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NSSR Paris 7/10/2016 - 1
www.phosphorusplatform.eu
Status of struvite production and regulation in Europe
Chris Thornton - European Sustainable Phosphorous Platform
• info@phosphorusplatform.eu
• www.phosphorusplatform.eu @phosphorusfacts
NSSR Paris 7/10/2016 - 2
www.phosphorusplatform.eu
Phosphorus recovery as struvite
• Mature technology
• Recovers phosphorus P
(and some nitrogen N) from solution
 as struvite
 requires liquor rich in soluble P
• Struvite = magnesium ammonium phosphate
 can be used directly as a fertiliser
 or blended with N, K, micro-nutrients
for specific crops
 or processed (micro-granulation)
for specific delivery to plant
Unitika, Japan, 1990s
NSSR Paris 7/10/2016 - 3
www.phosphorusplatform.eu
Drivers
• Prevent nuisance deposits, abrasion
• Improves sludge dewatering
• Improves biological P-removal
(avoid return of P from dewatering)
• Sale as fertiliser
 Waternet Amsterdam: 900 t struvite/y = 400 K€ savings*
 Thames Water UK: 150 t struvite = 200 KUK£/y savings, 37 K£/y struvite sales*
 Berlin Wasser = 720 t struvite/y = 300 K€/y savings
 Severn Trent UK = 165 KUK£/y savings
 Aurhus – Suez– operating savings = c. 2x struvite sales income. ROI = 6 years
(* in SCOPE Newsletters n°99, 101, 115, 121 on www.phosphorusplatform.eu )
Severn Trent Water
NSSR Paris 7/10/2016 - 4
www.phosphorusplatform.eu
Value as fertiliser
• Not water soluble
• Releases nutrients as plants need them
• Does not burn roots
• Over 50 published pot trials, field tests, with different crops
show fertiliser effectiveness*
• TIMAC (NL)* develops as ultra-localised maize starter fertiliser
• Relatively small production tonnages and green image: often
niche marketing, e.g. sports fields, municipal parks …
(* in SCOPE Newsletters n°43, 121 on www.phosphorusplatform.eu )
NSSR Paris 7/10/2016 - 5
www.phosphorusplatform.eu
State of implementation
• Municipal waste water
- only from sewage works
operating biological P-removal
with anaerobic sludge digestion (tendency : ↑)
- c. 15 plants operational or under construction
• Food industry - several plants
• Animal manure
- technically feasible, several R&D pilots
- to date farmers not willing to pay for manure treatment
- pressure to respect regulations : ↑
NuReSys: struvite from
potato processing, dairy food industry,
pharmaceuticals industry (since 2006)
NSSR Paris 7/10/2016 - 6
www.phosphorusplatform.eu
Aquafin Leuven BE, Braunschweig D NuReSys
Berliner Wasserbetriebe D, Neuwerk D, Echten NL,Amsterdam
WEST NL, Uelzen D, Salzgitter D, Wolfsburg D
Airprex
Thames Water Slough GB,Amersfoort NL, Appeldoorn NL, Canal
Isabel II Madrid ES
(+ c. 15 sewage works in USA & Canada)
Ostara (Pearl /
CrystalGreen)
Calahorra ES PhorWater/DAM
Oldburgen D, Severn Trent Stoke GB, Tilburg NL Phospaq
Castres F Naskeo
Helsingborg DK Veolia (Struvia)
Aarhus DK, Herning DK Suez (Phosgreen)
Offenburg Stuttgart process
Struvite installations
full scale in municipal sewage works,operating or underway
NSSR Paris 7/10/2016 - 7
www.phosphorusplatform.eu
Struvite installations - currently in operation or underway
https://de.batchgeo.com/map/f4c921a4573967d7e18aa0e651cc3264
NSSR Paris 7/10/2016 - 8
www.phosphorusplatform.eu
Documents ?
Germany Authorised ?
Sold as ‘partially solubilised
rock phosphate’?
NL Authorised by law 29/3/16 Online*
Flanders Authorised by Ministry letter Online*
Denmark Authorised by Ministry letter Online*
UK Authorised No documents to date
France NOT authorised
Spain NOT authorised
USA Federal? States? No documents to date
Canada Federal? States? No documents to date
* See www.phosphorusplatform.eu/regulatory
Regulatory status of struvite as fertiliser
NSSR Paris 7/10/2016 - 9
www.phosphorusplatform.eu
Regulatory status of struvite as fertiliser:
Questions:
-“Mutual recognition”
If struvite is authorised as a fertiliser in one Member State,(MS)
then another should recognise this as applicable on their territory also
- but does this apply to the “chemical struvite” ? Only to a specific company’s
(authorised) product ?
- End-of-Waste:
Authorisation as fertiliser does not necessarily mean End-of-Waste
- End-of-Waste seems to function differently in different MS: some require a national
procedure,some accept company self-declaration
NSSR Paris 7/10/2016 - 10
www.phosphorusplatform.eu
Status at EU level
• EU Fertilisers Regulation (EUFR)
- currently in discussion
in Council & Parliament
- struvite is NOT included
• STRUBIAS process (struvite, biochars, ashes)
- mandate from DG GROW to JRC – launched July 2016
- impact assessment / criteria proposal
- (should) propose criteria for struvite
to add into the revised EUFR
as ‘CMC’ (component material category)
Waternet NL (AirPrex)
NSSR Paris 7/10/2016 - 11
www.phosphorusplatform.eu
Challenges
• EU Fertilisers Regulation (EUFR)
- proposed amendments to contaminant limits
- political acceptance of struvite from municipal sewage
- sewage excluded from compost, digestates in EUFR
-“risk” (perceived or real) of pathogens, pharmaceuticals
- traceability?
• NL Government
- currently also discussing limits on pathogens, pharmaceuticals
• STRUBIAS process
- need to input data for Impact Assessment: market potential
- data on contaminants, pathogens and pharmaceuticals
Ostara
NSSR Paris 7/10/2016 - 12
www.phosphorusplatform.eu
Challenges
• Standards
- dry matter (crystal water loss 56C)
- US AFPC n2 “free water”
- ISO/AWI 19745 under development?
- plant nutrient availability
- organics / organic carbon?
- contaminants?
• Quality protocols
- what “is” struvite ?
- beyond EU Fertiliser Regulation requirements
- REACH Substance Identity ?
- marketing / user confidence
Naskeo, Castres,
France
NSSR Paris 7/10/2016 - 13
www.phosphorusplatform.eu
Challenges: REACH
• Art 2(7)d 1) of REACH:
a “recovered substance” only needs to be registered once. That is,
after one producer has registered then others producers do not
need to register
• Important to facilitate recycling
• Applicable to recovered struvite: letter from DG GROW to ESPP
7/12/2015 published at www.phosphorusplatform.eu/regulatory
• Struvite registered by Berlin Wasser (Lead Registrant), Aarhus
Vand Denmark and by Hoogheemraadschap Amstel
NSSR Paris 7/10/2016 - 14
www.phosphorusplatform.eu
Challenges: REACH
• Current REACH dossier is incomplete, out of date
- endpoints not conform to updated ECHA Guidance
- no test data for skin irritation/corrosion, eye
irritation/corrosion, acute oral toxicity are (read-across used but
known to be not applicable for inorganic phosphates)
- new study data available should be added
- Substance Identity missing “boundary conditions”
• But Art 2(7)d means there is no cost-sharing obligation
- so how to organise this ?
NSSR Paris 7/10/2016 - 15
www.phosphorusplatform.eu
ESPP: a coalition for action
• Bring together industry, R&D, public authorities, stakeholders
water & waste industries, mineral and organic fertilisers,
chemicals, P-recycling products and processes …
• Share vision for sustainable phosphorus in Europe
• Dialogue & network expertise and experience
• Build awareness
• Assess and propose policy & regulatory developments
• Disseminate innovation, business cases, value chains
Membership is open to companies,governments, regions,knowledge centres,NGOs …
www.phosphorusplatform.eu/BecomeAMember
NSSR Paris 7/10/2016 - 16
www.phosphorusplatform.eu
Status of struvite production and regulation in Europe
Chris Thornton - European Sustainable Phosphorous Platform
• info@phosphorusplatform.eu
• www.phosphorusplatform.eu @phosphorusfacts

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Status of struvite production and regulation in Europe - North Sea Resources Roundabout (NSSR) meeting 07-10-2016

  • 1. NSSR Paris 7/10/2016 - 1 www.phosphorusplatform.eu Status of struvite production and regulation in Europe Chris Thornton - European Sustainable Phosphorous Platform • info@phosphorusplatform.eu • www.phosphorusplatform.eu @phosphorusfacts
  • 2. NSSR Paris 7/10/2016 - 2 www.phosphorusplatform.eu Phosphorus recovery as struvite • Mature technology • Recovers phosphorus P (and some nitrogen N) from solution  as struvite  requires liquor rich in soluble P • Struvite = magnesium ammonium phosphate  can be used directly as a fertiliser  or blended with N, K, micro-nutrients for specific crops  or processed (micro-granulation) for specific delivery to plant Unitika, Japan, 1990s
  • 3. NSSR Paris 7/10/2016 - 3 www.phosphorusplatform.eu Drivers • Prevent nuisance deposits, abrasion • Improves sludge dewatering • Improves biological P-removal (avoid return of P from dewatering) • Sale as fertiliser  Waternet Amsterdam: 900 t struvite/y = 400 K€ savings*  Thames Water UK: 150 t struvite = 200 KUK£/y savings, 37 K£/y struvite sales*  Berlin Wasser = 720 t struvite/y = 300 K€/y savings  Severn Trent UK = 165 KUK£/y savings  Aurhus – Suez– operating savings = c. 2x struvite sales income. ROI = 6 years (* in SCOPE Newsletters n°99, 101, 115, 121 on www.phosphorusplatform.eu ) Severn Trent Water
  • 4. NSSR Paris 7/10/2016 - 4 www.phosphorusplatform.eu Value as fertiliser • Not water soluble • Releases nutrients as plants need them • Does not burn roots • Over 50 published pot trials, field tests, with different crops show fertiliser effectiveness* • TIMAC (NL)* develops as ultra-localised maize starter fertiliser • Relatively small production tonnages and green image: often niche marketing, e.g. sports fields, municipal parks … (* in SCOPE Newsletters n°43, 121 on www.phosphorusplatform.eu )
  • 5. NSSR Paris 7/10/2016 - 5 www.phosphorusplatform.eu State of implementation • Municipal waste water - only from sewage works operating biological P-removal with anaerobic sludge digestion (tendency : ↑) - c. 15 plants operational or under construction • Food industry - several plants • Animal manure - technically feasible, several R&D pilots - to date farmers not willing to pay for manure treatment - pressure to respect regulations : ↑ NuReSys: struvite from potato processing, dairy food industry, pharmaceuticals industry (since 2006)
  • 6. NSSR Paris 7/10/2016 - 6 www.phosphorusplatform.eu Aquafin Leuven BE, Braunschweig D NuReSys Berliner Wasserbetriebe D, Neuwerk D, Echten NL,Amsterdam WEST NL, Uelzen D, Salzgitter D, Wolfsburg D Airprex Thames Water Slough GB,Amersfoort NL, Appeldoorn NL, Canal Isabel II Madrid ES (+ c. 15 sewage works in USA & Canada) Ostara (Pearl / CrystalGreen) Calahorra ES PhorWater/DAM Oldburgen D, Severn Trent Stoke GB, Tilburg NL Phospaq Castres F Naskeo Helsingborg DK Veolia (Struvia) Aarhus DK, Herning DK Suez (Phosgreen) Offenburg Stuttgart process Struvite installations full scale in municipal sewage works,operating or underway
  • 7. NSSR Paris 7/10/2016 - 7 www.phosphorusplatform.eu Struvite installations - currently in operation or underway https://de.batchgeo.com/map/f4c921a4573967d7e18aa0e651cc3264
  • 8. NSSR Paris 7/10/2016 - 8 www.phosphorusplatform.eu Documents ? Germany Authorised ? Sold as ‘partially solubilised rock phosphate’? NL Authorised by law 29/3/16 Online* Flanders Authorised by Ministry letter Online* Denmark Authorised by Ministry letter Online* UK Authorised No documents to date France NOT authorised Spain NOT authorised USA Federal? States? No documents to date Canada Federal? States? No documents to date * See www.phosphorusplatform.eu/regulatory Regulatory status of struvite as fertiliser
  • 9. NSSR Paris 7/10/2016 - 9 www.phosphorusplatform.eu Regulatory status of struvite as fertiliser: Questions: -“Mutual recognition” If struvite is authorised as a fertiliser in one Member State,(MS) then another should recognise this as applicable on their territory also - but does this apply to the “chemical struvite” ? Only to a specific company’s (authorised) product ? - End-of-Waste: Authorisation as fertiliser does not necessarily mean End-of-Waste - End-of-Waste seems to function differently in different MS: some require a national procedure,some accept company self-declaration
  • 10. NSSR Paris 7/10/2016 - 10 www.phosphorusplatform.eu Status at EU level • EU Fertilisers Regulation (EUFR) - currently in discussion in Council & Parliament - struvite is NOT included • STRUBIAS process (struvite, biochars, ashes) - mandate from DG GROW to JRC – launched July 2016 - impact assessment / criteria proposal - (should) propose criteria for struvite to add into the revised EUFR as ‘CMC’ (component material category) Waternet NL (AirPrex)
  • 11. NSSR Paris 7/10/2016 - 11 www.phosphorusplatform.eu Challenges • EU Fertilisers Regulation (EUFR) - proposed amendments to contaminant limits - political acceptance of struvite from municipal sewage - sewage excluded from compost, digestates in EUFR -“risk” (perceived or real) of pathogens, pharmaceuticals - traceability? • NL Government - currently also discussing limits on pathogens, pharmaceuticals • STRUBIAS process - need to input data for Impact Assessment: market potential - data on contaminants, pathogens and pharmaceuticals Ostara
  • 12. NSSR Paris 7/10/2016 - 12 www.phosphorusplatform.eu Challenges • Standards - dry matter (crystal water loss 56C) - US AFPC n2 “free water” - ISO/AWI 19745 under development? - plant nutrient availability - organics / organic carbon? - contaminants? • Quality protocols - what “is” struvite ? - beyond EU Fertiliser Regulation requirements - REACH Substance Identity ? - marketing / user confidence Naskeo, Castres, France
  • 13. NSSR Paris 7/10/2016 - 13 www.phosphorusplatform.eu Challenges: REACH • Art 2(7)d 1) of REACH: a “recovered substance” only needs to be registered once. That is, after one producer has registered then others producers do not need to register • Important to facilitate recycling • Applicable to recovered struvite: letter from DG GROW to ESPP 7/12/2015 published at www.phosphorusplatform.eu/regulatory • Struvite registered by Berlin Wasser (Lead Registrant), Aarhus Vand Denmark and by Hoogheemraadschap Amstel
  • 14. NSSR Paris 7/10/2016 - 14 www.phosphorusplatform.eu Challenges: REACH • Current REACH dossier is incomplete, out of date - endpoints not conform to updated ECHA Guidance - no test data for skin irritation/corrosion, eye irritation/corrosion, acute oral toxicity are (read-across used but known to be not applicable for inorganic phosphates) - new study data available should be added - Substance Identity missing “boundary conditions” • But Art 2(7)d means there is no cost-sharing obligation - so how to organise this ?
  • 15. NSSR Paris 7/10/2016 - 15 www.phosphorusplatform.eu ESPP: a coalition for action • Bring together industry, R&D, public authorities, stakeholders water & waste industries, mineral and organic fertilisers, chemicals, P-recycling products and processes … • Share vision for sustainable phosphorus in Europe • Dialogue & network expertise and experience • Build awareness • Assess and propose policy & regulatory developments • Disseminate innovation, business cases, value chains Membership is open to companies,governments, regions,knowledge centres,NGOs … www.phosphorusplatform.eu/BecomeAMember
  • 16. NSSR Paris 7/10/2016 - 16 www.phosphorusplatform.eu Status of struvite production and regulation in Europe Chris Thornton - European Sustainable Phosphorous Platform • info@phosphorusplatform.eu • www.phosphorusplatform.eu @phosphorusfacts