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CHEMISTRY REVISION GUIDE
          for CIE IGCSE Coordinated Science (2012 Syllabus)
This revision guide is designed to help you study for the      Some very useful websites to help you further your
chemistry part of the IGCSE Coordinated Science course.        understanding include:
                                                                    •http://www.docbrown.info/ - whilst not the
The guide contains everything that the syllabus says you            prettiest site this contains a lot of very useful and
need you need to know, and nothing extra.                           nicely explained information.
                                                                    •http://www.bbc.co.uk/schools/gcsebitesize/scienc
The material that is in the supplementary part of the               e/ - well presented with many clear diagrams,
course (which can be ignored by core candidates) is                 animations and quizzes. Can occasionally lack
highlighted in dashed boxes:                                        depth.
                                                                    •http://www.chemguide.co.uk/ - whilst mostly
                                                                    targeted at A-Levels this site contains very detailed
                                                                    information suitable for those looking to deepen
                                                                    their knowledge and hit the highest grades.
Whilst this guide is intended to help with your revision, it
should not be your only revision. It is intended as a          Finally, remember revision is not just reading but should
starting point but only a starting point. You should make      be an active process and could involve:
sure that you also read your text books and use the                   •Making notes
internet to supplement your study in conjunction with                 •Condensing class notes
your syllabus document.                                               •Drawing Mind-maps
                                                                      •Practicing past exam questions
Whilst this guide does contain the entire syllabus, it just           •Making flashcards
has the bare minimum and is not in itself sufficient for       The golden rule is that what makes you think makes you
those candidates aiming for the highest grades. If that is     learn.
you, you should make sure you read around a range of
sources to get a deeper knowledge and understanding.                                           Happy studying, Mr Field.
C1: THE PARTICULATE NATURE OF
                 MATTER                                                                        Solids, Liquids and
Atom: The smallest particle An atom:
of matter
                                                      Some atoms:                              Gases


Molecule: A small particle   Molecules of an element: Molecules of a
made from more than one                               compound:
atom bonded together




Element: A substance         A solid element:         A gaseous element:
                                                                            SOLIDS LIQUIDS AND GASES
made of only one type of
                                                                            The particles in solids, liquids and gases are held near to each other by forces of
atom
                                                                            attraction. The strength of these forces determines a substance’s melting and
                                                                            boiling points.

                                                                            In a solid, the forces of attraction are strongest, holding the particles tightly in
Compound: A substance     A solid compound            A gaseous compound:   position. As the solid is heated, and the particles vibrate faster, these forces are
made from two or more                                                       partially overcome allowing the particles to move freely as a liquid – this is called
different elements bonded                                                   melting. As the liquid is heated more, the particles gain so much energy that the
together                                                                    forces of attraction break completely allowing particles to ‘fly around’ as a gas –
                                                                            this is called boiling. The reverse of the these processes are condensing and
                                                                            freezing. Under specific conditions, some solids can turn straight to gases – a
                                                                            process called subliming (the reverse is called desubliming).

                                                                             PROPERTIES
Mixture: A substance         A mixture of compounds and elements:
                                                                             Solids                      Liquids                      Gases
made from two or more
                                                                             •Have a fixed shape         •Take the shape of their     •Take the shape of their
elements or compounds
                                                                             •Can’t be compressed        container                    container
mixed but not joined
                                                                             •Particles close together   •Can’t be compressed         •Can be compressed
                                                                             in a regular pattern        •Particles close together    •Particles widely spaced
                                                                             •Particles vibrate around   but disordered               in random order
                                                                             a fixed point               •Particles move freely       •Particles moving very
                                                                                                                                      fast.
PAPER CHROMATOGRAPHY                                     best possible separation of spots.
             C2: EXPERIMENTAL                                         Paper chromatography is a technique that can be
                                                                      used to separate mixtures of dyes or pigments and
                TECHNIQUES                                            is used to test the purity of a mixture or to see
                                                                      what it contains. Firstly a very strong solution of
                                                                      the mixture is prepared which is used to build up a
FILTRATION
                                                                      small intense spot on a piece of absorbent paper.
Used to separate solids
                                                                      This is then placed in a jar of solvent (with a lid). As
from liquids. The mixture
                                                                      the solvent soaks up the paper, it dissolves the
is poured through a filter
                                                                      mixture-spot, causing it to move up the paper with
paper in a funnel. The
                                                                      the solvent. However since compounds have
liquid can pass through
                                                                      different levels of solubility, they move up the
the small holes in the
                                                                      paper at different speeds causing the individual
filter paper (to become
                                                                      components to separate out. The solvent or
the filtrate) and the solid
                                                                      combination of solvents can be changed to get the
 gets left behind
(called the residue).
                                                                      PURITY                                                   FRACTIONAL DISTILLATION
                                                                      It is important for chemists to be able to purify the    When the liquids being distilled have similar
CRYSTALLISATION                                                       compounds they make, this is because the                 boiling points, normal distillation can’t separate
Crystallisation is used to separate mixtures of solid dissolved in    impurities could be dangerous or just un-useful.         them completely but simply gives a purer
liquid and relies on the fact that solids are more soluble at         This is especially true for chemists making              mixture. In this case a fractionating column is
higher temperatures. A solution containing a solid is cooled          compounds that are consumed by people such as            used. This provides a large surface area for
down until crystals form in the solution, these can then be           drugs or food additives since the impurities may be      condensation meaning much purer ‘fractions’ are
collected by filtration.                                              toxic which would be very bad news!                      produced. The most important use of this is
                                                                                                                               separating crude oil into it’s useful components.
The related technique of recrystallisation can be used to             WHICH TECHNIQUE?
separate a mixture of two soluble solids by taking advantage of       You need to be able to select appropriate methods
the difference in their solubility. The mixture is dissolved in the   to separate a given mixture. The key to this is look
smallest possible amount of hot solvent. As the solution cools,       for differences in the properties of the
the less soluble compound forms crystals that can be collected        components of the mixture such as their state,
by filtration whilst the more soluble compound stays dissolved.       solubility, melting/boiling point and so on. Then
                                                                      pick the method that best takes advantage of this
DISTILLATION                                                          difference.
In distillation a mixture of
liquids is separated using the                                        MELTING/BOILING POINTS
differences in their boiling                                          No two substances have the exact same melting
points. The mixture is heated                                         and boiling points. We can take advantage of this
until the liquid with the lowest                                      to test the purity of a compound we have made. If
boiling point boils, the vapours                                      we know what the melting or boiling point of the
then condense on the cold                                             pure compound should be, we can then measure
surface of the condenser and                                          the melting or boiling point of a sample we have
the pure(er) liquid is collected.                                     produced and the closer it is to the pure value, the
                                                                      more pure it is likely to be.
C3: ATOMS, ELEMENTS AND                                        A NOBLE MATTER




                                                                                                                                                                                                                         Group VIII: Noble Gases
                                                                                                              H
                                                                   The Noble Gases (He, Ne, Ar




                                                                                                                                                                                                   Group VII: Halogens
   COMPOUNDS – Structures and                                                                                                                                                     Non-metals




                                                                                                     Group I: Alkali Metals
                                                                                                                              Group II: Alkali-Earth
                                                                   etc) have full outer shells
                                                                   containing either 2 or 8
            Bonding                                                electrons. This is very stable
                                                                   which is why the Noble gases
ELECTRON ARRANGEMENT/CONFIGURATION                                                                                                                     Transition Metals
                                                                   are so unreactive.
Electrons are arranged around atoms in specific shells. The                                                                                                                         Other
most important shell is the outer one as this controls an          Other elements tend to                                                                                           Metals
atom’s chemistry. We call the electrons in the outer shell         react in such a way as to
‘valence electrons’ because they are used for bonding. The         achieve a full outer shell by
number of electrons in the outer shell is the same an              gaining or losing electrons
element’s group number.                                            until they achieve this Noble
                                                                   Gas configuration.                                                                         Lanthanides and Actinides (metals)
The number of electrons around an atom is given by the
atom’s proton number. They are arranged in shells as follows:
        •1st Shell – Holds two electrons
                                                                   CHEMICAL VS PHYSICAL                                        STRUCTURE OF THE PERIODIC TABLE (PT                 ISOTOPES
        •2nd/3rd/4th Shells – Hold 8 electrons
                                                                   CHANGES                                                     on last page!)                                      Isotopes are atoms
•Example 1: Carbon. Proton        •Example 2: Chlorine. Proton     Physical changes are reversible                             Elements arranged in order of increasing            with the same proton
number is 6 which means           number is 17 which means         whereas chemical changes are                                proton number.                                      number but different
there are 6 electrons: 2 in the   there are 17 electrons: 2 in     not.                                                        Periods: The rows in the periodic table.            nucleon number.
1st shell and 4 in the second     the 1st shell, 8 in the second                                                               •For example Li, C and O are all in period 2.
                                  and 7 in the 3rd.                For example if you melted some
                                                                                                                               Groups: The columns in the PT.                      For example carbon
                                                                   solid sugar to a liquid and then
                                                                                                                               •Use roman numbers: I, II, III, IV, V, VI, VII,     has two main
                                                                   left it to cool, it would freeze
              C                                                                                                                VIII                                                isotopes – C-12 and
                                                                   back to solid sugar – this is a
                                                                                                                               •Eg. F, Cl, Br, I are all in Group VII              C-13. Carbon has a
                                                Cl                 physical change. If you took the
                                                                                                                               •Elements in the same group have similar            proton number of 6
                                                                   same sugar and burned it to
                                                                                                                               properties and react in similar ways: the           so they both contain
Checking Your Answer: To check                                     produce carbon dioxide and
                                                                                                                               halogens all react in the same way with             6 protons and 6
you are right, the period gives the                                water, there would be no easy
                                                                                                                               sodium to form sodium fluoride (NaF),               electrons but C-12
number of shells and the group gives the number of electrons       way to turn those back to sugar –
                                                                                                                               sodium chloride (NaCl), sodium bromide              has 6 neutrons and C-
in the outer shell. For example chlorine is in Period 3 and        this is a chemical change – new
                                                                                                                               (NaBr) and sodium iodide (NaI)                      13 has 7.
Group VII so it has 3 shells and 7 electrons in the outer shell.   substances are made.
Ions: The configuration of ions is the same as for atoms but       ATOMIC STRUCTURE                                           what the element is.
you have to take electrons away from positive ions and add                                                                                                                     Eg 1: Boron has 5 protons,
                                                                   Atoms are made of:
extra for negative ions. For example O/O2- Li/Li+                                                   In a square on the periodic table                                          6 neutrons (ie 11-5) and 5
                                                                   Protons: mass = 1, charge = +1
                                                                                                    the smaller number, the proton                                             electrons
                                                                   Neutrons: mass = 1, charge = 0
                                                                                                    number, gives the number of
                                                                   Electrons: mass = 0, charge = -1
                                                                                                    protons or electrons and the                                               Eg 2: Phosphorus has 15
      O              O2-                   Li            Li+       The numbers of each vary from    bigger number, the nucleon                                                 protons, 16 neutrons (ie
                                                                   element to element but it is the number the number of protons                                               31-16) and 15 electrons
                                                                   number of protons which decides and neutrons together.
C3: ATOMS, ELEMENTS AND




                                                                                                                                                                                                        Group VIII: Noble Gases
                                                                            IONIC BONDING
                                                                            An ionic bond is the attraction between two oppositely charged ions. Cations (positive) are formed




                                                                                                                                                                                  Group VII: Halogens
      COMPOUNDS – Bonding and                                                                                                                              Non-metals
                                                                            when atoms (usually metals) lose electrons. Anions (negative) are formed when atoms (usually non-
                                                                            metals) gain electrons.
              Structure
                                                                            Atoms will lose or gain electrons until they have a complete outer shell: elements in Groups I, II and III
MOLECULES                           When a substance melts, it is           will lose 1, 2 and 3 electrons respectively to form 1+, 2+ and 3+ ions. Atoms in Groups V, VI and VII
A molecule is a small particle      these weak intermolecular               gain 3, 2 and 1 electrons to form 3-, 2- and 1- ions. In an ionic compound the number of positive and
made from (usually) a few           forces that break NOT the               negative and charges must cancel out to neutral.
non-metal atoms bonded              strong covalent bonds.                  Example: NaF, sodium in Group I forms a 1+ ion Example: Li2O, lithium in Group I forms a 1+ ion
together.                                                                   and fluorine in group VII forms a 1- ion so one but oxygen in Group VI forms a 2- ion so two Li+
                                    Molecular compounds have
                                                                            Na+ is needed to balance out one F-             are needed to balance out one O2-
The atoms in a molecule are         low melting points and are
joined by strong covalent           volatile (evaporate easily) due
bonds. In a solid each              to the weak intermolecular
molecule is held close to its       forces, and insulate electricity                            F-         Na+                                Li+          O2-           Li+
neighbour by weak                   as all electrons are stuck in
intermolecular forces.              bonds and so unable to move.


                                                                            COVALENT BONDING                                                        GIANT IONIC LATTICES
                                                                            A covalent bond forms between two atoms and is the attraction           The positive and negative ions in
                                                                            of two atoms to a shared pair of electrons. Small groups of             an ionic compound don’t form
                                                                            covalent bonded atoms can join together to form molecules.              molecules but form crystals made
GIANT COVALENT LATTICES             Graphite: made of carbon                                                                                        of a repeating pattern of positive
A crystal made of a repeating       atoms arranged in hexagonal             The atoms share enough electrons to complete their outer                and negative ions called a giant
pattern of atoms joined with        sheets with long weak bonds             shells.
                                                                             Example: H O*, hydrogen is   Example: CO *, carbon is has              ionic lattice. Eg sodium chloride:
                                                                                        2                                  2
covalent bonds that repeats         between the sheets. This                 has one valence electron and     four valence electrons so
millions of times in all            means the sheets can easily              needs one more to complete       needs four more to complete
directions.                         separate making graphite a               the 1st shell, oxygen has six    its outer shell, oxygen needs
                                    good lubricant:                          valence electrons electrons so   two more. Thus each carbon
Diamond is made of carbon                                                    needs two more. Thus one         will react with two oxygens,
atoms arranged so that each C                                                oxygen will react with two       sharing two electrons with
is bonded in a pyramid                                                       hydrogens:                       each one. A bond involving
arrangement to 4 others. This                                                                                 two shared pairs is a double
makes it very hard, ideal for use                                                                                                                   Properties of Ionic Compounds
                                                                                                              bond.
in industrial drills:                  Silicon (IV) oxide (SiO2) has a           H          O          H                                            When you melt or dissolve an
                                               structure with each Si                                                                               ionic compound it conducts
                                                                                                                   O           C        O           electricity because the ions are
                                            joined to 4 O and each O
                                                    joined to 2 Si. It is                                                                           free to move towards the positive
                                                 the main ingredient        *Nb: In these diagrams only draw the outer shell and use                and negative electrodes. When
                                                              in glass.     different shapes/colours to show where electrons have come              solid the ions are stuck in position
                                                                            from. You should be able to draw at least: H2O, CH4, Cl2, HCl, H2,      and there are no free electrons so
                                                                            N2, O2, CO2, C2H4                                                       they don’t conduct.
CHEMICAL FORMULAS                                         You may be asked to
       C4: STOICHIOMETRY –                                          Formulas tell you the atoms that make up a                write a formula given a
                                                                    compound                                                  diagram of a molecule
      Formulas and Equations                                        Eg 1. H2O – two H, one O
                                                                                                                              for example glucose.
                                                                                                                              By counting you can see
                                                                    Eg 2. C2H6O – two C, six H, one O
                                                                                                                               there are 6 carbons,
                                                                    Eg 3. Mg(OH)2 – one Mg, two           O, two H*
SYMBOL EQUATIONS                                                                                                              12 hydrogens and
                                                                    Eg 4. CH2(CH3)2 – three C, 8 H*
•Show the reactants you start with and the products you                                                                       6 oxygens so the
make using symbols not words                                        *In this case everything in brackets is doubled           formula is C6H12O6
•Must contain an arrow ( ) NOT an equals sign (=)
•Must be balanced – same number of atoms on each side.              WORD EQUATIONS                                                  IONIC FORMULAS
•Balancing is done by placing numbers called coefficients in        •These tell you the names of the chemicals involved in          You can deduce the formula of an ionic
front of the formulas for the compounds/elements. For               reaction                                                        compound if you know the charges on the
example, ‘O2‘ means there is one oxygen molecule involved in        •The left hand side shows you what you start with and           ions involved. The total positive charge
a reaction but ‘2O2’ would mean there are two.                      is called the reactants                                         must balance out the total negative charge
          Example:. CH4(g) + O2(g) CO2)g) + H2O(g)*                 •The right hand side shows you what you make and is             so you must look for the lowest common
This is unbalanced as there are 4 ‘H’ on the left but only 2 ‘H’    called the products                                             multiple (LCM) of the charges.
on the right. This must be corrected by placing a ‘2’ in front of   •The left and right are connected by an arrow ( not
the ‘H2O’ so there are now 2 waters:                                                                                                Eg1. Calcium nitrate is made of Ca2+ ions and
                                                                    ‘=‘) which means ‘makes’ or ‘becomes’
              CH4 (g) + O2(g) CO2(g) +2H2O(g)                                                                                       NO3- ions. The LCM of 2 and 1 is 2 which
                                                                    •When you react a metal with oxygen to make a metal
Now the ‘H’ balances but there 4 ‘O’ on the right and only 2                                                                        means you need 1 Ca2+ ion and 2 NO3- ions
                                                                    oxide, the equation might be:
on the left. This must be balanced by placing a ‘2’ in front of                                                                     so the formula is Ca(NO3)2
                                                                               Iron + oxygen iron oxide
the ‘O2’ so that there are 2 oxygen molecules:                      •Many fuels burn in oxygen to produce carbon dioxide            Eg2. Aluminium oxide is made of Al3+ ions
              CH4(g) + 2O2(g) CO2(g) + 2H2O(g)                      and water for example:                                          and O2- ions. The LCM of 2 and 3 is 6 which
Now there is 1 ‘C’, 4 ‘H’ and 4 ‘O’ on each side so it balances.               Methane + oxygen carbon dioxide + water              means you need 2 Al3+ ions and 3 O2- ions so
                                                                                                                                    the formula is Al2O3.
In ionic equations, we tend to look only at the ions that
actually change. For example, when iron reacts with copper          CHEMICAL MASSES
sulphate to form iron sulphate and copper the equation is:          The relative atomic mass (Ar) of an element is the        Example 1: Water, H2O
        Fe(s) + Cu2+(aq) + SO42-(aq) Fe2+(aq) + SO42-(aq) + Cu(s)   mass of one atom relative to 1/12th the mass of C-        The Ar for H and O are 1.01 and 16.00 so:
In this case, the sulphate ion (SO42-) remains unchanged (we        12. It is just a number that allows us to compare         Mr(H2O) = 2 x 1.01 + 1 x 16.00 = 18.02
call it a spectator ion) so it can be left out of the equation to   the mass of atoms of different elements. Ar can be
give:                                                               found on the periodic table as the ‘large’ number         Example 2: Magnesium Hydroxide, Mg(OH)2
                   Fe(s) + Cu2+(aq) Fe2+(aq) + Cu(s)                in each square. For example Ar for carbon is 12.01        The Ar for Mg, O and H are 24.31, 16.00 and 1.01:
This allows us to see more clearly the actual chemical changes      and for iron is 55.85. Ar has no units since it is only   Mr(Mg(OH)2)       = 1 x 24.31 + 2 x 16.00 + 2 x 1.01
taking place.                                                       a relative number, allowing us to compare things.                           = 58.33
Note: You can’t change the little numbers (ie the 2 in H2O ) as
this changes the compound to something completely                   The relative formula mass (Mr) is the combined Ar Example 3: Decane, CH3(CH2)8CH3
different.                                                          of all the elements in the formula for a substance. The Ar for C and H are 12.01 and 1.01
                                                                    Mr also has no units for the same reason as above. Mr(decane) = 10 x 12.01 + 22 x 1.01 = 142.34
*The state symbols (s), (l), (g) and (aq) are used to indicate
solid, liquid, gas and ‘aqueous solution’ (dissolved in water).
THE MOLE
    C4: STOICHIOMETRY – The                                          A mole is 6.02x1023 of something. It is chosen so that a mole of something has the same mass in
                                                                     grams (molar mass, Mm) as its formula mass. For example the Mr of water is 18.02 so the Mm of water
          Mole Concept                                               is 18.02g; the Mr of decane is 142.34 so the Mm of decane is 142.34g. Importantly this means that
                                                                     18.02 g of water and 142.34g decane contains the same number of molecules.

EQUATIONS AND MOLE RATIOS                                                                 THE MOLES AND MASSES
Equations can be used to help us calculate the numbers of moles of substances             If you know the mass in grams of substance, you can calculate the number of moles
involved in a reaction. We can see this by studying the following reaction:               as follows:
                             2C2H6 + 7O2 4CO2 + 6H2O                                                       Moles = Mass */ Molar mass
Q1: How many moles of CO2 are produced by burning 1.0 mol of C2H6? We say that
                                                                                          Eg 1. How many moles is 27.03 g of H2O?
C2H6 is our ‘known’ and CO2 is our ‘unknown’ so:
                                                                                                Moles (H2O) = Mass / Molar mass = 27.03 / (2 x 1.01 + 16.00) = 1.50 mol
          Moles CO2 = moles known/knowns in eqn x unknowns in eqn
                     = 1.0 /2 x 4 = 1.0 x 2 = 2.0 mol                                     Eg 2. What is the mass of 0.05 mol of H2O. This time the equation must be
Q2: If 0.01 mol of CO2 is produced, how much H2O must also be produced? This              rearranged to give:
time CO2 is our known and H2O is our unknown so:                                                 Mass (H2O) = Moles x molar mass = 0.05 x (2 x 1.01 + 16.00) = 0.901g
          Moles H2O = moles known/knowns in eqn x unknowns in eqn
                                                                                          *Mass must be given in grams – you may need to convert from kg: x1000
                        = 0.01/4 x 6 = 0.0025 x 6 = 0.015 mol
*You must make sure your equation is balanced or your mole ratio will be wrong.           THE MOLES AND GASES
                                                                                          One mole of any gas has a volume of 24.0 dm3 (remember dm3 is the symbol for
CALCULATING REACTING QUANTITIES
                                                                                          decimetres cubed, aka litres) at room temperature and pressure. So for a gas:
Using what we know about calculating moles, we can now answer questions like: If
I have 100g X, how much Y is made? The key is to convert the known to moles 1st.                           Moles = Volume / 24.0
Example: What volume of H2 gas would be produced by reacting 12.15g                       Eg 1. How many moles of CO2 are present in 60 dm3?
magnesium with excess hydrochloric acid? First we need a balanced equation:                                Moles (CO2) = Volume / 24.0 = 60/24.0 = 2.50 mol
         Mg + 2HCl MgCl2 + H2                                                             Eg 2. What is the volume of 0.20 mol of H2 gas?.This time the equation must be
Then calculate moles of Mg (our known) we start with:                                     rearranged to give:
         Moles Mg = mass/molar mass = 12.15/24.30 = 0.50 mol                                              Volume (H2) = Moles x 24.0 = 0.20 x 24.0 = 4.80 dm3
Next we work out how many moles of H2 ( our unknown) we expect to produce:
                                                                                          *The volume must be in dm3 – to convert from cm3 divide by 1000
         Moles H2 = moles known/knowns in eqn x unknowns in eqn
                     = 0.50/1 x 1 = 0.50 mol
Finally we calculate the volume using our equations for a gas:                            THE MOLE AND SOLUTIONS
                 Volume H2 = moles x 24.0 = 0.50 x 24.0 = 12.0 dm3                        The concentration (strength) of a solution is measured in mol dm-3 (moles per
                                                                                          decimetre cubed). A 1.0 mol dm-3 solution contains 1 mol of substance dissolved in
                                                                                          each litre.
LIMITING REACTANTS                            moles of H2O could you make from 3 mol                       Moles = Concentration x Volume*
This is the reactant that will run out first. of H2 and 3 mol of O2. H2: 3/2 = 1.5, O2:
                                                                                          Eg 1. How many moles of NaOH are present in 2.5 dm3 of a 1.5 mol dm-3 solution?
It is important as this is the one you        3/1 = 3. This means there is enough O2 to
                                                                                                     Moles (NaOH) = concentration x volume = 1.5 x 2.5 = 3.75 mol
should then use for your calculations.        do the reaction 3 times but only enough
                                                                                          Eg 2. 0.15 mol NaCl is dissolved in 250 cm3 water. What concentration is this? This
You calculate it by dividing the number of H2 for 1.5 times so H2 is the limiting
                                                                                          time you must rearrange the equation to:
moles of reactant by the number of            reactant. Thus, moles H2O = 1.5 x (2/2) =
                                                                                                   Concentration = moles/volume = 0.15/(250/1000)* = 0.60 mol dm-3
times they appear in the equation. For 1.5 mol.
                                                                                          *The volume must be in dm3 – to convert from cm3 divide by 1000
example 2H2 + O2 2H2O. How many
ELECTROLYSIS                                        (right) positive copper ions move to the cathode
         C5: ELECTRICITY AND                                     Electrolysis is a process in which electricity is   and form copper metal. Negative chloride ions
                                                                 used to break compounds down into their             more to the anode and form chlorine gas.
              CHEMISTRY                                          elements. The mixture being electrolysed is
                                                                 called an electrolyte and must be liquid (either
                                                                 melted or dissolved) to allow the ions to move.                          Bubbles of gas
             Molten                                                                                                      Anode                                             Cathode
                                    Salt Solution                                                                                            formed
              Salt                                                                                                      (positive                                         (negative
                                                                 Cations (positive ions – remember they are
                                                                                                                       electrode)                                         electrode)
                     Metal, except with reactive metals (K,      ’puss-itive’) ions move to the cathode (the                         Cl Cl
                     Na, Li Ca, Mg) in which case H2 gas is      negative electrode) where they gain electrons,                     Cl Cl                Cu2+
Cathode      Metal
                     produced plus a solution of metal           usually forming a metal (or H).                                                                         Layer of metal
                     hydroxide                                                                                                            Cl-             Cl-       Cu      formed
                                                                 Anions (negative ions) move to the anode (the
                     Non Metal, except sulphates in which        positive electrode) where they lose electrons,                                                     Cu
Anode      Non-metal
                     case O2
                                                                                                                                          Cl-          Cu2+
                                                                 usually forming a non-metal (other than H).                                                        Cu Cations move
                                                                                                                     Anions move
ELECTROLYSIS OF COPPER SULPHATE                                                                                       to anode      Cl-         Cu2+          Cl-     Cl- to cathode
                                                                 In the electrolysis of copper chloride (CuCl2)
When copper sulphate is electrolysed using carbon electrodes,
you produce O2 gas at the anode and a layer of Cu metal at the   EXTRACTING ALUMINIUM                                Aluminium oxide ( the electrolyte) is dissolved in
cathode. This can be used to electroplate items by setting       Aluminium can’t be extracted by reduction of        molten ‘cryolite’ and placed in a large carbon
them as the cathode. However, when two copper electrodes         aluminium oxide (Al2O3) using carbon as carbon      lined vessel which acts as the cathode. A large
are used, what ends up happening is a transfer of copper from    is less reactive than aluminium. Instead            anode made of carbon is lowered into the
the anode to the cathode, this is used to purify copper.         aluminium is produced by electrolysis.              electrolyte. The processes that take place are:
When copper is made it contains lots of impurities. The copper                                                                          At the cathode:
is purified by electrolysis. A large lump of impure copper is                                                                           Aluminium ions gain electrons
used as the anode, the electrolyte is copper sulphate solution                                                                          to make liquid aluminium
and the cathode is made of pure copper.                                                                                                 Al3+ + 3e- Al(l)

At the anode, instead of anions losing electrons, neutral                                                                                 At the anode:
copper atoms lose electrons to become copper ions .                                                                                       Oxide ions lose electrons to
                     Cu(s) Cu2+(aq) + 2e-                                                                                                 make oxygen gas
These then move through the electrolyte to the cathode                                                                                    O2- ½ O2(g) + 2e-
where they become copper atoms again.                                                                                                     The oxygen reacts with the
                                        Cu2+(aq) + 2e- Cu(s)                                                                              carbon anode so it has to be
                                                                                                                                          replaced regularly
                                       The anode loses mass
                                       as copper atoms leave
                                       it and the cathode        ELECTROLYSIS OF BRINE
                                       gains mass as copper      When sodium chloride solution (brine) is
                                       atoms join it. The        electrolysed , chlorine gas is produced at the
                                       impurities sink to the    anode and hydrogen gas at the cathode (because
                                       bottom as a pile of       sodium is too reactive). A solution of sodium
                                       sludge.                   hydroxide is left behind.
QUANTIFYING ENERGY
      C6: ENERGY CHANGES IN                                        Using the ideas you learn in physics about specific heat capacity, you may have to calculate the
                                                                   amount of energy released by one mole of a substance.
       CHEMICAL REACTIONS
                                                                   Example: When 0.250 mol of Metal X reacts fully with 500 cm3 of 2.0 mol dm-3 HCl solution, the
                                                                   temperature increases by 15.4OC. How much energy is released when 1.0 mol X reacts with HCl?
EXOTHERMIC REACTIONS
                                                                   First calculate the heat evolved:
Exothermic reactions get hotter – the temperature increases.                                 Heat evolved = m.c.ΔT = 500 x 4.2 x 15.4 = 32340 J*
The energy given out can be used to keep the reaction going        Then calculate heat released per mole:
so that once started, they don’t stop until they have run out of                  Heat per mole = heat evolved / moles = 32340/0.250 = 129360J = 129.4 kJ
reactants.
                                                                   *ΔT is the temperature rise, m is the mass of the solution in grams which is assumed to equal its
Important examples of exothermic reactions include:                volume in cm3, c is the specific heat capacity of water which is 4.2 J K-1 g-1
        •Combustion of fuels
        •Acid-base neutralisations
        •Displacement reactions
        •Respiration in cells

ENDOTHERMIC REACTIONS

Endothermic reactions reactions get colder – the temperature
decreases. Generally endothermic reactions need a constant
energy supply to keep them going

Important examples of exothermic reactions include:
        •Dissolving of many (but not all) salts
        •Thermal decompositions
                                                                   Yes this unit really is this small – in fact you don’t even really need the stuff about quantifying energy,
        •Photosynthesis
                                                                                                  I just put it in there as it often proves useful!!
        •Cooking!!!

ENERGY CHANGES
In exothermic reactions, chemical energy stored in the
reactants gets converted to heat energy. The products have
less chemical energy than the reactants and the difference is
the amount of heat released.

In endothermic reactions, heat energy gets converted to
chemical energy. The products have more chemical energy
than the reactants and the difference between the two is the
energy that had to be supplied to make the reaction go.
MEASURING REACTION RATES
                                                                      If a reaction produces gas, you can easily measure the reaction rate by collecting the gas (either in an
     C7: CHEMICAL REACTIONS                                           upturned measuring cylinder full of water or a gas syringe) and recording how much has been
                                                                      collected each second.


RATES OF REACTION
The ‘speed’ of a reaction is called its rate and is simply the
amount of new product formed every second.

For a chemical reaction to happen, the reacting particles need
to collide with enough energy. Anything that increases the
number of collisions or their energy will increase the rate.
Temperature
Increasing temperature increases the rate of a reaction.
                                                                      MEASURING REACTION RATES                                             INVESTIGATING REACTION RATES
This is because particles are moving faster which means more          On a graph showing the change in concentration of reactants          To investigate a factor influencing
collisions and higher energy collisions.                              or products, the gradient of the line tells you the reaction rate:   reaction rate, you must change it
                                                                      steeper = faster,                                                    whilst keeping the others constant.
Concentration                                                         flat = stopped                                                       For example, investigating the
Increasing the concentration of a solution increases the rate of                                                                           effect of concentration, you could
a reaction.                                                                                                                                carry out the reaction at 5 different
                                                                                                                                           concentrations whilst making sure
This is because it means there are more particles available to                                                                             the temperature, particle size and
react which leads to more collisions.                                                                                                      presence/absence of a catalyst
                                                                                                                                           remains the same.
Surface Area/Particle size
                                            Increasing the total      REDOX REACTIONS                     together.                            DANGEROUS RATES
                                            surface area of           Reduction means a substances                                             Factories that produce
                                            particles (by using       loses oxygen. Oxidation means a     Another way to look at this is to    flammable powders (for
                                            finer powder)             substance gains oxygen. For         think of oxidation as the loss of    example bread flour) have to
                                            increases the rate of a   example:                            electrons and reduction as the       be careful about sparks since
                                            reaction because it            2Fe2O3 + 3C 4Fe + 3CO2         gain of electrons (OILRIG). Eg: in   the very fine powder particles
                                            means more particles      Fe2O3 is reduced because it loses   the electrolysis of molten sodium    burn with a VERY high reaction
                                            at the surface are        oxygen to become Fe. C is           bromide. At the anode:               rate causing explosions.
                                            exposed to collisions.    oxidised because it gains oxygen               2Br- Br2 + 2e-
                                                                      to become CO2. C is called a        This is an oxidation because the     Similar is true underground in
                                                                      reducing agent because it causes    bromide ions lose electrons.         coal mines where gas can build
Catalysts                                                             Fe2O3 to get reduced. Reactions     At the cathode:                      up. Gas can be thought of as
Catalysts are substances that speed up a reaction without             like this are called redox                      Na+ + e- Na              the finest possible powder so
getting used up. Whenever a catalyst is present, the rate of          reactions because an oxidation      This is a reduction because the      they too react explosively fast.
reaction increases.                                                   AND a reduction take place          sodium ions gain electrons.
THE pH SCALE                      Litmus indicator
   C8: ACIDS, BASES AND SALTS                                    Neutral substances have a pH=7 turns red in acids
                                                                 Acids have a pH of less than 7    and blue in alkalis.
       – Reactions of Acids                                      Alkalis have a pH greater than 7
                                                                                                   Universal indicator
                                                                 pH can be measured with colour has many colours
REACTIONS OF ACIDS                                               changing indicators or digital pH (see chart).
You need to memorise these reactions, each one shows the         meters
general word equation then a specific example with symbols.
                                                                 WHAT IS THE SALT?
Acids and Metals
                                                                 To work out which salt is formed during neutralisation reactions you need to know the ions formed by
                Acid + Metal    Salt + Hydrogen
                                                                 the acid or alkali when it dissolves.
•Hydrochloric acid + lithium   lithium chloride + hydrogen
•     2HCl(aq)     + 2Li(s)         2LiCl(aq)   + H2(g)           Substance                           Cation(s) Formed Anion(s) Formed Working out the name is
                                                                                                                                           easy, you just combine the
Acids and Base (like alkali but not always soluble)               Hydrochloric acid, HCl              1 H+             Cl- , chloride      name of the cation from
                   Acid + Base Salt + Water                       Nitric acid, HNO3                   1 H+             NO3- , nitrate      the alkali with the anion
•Sulphuric acid + sodium hydroxide sodium sulphate + water        Sulphuric acid, H2SO4               2H +             SO4  2- , sulphate  from the acid.
• H2SO4(aq) +         2NaOH(aq)           Na2SO4(aq) + 2H2O(l)   Phosphoric acid, H3PO4             3 H+                  PO43- , phosphate   For example potassium
Acids and Carbonates                                             Sodium hydroxide, NaOH             Na+ , sodium          1 OH-               sulphate and sulphuric acid
       Acid + Carbonate Salt + Water + Carbon Dioxide            Potassium hydroxide, KOH           K+ , potassium        1 OH-               makes potassium sulphate.
•Nitric acid + calcium carbonate calcium nitrate + water +
                                                                 Magnesium hydroxide, Mg(OH)2       Mg2+ , magnesium      2 OH-               Magnesium hydroxide and
.                                              carbon dioxide
                                                                 Ammonium hydroxide, NH4OH          NH4+ , ammonium       1 OH-               phosphoric acid makes
• 2HNO3(aq) + CaCO3(s)        Ca(NO3)2(aq) + H2O(l) + CO2(g)
                                                                                                                                              magnesium phosphate
PREPARING SALTS                                                  Working out the formula of the salt is a little more complicated, the key is to make sure the positive
To prepare any given salt, you first need                        and negative charges on the cancel each other out to zero.
 to work out which acid and alkali to                                     Eg 1. Potassium nitrate                    Eg 2. Magnesium phosphate
react together (see right). Then react                                    K+ has one plus charge                     Mg2+ has two plus charges
them in appropriate quantities so they               ACID                 SO42- has two minus charges                PO43- has three minus charges
exactly neutralise each other. You can
either calculate the right amounts                                        You need two K+ to balance out one        So you need three Mg2+ to balance out
(see Unit C4) or find it experimentally                                   SO42- so the formula is K2SO4             two PO43- so the formula is Mg3(PO4)2
from a titration.                                                Finally, to write a balanced equation, you need to get the right number of waters, the simplest way is
                                                                 to remember that each ‘H+’ from an acid makes one water.
Once you have done this you can use                                Eg 1. Potassium hydroxide and sulphuric acid Eg 2. Magnesium phosphate
the appropriate techniques to separate                             As we have seen it makes K2SO4 which requires As we have seen it makes Mg3(PO4)2 which
the salt from the rest of the solution                             one H2SO4 and two KOH. Two H2O are made           requires two H3PO4 and three Mg(OH)2. Six H2O
(See Unit C2).                                                     since the one H2SO4 produces two H+ ions          are made since each of the two H3PO4 produces
                                                                                                                     three H+ ions.
                                 ALKALI +                                    H2SO4 + 2KOH K2SO4 + 2H2O
                                                                                                                         2H3PO4 + 3Mg(OH)2 Mg3(PO4)2 + 6H20
                                INDICATOR
TESTING FOR IONS: Most of these involve forming insoluble precipitates – they go cloudy.
   C8: ACIDS, BASES AND SALTS
                                                                     Test for...             By....             Positive                          The reaction
        – Chemical Testing                                                                                       result
                                                                    Chloride ions, Add acidified silver White precipitate          Forms insoluble silver chloride:
TESTING GASES                                                       Cl-            nitrate                                         Cl-(aq) + AgNO3(aq)   AgCl(s) + NO3-(aq)
Hydrogen:
•A test tube of hydrogen produces a ‘squeaky pop’ with a
lighted splint                                                      Sulphate ions, Add acidified           White precipitate       Insoluble barium sulphate formed:
Oxygen:                                                             SO42-          barium nitrate                                  SO42-(aq) + Ba(NO3)2(aq) BaSO4(s) + 2NO3-(aq)
•A test tube of oxygen can re-light a glowing splint.
                                                                    Carbonate          Add acid and        Rapid gas formation The acid reacts with carbonate to make
Chlorine:
                                                                    ions, CO32-        bubble the gas      which turns         carbon dioxide gas:
•Bleaches the colour from damp litmus paper.
                                                                                       formed in           limewater cloudy CO32-(s) + 2H+(aq) CO2(g) + H2O(l)
Ammonia:                                                                               limewater                               The CO2 reacts with limewater to make
•Turns damp red litmus paper blue.                                                                                             insoluble calcium carbonate.
Carbon dioxide:                                                     Nitrate ions,      Boil with sodium    Red litmus paper    The nitrate gets reduced by aluminium
•Turns limewater cloudy.                                            NO3-               hydroxide and       turns blue          which is a strong reducing agent and forms
                                                                                       aluminium foil.                         ammonia.
                                                                                       Test the gas with
OXIDES                                                                                 damp red litmus                             Ammonia is an alkali so can turn the red
The oxides of most metals are basic (the opposite of acidic). For                      paper.                                      litmus paper blue.
example sodium oxide (Na2O) forms the alkali sodium                 Copper (II),       Add sodium             Blue precipitate     Insoluble copper (II) hydroxide formed:
hydroxide when it reacts with water.                                Cu2+               hydroxide followed that dissolves when      Cu2+(aq) + 2NaOH(aq) Cu(OH)2(s) + 2Na+(aq)
                                                                                       by ammonia             ammonia added        When ammonia is added a soluble complex
Most oxides of non-metals are acidic. For example, sulphur                             solution                                    forms so the precipitate dissolves.
trioxide (SO3) forms sulphuric acid when it dissolves in water.
                                                                    Iron (II), Fe2+    Add sodium             Green precipitate    Insoluble iron (II) hydroxide formed:
                                                                                       hydroxide followed insoluble in             Fe2+(aq) + 2NaOH(aq) Fe(OH)2(s) + 2Na+(aq)
Some oxides can behave like acids or bases and are called
                                                                                       by ammonia             ammonia              Ammonia does not react with the iron (II)
amphoteric. For example aluminium oxide (Al2O3) can react
                                                                                       solution. Tests
                                                                                        Yet More                                   hydroxide so it does not dissolve.
with the alkali NaOH to from sodium aluminium hydroxide                                 You need to remember these chemical
(NaAl(OH)4) or with hydrochloric acid to form aluminium             Iron (III), Fe3+   Add sodium
                                                                                        tests:                Brown precipitate    Insoluble iron (III) hydroxide formed:
chloride (AlCl3)                                                                       hydroxide(see Unit C7)
                                                                                        •Oxygen    followed insoluble in           Fe3+(aq) + 3NaOH(aq) Fe(OH)3(s) + 3Na+(aq)
                                                                                       by ammonia lighting a test-tube of H
                                                                                        •Hydrogen –           ammonia              Ammonia does not react with the iron (III)
                                                                                                                               2
ACID ENVIRONMENTS                                                                      solution.
                                                                                        with a splint gives a squeaky pop          hydroxide so it does not dissolve.
Acid soils grow poor crops so the acidity is reduced by             Zinc, Zn2+         Add sodium             White precipitate
                                                                                        •Carbon dioxide – when bubbled             Insoluble zinc hydroxide formed:
neutralising it with lime (CaO, calcium oxide)                                          through limewater soluble in both
                                                                                       hydroxide followed it turns it cloudy.      Zn2+(aq) + 2NaOH(aq) Zn(OH)2(s) + 2Na+(aq)
                                                                                       by ammonia             ammonia or more      Both ammonia and sodium hydroxide react
Acidic gases from factory chimneys (like sulphur dioxide) can                          solution or more sodium hydroxide           with the zinc hydroxide to form a soluble
dissolve in the water in clouds to form harmful acid rain.                             sodium hydroxide.                           complex.
GROUP I (Li, Na, K....)                               GROUP VII (F, Cl, Br, I...)
                                                                   The metals of Group I (aka the alkali metals) are     The elements of Group VII are better known as
       C9: THE PERIODIC TABLE                                      soft, silvery grey, reactive metals. Down the group   the halogens. As we go down the group they get:
                                                                   they get:                                                       •Less reactive
                                                                              •Softer                                              •Higher melting point (Cl2 is gas, Br2 is
                                                                              •Lower melting point                                 liquid, I2 is solid)
THE PERIODIC TABLE                                                            •More reactive                                       •Darker colour (Cl2 is pale green, Br2 is
The periodic table is arranged in order of increasing proton       They all react with water as follows:                           reddy-brown, I2 is dark brown)
number – starting at Hydrogen with a proton number of one             Metal + water metal hydroxide + hydrogen           They will react with ions of other halogens (halide
and working along the rows.                                        •Lithium + water lithium hydroxide + hydrogen         ions) that are below them in the group. For
                                                                   • Li       + H2O             LiOH       +    H2       example:
Periods:
                                                                   •Lithium reacts the slowest, Na reacts faster, K                      Cl2 + 2Br- 2Cl- + Br2
The rows in the periodic table are called periods. Going along a
                                                                   reacts faster still and so on.                        Because Cl is more reactive than Br. However,
period, the elements change from metals to non-metals.
                                                                                                                                         Br2 + Cl- no reaction
Usually, one or two elements in the period are called
                                                                                                                         As Br is less reactive than Cl.
metalloids – these have some properties of a metal and some
properties of a non-metal.
                                                                   TRANSITION ELEMENTS                                   GROUP 0/VIII (He, Ne, Ar, Kr....)
Groups:                                                            These are the metals in the long middle block of      The gases of Group 0 are called the Noble Gases
These are the columns in the periodic table. Elements in the       the periodic table.                                   because they are very unreactive. This is because
same group share similar properties.                                                                                     they have full outer shells of electrons which is
                                                                   Their important properties include:                   very stable.
Groups I and II are always metals. Groups VII and 0/VIII are                •High melting/boiling points
always non-metals and elements in groups III, IV, V and VI can              •High densities                              They exist as single atoms rather than molecules.
be metals, metalloids or non-metals depending on the period.                •Form strongly coloured compounds
                                                                            •(Often) Act as catalysts – both as          They are used whenever an inert (unreactive)
The Periodic Table and Atomic Structure:                                    elements and when combined in                atmosphere is needed. For example:
The periodic table can be used to work out the arrangement of               compounds                                    •Light Bulbs – Argon surrounds the coiled
electrons:                                                                                                               filament as even when white hot, it won’t react.
         •Period number = number of shells
                                                                                                                         Helium has a very low density (1/7th that of air)
         •Group number = electrons in outer shell
                                                                                                                         so is used to make airships and blimps float.
For example: Chlorine is in Period 3 and Group VII so it has 3
electron shells and 7 electrons in the outer shell.                METALS (really belongs in C10 but didn’t quite fit)           •High melting/boiling point
                                                                   Most of the known elements are metals.                        •Sonorous – ‘ring’ when hit
                                                                                                                                 •Ductile – can be pulled into wires
                                                                   All metals:
                                                                            Conduct electricity, conduct heat, are       Many metals react with:
                              Cl                                            shiny                                              •Acids – to form salt and hydrogen
                                                                                                                               •Oxygen – to form (basic) oxides
                                                                   Most metals are also:                                       •Sulphur – to form sulphides
                                                                          •Malleable – can be beaten into shape          When metals bond to non metals they form ionic
                                                                          •Strong                                        bonds.
REACTIVITY OF METALS                                                                  REACTIVITY SERIES
                                                                     The reactivity of metals can be seen by the way they react with steam or
                                                                                                                                                                      MOST REACTIVE
                   C10: METALS                                       with acid (see Unit C6 for the reactivity series).
                                                                                                                                                                       Potassium, K
                                                                     Reaction with water (see Unit C2 for details of this reaction):
                                                                                                                                                                       Sodium, Na
                                                                     The most reactive metals (K-Ca) react with cold water, fairly reactive metals
                                                                                                                                                                       Calcium, Ca
EXTRACTING METALS FROM THEIR ORES                                    (Mg-Fe) will only react with steam whereas the least reactive metals (Sn-
                                                                                                                                                                      Magnesium, Mg
Rocks that contain a significant amount of a metal are called        Pt) don’t react at all.
                                                                                                                                                                      Aluminium, Al




                                                                                                                                                         REACTIVITY
ores. The metals are present as compounds – often oxides or          Reaction with dilute acids (see Unit C9 for details)                                               (Carbon, C)
sulphides of the metal. For example lead can be extracted from       The reaction of metals with acids shows a similar patter with the most                               Zinc, Zn
an ore called galena (PbS, lead sulphide).                           reactive metals (K-Ca) reacting violently, the fairly reactive metals (Mg-Pb)                        Iron, Fe
Metals that are less reactive than carbon can be extracted by        reacting gradually more slowly and the least reactive metals (Cu-Pt) not                              Tin, Sn
using carbon as a reducing agent (to steal the oxygen/               reacting at all.                                                                                     Lead, Pb
sulphur). More reactive metals are extracted by electrolysis.                                                                                                         (Hydrogen, H)
                                                                     Displacement Reactions
                                                                                                                                                                        Copper, Cu
Iron is less reactive than carbon so can be reduced by it. This is    The reactivity of metals relates to how easily they form ions, more
                                                                                                                                                                         Silver, Ag
done in a blast furnace. Study the diagram then read the              reactive metals like K form K+ ions much more easily than less reactive
                                                                                                                                                                         Gold, Au
following:                                                            metals like Cu can form Cu+ ions. A more reactive metal will reduce a less
                                                                                                                                                                       Platinum, Pt
•Step 1: Carbon (coke) reacts with oxygen (from the hot air           reactive metal:
blast)                                                                                                                                                                LEAST REACTIVE
                                                                      Eg 1. Reaction with aqueous ions
          C (s)+ O2(g) CO2(g)                                                  Zinc + Copper sulphate Zinc sulphate + copper
•Step 2: Carbon dioxide reacts with more carbon to make                        Zn(s) + Cu2+(aq) + SO42-(aq) Zn2+(aq) + SO42-(aq) + Cu2+(aq)             USES OF METALS
carbon monoxide                                                       This happens because Zn is more reactive than Cu so is able to reduce it.         Metals have many uses
          CO2(g) + C(s) 2CO(g)                                                                                                                          including:
•Step 3: Carbon monoxide reduces the iron oxide (iron ore) to         Eg 2. Reaction with metal oxides                                                  •Aluminium – and its
make molten liquid iron.                                                       Iron oxide + aluminium aluminium oxide + iron                            alloys used for aircraft
          Fe2O3(s) + CO(g) Fe(l) + CO2(g)                             This happens since Al is more reactive than Fe so is able to reduce it.           as they have low density
The limestone (CaCO3) reacts with impurities such as silicon to       These are called displacement reactions because the more reactive metal           and great strength
form an easy-to-collect waste called slag (calcium silicate,          takes the place of the less reactive metal.                                       •Aluminium – used for
CaSiO3): CaCO3 +SiO2 CaSiO 3+ CO2                                                                                                                       food containers as the
                                                                     ALLOYS                                    Alloys are often harder than the         waterproof oxide layer
                                                                     Alloys are ‘mixtures of metals’           metals they are made from. In pure       on its surface prevents
                                                                     (although sometimes they can              metals atoms are neatly lined up         corrosion which could
                                                                     contain a non-metal) that are made        meaning they can slip past each          taint the food.
                                                                     by mixing molten metals.                  easily when hit. In alloys there are     •Zinc - used to protect
                                      Step 3 happens here                                                      atoms of different sizes which don’t     steel either by coating it
                                                                     Alloys often have very different                                                   (galvanising) or as
                                                                                                               line up neatly so can’t slip past each
                                                                     properties to the metals they are                                                  sacrificial protection –
                                      Step 2 happens here                                                      other so easily making them harder.
                                                                     made from and by varying their                                                     i.e. on a ship’s hull – a
                                                                                                                   Element              Alloy
                                      Step 1 happens here            metals can be tailored to have                                                     lump of zinc prevents
                                                                     specific desirable properties – this is                                            rust as it is more
                                                                     called metallurgy.                                                                 reactive so corrodes
                                                                                                                                                        instead of the steel hull.
CARBON DIOXIDE, CO2                                    Thermal decomposition of carbonates e.g.:
                                                                      There are many ways to produce CO2 including:                       CaCO3 CaO + CO2
          C11: AIR AND WATER
                                                                      Burning carbon-containing fuels:                       As a by product of respiration in living cells:
                                                                                  CH4 + 2O2 CO2 + 2H2O                                   C6H12O6 + O2 CO2 + H2O

WATER, H2O                         Drinking Water                     AIR POLLUTION                                                        RUSTING
Water is the most useful           Water drawn from rivers can        Many of man’s activities pollute the air. Pollutants include:        Rust (hydrated iron (III) oxide) affects
compound known to man. In contain pollutants such as                                                                                       most structures made of iron (or
                                                                      Carbon monoxide, CO
the home it is used for            fertilizers, dissolved organic                                                                          steel) and causes huge damage:
                                                                      •Formed when fuels burn without enough O2.
cooking, cleaning and              matter, harmful bacteria and                                                                              Iron + oxygen + water hydrated
                                                                      •CO prevents the blood from carrying oxygen leading to death
transporting waste. In industry industrial waste that make it                                                                                           iron (III) oxide
                                                                      by suffocation
it is used for cooling hot         unfit to drink. At treatment                                                                            Rust can be prevented by taking
machinery, cleaning and as a plants, two main processes are           Sulphur dioxide, SO2                                                 steps making sure either oxygen or
solvent. Water is useful for       used to make water safe:           •Formed by burning fossil fuels containing sulphur impurities.       water can’t reach the iron. The main
cleaning as it is able to dissolve                                    •Dissolves in water in clouds to form sulphurous acid which          ways to do this involve covering the
                                   Filtration – the water is passed   falls as acid rain                                                   metal with: paint (bridges and other
many types of ‘dirt’.
                                   through a series of increasingly   •Acid rain corrodes buildings and damages ecosystems                 structures); oil/grease (moving
A simple test for water is that fine filters that trap suspended      •Irritates the respiratory system when inhaled.                      machine parts) or another metal such
it is able to turn cobalt chloride particles. Activated carbon is                                                                          as zinc (galvanising).
paper from blue to pink.           used to filter out dissolved       Nitrogen Oxides, NOx
                                   pollutants.                        •Formed by burning fuels in engines and power stations.              FERTILISERS
                                   Chlorination – chlorine is         •Dissolves in cloud water to form nitric acid thus acid rain.        Fertilisers are chemicals applied to
                                   added to the water which           •Irritates the respiratory system when inhaled.                      plants to improve their growth and
                                   destroys bacteria.                                                                                      increase the amounts of products
                                                                      NITROGEN AND AMMONIA             to make an economical               such as fruits, nuts, leaves, roots and
AIR                              man’s activities such as             Ammonia (NH3) is a smelly gas.   amount of ammonia. To speed         flowers that they produce for us.
Air is a mixture of gases        burning fossil fuels and             One way to produce it is to      it up, the reaction is done at      They work by supplying plants with
comprising:                      deforestation. This is a concern     react ammonium (NH4+) salts      high temperature (~450OC)           the vital elements they need
                                 as CO2 is able to absorb the         with an alkali (OH-) eg:         with an iron oxide catalyst.        including Nitrogen - in the form or
                                 infrared radiation (heat)              NH4Cl + NaOH NH3 + H2O         High pressure (~200 times           nitrate (NO3- containing) salts;
                                 radiated by the ground when              .                + NaCl      atmospheric pressure) is used       phosphorous – in the form of
                                 the sun heats it up (the                                              to increase the proportion of       phosphate (PO43- containing) salts
                                 greenhouse effect). More CO2         Ammonia is vital to produce      NH3 formed.                         and potassium (K+ containing) salts.
                                 means more trapped heat              the nitrates used in fertilisers
                                 leading to global warming.           and explosives. It is produced The nitrogen comes from the           CATALYTIC CONVERTERS
                                                                      by the Haber process:            air and hydrogen comes from
The ‘other’ is mostly argon                                                                            reacting methane (CH4) gas          Fit to a car’s exhaust and use a
                                 Global warming is a major                 N2(g) + 3H2(g)     2NH3
with CO2, water vapour and                                                                             with steam.                         platinum or palladium catalyst to
                                 problem because
many trace gases.                                                     The reaction is reversible                                           convert harmful gases to safer gases:
                                 temperatures are rising faster                                        Nitrogen and oxygen can be
                                                                      which means much of the                                              for example nitrogen oxides are
Although the proportion of       than nature’s ability to adapt –                                      separated from air by cooling it
                                                                      product turns back to                                                reduced back to nitrogen gas and
carbon dioxide is very small     this makes the future of both
                                                                      reactants as soon as it is made, to a liquid and using fractional    oxygen gas.
(~0.04%) it is increasing due to farming and of our ecosystems
                                 very uncertain.                      this means it takes a long time distillation.
THE CONTACT PROCESS
                                                                        Sulphuric acid is produced by the Contact Process.
                  C12: SULPHUR
                                                                        This involves are three chemical reactions. First sulphur is burnt in air to produce sulphur dioxide
                                                                        (SO2):
                                                                                                                      S + O2 SO2
SULPHURIC ACID, H2SO4
Sulphuric acid is a very important compound used in many                Secondly SO2 is reacted with further oxygen to make sulphur trioxide (SO3):
industrial processes including:
           •Fertiliser production                                                                                        2SO2 + O2   SO3
           •Oil refining
           •Paper making                                                This reaction is reversible, so to maximise the amount of SO3 made, they use a high temperature
           •Steel making                                                (425OC), medium-high pressure (1-2 times atmospheric pressure) and a catalyst (vanadium (V) oxide,
It is also the acid found in car batteries.                             V2O5).
Sulphuric acid is a strong acid which when diluted in water             Finally, the sulphur trioxide is produced by first dissolving it in sulphuric acid to make oleum (H2S2O7)
produces two protons and a sulphate ion:                                which then makes more sulphuric acid on the addition of water:

                   H2SO4(l)   2H+(aq) + SO42-(aq)                                                                   SO3 + H2SO4      H2S2O7
It exhibits all the reactions typical of an acid as seen by its                                                    H2S2O7 + H2O      2H2SO4
reactions with metals, alkalis, metal oxides and carbonates.
(see Unit C8 for details).                                              Note: trying to dissolve SO3 directly in water produces a very fine mist of sulphuric with limited uses.




                                                                  This is another tiny unit with very little to learn.
USES OF CALCIUM CARBONATE
                                                                  Powdered calcium carbonate can be added directly to soils to raise their pH (reduce their acidity).
            C13: CARBONATES                                       We can also make calcium oxide (CaO, aka ‘quicklime’) by heating powdered calcium carbonate to
                                                                  about 1000OC, producing carbon dioxide as a by-product:

CALCIUM CARBONATE, CaCO3                                                                                     CaCO3(s)   CaO(s) + CO2(g)
Calcium carbonate is a very common mineral and makes up the
bulk of many common rocks including:                              This is called a thermal decomposition as heat is used to break down or decompose the calcium
         •Chalk                                                   carbonate. Calcium oxide is one of the key ingredients in cement.
         •Limestone
         •Marble                                                  Another useful product, calcium hydroxide (Ca(OH)2, ‘slaked lime’) is made by adding water to
                                                                  calcium oxide:
Whilst solid limestone is often used in construction, powdered                                          CaO + H2O Ca(OH)2
limestone has many industrial uses.
                                                                  Slaked lime has many uses including:
                                                                           •Raising soil pH quickly (when powdered calcium carbonate might take too long)
                                                                           •Neutralising acidic industrial waste
                                                                           •Sewage treatment – it helps small particles of waste to clump together into easily
                                                                           removed lumps.




                                                                 Another mini-unit with very little in it!
Chemistry revision pack_-_2012
Chemistry revision pack_-_2012
Chemistry revision pack_-_2012

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Chemistry revision pack_-_2012

  • 1. CHEMISTRY REVISION GUIDE for CIE IGCSE Coordinated Science (2012 Syllabus) This revision guide is designed to help you study for the Some very useful websites to help you further your chemistry part of the IGCSE Coordinated Science course. understanding include: •http://www.docbrown.info/ - whilst not the The guide contains everything that the syllabus says you prettiest site this contains a lot of very useful and need you need to know, and nothing extra. nicely explained information. •http://www.bbc.co.uk/schools/gcsebitesize/scienc The material that is in the supplementary part of the e/ - well presented with many clear diagrams, course (which can be ignored by core candidates) is animations and quizzes. Can occasionally lack highlighted in dashed boxes: depth. •http://www.chemguide.co.uk/ - whilst mostly targeted at A-Levels this site contains very detailed information suitable for those looking to deepen their knowledge and hit the highest grades. Whilst this guide is intended to help with your revision, it should not be your only revision. It is intended as a Finally, remember revision is not just reading but should starting point but only a starting point. You should make be an active process and could involve: sure that you also read your text books and use the •Making notes internet to supplement your study in conjunction with •Condensing class notes your syllabus document. •Drawing Mind-maps •Practicing past exam questions Whilst this guide does contain the entire syllabus, it just •Making flashcards has the bare minimum and is not in itself sufficient for The golden rule is that what makes you think makes you those candidates aiming for the highest grades. If that is learn. you, you should make sure you read around a range of sources to get a deeper knowledge and understanding. Happy studying, Mr Field.
  • 2. C1: THE PARTICULATE NATURE OF MATTER Solids, Liquids and Atom: The smallest particle An atom: of matter Some atoms: Gases Molecule: A small particle Molecules of an element: Molecules of a made from more than one compound: atom bonded together Element: A substance A solid element: A gaseous element: SOLIDS LIQUIDS AND GASES made of only one type of The particles in solids, liquids and gases are held near to each other by forces of atom attraction. The strength of these forces determines a substance’s melting and boiling points. In a solid, the forces of attraction are strongest, holding the particles tightly in Compound: A substance A solid compound A gaseous compound: position. As the solid is heated, and the particles vibrate faster, these forces are made from two or more partially overcome allowing the particles to move freely as a liquid – this is called different elements bonded melting. As the liquid is heated more, the particles gain so much energy that the together forces of attraction break completely allowing particles to ‘fly around’ as a gas – this is called boiling. The reverse of the these processes are condensing and freezing. Under specific conditions, some solids can turn straight to gases – a process called subliming (the reverse is called desubliming). PROPERTIES Mixture: A substance A mixture of compounds and elements: Solids Liquids Gases made from two or more •Have a fixed shape •Take the shape of their •Take the shape of their elements or compounds •Can’t be compressed container container mixed but not joined •Particles close together •Can’t be compressed •Can be compressed in a regular pattern •Particles close together •Particles widely spaced •Particles vibrate around but disordered in random order a fixed point •Particles move freely •Particles moving very fast.
  • 3. PAPER CHROMATOGRAPHY best possible separation of spots. C2: EXPERIMENTAL Paper chromatography is a technique that can be used to separate mixtures of dyes or pigments and TECHNIQUES is used to test the purity of a mixture or to see what it contains. Firstly a very strong solution of the mixture is prepared which is used to build up a FILTRATION small intense spot on a piece of absorbent paper. Used to separate solids This is then placed in a jar of solvent (with a lid). As from liquids. The mixture the solvent soaks up the paper, it dissolves the is poured through a filter mixture-spot, causing it to move up the paper with paper in a funnel. The the solvent. However since compounds have liquid can pass through different levels of solubility, they move up the the small holes in the paper at different speeds causing the individual filter paper (to become components to separate out. The solvent or the filtrate) and the solid combination of solvents can be changed to get the gets left behind (called the residue). PURITY FRACTIONAL DISTILLATION It is important for chemists to be able to purify the When the liquids being distilled have similar CRYSTALLISATION compounds they make, this is because the boiling points, normal distillation can’t separate Crystallisation is used to separate mixtures of solid dissolved in impurities could be dangerous or just un-useful. them completely but simply gives a purer liquid and relies on the fact that solids are more soluble at This is especially true for chemists making mixture. In this case a fractionating column is higher temperatures. A solution containing a solid is cooled compounds that are consumed by people such as used. This provides a large surface area for down until crystals form in the solution, these can then be drugs or food additives since the impurities may be condensation meaning much purer ‘fractions’ are collected by filtration. toxic which would be very bad news! produced. The most important use of this is separating crude oil into it’s useful components. The related technique of recrystallisation can be used to WHICH TECHNIQUE? separate a mixture of two soluble solids by taking advantage of You need to be able to select appropriate methods the difference in their solubility. The mixture is dissolved in the to separate a given mixture. The key to this is look smallest possible amount of hot solvent. As the solution cools, for differences in the properties of the the less soluble compound forms crystals that can be collected components of the mixture such as their state, by filtration whilst the more soluble compound stays dissolved. solubility, melting/boiling point and so on. Then pick the method that best takes advantage of this DISTILLATION difference. In distillation a mixture of liquids is separated using the MELTING/BOILING POINTS differences in their boiling No two substances have the exact same melting points. The mixture is heated and boiling points. We can take advantage of this until the liquid with the lowest to test the purity of a compound we have made. If boiling point boils, the vapours we know what the melting or boiling point of the then condense on the cold pure compound should be, we can then measure surface of the condenser and the melting or boiling point of a sample we have the pure(er) liquid is collected. produced and the closer it is to the pure value, the more pure it is likely to be.
  • 4. C3: ATOMS, ELEMENTS AND A NOBLE MATTER Group VIII: Noble Gases H The Noble Gases (He, Ne, Ar Group VII: Halogens COMPOUNDS – Structures and Non-metals Group I: Alkali Metals Group II: Alkali-Earth etc) have full outer shells containing either 2 or 8 Bonding electrons. This is very stable which is why the Noble gases ELECTRON ARRANGEMENT/CONFIGURATION Transition Metals are so unreactive. Electrons are arranged around atoms in specific shells. The Other most important shell is the outer one as this controls an Other elements tend to Metals atom’s chemistry. We call the electrons in the outer shell react in such a way as to ‘valence electrons’ because they are used for bonding. The achieve a full outer shell by number of electrons in the outer shell is the same an gaining or losing electrons element’s group number. until they achieve this Noble Gas configuration. Lanthanides and Actinides (metals) The number of electrons around an atom is given by the atom’s proton number. They are arranged in shells as follows: •1st Shell – Holds two electrons CHEMICAL VS PHYSICAL STRUCTURE OF THE PERIODIC TABLE (PT ISOTOPES •2nd/3rd/4th Shells – Hold 8 electrons CHANGES on last page!) Isotopes are atoms •Example 1: Carbon. Proton •Example 2: Chlorine. Proton Physical changes are reversible Elements arranged in order of increasing with the same proton number is 6 which means number is 17 which means whereas chemical changes are proton number. number but different there are 6 electrons: 2 in the there are 17 electrons: 2 in not. Periods: The rows in the periodic table. nucleon number. 1st shell and 4 in the second the 1st shell, 8 in the second •For example Li, C and O are all in period 2. and 7 in the 3rd. For example if you melted some Groups: The columns in the PT. For example carbon solid sugar to a liquid and then •Use roman numbers: I, II, III, IV, V, VI, VII, has two main left it to cool, it would freeze C VIII isotopes – C-12 and back to solid sugar – this is a •Eg. F, Cl, Br, I are all in Group VII C-13. Carbon has a Cl physical change. If you took the •Elements in the same group have similar proton number of 6 same sugar and burned it to properties and react in similar ways: the so they both contain Checking Your Answer: To check produce carbon dioxide and halogens all react in the same way with 6 protons and 6 you are right, the period gives the water, there would be no easy sodium to form sodium fluoride (NaF), electrons but C-12 number of shells and the group gives the number of electrons way to turn those back to sugar – sodium chloride (NaCl), sodium bromide has 6 neutrons and C- in the outer shell. For example chlorine is in Period 3 and this is a chemical change – new (NaBr) and sodium iodide (NaI) 13 has 7. Group VII so it has 3 shells and 7 electrons in the outer shell. substances are made. Ions: The configuration of ions is the same as for atoms but ATOMIC STRUCTURE what the element is. you have to take electrons away from positive ions and add Eg 1: Boron has 5 protons, Atoms are made of: extra for negative ions. For example O/O2- Li/Li+ In a square on the periodic table 6 neutrons (ie 11-5) and 5 Protons: mass = 1, charge = +1 the smaller number, the proton electrons Neutrons: mass = 1, charge = 0 number, gives the number of Electrons: mass = 0, charge = -1 protons or electrons and the Eg 2: Phosphorus has 15 O O2- Li Li+ The numbers of each vary from bigger number, the nucleon protons, 16 neutrons (ie element to element but it is the number the number of protons 31-16) and 15 electrons number of protons which decides and neutrons together.
  • 5. C3: ATOMS, ELEMENTS AND Group VIII: Noble Gases IONIC BONDING An ionic bond is the attraction between two oppositely charged ions. Cations (positive) are formed Group VII: Halogens COMPOUNDS – Bonding and Non-metals when atoms (usually metals) lose electrons. Anions (negative) are formed when atoms (usually non- metals) gain electrons. Structure Atoms will lose or gain electrons until they have a complete outer shell: elements in Groups I, II and III MOLECULES When a substance melts, it is will lose 1, 2 and 3 electrons respectively to form 1+, 2+ and 3+ ions. Atoms in Groups V, VI and VII A molecule is a small particle these weak intermolecular gain 3, 2 and 1 electrons to form 3-, 2- and 1- ions. In an ionic compound the number of positive and made from (usually) a few forces that break NOT the negative and charges must cancel out to neutral. non-metal atoms bonded strong covalent bonds. Example: NaF, sodium in Group I forms a 1+ ion Example: Li2O, lithium in Group I forms a 1+ ion together. and fluorine in group VII forms a 1- ion so one but oxygen in Group VI forms a 2- ion so two Li+ Molecular compounds have Na+ is needed to balance out one F- are needed to balance out one O2- The atoms in a molecule are low melting points and are joined by strong covalent volatile (evaporate easily) due bonds. In a solid each to the weak intermolecular molecule is held close to its forces, and insulate electricity F- Na+ Li+ O2- Li+ neighbour by weak as all electrons are stuck in intermolecular forces. bonds and so unable to move. COVALENT BONDING GIANT IONIC LATTICES A covalent bond forms between two atoms and is the attraction The positive and negative ions in of two atoms to a shared pair of electrons. Small groups of an ionic compound don’t form covalent bonded atoms can join together to form molecules. molecules but form crystals made GIANT COVALENT LATTICES Graphite: made of carbon of a repeating pattern of positive A crystal made of a repeating atoms arranged in hexagonal The atoms share enough electrons to complete their outer and negative ions called a giant pattern of atoms joined with sheets with long weak bonds shells. Example: H O*, hydrogen is Example: CO *, carbon is has ionic lattice. Eg sodium chloride: 2 2 covalent bonds that repeats between the sheets. This has one valence electron and four valence electrons so millions of times in all means the sheets can easily needs one more to complete needs four more to complete directions. separate making graphite a the 1st shell, oxygen has six its outer shell, oxygen needs good lubricant: valence electrons electrons so two more. Thus each carbon Diamond is made of carbon needs two more. Thus one will react with two oxygens, atoms arranged so that each C oxygen will react with two sharing two electrons with is bonded in a pyramid hydrogens: each one. A bond involving arrangement to 4 others. This two shared pairs is a double makes it very hard, ideal for use Properties of Ionic Compounds bond. in industrial drills: Silicon (IV) oxide (SiO2) has a H O H When you melt or dissolve an structure with each Si ionic compound it conducts O C O electricity because the ions are joined to 4 O and each O joined to 2 Si. It is free to move towards the positive the main ingredient *Nb: In these diagrams only draw the outer shell and use and negative electrodes. When in glass. different shapes/colours to show where electrons have come solid the ions are stuck in position from. You should be able to draw at least: H2O, CH4, Cl2, HCl, H2, and there are no free electrons so N2, O2, CO2, C2H4 they don’t conduct.
  • 6. CHEMICAL FORMULAS You may be asked to C4: STOICHIOMETRY – Formulas tell you the atoms that make up a write a formula given a compound diagram of a molecule Formulas and Equations Eg 1. H2O – two H, one O for example glucose. By counting you can see Eg 2. C2H6O – two C, six H, one O there are 6 carbons, Eg 3. Mg(OH)2 – one Mg, two O, two H* SYMBOL EQUATIONS 12 hydrogens and Eg 4. CH2(CH3)2 – three C, 8 H* •Show the reactants you start with and the products you 6 oxygens so the make using symbols not words *In this case everything in brackets is doubled formula is C6H12O6 •Must contain an arrow ( ) NOT an equals sign (=) •Must be balanced – same number of atoms on each side. WORD EQUATIONS IONIC FORMULAS •Balancing is done by placing numbers called coefficients in •These tell you the names of the chemicals involved in You can deduce the formula of an ionic front of the formulas for the compounds/elements. For reaction compound if you know the charges on the example, ‘O2‘ means there is one oxygen molecule involved in •The left hand side shows you what you start with and ions involved. The total positive charge a reaction but ‘2O2’ would mean there are two. is called the reactants must balance out the total negative charge Example:. CH4(g) + O2(g) CO2)g) + H2O(g)* •The right hand side shows you what you make and is so you must look for the lowest common This is unbalanced as there are 4 ‘H’ on the left but only 2 ‘H’ called the products multiple (LCM) of the charges. on the right. This must be corrected by placing a ‘2’ in front of •The left and right are connected by an arrow ( not the ‘H2O’ so there are now 2 waters: Eg1. Calcium nitrate is made of Ca2+ ions and ‘=‘) which means ‘makes’ or ‘becomes’ CH4 (g) + O2(g) CO2(g) +2H2O(g) NO3- ions. The LCM of 2 and 1 is 2 which •When you react a metal with oxygen to make a metal Now the ‘H’ balances but there 4 ‘O’ on the right and only 2 means you need 1 Ca2+ ion and 2 NO3- ions oxide, the equation might be: on the left. This must be balanced by placing a ‘2’ in front of so the formula is Ca(NO3)2 Iron + oxygen iron oxide the ‘O2’ so that there are 2 oxygen molecules: •Many fuels burn in oxygen to produce carbon dioxide Eg2. Aluminium oxide is made of Al3+ ions CH4(g) + 2O2(g) CO2(g) + 2H2O(g) and water for example: and O2- ions. The LCM of 2 and 3 is 6 which Now there is 1 ‘C’, 4 ‘H’ and 4 ‘O’ on each side so it balances. Methane + oxygen carbon dioxide + water means you need 2 Al3+ ions and 3 O2- ions so the formula is Al2O3. In ionic equations, we tend to look only at the ions that actually change. For example, when iron reacts with copper CHEMICAL MASSES sulphate to form iron sulphate and copper the equation is: The relative atomic mass (Ar) of an element is the Example 1: Water, H2O Fe(s) + Cu2+(aq) + SO42-(aq) Fe2+(aq) + SO42-(aq) + Cu(s) mass of one atom relative to 1/12th the mass of C- The Ar for H and O are 1.01 and 16.00 so: In this case, the sulphate ion (SO42-) remains unchanged (we 12. It is just a number that allows us to compare Mr(H2O) = 2 x 1.01 + 1 x 16.00 = 18.02 call it a spectator ion) so it can be left out of the equation to the mass of atoms of different elements. Ar can be give: found on the periodic table as the ‘large’ number Example 2: Magnesium Hydroxide, Mg(OH)2 Fe(s) + Cu2+(aq) Fe2+(aq) + Cu(s) in each square. For example Ar for carbon is 12.01 The Ar for Mg, O and H are 24.31, 16.00 and 1.01: This allows us to see more clearly the actual chemical changes and for iron is 55.85. Ar has no units since it is only Mr(Mg(OH)2) = 1 x 24.31 + 2 x 16.00 + 2 x 1.01 taking place. a relative number, allowing us to compare things. = 58.33 Note: You can’t change the little numbers (ie the 2 in H2O ) as this changes the compound to something completely The relative formula mass (Mr) is the combined Ar Example 3: Decane, CH3(CH2)8CH3 different. of all the elements in the formula for a substance. The Ar for C and H are 12.01 and 1.01 Mr also has no units for the same reason as above. Mr(decane) = 10 x 12.01 + 22 x 1.01 = 142.34 *The state symbols (s), (l), (g) and (aq) are used to indicate solid, liquid, gas and ‘aqueous solution’ (dissolved in water).
  • 7. THE MOLE C4: STOICHIOMETRY – The A mole is 6.02x1023 of something. It is chosen so that a mole of something has the same mass in grams (molar mass, Mm) as its formula mass. For example the Mr of water is 18.02 so the Mm of water Mole Concept is 18.02g; the Mr of decane is 142.34 so the Mm of decane is 142.34g. Importantly this means that 18.02 g of water and 142.34g decane contains the same number of molecules. EQUATIONS AND MOLE RATIOS THE MOLES AND MASSES Equations can be used to help us calculate the numbers of moles of substances If you know the mass in grams of substance, you can calculate the number of moles involved in a reaction. We can see this by studying the following reaction: as follows: 2C2H6 + 7O2 4CO2 + 6H2O Moles = Mass */ Molar mass Q1: How many moles of CO2 are produced by burning 1.0 mol of C2H6? We say that Eg 1. How many moles is 27.03 g of H2O? C2H6 is our ‘known’ and CO2 is our ‘unknown’ so: Moles (H2O) = Mass / Molar mass = 27.03 / (2 x 1.01 + 16.00) = 1.50 mol Moles CO2 = moles known/knowns in eqn x unknowns in eqn = 1.0 /2 x 4 = 1.0 x 2 = 2.0 mol Eg 2. What is the mass of 0.05 mol of H2O. This time the equation must be Q2: If 0.01 mol of CO2 is produced, how much H2O must also be produced? This rearranged to give: time CO2 is our known and H2O is our unknown so: Mass (H2O) = Moles x molar mass = 0.05 x (2 x 1.01 + 16.00) = 0.901g Moles H2O = moles known/knowns in eqn x unknowns in eqn *Mass must be given in grams – you may need to convert from kg: x1000 = 0.01/4 x 6 = 0.0025 x 6 = 0.015 mol *You must make sure your equation is balanced or your mole ratio will be wrong. THE MOLES AND GASES One mole of any gas has a volume of 24.0 dm3 (remember dm3 is the symbol for CALCULATING REACTING QUANTITIES decimetres cubed, aka litres) at room temperature and pressure. So for a gas: Using what we know about calculating moles, we can now answer questions like: If I have 100g X, how much Y is made? The key is to convert the known to moles 1st. Moles = Volume / 24.0 Example: What volume of H2 gas would be produced by reacting 12.15g Eg 1. How many moles of CO2 are present in 60 dm3? magnesium with excess hydrochloric acid? First we need a balanced equation: Moles (CO2) = Volume / 24.0 = 60/24.0 = 2.50 mol Mg + 2HCl MgCl2 + H2 Eg 2. What is the volume of 0.20 mol of H2 gas?.This time the equation must be Then calculate moles of Mg (our known) we start with: rearranged to give: Moles Mg = mass/molar mass = 12.15/24.30 = 0.50 mol Volume (H2) = Moles x 24.0 = 0.20 x 24.0 = 4.80 dm3 Next we work out how many moles of H2 ( our unknown) we expect to produce: *The volume must be in dm3 – to convert from cm3 divide by 1000 Moles H2 = moles known/knowns in eqn x unknowns in eqn = 0.50/1 x 1 = 0.50 mol Finally we calculate the volume using our equations for a gas: THE MOLE AND SOLUTIONS Volume H2 = moles x 24.0 = 0.50 x 24.0 = 12.0 dm3 The concentration (strength) of a solution is measured in mol dm-3 (moles per decimetre cubed). A 1.0 mol dm-3 solution contains 1 mol of substance dissolved in each litre. LIMITING REACTANTS moles of H2O could you make from 3 mol Moles = Concentration x Volume* This is the reactant that will run out first. of H2 and 3 mol of O2. H2: 3/2 = 1.5, O2: Eg 1. How many moles of NaOH are present in 2.5 dm3 of a 1.5 mol dm-3 solution? It is important as this is the one you 3/1 = 3. This means there is enough O2 to Moles (NaOH) = concentration x volume = 1.5 x 2.5 = 3.75 mol should then use for your calculations. do the reaction 3 times but only enough Eg 2. 0.15 mol NaCl is dissolved in 250 cm3 water. What concentration is this? This You calculate it by dividing the number of H2 for 1.5 times so H2 is the limiting time you must rearrange the equation to: moles of reactant by the number of reactant. Thus, moles H2O = 1.5 x (2/2) = Concentration = moles/volume = 0.15/(250/1000)* = 0.60 mol dm-3 times they appear in the equation. For 1.5 mol. *The volume must be in dm3 – to convert from cm3 divide by 1000 example 2H2 + O2 2H2O. How many
  • 8. ELECTROLYSIS (right) positive copper ions move to the cathode C5: ELECTRICITY AND Electrolysis is a process in which electricity is and form copper metal. Negative chloride ions used to break compounds down into their more to the anode and form chlorine gas. CHEMISTRY elements. The mixture being electrolysed is called an electrolyte and must be liquid (either melted or dissolved) to allow the ions to move. Bubbles of gas Molten Anode Cathode Salt Solution formed Salt (positive (negative Cations (positive ions – remember they are electrode) electrode) Metal, except with reactive metals (K, ’puss-itive’) ions move to the cathode (the Cl Cl Na, Li Ca, Mg) in which case H2 gas is negative electrode) where they gain electrons, Cl Cl Cu2+ Cathode Metal produced plus a solution of metal usually forming a metal (or H). Layer of metal hydroxide Cl- Cl- Cu formed Anions (negative ions) move to the anode (the Non Metal, except sulphates in which positive electrode) where they lose electrons, Cu Anode Non-metal case O2 Cl- Cu2+ usually forming a non-metal (other than H). Cu Cations move Anions move ELECTROLYSIS OF COPPER SULPHATE to anode Cl- Cu2+ Cl- Cl- to cathode In the electrolysis of copper chloride (CuCl2) When copper sulphate is electrolysed using carbon electrodes, you produce O2 gas at the anode and a layer of Cu metal at the EXTRACTING ALUMINIUM Aluminium oxide ( the electrolyte) is dissolved in cathode. This can be used to electroplate items by setting Aluminium can’t be extracted by reduction of molten ‘cryolite’ and placed in a large carbon them as the cathode. However, when two copper electrodes aluminium oxide (Al2O3) using carbon as carbon lined vessel which acts as the cathode. A large are used, what ends up happening is a transfer of copper from is less reactive than aluminium. Instead anode made of carbon is lowered into the the anode to the cathode, this is used to purify copper. aluminium is produced by electrolysis. electrolyte. The processes that take place are: When copper is made it contains lots of impurities. The copper At the cathode: is purified by electrolysis. A large lump of impure copper is Aluminium ions gain electrons used as the anode, the electrolyte is copper sulphate solution to make liquid aluminium and the cathode is made of pure copper. Al3+ + 3e- Al(l) At the anode, instead of anions losing electrons, neutral At the anode: copper atoms lose electrons to become copper ions . Oxide ions lose electrons to Cu(s) Cu2+(aq) + 2e- make oxygen gas These then move through the electrolyte to the cathode O2- ½ O2(g) + 2e- where they become copper atoms again. The oxygen reacts with the Cu2+(aq) + 2e- Cu(s) carbon anode so it has to be replaced regularly The anode loses mass as copper atoms leave it and the cathode ELECTROLYSIS OF BRINE gains mass as copper When sodium chloride solution (brine) is atoms join it. The electrolysed , chlorine gas is produced at the impurities sink to the anode and hydrogen gas at the cathode (because bottom as a pile of sodium is too reactive). A solution of sodium sludge. hydroxide is left behind.
  • 9. QUANTIFYING ENERGY C6: ENERGY CHANGES IN Using the ideas you learn in physics about specific heat capacity, you may have to calculate the amount of energy released by one mole of a substance. CHEMICAL REACTIONS Example: When 0.250 mol of Metal X reacts fully with 500 cm3 of 2.0 mol dm-3 HCl solution, the temperature increases by 15.4OC. How much energy is released when 1.0 mol X reacts with HCl? EXOTHERMIC REACTIONS First calculate the heat evolved: Exothermic reactions get hotter – the temperature increases. Heat evolved = m.c.ΔT = 500 x 4.2 x 15.4 = 32340 J* The energy given out can be used to keep the reaction going Then calculate heat released per mole: so that once started, they don’t stop until they have run out of Heat per mole = heat evolved / moles = 32340/0.250 = 129360J = 129.4 kJ reactants. *ΔT is the temperature rise, m is the mass of the solution in grams which is assumed to equal its Important examples of exothermic reactions include: volume in cm3, c is the specific heat capacity of water which is 4.2 J K-1 g-1 •Combustion of fuels •Acid-base neutralisations •Displacement reactions •Respiration in cells ENDOTHERMIC REACTIONS Endothermic reactions reactions get colder – the temperature decreases. Generally endothermic reactions need a constant energy supply to keep them going Important examples of exothermic reactions include: •Dissolving of many (but not all) salts •Thermal decompositions Yes this unit really is this small – in fact you don’t even really need the stuff about quantifying energy, •Photosynthesis I just put it in there as it often proves useful!! •Cooking!!! ENERGY CHANGES In exothermic reactions, chemical energy stored in the reactants gets converted to heat energy. The products have less chemical energy than the reactants and the difference is the amount of heat released. In endothermic reactions, heat energy gets converted to chemical energy. The products have more chemical energy than the reactants and the difference between the two is the energy that had to be supplied to make the reaction go.
  • 10. MEASURING REACTION RATES If a reaction produces gas, you can easily measure the reaction rate by collecting the gas (either in an C7: CHEMICAL REACTIONS upturned measuring cylinder full of water or a gas syringe) and recording how much has been collected each second. RATES OF REACTION The ‘speed’ of a reaction is called its rate and is simply the amount of new product formed every second. For a chemical reaction to happen, the reacting particles need to collide with enough energy. Anything that increases the number of collisions or their energy will increase the rate. Temperature Increasing temperature increases the rate of a reaction. MEASURING REACTION RATES INVESTIGATING REACTION RATES This is because particles are moving faster which means more On a graph showing the change in concentration of reactants To investigate a factor influencing collisions and higher energy collisions. or products, the gradient of the line tells you the reaction rate: reaction rate, you must change it steeper = faster, whilst keeping the others constant. Concentration flat = stopped For example, investigating the Increasing the concentration of a solution increases the rate of effect of concentration, you could a reaction. carry out the reaction at 5 different concentrations whilst making sure This is because it means there are more particles available to the temperature, particle size and react which leads to more collisions. presence/absence of a catalyst remains the same. Surface Area/Particle size Increasing the total REDOX REACTIONS together. DANGEROUS RATES surface area of Reduction means a substances Factories that produce particles (by using loses oxygen. Oxidation means a Another way to look at this is to flammable powders (for finer powder) substance gains oxygen. For think of oxidation as the loss of example bread flour) have to increases the rate of a example: electrons and reduction as the be careful about sparks since reaction because it 2Fe2O3 + 3C 4Fe + 3CO2 gain of electrons (OILRIG). Eg: in the very fine powder particles means more particles Fe2O3 is reduced because it loses the electrolysis of molten sodium burn with a VERY high reaction at the surface are oxygen to become Fe. C is bromide. At the anode: rate causing explosions. exposed to collisions. oxidised because it gains oxygen 2Br- Br2 + 2e- to become CO2. C is called a This is an oxidation because the Similar is true underground in reducing agent because it causes bromide ions lose electrons. coal mines where gas can build Catalysts Fe2O3 to get reduced. Reactions At the cathode: up. Gas can be thought of as Catalysts are substances that speed up a reaction without like this are called redox Na+ + e- Na the finest possible powder so getting used up. Whenever a catalyst is present, the rate of reactions because an oxidation This is a reduction because the they too react explosively fast. reaction increases. AND a reduction take place sodium ions gain electrons.
  • 11. THE pH SCALE Litmus indicator C8: ACIDS, BASES AND SALTS Neutral substances have a pH=7 turns red in acids Acids have a pH of less than 7 and blue in alkalis. – Reactions of Acids Alkalis have a pH greater than 7 Universal indicator pH can be measured with colour has many colours REACTIONS OF ACIDS changing indicators or digital pH (see chart). You need to memorise these reactions, each one shows the meters general word equation then a specific example with symbols. WHAT IS THE SALT? Acids and Metals To work out which salt is formed during neutralisation reactions you need to know the ions formed by Acid + Metal Salt + Hydrogen the acid or alkali when it dissolves. •Hydrochloric acid + lithium lithium chloride + hydrogen • 2HCl(aq) + 2Li(s) 2LiCl(aq) + H2(g) Substance Cation(s) Formed Anion(s) Formed Working out the name is easy, you just combine the Acids and Base (like alkali but not always soluble) Hydrochloric acid, HCl 1 H+ Cl- , chloride name of the cation from Acid + Base Salt + Water Nitric acid, HNO3 1 H+ NO3- , nitrate the alkali with the anion •Sulphuric acid + sodium hydroxide sodium sulphate + water Sulphuric acid, H2SO4 2H + SO4 2- , sulphate from the acid. • H2SO4(aq) + 2NaOH(aq) Na2SO4(aq) + 2H2O(l) Phosphoric acid, H3PO4 3 H+ PO43- , phosphate For example potassium Acids and Carbonates Sodium hydroxide, NaOH Na+ , sodium 1 OH- sulphate and sulphuric acid Acid + Carbonate Salt + Water + Carbon Dioxide Potassium hydroxide, KOH K+ , potassium 1 OH- makes potassium sulphate. •Nitric acid + calcium carbonate calcium nitrate + water + Magnesium hydroxide, Mg(OH)2 Mg2+ , magnesium 2 OH- Magnesium hydroxide and . carbon dioxide Ammonium hydroxide, NH4OH NH4+ , ammonium 1 OH- phosphoric acid makes • 2HNO3(aq) + CaCO3(s) Ca(NO3)2(aq) + H2O(l) + CO2(g) magnesium phosphate PREPARING SALTS Working out the formula of the salt is a little more complicated, the key is to make sure the positive To prepare any given salt, you first need and negative charges on the cancel each other out to zero. to work out which acid and alkali to Eg 1. Potassium nitrate Eg 2. Magnesium phosphate react together (see right). Then react K+ has one plus charge Mg2+ has two plus charges them in appropriate quantities so they ACID SO42- has two minus charges PO43- has three minus charges exactly neutralise each other. You can either calculate the right amounts You need two K+ to balance out one So you need three Mg2+ to balance out (see Unit C4) or find it experimentally SO42- so the formula is K2SO4 two PO43- so the formula is Mg3(PO4)2 from a titration. Finally, to write a balanced equation, you need to get the right number of waters, the simplest way is to remember that each ‘H+’ from an acid makes one water. Once you have done this you can use Eg 1. Potassium hydroxide and sulphuric acid Eg 2. Magnesium phosphate the appropriate techniques to separate As we have seen it makes K2SO4 which requires As we have seen it makes Mg3(PO4)2 which the salt from the rest of the solution one H2SO4 and two KOH. Two H2O are made requires two H3PO4 and three Mg(OH)2. Six H2O (See Unit C2). since the one H2SO4 produces two H+ ions are made since each of the two H3PO4 produces three H+ ions. ALKALI + H2SO4 + 2KOH K2SO4 + 2H2O 2H3PO4 + 3Mg(OH)2 Mg3(PO4)2 + 6H20 INDICATOR
  • 12. TESTING FOR IONS: Most of these involve forming insoluble precipitates – they go cloudy. C8: ACIDS, BASES AND SALTS Test for... By.... Positive The reaction – Chemical Testing result Chloride ions, Add acidified silver White precipitate Forms insoluble silver chloride: TESTING GASES Cl- nitrate Cl-(aq) + AgNO3(aq) AgCl(s) + NO3-(aq) Hydrogen: •A test tube of hydrogen produces a ‘squeaky pop’ with a lighted splint Sulphate ions, Add acidified White precipitate Insoluble barium sulphate formed: Oxygen: SO42- barium nitrate SO42-(aq) + Ba(NO3)2(aq) BaSO4(s) + 2NO3-(aq) •A test tube of oxygen can re-light a glowing splint. Carbonate Add acid and Rapid gas formation The acid reacts with carbonate to make Chlorine: ions, CO32- bubble the gas which turns carbon dioxide gas: •Bleaches the colour from damp litmus paper. formed in limewater cloudy CO32-(s) + 2H+(aq) CO2(g) + H2O(l) Ammonia: limewater The CO2 reacts with limewater to make •Turns damp red litmus paper blue. insoluble calcium carbonate. Carbon dioxide: Nitrate ions, Boil with sodium Red litmus paper The nitrate gets reduced by aluminium •Turns limewater cloudy. NO3- hydroxide and turns blue which is a strong reducing agent and forms aluminium foil. ammonia. Test the gas with OXIDES damp red litmus Ammonia is an alkali so can turn the red The oxides of most metals are basic (the opposite of acidic). For paper. litmus paper blue. example sodium oxide (Na2O) forms the alkali sodium Copper (II), Add sodium Blue precipitate Insoluble copper (II) hydroxide formed: hydroxide when it reacts with water. Cu2+ hydroxide followed that dissolves when Cu2+(aq) + 2NaOH(aq) Cu(OH)2(s) + 2Na+(aq) by ammonia ammonia added When ammonia is added a soluble complex Most oxides of non-metals are acidic. For example, sulphur solution forms so the precipitate dissolves. trioxide (SO3) forms sulphuric acid when it dissolves in water. Iron (II), Fe2+ Add sodium Green precipitate Insoluble iron (II) hydroxide formed: hydroxide followed insoluble in Fe2+(aq) + 2NaOH(aq) Fe(OH)2(s) + 2Na+(aq) Some oxides can behave like acids or bases and are called by ammonia ammonia Ammonia does not react with the iron (II) amphoteric. For example aluminium oxide (Al2O3) can react solution. Tests Yet More hydroxide so it does not dissolve. with the alkali NaOH to from sodium aluminium hydroxide You need to remember these chemical (NaAl(OH)4) or with hydrochloric acid to form aluminium Iron (III), Fe3+ Add sodium tests: Brown precipitate Insoluble iron (III) hydroxide formed: chloride (AlCl3) hydroxide(see Unit C7) •Oxygen followed insoluble in Fe3+(aq) + 3NaOH(aq) Fe(OH)3(s) + 3Na+(aq) by ammonia lighting a test-tube of H •Hydrogen – ammonia Ammonia does not react with the iron (III) 2 ACID ENVIRONMENTS solution. with a splint gives a squeaky pop hydroxide so it does not dissolve. Acid soils grow poor crops so the acidity is reduced by Zinc, Zn2+ Add sodium White precipitate •Carbon dioxide – when bubbled Insoluble zinc hydroxide formed: neutralising it with lime (CaO, calcium oxide) through limewater soluble in both hydroxide followed it turns it cloudy. Zn2+(aq) + 2NaOH(aq) Zn(OH)2(s) + 2Na+(aq) by ammonia ammonia or more Both ammonia and sodium hydroxide react Acidic gases from factory chimneys (like sulphur dioxide) can solution or more sodium hydroxide with the zinc hydroxide to form a soluble dissolve in the water in clouds to form harmful acid rain. sodium hydroxide. complex.
  • 13. GROUP I (Li, Na, K....) GROUP VII (F, Cl, Br, I...) The metals of Group I (aka the alkali metals) are The elements of Group VII are better known as C9: THE PERIODIC TABLE soft, silvery grey, reactive metals. Down the group the halogens. As we go down the group they get: they get: •Less reactive •Softer •Higher melting point (Cl2 is gas, Br2 is •Lower melting point liquid, I2 is solid) THE PERIODIC TABLE •More reactive •Darker colour (Cl2 is pale green, Br2 is The periodic table is arranged in order of increasing proton They all react with water as follows: reddy-brown, I2 is dark brown) number – starting at Hydrogen with a proton number of one Metal + water metal hydroxide + hydrogen They will react with ions of other halogens (halide and working along the rows. •Lithium + water lithium hydroxide + hydrogen ions) that are below them in the group. For • Li + H2O LiOH + H2 example: Periods: •Lithium reacts the slowest, Na reacts faster, K Cl2 + 2Br- 2Cl- + Br2 The rows in the periodic table are called periods. Going along a reacts faster still and so on. Because Cl is more reactive than Br. However, period, the elements change from metals to non-metals. Br2 + Cl- no reaction Usually, one or two elements in the period are called As Br is less reactive than Cl. metalloids – these have some properties of a metal and some properties of a non-metal. TRANSITION ELEMENTS GROUP 0/VIII (He, Ne, Ar, Kr....) Groups: These are the metals in the long middle block of The gases of Group 0 are called the Noble Gases These are the columns in the periodic table. Elements in the the periodic table. because they are very unreactive. This is because same group share similar properties. they have full outer shells of electrons which is Their important properties include: very stable. Groups I and II are always metals. Groups VII and 0/VIII are •High melting/boiling points always non-metals and elements in groups III, IV, V and VI can •High densities They exist as single atoms rather than molecules. be metals, metalloids or non-metals depending on the period. •Form strongly coloured compounds •(Often) Act as catalysts – both as They are used whenever an inert (unreactive) The Periodic Table and Atomic Structure: elements and when combined in atmosphere is needed. For example: The periodic table can be used to work out the arrangement of compounds •Light Bulbs – Argon surrounds the coiled electrons: filament as even when white hot, it won’t react. •Period number = number of shells Helium has a very low density (1/7th that of air) •Group number = electrons in outer shell so is used to make airships and blimps float. For example: Chlorine is in Period 3 and Group VII so it has 3 electron shells and 7 electrons in the outer shell. METALS (really belongs in C10 but didn’t quite fit) •High melting/boiling point Most of the known elements are metals. •Sonorous – ‘ring’ when hit •Ductile – can be pulled into wires All metals: Conduct electricity, conduct heat, are Many metals react with: Cl shiny •Acids – to form salt and hydrogen •Oxygen – to form (basic) oxides Most metals are also: •Sulphur – to form sulphides •Malleable – can be beaten into shape When metals bond to non metals they form ionic •Strong bonds.
  • 14. REACTIVITY OF METALS REACTIVITY SERIES The reactivity of metals can be seen by the way they react with steam or MOST REACTIVE C10: METALS with acid (see Unit C6 for the reactivity series). Potassium, K Reaction with water (see Unit C2 for details of this reaction): Sodium, Na The most reactive metals (K-Ca) react with cold water, fairly reactive metals Calcium, Ca EXTRACTING METALS FROM THEIR ORES (Mg-Fe) will only react with steam whereas the least reactive metals (Sn- Magnesium, Mg Rocks that contain a significant amount of a metal are called Pt) don’t react at all. Aluminium, Al REACTIVITY ores. The metals are present as compounds – often oxides or Reaction with dilute acids (see Unit C9 for details) (Carbon, C) sulphides of the metal. For example lead can be extracted from The reaction of metals with acids shows a similar patter with the most Zinc, Zn an ore called galena (PbS, lead sulphide). reactive metals (K-Ca) reacting violently, the fairly reactive metals (Mg-Pb) Iron, Fe Metals that are less reactive than carbon can be extracted by reacting gradually more slowly and the least reactive metals (Cu-Pt) not Tin, Sn using carbon as a reducing agent (to steal the oxygen/ reacting at all. Lead, Pb sulphur). More reactive metals are extracted by electrolysis. (Hydrogen, H) Displacement Reactions Copper, Cu Iron is less reactive than carbon so can be reduced by it. This is The reactivity of metals relates to how easily they form ions, more Silver, Ag done in a blast furnace. Study the diagram then read the reactive metals like K form K+ ions much more easily than less reactive Gold, Au following: metals like Cu can form Cu+ ions. A more reactive metal will reduce a less Platinum, Pt •Step 1: Carbon (coke) reacts with oxygen (from the hot air reactive metal: blast) LEAST REACTIVE Eg 1. Reaction with aqueous ions C (s)+ O2(g) CO2(g) Zinc + Copper sulphate Zinc sulphate + copper •Step 2: Carbon dioxide reacts with more carbon to make Zn(s) + Cu2+(aq) + SO42-(aq) Zn2+(aq) + SO42-(aq) + Cu2+(aq) USES OF METALS carbon monoxide This happens because Zn is more reactive than Cu so is able to reduce it. Metals have many uses CO2(g) + C(s) 2CO(g) including: •Step 3: Carbon monoxide reduces the iron oxide (iron ore) to Eg 2. Reaction with metal oxides •Aluminium – and its make molten liquid iron. Iron oxide + aluminium aluminium oxide + iron alloys used for aircraft Fe2O3(s) + CO(g) Fe(l) + CO2(g) This happens since Al is more reactive than Fe so is able to reduce it. as they have low density The limestone (CaCO3) reacts with impurities such as silicon to These are called displacement reactions because the more reactive metal and great strength form an easy-to-collect waste called slag (calcium silicate, takes the place of the less reactive metal. •Aluminium – used for CaSiO3): CaCO3 +SiO2 CaSiO 3+ CO2 food containers as the ALLOYS Alloys are often harder than the waterproof oxide layer Alloys are ‘mixtures of metals’ metals they are made from. In pure on its surface prevents (although sometimes they can metals atoms are neatly lined up corrosion which could contain a non-metal) that are made meaning they can slip past each taint the food. by mixing molten metals. easily when hit. In alloys there are •Zinc - used to protect Step 3 happens here atoms of different sizes which don’t steel either by coating it Alloys often have very different (galvanising) or as line up neatly so can’t slip past each properties to the metals they are sacrificial protection – Step 2 happens here other so easily making them harder. made from and by varying their i.e. on a ship’s hull – a Element Alloy Step 1 happens here metals can be tailored to have lump of zinc prevents specific desirable properties – this is rust as it is more called metallurgy. reactive so corrodes instead of the steel hull.
  • 15. CARBON DIOXIDE, CO2 Thermal decomposition of carbonates e.g.: There are many ways to produce CO2 including: CaCO3 CaO + CO2 C11: AIR AND WATER Burning carbon-containing fuels: As a by product of respiration in living cells: CH4 + 2O2 CO2 + 2H2O C6H12O6 + O2 CO2 + H2O WATER, H2O Drinking Water AIR POLLUTION RUSTING Water is the most useful Water drawn from rivers can Many of man’s activities pollute the air. Pollutants include: Rust (hydrated iron (III) oxide) affects compound known to man. In contain pollutants such as most structures made of iron (or Carbon monoxide, CO the home it is used for fertilizers, dissolved organic steel) and causes huge damage: •Formed when fuels burn without enough O2. cooking, cleaning and matter, harmful bacteria and Iron + oxygen + water hydrated •CO prevents the blood from carrying oxygen leading to death transporting waste. In industry industrial waste that make it iron (III) oxide by suffocation it is used for cooling hot unfit to drink. At treatment Rust can be prevented by taking machinery, cleaning and as a plants, two main processes are Sulphur dioxide, SO2 steps making sure either oxygen or solvent. Water is useful for used to make water safe: •Formed by burning fossil fuels containing sulphur impurities. water can’t reach the iron. The main cleaning as it is able to dissolve •Dissolves in water in clouds to form sulphurous acid which ways to do this involve covering the Filtration – the water is passed falls as acid rain metal with: paint (bridges and other many types of ‘dirt’. through a series of increasingly •Acid rain corrodes buildings and damages ecosystems structures); oil/grease (moving A simple test for water is that fine filters that trap suspended •Irritates the respiratory system when inhaled. machine parts) or another metal such it is able to turn cobalt chloride particles. Activated carbon is as zinc (galvanising). paper from blue to pink. used to filter out dissolved Nitrogen Oxides, NOx pollutants. •Formed by burning fuels in engines and power stations. FERTILISERS Chlorination – chlorine is •Dissolves in cloud water to form nitric acid thus acid rain. Fertilisers are chemicals applied to added to the water which •Irritates the respiratory system when inhaled. plants to improve their growth and destroys bacteria. increase the amounts of products NITROGEN AND AMMONIA to make an economical such as fruits, nuts, leaves, roots and AIR man’s activities such as Ammonia (NH3) is a smelly gas. amount of ammonia. To speed flowers that they produce for us. Air is a mixture of gases burning fossil fuels and One way to produce it is to it up, the reaction is done at They work by supplying plants with comprising: deforestation. This is a concern react ammonium (NH4+) salts high temperature (~450OC) the vital elements they need as CO2 is able to absorb the with an alkali (OH-) eg: with an iron oxide catalyst. including Nitrogen - in the form or infrared radiation (heat) NH4Cl + NaOH NH3 + H2O High pressure (~200 times nitrate (NO3- containing) salts; radiated by the ground when . + NaCl atmospheric pressure) is used phosphorous – in the form of the sun heats it up (the to increase the proportion of phosphate (PO43- containing) salts greenhouse effect). More CO2 Ammonia is vital to produce NH3 formed. and potassium (K+ containing) salts. means more trapped heat the nitrates used in fertilisers leading to global warming. and explosives. It is produced The nitrogen comes from the CATALYTIC CONVERTERS by the Haber process: air and hydrogen comes from The ‘other’ is mostly argon reacting methane (CH4) gas Fit to a car’s exhaust and use a Global warming is a major N2(g) + 3H2(g) 2NH3 with CO2, water vapour and with steam. platinum or palladium catalyst to problem because many trace gases. The reaction is reversible convert harmful gases to safer gases: temperatures are rising faster Nitrogen and oxygen can be which means much of the for example nitrogen oxides are Although the proportion of than nature’s ability to adapt – separated from air by cooling it product turns back to reduced back to nitrogen gas and carbon dioxide is very small this makes the future of both reactants as soon as it is made, to a liquid and using fractional oxygen gas. (~0.04%) it is increasing due to farming and of our ecosystems very uncertain. this means it takes a long time distillation.
  • 16. THE CONTACT PROCESS Sulphuric acid is produced by the Contact Process. C12: SULPHUR This involves are three chemical reactions. First sulphur is burnt in air to produce sulphur dioxide (SO2): S + O2 SO2 SULPHURIC ACID, H2SO4 Sulphuric acid is a very important compound used in many Secondly SO2 is reacted with further oxygen to make sulphur trioxide (SO3): industrial processes including: •Fertiliser production 2SO2 + O2 SO3 •Oil refining •Paper making This reaction is reversible, so to maximise the amount of SO3 made, they use a high temperature •Steel making (425OC), medium-high pressure (1-2 times atmospheric pressure) and a catalyst (vanadium (V) oxide, It is also the acid found in car batteries. V2O5). Sulphuric acid is a strong acid which when diluted in water Finally, the sulphur trioxide is produced by first dissolving it in sulphuric acid to make oleum (H2S2O7) produces two protons and a sulphate ion: which then makes more sulphuric acid on the addition of water: H2SO4(l) 2H+(aq) + SO42-(aq) SO3 + H2SO4 H2S2O7 It exhibits all the reactions typical of an acid as seen by its H2S2O7 + H2O 2H2SO4 reactions with metals, alkalis, metal oxides and carbonates. (see Unit C8 for details). Note: trying to dissolve SO3 directly in water produces a very fine mist of sulphuric with limited uses. This is another tiny unit with very little to learn.
  • 17. USES OF CALCIUM CARBONATE Powdered calcium carbonate can be added directly to soils to raise their pH (reduce their acidity). C13: CARBONATES We can also make calcium oxide (CaO, aka ‘quicklime’) by heating powdered calcium carbonate to about 1000OC, producing carbon dioxide as a by-product: CALCIUM CARBONATE, CaCO3 CaCO3(s) CaO(s) + CO2(g) Calcium carbonate is a very common mineral and makes up the bulk of many common rocks including: This is called a thermal decomposition as heat is used to break down or decompose the calcium •Chalk carbonate. Calcium oxide is one of the key ingredients in cement. •Limestone •Marble Another useful product, calcium hydroxide (Ca(OH)2, ‘slaked lime’) is made by adding water to calcium oxide: Whilst solid limestone is often used in construction, powdered CaO + H2O Ca(OH)2 limestone has many industrial uses. Slaked lime has many uses including: •Raising soil pH quickly (when powdered calcium carbonate might take too long) •Neutralising acidic industrial waste •Sewage treatment – it helps small particles of waste to clump together into easily removed lumps. Another mini-unit with very little in it!