of reactant or product against time (0 Mark)
  • 26. Meaning Of Rate Of Reaction A rate of reaction is high if the reaction occurs fast within a short period of time.. A rate of reaction is low if the reaction occurs slowly within a long period of time.. A rate of reaction is inversely proportional to time: Rate of reaction α 1 time taken
  • 27. Meaning Of Rate Of Reactions The Higher rate of reaction the shorter time taken to complete the reaction The lower rate of reaction the longer time taken to complete reaction granule powder 5 minute 1 minute Which is the higher rate of reaction?
  • 28. CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g)
  • 29. CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g)
  • 30.
  • 31. Increase in total amount of mass / concentration of the product of reaction per unit of time
  • 32. Total volume of the gas released.
  • 33.
  • 34. Increase in total amount of mass / concentration of the product of reaction per unit of time
  • 35. Total volume of the gas released. CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) Deliverytube Conical flask burette water Must shade!
  • 36. Formation of precipitate. Na2SO3+2HCl->NaCl+S+SO2+H20 PERCIPITATE stopwatch
  • 37. Precipitatethe formation of insoluble ionic compounds. Does NOT dissolve in water.
  • 38. Example:Study the reaction: Between calcium carbonate and excess 1 mol dm-3 hydrochloride acid.CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g)
  • 39. CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g)
  • 40. Observable changes CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) stopwatch
  • 41. Observable changes CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) Hydrometer
  • 42. Observable changes CaCO3 (s) + 2HCl (aq) -> CaCl2 (aq) + H2O + CO2 (g) Hydrometer
  • 43. Observable changes CaCO3 (s) + 2HCl (aq) -> CaCl2(aq) + H2O + CO2 (g) Displacement Of water
  • 44.
  • 45.
  • 46. Introduction to the Rate of Reaction A reaction between small pieces of excess calcium carbonate with 80 cm3 hydrochloric acid 0.05M is conducted a laboratory to study the rate of reaction at interval time. The volume of gas released is recorded in the table below.
  • 47. 40 40 30 30 27.00cm3 37.00cm3 Volume : 37-27=10 cm3
  • 48. (a) Draw an apparatus to shows how this experiment can be conducted at laboratory. Must label the diagram!
  • 49. x x
  • 52. (b) Write a balance chemical equation for this reaction. CaCO3 (s) + 2HCl (aq) -> CaCl2(aq) + H2O + CO2 (g)
  • 53. (c) CaCO3 + 2HCl -> CaCl2 + H2O + CO2 CaCO3 + 2H++2Cl- -> Ca2++2Cl- + H2O + CO2 CaCO3 + 2H++ -> Ca2++ H2O + CO2 Remember !!! Only separate soluble salt Don’t separate covalentand insoluble salt
  • 55. (e) A reaction between small pieces of excess calcium carbonate with 80 cm3hydrochloric acid 0.05M is conducted a laboratory to study the rate of reaction at interval time. Number of mole in the solution will use : MV Mol, n = 1000 0.05(80) = 1000 = 0.004 mol
  • 56. (f) CaCO3 + 2HCl -> CaCl2 + H2O + CO2 From the chemical equation : Mole Ratios: 2 mol HCl : 1 mol CO2 0.004 mol HCl : 0.004 mol HCl × 1 mol CO2 2 mol HCl = 0.002 mol CO2 Volume of gas Co2 at room condition = 0.002×24 0.048 dm3 =
  • 57. (g) Because some of carbon dioxide gas can escape to surrounding during the experiment.
  • 58. (h)
  • 59. Volume of CO2, cm3 Connect the point without using ruler! Not all the point is connected Time , s
  • 60. Volume of CO2 cm3 Cannot like this graph Straight line It’s must be smooth graph Time s
  • 61. (i) Average Rate Of reaction The average rate of reaction in the first 90 seconds. = The total volume of gas released in the first 90 seconds Time taken 33.5÷90=0.372 cm3s-1 unit = Not cm3 per second
  • 62. i(ii) The average rate of reaction in the whole experiment. = The total volume of gas released in the whole experiment Time taken 47.5÷180= 0.264cm3s-1 =
  • 63. (h) Volume of gas against time y x α How to fit your scale in graph? For y: use ratio 5: 10 Check it’s enough by 5÷10=0.5 Maximum volume 47.5÷0.5=95 small boxes How about x:? 30÷10=3 Maximum 240÷3=80small boxes
  • 64. Analysis of Data Rate of reaction at t second = gradient AB = p/q cm3 s-1 Total volume of Hydrogen gas/cm3 Tangent is a line that touch just 1 point of graph in order to calculate gradient B Tangent p A q Cannot take directly at x t Time (second)
  • 65. Tangent Cannot touch more than 2 point because each of point have different gradient Only touch 1 point of curve
  • 67. Analysis of data Total Volume of CO2(cm3) F D E Rate of reaction at t1 = gradient AB B Rate of reaction at t2 = gradient CD C Rate of reaction at t3 = gradient EF Each of point have different gradient! A t1 t3 t2 Time (second)
  • 68. Two method to calculate tangent: Total volume of Hydrogen gas/cm3 number of small boxes ×value of 1 small unit box B Tangent Y A X Time (second)
  • 69. First Method Gradient of graph: Total volume of Hydrogen gas/cm3 m = ΔY ΔX B m = Y2-y1 y2 X2-x1 Tangent A y1 Time (second) x1 x2
  • 70. Analysis of Data Rate of reaction at t second = gradient AB = p/q cm3 s-1 Total volume of Hydrogen gas/cm3 B Tangent p A q t Time (second)
  • 71. Analysis of data Total Volume of CO2(cm3) F D E Rate of reaction at t1 = gradient AB B Rate of reaction at t2 = gradient CD C Rate of reaction at t3 = gradient EF A t1 t3 t2 Time (second)
  • 72. From the answer of question (i) (iii) and (i) (iv), make a conclusion from the calculation of this experiment. (j) Ans : Rate of reaction will decreases
  • 73. (k) Explain why does there is a difference of the rate of reaction at 30 second and 120 second. Ans: Rate of reaction at 30 second is higher because number of particles of reactant is higher than 120 second
  • 74.
  • 75.
  • 76. The temperature of acid is increased.
  • 77. A bigger conical flask is used.
  • 78. The conical flask containing acid is shaken.