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POWER POINT
PRESENTATAION
WELCOME
Ammonification
 Nitrogen enters the soil through the
decomposition of protein in dead organic
matter
Amino acids + 11
/2O2 → CO2 + H2O + NH3 + 736kJ
 This process liberates a lot of energy which
can be used by the saprotrophic microbes
© 2008 Paul Billiet ODWS
Nitrification
 This involves two oxidation processes
 The ammonia produced by ammonification is an
energy rich substrate for Nitrosomas bacteria
They oxidise it to nitrite:
NH3 + 11
/2O2 → NO2
-
+ H2O + 276kJ
This in turn provides a substrate for Nitrobacter
bacteria oxidise the nitrite to nitrate:
NO3
-
+ 1
/2O2 → NO3
-
+ 73 kJ
 This energy is the only source of energy for
these prokaryotes
 They are chemoautotrophs
© 2008 Paul Billiet ODWS
Root uptake
Nitrate NO3
-
Plant
protein
Soil organic
nitrogen
Nitrogen from the atmosphere
Biological
fixation
Atmospheric
fixationOut
gassin
g
Atmospheric Nitrogen
4 000 000 000 Gt
© 2008 Paul Billiet ODWS
Atmospheric nitrogen fixation
 Electrical storms
 Lightning provides sufficient energy to split
the nitrogen atoms of nitrogen gas,
 Forming oxides of nitrogen NOx and NO2
© 2008 Paul Billiet ODWS
Atmospheric Pollution
 This also happens inside the internal combustion
engines of cars
 The exhaust emissions of cars contribute a lot to
atmospheric pollution in the form of NOx
 These compounds form photochemical smogs
 They are green house gases
 They dissolve in rain to contribute to acid rain in the
form of nitric acid
 The rain falling on soil and running into rivers
 They contribute to the eutrophication of water
bodies
© 2008 Paul Billiet ODWS
Eutrophication
 Nutrient enrichment of water bodies
 Nitrates and ammonia are very soluble in
water
 They are easily washed (leached) from free
draining soils
 These soils tend to be deficient in nitrogen
 When fertiliser is added to these soils it too
will be washed out into water bodies
 There algae benefit from the extra nitrogen
 This leads to a serious form of water pollution
© 2008 Paul Billiet ODWS
Sediments 10 Gt
Nitrification
Root
uptake
Biological
fixation
Nitrification
Ammonium NH4
+
Ammonification
Nitrite NO2
-
Dissolved in water
6000 Gt
Denitrification
Leaching
Nitrate
NO3
-
Soil organic
nitrogen 9500 Gt
Atmospheric
fixation
Out
gassin
g Industrial
fixation
Plant
protein
3500 Gt
Animal
protein
Atmospheric Nitrogen
4 000 000 000 Gt
© 2008 Paul Billiet ODWS

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Ppt of n cycle

  • 3.
  • 4. Ammonification  Nitrogen enters the soil through the decomposition of protein in dead organic matter Amino acids + 11 /2O2 → CO2 + H2O + NH3 + 736kJ  This process liberates a lot of energy which can be used by the saprotrophic microbes © 2008 Paul Billiet ODWS
  • 5. Nitrification  This involves two oxidation processes  The ammonia produced by ammonification is an energy rich substrate for Nitrosomas bacteria They oxidise it to nitrite: NH3 + 11 /2O2 → NO2 - + H2O + 276kJ This in turn provides a substrate for Nitrobacter bacteria oxidise the nitrite to nitrate: NO3 - + 1 /2O2 → NO3 - + 73 kJ  This energy is the only source of energy for these prokaryotes  They are chemoautotrophs © 2008 Paul Billiet ODWS
  • 6. Root uptake Nitrate NO3 - Plant protein Soil organic nitrogen Nitrogen from the atmosphere Biological fixation Atmospheric fixationOut gassin g Atmospheric Nitrogen 4 000 000 000 Gt © 2008 Paul Billiet ODWS
  • 7. Atmospheric nitrogen fixation  Electrical storms  Lightning provides sufficient energy to split the nitrogen atoms of nitrogen gas,  Forming oxides of nitrogen NOx and NO2 © 2008 Paul Billiet ODWS
  • 8. Atmospheric Pollution  This also happens inside the internal combustion engines of cars  The exhaust emissions of cars contribute a lot to atmospheric pollution in the form of NOx  These compounds form photochemical smogs  They are green house gases  They dissolve in rain to contribute to acid rain in the form of nitric acid  The rain falling on soil and running into rivers  They contribute to the eutrophication of water bodies © 2008 Paul Billiet ODWS
  • 9. Eutrophication  Nutrient enrichment of water bodies  Nitrates and ammonia are very soluble in water  They are easily washed (leached) from free draining soils  These soils tend to be deficient in nitrogen  When fertiliser is added to these soils it too will be washed out into water bodies  There algae benefit from the extra nitrogen  This leads to a serious form of water pollution © 2008 Paul Billiet ODWS
  • 10. Sediments 10 Gt Nitrification Root uptake Biological fixation Nitrification Ammonium NH4 + Ammonification Nitrite NO2 - Dissolved in water 6000 Gt Denitrification Leaching Nitrate NO3 - Soil organic nitrogen 9500 Gt Atmospheric fixation Out gassin g Industrial fixation Plant protein 3500 Gt Animal protein Atmospheric Nitrogen 4 000 000 000 Gt © 2008 Paul Billiet ODWS