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 A simplified approach to chemical
 health risk assessments
 Developed by the British Health and
 Safety Executive
 Originally intended to be used by
 small businesses with limited access
 to expertise
No longer available to
purchase as hard copy.

Assessments have to be
carried out using website
http://www.hse.gov.uk/coshh/essentials/index.htm
Control sheets are also
available on a wide range
of common industrial
processes at
http://www.hse.gov.uk/pu
bns/guidance/index.htm
Specific control sheets are
also available for a wide range
of common industrial
processes at
http://www.hse.gov.uk/pubns
/guidance/index.htm
The International Labor
Organisation (ILO) has
adopted COSHH
Essentials as the basis
of their “International
Chemical Control
Toolkit”
http://www.ilo.org/legacy/english/protection/safework/ctrl_banding/toolkit/icct/index.htm
1. Assign hazard group



     2. How much is used?



3. Determine dustiness / volatility



   4. Identify control approach



5. Find appropriate control sheets
1. Assign Hazard Group
Hazard group (A to E) depends on
“R phrases” assigned by supplier
and provided on the label and
safety data sheet
Group “A” represents low hazard

Group “E” for most serious hazards
Additional Group “S” for substances
that present a skin hazard
A               B           C              D                   E                S
R36             R20         R23            R26                 R40 Muta cat 3   R21
R36/38          R20/21      R23/24         R26/27              R42              R24
R38             R20/21/22   R23/24/25      R26/27/28           R42/43           R27
R65             R21,        R23/25         R26/28              R45              R34
R66             R21/22      R24            R27                 R46              R35
R67             R22         R24/25         R27/28              R49              R36
All dusts and               R25            R28                                  R36/37
vapours not                 R34            R40 Carc. Cat. 3,                    R36/37/38
allocated to                R35            R48/23                               R36/38
another band                R36/37         R48/23/24                            R38
                            R36/37/38      R48/23/24/25                         R41
                            R37            R48/23/25                            R42
                            R37/38         R48/24                               R42/43
                            R41,           R48/24/25                            R43
                            R43,           R48/25                               R48/21
                            R48/20         R60,                                 R48/21/22
                            R48/20/21      R61,                                 R48/22
                            R48/20/21/22   R62,                                 R48/23
                            R48/20/22      R63,                                 R48/24
                            R48/21         R64                                  R48/24/25
                            R48/21/22                                           R48/25
                            R48/22                                              R66
1. Assign Hazard Group


2. How much is used?
How much is used?

         Solids      Liquids
Small    Grams       millilitres
Medium   Kilograms   litres
Large    Tonnes      Cubic metres
1. Assign Hazard Group


      2. How much is used?


3. Determine dustiness / volatility
Solids – How dusty?
Low      Pellet-like solids that don't break up.
         Little dust visible during use

Medium   Crystalline, granular solids.
         When used, dust is seen but settles out
         quickly

High     Fine, light powders.
         When used dust clouds remain in air for
         some time
Liquids – How volatile?




                          Source: ILO toolkit
1. Assign Hazard Group


      2. How much is used?


3. Determine dustiness / volatility


   4. Identify control approach
Control Approach




                   Source: ILO toolkit
1. Assign Hazard Group


      2. How much is used?


3. Determine dustiness / volatility


   4. Identify control approach


5. Find appropriate control sheets
Difficult to obtain other
than by undertaking an
assessment using the
website
ILO Task Specific Control Guidance Sheet




                                           Source: ILO toolkit
ILO Task Specific Control Guidance Sheet




                                           Source: ILO
                                           toolkit
ILO Task Specific Control Guidance Sheet




                                      Source: ILO toolkit
1. Assign Hazard Group


      2. How much is used?


3. Determine dustiness / volatility


   4. Identify control approach


5. Find appropriate control sheets
Scenario 1 – Making up slurry from
cerium oxide powder
Scenario 1 – Making up slurry from
cerium oxide powder


                 A few kilograms of
                 powder weighed
                 out about 6 times
                 per day
Scenario 1 – Making up slurry from
cerium oxide powder


                 Added to water
                 and mixed to form
                 slurry which is used
                 to polish glass
Cerium oxide powder
 Not classified as hazardous
 Fine, dusty powder
A               B           C              D                   E                S
R36             R20         R23            R26                 R40 Muta cat 3   R21
R36/38          R20/21      R23/24         R26/27              R42              R24
R38             R20/21/22   R23/24/25      R26/27/28           R42/43           R27
R65             R21,        R23/25         R26/28              R45              R34
R66             R21/22      R24            R27                 R46              R35
R67             R22         R24/25         R27/28              R49              R36
All dusts and               R25            R28                                  R36/37
vapours not                 R34            R40 Carc. Cat. 3,                    R36/37/38
allocated to                R35            R48/23                               R36/38
another band                R36/37         R48/23/24                            R38
                            R36/37/38      R48/23/24/25                         R41
                            R37            R48/23/25                            R42
                            R37/38         R48/24                               R42/43
                            R41,           R48/24/25                            R43
                            R43,           R48/25                               R48/21
                            R48/20         R60,                                 R48/21/22
                            R48/20/21      R61,                                 R48/22
                            R48/20/21/22   R62,                                 R48/23
                            R48/20/22      R63,                                 R48/24
                            R48/21         R64                                  R48/24/25
                            R48/21/22                                           R48/25
                            R48/22                                              R66
A               B           C              D                   E                S
R36             R20         R23            R26                 R40 Muta cat 3   R21
R36/38          R20/21      R23/24         R26/27              R42              R24
R38             R20/21/22   R23/24/25      R26/27/28           R42/43           R27
R65             R21,        R23/25         R26/28              R45              R34
R66             R21/22      R24            R27                 R46              R35
R67             R22         R24/25         R27/28              R49              R36
All dusts and               R25            R28                                  R36/37
vapours not                 R34            R40 Carc. Cat. 3,                    R36/37/38
allocated to                R35            R48/23                               R36/38
another band                R36/37         R48/23/24                            R38
                            R36/37/38      R48/23/24/25                         R41
                            R37            R48/23/25                            R42
                            R37/38         R48/24                               R42/43
                            R41,           R48/24/25                            R43
                            R43,           R48/25                               R48/21
                            R48/20         R60,                                 R48/21/22
                            R48/20/21      R61,                                 R48/22
                            R48/20/21/22   R62,                                 R48/23
                            R48/20/22      R63,                                 R48/24
                            R48/21         R64                                  R48/24/25
                            R48/21/22                                           R48/25
                            R48/22                                              R66
How much is used?

         Solids      Liquids
Small    Grams       millilitres
Medium   Kilograms   litres
Large    Tonnes      Cubic metres
How much is used?

         Solids      Liquids
Small    Grams       millilitres
Medium   Kilograms   litres
Large    Tonnes      Cubic metres
Solids – How dusty?
Low      Pellet-like solids that don't break up.
         Little dust visible during use

Medium   Crystalline, granular solids.
         When used, dust is seen but settles out
         quickly

High     Fine, light powders.
         When used dust clouds remain in air for
         some time
Solids – How dusty?
Low      Pellet-like solids that don't break up.
         Little dust visible during use

Medium   Crystalline, granular solids.
         When used, dust is seen but settles out
         quickly

High     Fine, light powders.
         When used dust clouds remain in air for
         some time
Stage 4 – Control Approach




                             Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Scenario 2
Cleaning rollers with
n-butyl acetate
 Sponge soaked in n-butyl acetate used to
  clean screen printing rollers
 Applied manually
 Operation takes approx. 15 minutes
 Done about 4 times per day
n-butyl acetate
 Boiling Point: 124 -128°C
 R11 - Highly flammable
 R36 - Irritating to eyes
 R37 - Irritating to respiratory system
A               B           C              D                   E                S
R36             R20         R23            R26                 R40 Muta cat 3   R21
R36/38          R20/21      R23/24         R26/27              R42              R24
R38             R20/21/22   R23/24/25      R26/27/28           R42/43           R27
R65             R21,        R23/25         R26/28              R45              R34
R66             R21/22      R24            R27                 R46              R35
R67             R22         R24/25         R27/28              R49              R36
All dusts and               R25            R28                                  R36/37
vapours not                 R34            R40 Carc. Cat. 3,                    R36/37/38
allocated to                R35            R48/23                               R36/38
another band                R36/37         R48/23/24                            R38
                            R36/37/38      R48/23/24/25                         R41
                            R37            R48/23/25                            R42
                            R37/38         R48/24                               R42/43
                            R41,           R48/24/25                            R43
                            R43,           R48/25                               R48/21
                            R48/20         R60,                                 R48/21/22
                            R48/20/21      R61,                                 R48/22
                            R48/20/21/22   R62,                                 R48/23
                            R48/20/22      R63,                                 R48/24
                            R48/21         R64                                  R48/24/25
                            R48/21/22                                           R48/25
                            R48/22                                              R66
A               B           C              D                   E                S
R36             R20         R23            R26                 R40 Muta cat 3   R21
R36/38          R20/21      R23/24         R26/27              R42              R24
R38             R20/21/22   R23/24/25      R26/27/28           R42/43           R27
R65             R21,        R23/25         R26/28              R45              R34
R66             R21/22      R24            R27                 R46              R35
R67             R22         R24/25         R27/28              R49              R36
All dusts and               R25            R28                                  R36/37
vapours not                 R34            R40 Carc. Cat. 3,                    R36/37/38
allocated to                R35            R48/23                               R36/38
another band                R36/37         R48/23/24                            R38
                            R36/37/38      R48/23/24/25                         R41
                            R37            R48/23/25                            R42
                            R37/38         R48/24                               R42/43
                            R41,           R48/24/25                            R43
                            R43,           R48/25                               R48/21
                            R48/20         R60,                                 R48/21/22
                            R48/20/21      R61,                                 R48/22
                            R48/20/21/22   R62,                                 R48/23
                            R48/20/22      R63,                                 R48/24
                            R48/21         R64                                  R48/24/25
                            R48/21/22                                           R48/25
                            R48/22                                              R66
A               B           C              D                   E                S
R36             R20         R23            R26                 R40 Muta cat 3   R21
R36/38          R20/21      R23/24         R26/27              R42              R24
R38             R20/21/22   R23/24/25      R26/27/28           R42/43           R27
R65             R21,        R23/25         R26/28              R45              R34
R66             R21/22      R24            R27                 R46              R35
R67             R22         R24/25         R27/28              R49              R36
All dusts and               R25            R28                                  R36/37
vapours not                 R34            R40 Carc. Cat. 3,                    R36/37/38
allocated to                R35            R48/23                               R36/38
another band                R36/37         R48/23/24                            R38
                            R36/37/38      R48/23/24/25                         R41
                            R37            R48/23/25                            R42
                            R37/38         R48/24                               R42/43
                            R41,           R48/24/25                            R43
                            R43,           R48/25                               R48/21
                            R48/20         R60,                                 R48/21/22
                            R48/20/21      R61,                                 R48/22
                            R48/20/21/22   R62,                                 R48/23
                            R48/20/22      R63,                                 R48/24
                            R48/21         R64                                  R48/24/25
                            R48/21/22                                           R48/25
                            R48/22                                              R66
How much is used?

         Solids      Liquids
Small    Grams       millilitres
Medium   Kilograms   litres
Large    Tonnes      Cubic metres
Solids      Liquids
Small    Grams       millilitres
Medium   Kilograms   litres
Large    Tonnes      Cubic metres
Liquids – How volatile?




                          Source: ILO toolkit
Liquids – How volatile?




                          Boiling Point: 124 - 128°C


                           Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Stage 4 – Control Approach




                             Source: ILO toolkit
Mike Slater, Diamond Environmental Ltd. (occhygiene@btconnect.com)




     This presentation is distributed under the Creative Commons
                Attribution-NonCommercial-ShareAlike
                        UK:International Licence

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COSHH essentials

  • 1.
  • 2.  A simplified approach to chemical health risk assessments
  • 3.  Developed by the British Health and Safety Executive
  • 4.  Originally intended to be used by small businesses with limited access to expertise
  • 5.
  • 6. No longer available to purchase as hard copy. Assessments have to be carried out using website
  • 8. Control sheets are also available on a wide range of common industrial processes at http://www.hse.gov.uk/pu bns/guidance/index.htm
  • 9. Specific control sheets are also available for a wide range of common industrial processes at http://www.hse.gov.uk/pubns /guidance/index.htm
  • 10. The International Labor Organisation (ILO) has adopted COSHH Essentials as the basis of their “International Chemical Control Toolkit”
  • 12.
  • 13. 1. Assign hazard group 2. How much is used? 3. Determine dustiness / volatility 4. Identify control approach 5. Find appropriate control sheets
  • 15. Hazard group (A to E) depends on “R phrases” assigned by supplier and provided on the label and safety data sheet
  • 16. Group “A” represents low hazard Group “E” for most serious hazards
  • 17. Additional Group “S” for substances that present a skin hazard
  • 18. A B C D E S R36 R20 R23 R26 R40 Muta cat 3 R21 R36/38 R20/21 R23/24 R26/27 R42 R24 R38 R20/21/22 R23/24/25 R26/27/28 R42/43 R27 R65 R21, R23/25 R26/28 R45 R34 R66 R21/22 R24 R27 R46 R35 R67 R22 R24/25 R27/28 R49 R36 All dusts and R25 R28 R36/37 vapours not R34 R40 Carc. Cat. 3, R36/37/38 allocated to R35 R48/23 R36/38 another band R36/37 R48/23/24 R38 R36/37/38 R48/23/24/25 R41 R37 R48/23/25 R42 R37/38 R48/24 R42/43 R41, R48/24/25 R43 R43, R48/25 R48/21 R48/20 R60, R48/21/22 R48/20/21 R61, R48/22 R48/20/21/22 R62, R48/23 R48/20/22 R63, R48/24 R48/21 R64 R48/24/25 R48/21/22 R48/25 R48/22 R66
  • 19. 1. Assign Hazard Group 2. How much is used?
  • 20. How much is used? Solids Liquids Small Grams millilitres Medium Kilograms litres Large Tonnes Cubic metres
  • 21. 1. Assign Hazard Group 2. How much is used? 3. Determine dustiness / volatility
  • 22. Solids – How dusty? Low Pellet-like solids that don't break up. Little dust visible during use Medium Crystalline, granular solids. When used, dust is seen but settles out quickly High Fine, light powders. When used dust clouds remain in air for some time
  • 23. Liquids – How volatile? Source: ILO toolkit
  • 24. 1. Assign Hazard Group 2. How much is used? 3. Determine dustiness / volatility 4. Identify control approach
  • 25.
  • 26. Control Approach Source: ILO toolkit
  • 27. 1. Assign Hazard Group 2. How much is used? 3. Determine dustiness / volatility 4. Identify control approach 5. Find appropriate control sheets
  • 28. Difficult to obtain other than by undertaking an assessment using the website
  • 29. ILO Task Specific Control Guidance Sheet Source: ILO toolkit
  • 30. ILO Task Specific Control Guidance Sheet Source: ILO toolkit
  • 31. ILO Task Specific Control Guidance Sheet Source: ILO toolkit
  • 32. 1. Assign Hazard Group 2. How much is used? 3. Determine dustiness / volatility 4. Identify control approach 5. Find appropriate control sheets
  • 33.
  • 34. Scenario 1 – Making up slurry from cerium oxide powder
  • 35. Scenario 1 – Making up slurry from cerium oxide powder A few kilograms of powder weighed out about 6 times per day
  • 36. Scenario 1 – Making up slurry from cerium oxide powder Added to water and mixed to form slurry which is used to polish glass
  • 37. Cerium oxide powder  Not classified as hazardous  Fine, dusty powder
  • 38. A B C D E S R36 R20 R23 R26 R40 Muta cat 3 R21 R36/38 R20/21 R23/24 R26/27 R42 R24 R38 R20/21/22 R23/24/25 R26/27/28 R42/43 R27 R65 R21, R23/25 R26/28 R45 R34 R66 R21/22 R24 R27 R46 R35 R67 R22 R24/25 R27/28 R49 R36 All dusts and R25 R28 R36/37 vapours not R34 R40 Carc. Cat. 3, R36/37/38 allocated to R35 R48/23 R36/38 another band R36/37 R48/23/24 R38 R36/37/38 R48/23/24/25 R41 R37 R48/23/25 R42 R37/38 R48/24 R42/43 R41, R48/24/25 R43 R43, R48/25 R48/21 R48/20 R60, R48/21/22 R48/20/21 R61, R48/22 R48/20/21/22 R62, R48/23 R48/20/22 R63, R48/24 R48/21 R64 R48/24/25 R48/21/22 R48/25 R48/22 R66
  • 39. A B C D E S R36 R20 R23 R26 R40 Muta cat 3 R21 R36/38 R20/21 R23/24 R26/27 R42 R24 R38 R20/21/22 R23/24/25 R26/27/28 R42/43 R27 R65 R21, R23/25 R26/28 R45 R34 R66 R21/22 R24 R27 R46 R35 R67 R22 R24/25 R27/28 R49 R36 All dusts and R25 R28 R36/37 vapours not R34 R40 Carc. Cat. 3, R36/37/38 allocated to R35 R48/23 R36/38 another band R36/37 R48/23/24 R38 R36/37/38 R48/23/24/25 R41 R37 R48/23/25 R42 R37/38 R48/24 R42/43 R41, R48/24/25 R43 R43, R48/25 R48/21 R48/20 R60, R48/21/22 R48/20/21 R61, R48/22 R48/20/21/22 R62, R48/23 R48/20/22 R63, R48/24 R48/21 R64 R48/24/25 R48/21/22 R48/25 R48/22 R66
  • 40. How much is used? Solids Liquids Small Grams millilitres Medium Kilograms litres Large Tonnes Cubic metres
  • 41. How much is used? Solids Liquids Small Grams millilitres Medium Kilograms litres Large Tonnes Cubic metres
  • 42. Solids – How dusty? Low Pellet-like solids that don't break up. Little dust visible during use Medium Crystalline, granular solids. When used, dust is seen but settles out quickly High Fine, light powders. When used dust clouds remain in air for some time
  • 43. Solids – How dusty? Low Pellet-like solids that don't break up. Little dust visible during use Medium Crystalline, granular solids. When used, dust is seen but settles out quickly High Fine, light powders. When used dust clouds remain in air for some time
  • 44. Stage 4 – Control Approach Source: ILO toolkit
  • 45. Stage 4 – Control Approach Source: ILO toolkit
  • 46. Stage 4 – Control Approach Source: ILO toolkit
  • 47. Stage 4 – Control Approach Source: ILO toolkit
  • 48. Stage 4 – Control Approach Source: ILO toolkit
  • 49.
  • 50.
  • 51.
  • 52.
  • 53.
  • 54.
  • 55.
  • 56.
  • 57.
  • 58. Scenario 2 Cleaning rollers with n-butyl acetate
  • 59.  Sponge soaked in n-butyl acetate used to clean screen printing rollers  Applied manually  Operation takes approx. 15 minutes  Done about 4 times per day
  • 60. n-butyl acetate  Boiling Point: 124 -128°C  R11 - Highly flammable  R36 - Irritating to eyes  R37 - Irritating to respiratory system
  • 61. A B C D E S R36 R20 R23 R26 R40 Muta cat 3 R21 R36/38 R20/21 R23/24 R26/27 R42 R24 R38 R20/21/22 R23/24/25 R26/27/28 R42/43 R27 R65 R21, R23/25 R26/28 R45 R34 R66 R21/22 R24 R27 R46 R35 R67 R22 R24/25 R27/28 R49 R36 All dusts and R25 R28 R36/37 vapours not R34 R40 Carc. Cat. 3, R36/37/38 allocated to R35 R48/23 R36/38 another band R36/37 R48/23/24 R38 R36/37/38 R48/23/24/25 R41 R37 R48/23/25 R42 R37/38 R48/24 R42/43 R41, R48/24/25 R43 R43, R48/25 R48/21 R48/20 R60, R48/21/22 R48/20/21 R61, R48/22 R48/20/21/22 R62, R48/23 R48/20/22 R63, R48/24 R48/21 R64 R48/24/25 R48/21/22 R48/25 R48/22 R66
  • 62. A B C D E S R36 R20 R23 R26 R40 Muta cat 3 R21 R36/38 R20/21 R23/24 R26/27 R42 R24 R38 R20/21/22 R23/24/25 R26/27/28 R42/43 R27 R65 R21, R23/25 R26/28 R45 R34 R66 R21/22 R24 R27 R46 R35 R67 R22 R24/25 R27/28 R49 R36 All dusts and R25 R28 R36/37 vapours not R34 R40 Carc. Cat. 3, R36/37/38 allocated to R35 R48/23 R36/38 another band R36/37 R48/23/24 R38 R36/37/38 R48/23/24/25 R41 R37 R48/23/25 R42 R37/38 R48/24 R42/43 R41, R48/24/25 R43 R43, R48/25 R48/21 R48/20 R60, R48/21/22 R48/20/21 R61, R48/22 R48/20/21/22 R62, R48/23 R48/20/22 R63, R48/24 R48/21 R64 R48/24/25 R48/21/22 R48/25 R48/22 R66
  • 63. A B C D E S R36 R20 R23 R26 R40 Muta cat 3 R21 R36/38 R20/21 R23/24 R26/27 R42 R24 R38 R20/21/22 R23/24/25 R26/27/28 R42/43 R27 R65 R21, R23/25 R26/28 R45 R34 R66 R21/22 R24 R27 R46 R35 R67 R22 R24/25 R27/28 R49 R36 All dusts and R25 R28 R36/37 vapours not R34 R40 Carc. Cat. 3, R36/37/38 allocated to R35 R48/23 R36/38 another band R36/37 R48/23/24 R38 R36/37/38 R48/23/24/25 R41 R37 R48/23/25 R42 R37/38 R48/24 R42/43 R41, R48/24/25 R43 R43, R48/25 R48/21 R48/20 R60, R48/21/22 R48/20/21 R61, R48/22 R48/20/21/22 R62, R48/23 R48/20/22 R63, R48/24 R48/21 R64 R48/24/25 R48/21/22 R48/25 R48/22 R66
  • 64. How much is used? Solids Liquids Small Grams millilitres Medium Kilograms litres Large Tonnes Cubic metres
  • 65. Solids Liquids Small Grams millilitres Medium Kilograms litres Large Tonnes Cubic metres
  • 66. Liquids – How volatile? Source: ILO toolkit
  • 67. Liquids – How volatile? Boiling Point: 124 - 128°C Source: ILO toolkit
  • 68. Stage 4 – Control Approach Source: ILO toolkit
  • 69. Stage 4 – Control Approach Source: ILO toolkit
  • 70. Stage 4 – Control Approach Source: ILO toolkit
  • 71. Stage 4 – Control Approach Source: ILO toolkit
  • 72. Stage 4 – Control Approach Source: ILO toolkit
  • 73.
  • 74.
  • 75.
  • 76.
  • 77.
  • 78.
  • 79.
  • 80.
  • 81. Mike Slater, Diamond Environmental Ltd. (occhygiene@btconnect.com) This presentation is distributed under the Creative Commons Attribution-NonCommercial-ShareAlike UK:International Licence