8- What products would be formed from the reaction of isobutyl bromide.docx

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8. What products would be formed from the reaction of isobutyl bromide, (CH3)2CHCH2Br, with each of the following reagents? a. NaOH b. NaOCH3 c. NaCN d. KOt-Bu/tBuOH e. NaOAc (NaOOCCH3) HCCH-CH2-A H3 Solution (a) (CH 3 ) 2 CHCH 2 Br + NaOH --------> (CH 3 ) 2 CHCH 2 OH + NaBr (b) (CH 3 ) 2 CHCH 2 Br +NaOCH3 ---------> (CH 3 ) 2 CHCH 2 OCH 3 + NaBr (c) (CH 3 ) 2 CHCH 2 Br + NaCN --------> (CH 3 ) 2 CHCH 2 CN + NaBr (d) (CH 3 ) 2 CHCH 2 Br --- KOt-Bu / tBuOH --------> (CH 3 ) 2 C=CH 2 (e) (CH 3 ) 2 CHCH 2 Br --- NaOAc -----> (CH 3 ) 2 C=CH 2 .

8. What products would be formed from the reaction of isobutyl bromide, (CH3)2CHCH2Br,
with each of the following reagents? a. NaOH b. NaOCH3 c. NaCN d. KOt-Bu/tBuOH e.
NaOAc (NaOOCCH3) HCCH-CH2-A H3
Solution
(a)
(CH 3 ) 2 CHCH 2 Br + NaOH --------> (CH 3 ) 2 CHCH 2 OH + NaBr
(b)
(CH 3 ) 2 CHCH 2 Br +NaOCH3 ---------> (CH 3 ) 2 CHCH 2 OCH 3 + NaBr
(c)
(CH 3 ) 2 CHCH 2 Br + NaCN --------> (CH 3 ) 2 CHCH 2 CN + NaBr
(d)
(CH 3 ) 2 CHCH 2 Br --- KOt-Bu / tBuOH --------> (CH 3 ) 2 C=CH 2
(e)
(CH 3 ) 2 CHCH 2 Br --- NaOAc -----> (CH 3 ) 2 C=CH 2

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Mehran University Newsletter Vol-X, Issue-I, 2024

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8- What products would be formed from the reaction of isobutyl bromide.docx

1. 8. What products would be formed from the reaction of isobutyl bromide, (CH3)2CHCH2Br, with each of the following reagents? a. NaOH b. NaOCH3 c. NaCN d. KOt-Bu/tBuOH e. NaOAc (NaOOCCH3) HCCH-CH2-A H3 Solution (a) (CH 3 ) 2 CHCH 2 Br + NaOH --------> (CH 3 ) 2 CHCH 2 OH + NaBr (b) (CH 3 ) 2 CHCH 2 Br +NaOCH3 ---------> (CH 3 ) 2 CHCH 2 OCH 3 + NaBr (c) (CH 3 ) 2 CHCH 2 Br + NaCN --------> (CH 3 ) 2 CHCH 2 CN + NaBr (d) (CH 3 ) 2 CHCH 2 Br --- KOt-Bu / tBuOH --------> (CH 3 ) 2 C=CH 2 (e) (CH 3 ) 2 CHCH 2 Br --- NaOAc -----> (CH 3 ) 2 C=CH 2