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Drinking	
  water	
  &	
  Lead	
  Contamina2on	
  
                                                                                                           Kari	
  Knisely1,	
  Aus2n	
  Atkins2,	
  Jeff	
  Cunningham3	
  
                         1.	
  Sligh	
  Middle	
  School;	
  2.	
  Department	
  of	
  Civil	
  &	
  Environmental	
  Engineering,	
  University	
  of	
  South	
  Florida	
  3.	
  Department	
  of	
  Civil	
  &	
  Environmental	
  Engineering,	
  University	
  of	
  South	
  Florida	
  


 Abstract	
                                                                                                            Approach	
                                                                                                                                  Conclusions	
  
In	
  Madagascar	
  only	
  47%	
  of	
  the	
  popula+on	
  has	
  access	
  to	
  clean	
  drinking	
  
water.	
  In	
  the	
  Eastern	
  part	
  of	
  the	
  island,	
  local	
  ar+sans	
  dig	
  shallow	
  
                                                                                                                       3	
  Methods	
  tested	
                                                                                                                    Aker	
  researching	
  the	
  different	
  methods	
  displayed	
  in	
  
drinking	
  water	
  wells	
  and	
  install	
  locally	
  manufactured	
  pumps.	
  Lead	
                            1.  Atomic	
  Absorp+on	
  Spectroscopy	
  (AAS)	
                                                                                          the	
  table,	
  the	
  ASV	
  has	
  proven	
  to	
  be	
  consistent	
  in	
  its	
  
from	
  old	
  ba5eries	
  is	
  used	
  for	
  various	
  parts	
  of	
  these	
  pump	
  systems	
  as	
             2.  Anodic	
  Stripping	
  Voltammetry	
  (ASV)	
                                                                                           results	
  while	
  the	
  Colorimetry	
  methods	
  have	
  been	
  very	
  
floats	
  and	
  as	
  solder	
  on	
  the	
  screen	
  in	
  contact	
  with	
  the	
  water.	
                        3.  Field	
  Kit	
  -­‐	
  Colorimeter	
                                                                                                    inconsistent.	
  	
  	
  
Preliminary	
  sampling	
  of	
  wells	
  in	
  2010	
  and	
  analysis	
  for	
  lead	
  using	
  ICP-­‐                                                                                                                                                          	
  
MS	
  at	
  the	
  University	
  of	
  South	
  Florida	
  (USF)	
  indicated	
  that	
  there	
  were	
  
some	
  wells	
  with	
  lead	
  levels	
  above	
  safe	
  limits	
  of	
  10	
  ug/L	
  as	
  set	
  by	
  the	
     7	
  Concentra+on	
  Levels	
  made	
  to	
  be	
  tested	
                                                                                 The	
  Anodic	
  Stripping	
  Voltammetry	
  (ASV),	
  clearly	
  is	
  the	
  
World	
  Health	
  Organiza+on.	
  Through	
  the	
  Master’s	
  Interna+onal	
                                        •  1	
  mg/L	
                                                                                                                              best	
  and	
  most	
  reliable	
  method	
  for	
  accurate	
  readings	
  of	
  
program	
  in	
  Civil	
  and	
  Environmental	
  Engineering	
  at	
  USF,	
  our	
  team	
                           •  150	
  μg/L	
                                                                                                                            lead	
  contamina+ons	
  less	
  than	
  100	
  μg/L.	
  	
  It	
  is	
  unclear	
  at	
  
currently	
  has	
  a	
  member	
  on	
  the	
  ground	
  in	
  Madagascar	
  who	
  wishes	
  to	
                    •  100	
  μg/L	
                                                                                                                            this	
  +me,	
  what	
  method	
  is	
  most	
  accurate	
  and	
  
test	
  these	
  levels	
  in	
  the	
  field.	
  This	
  research	
  compared	
  the	
  effec+veness	
                  •  50	
  μg/L	
                                                                                                                             recommended	
  for	
  concentra+on	
  levels	
  over	
  100	
  μg/L,	
  
of	
  different	
  analy+cal	
  methods	
  to	
  measure	
  the	
  level	
  of	
  lead	
  
                                                                                                                       •  10	
  μg/L	
                                                                                                                             but	
  will	
  con+nue	
  to	
  be	
  researched.	
  	
  The	
  ASV	
  is	
  
contamina+on	
  in	
  drinking	
  water.	
  	
  The	
  mobile/portable	
  analy+cal	
  
methods	
  include	
  Anodic	
  Stripping	
  Voltammetry	
  (ASV)	
  and	
  Colorimetry	
                              •  5	
  μg/L	
                                                                                                                              lightweight,	
  easy	
  to	
  use,	
  and	
  does	
  not	
  require	
  
with	
  various	
  reagents	
  for	
  color	
  development.	
  Analysis	
  via	
  lab	
  based	
                       •  1	
  μg/L	
                                                                                                                              electricity	
  as	
  well	
  as	
  fairly	
  accurate	
  when	
  used	
  to	
  test	
  
methods	
  like	
  the	
  Graphite	
  Furnace	
  Atomic	
  Absorp+on	
  Spectroscopy	
                                                                                                                                                                             the	
  lead	
  levels	
  in	
  the	
  standards.	
  	
  	
  

                                                                                                                       Results	
                                                                                                                                   	
  
(GFAAS)	
  were	
  used	
  to	
  compare	
  with	
  the	
  field	
  based	
  kits.	
  The	
  results	
  
from	
  this	
  work	
  will	
  be	
  used	
  to	
  iden+fy	
  the	
  most	
  suitable	
  method	
  of	
                                                                                                                                                           At	
  this	
  +me,	
  it	
  will	
  be	
  recommended	
  that	
  USF	
  select	
  
analysis	
  for	
  field	
  measurements	
  of	
  lead	
  in	
  drinking	
  water	
  in	
                                                                                                                                                                           the	
  ASV	
  as	
  the	
  measurement	
  method	
  to	
  be	
  used	
  in	
  the	
  
Madagascar.	
                                                                                                          u           The	
  AA	
  requires	
  electricity,	
  gas,	
  and	
  is	
  not	
  a	
  mobile	
  method	
  
	
                                                                                                                                                                                                                                                                 field	
  in	
  Madagascar	
  to	
  measure	
  the	
  lead	
  concentra+on	
  
                                                                                                                       u           The	
  ASV	
  was	
  extremely	
  self	
  explanatory,	
  accurate,	
  the	
  fastest	
  
 Background	
                                                                                                                       method,	
  lightweight	
  and	
  mobile	
  requiring	
  4	
  AA	
  ba5eries	
  
                                                                                                                                                                                                                                                                   levels	
  in	
  the	
  drinking	
  water	
  supplies.	
  

 While	
  traveling	
  to	
  Madagascar,	
  USF	
  iden+fied	
  a	
  major	
  
                                                                                                                       u           The	
  Colorimeter	
  was	
  not	
  consistent	
  in	
  its	
  readings,	
  the	
  chemical	
  
 health	
  risk	
  for	
  the	
  residents	
  of	
  the	
  under	
  developed	
                                                     tes+ng	
  process	
  was	
  extremely	
  complicated	
  and	
  +me	
  consuming,	
  but	
  
 third	
  world	
  country.	
  The	
  most	
  common	
  source	
                                                                    was	
  very	
  lightweight	
  and	
  mobile	
  requiring	
  ba5eries.	
  	
  	
  
 currently	
  used	
  in	
  most	
  villages	
  to	
  retrieve	
  drinking	
                                           	
  
 water	
  is	
  being	
  made	
  out	
  of	
  melted	
  lead.	
  	
  The	
  
 assump+on	
  is	
  that	
  the	
  level	
  of	
  lead	
  found	
  in	
  their	
  
 drinking	
  water	
  pumped	
  from	
  these	
  units	
  contain	
  an	
  
                                                                                                                       The	
  table	
  below	
  demonstrates	
  the	
  readings	
  each	
  method	
  displayed	
  each	
  
                                                                                                                       5me	
  it	
  was	
  tested.	
  	
  The	
  closer	
  to	
  the	
  standard	
  the	
  more	
  accurate	
  the	
  test.	
                      References	
  
 unhealthy	
  concentra+on	
  of	
  lead	
  posing	
  even	
  more	
                                                   Standard	
  	
   Method	
  1	
  	
   Method	
  2	
                Method	
  3	
                      Method	
  3	
                          u       All	
  photos	
  taken	
  from	
  google	
  images	
  or	
  personal	
  
 serious	
  health	
  risks	
  to	
  the	
  country	
  already	
  struggling	
                                         Levels	
         AA	
                ASV	
                        Field	
  Kit-­‐	
  Colorimeter	
   Field	
  Kit	
  –	
  Colorimeter	
              camera	
  
 to	
  survive	
  many	
  water	
  borne	
  illnesses.	
  	
  USF	
  is	
  seeking	
                                                                                                     w/	
  HACH	
  Chemicals	
  	
   w/	
  Leadquick	
  Chemicals	
  
 to	
  iden+fy	
  which	
  method	
  would	
  be	
  most	
  efficient	
  yet	
  
                                                                                                                       1	
  mg/L	
           TBA	
         Not	
  in	
  range	
          Not	
  a5empted	
                  Not	
  aWempted	
                      	
  
 effec+ve	
  to	
  use	
  in	
  the	
  field	
  where	
  electricity	
  is	
  usually	
  
 not	
  available.	
                                                                                                   150	
  μg/L	
         TBA	
         Not	
  in	
  range	
          123	
                              100,	
  55,	
  75	
  
                                                                                                                       100	
  μg/L	
  	
     TBA	
         95	
                          Not	
  a5empted	
                  63,	
  55,	
  43	
  
Objec2ve	
                                                                                                             50	
  μg/L	
  
                                                                                                                       10	
  μg/L	
  
                                                                                                                                             TBA	
  
                                                                                                                                             TBA	
  
                                                                                                                                                           44,	
  42,	
  49,	
  44	
  
                                                                                                                                                           7,	
  3	
  
                                                                                                                                                                                         30	
  
                                                                                                                                                                                         Not	
  a5empted	
  
                                                                                                                                                                                                                            34,	
  29,	
  32	
  
                                                                                                                                                                                                                            <3,	
  <3,	
  <3	
  
To	
  compare	
  results	
  given	
  by	
  3	
  different	
  methods	
  on	
  the	
  7	
  different	
  lead	
  
concentra+on	
  levels	
  in	
  drinking	
  water	
  and	
  conclude	
  which	
  method	
  is	
                        5	
  μg/L	
           TBA	
         6,	
  5	
                     Not	
  a5empted	
                  <3,	
  <3,	
  <3	
  
most	
  effec+ve	
  to	
  be	
  used	
  in	
  the	
  field	
  in	
  Madagascar.	
                                        2	
  μg/L	
           TBA	
         14,	
  20	
                   Not	
  a5empted	
                  Not	
  aWempted	
  
                                                                                                                       0	
  μg/L	
           TBA	
         48,	
  14	
                   Not	
  a5empted	
                  <3,	
  <3,	
  <3	
  

             For	
  more	
  informa+on	
  about	
  the	
  program	
  visit:	
  h5p://wareret.net.	
  	
  The	
  Water	
  Awareness	
  Research	
  and	
  Educa+on	
  (WARE)	
  Research	
  Experience	
  for	
  Teachers	
  (RET)	
  is	
  funded	
  by	
  the	
  Na+onal	
  Science	
  Founda+on	
  under	
  award	
  number	
  1200682.	
  
                                                                                                                                                                        	
  

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Knisely ret poster_

  • 1. Drinking  water  &  Lead  Contamina2on   Kari  Knisely1,  Aus2n  Atkins2,  Jeff  Cunningham3   1.  Sligh  Middle  School;  2.  Department  of  Civil  &  Environmental  Engineering,  University  of  South  Florida  3.  Department  of  Civil  &  Environmental  Engineering,  University  of  South  Florida   Abstract   Approach   Conclusions   In  Madagascar  only  47%  of  the  popula+on  has  access  to  clean  drinking   water.  In  the  Eastern  part  of  the  island,  local  ar+sans  dig  shallow   3  Methods  tested   Aker  researching  the  different  methods  displayed  in   drinking  water  wells  and  install  locally  manufactured  pumps.  Lead   1.  Atomic  Absorp+on  Spectroscopy  (AAS)   the  table,  the  ASV  has  proven  to  be  consistent  in  its   from  old  ba5eries  is  used  for  various  parts  of  these  pump  systems  as   2.  Anodic  Stripping  Voltammetry  (ASV)   results  while  the  Colorimetry  methods  have  been  very   floats  and  as  solder  on  the  screen  in  contact  with  the  water.   3.  Field  Kit  -­‐  Colorimeter   inconsistent.       Preliminary  sampling  of  wells  in  2010  and  analysis  for  lead  using  ICP-­‐   MS  at  the  University  of  South  Florida  (USF)  indicated  that  there  were   some  wells  with  lead  levels  above  safe  limits  of  10  ug/L  as  set  by  the   7  Concentra+on  Levels  made  to  be  tested   The  Anodic  Stripping  Voltammetry  (ASV),  clearly  is  the   World  Health  Organiza+on.  Through  the  Master’s  Interna+onal   •  1  mg/L   best  and  most  reliable  method  for  accurate  readings  of   program  in  Civil  and  Environmental  Engineering  at  USF,  our  team   •  150  μg/L   lead  contamina+ons  less  than  100  μg/L.    It  is  unclear  at   currently  has  a  member  on  the  ground  in  Madagascar  who  wishes  to   •  100  μg/L   this  +me,  what  method  is  most  accurate  and   test  these  levels  in  the  field.  This  research  compared  the  effec+veness   •  50  μg/L   recommended  for  concentra+on  levels  over  100  μg/L,   of  different  analy+cal  methods  to  measure  the  level  of  lead   •  10  μg/L   but  will  con+nue  to  be  researched.    The  ASV  is   contamina+on  in  drinking  water.    The  mobile/portable  analy+cal   methods  include  Anodic  Stripping  Voltammetry  (ASV)  and  Colorimetry   •  5  μg/L   lightweight,  easy  to  use,  and  does  not  require   with  various  reagents  for  color  development.  Analysis  via  lab  based   •  1  μg/L   electricity  as  well  as  fairly  accurate  when  used  to  test   methods  like  the  Graphite  Furnace  Atomic  Absorp+on  Spectroscopy   the  lead  levels  in  the  standards.       Results     (GFAAS)  were  used  to  compare  with  the  field  based  kits.  The  results   from  this  work  will  be  used  to  iden+fy  the  most  suitable  method  of   At  this  +me,  it  will  be  recommended  that  USF  select   analysis  for  field  measurements  of  lead  in  drinking  water  in   the  ASV  as  the  measurement  method  to  be  used  in  the   Madagascar.   u  The  AA  requires  electricity,  gas,  and  is  not  a  mobile  method     field  in  Madagascar  to  measure  the  lead  concentra+on   u  The  ASV  was  extremely  self  explanatory,  accurate,  the  fastest   Background   method,  lightweight  and  mobile  requiring  4  AA  ba5eries   levels  in  the  drinking  water  supplies.   While  traveling  to  Madagascar,  USF  iden+fied  a  major   u  The  Colorimeter  was  not  consistent  in  its  readings,  the  chemical   health  risk  for  the  residents  of  the  under  developed   tes+ng  process  was  extremely  complicated  and  +me  consuming,  but   third  world  country.  The  most  common  source   was  very  lightweight  and  mobile  requiring  ba5eries.       currently  used  in  most  villages  to  retrieve  drinking     water  is  being  made  out  of  melted  lead.    The   assump+on  is  that  the  level  of  lead  found  in  their   drinking  water  pumped  from  these  units  contain  an   The  table  below  demonstrates  the  readings  each  method  displayed  each   5me  it  was  tested.    The  closer  to  the  standard  the  more  accurate  the  test.   References   unhealthy  concentra+on  of  lead  posing  even  more   Standard     Method  1     Method  2   Method  3   Method  3   u  All  photos  taken  from  google  images  or  personal   serious  health  risks  to  the  country  already  struggling   Levels   AA   ASV   Field  Kit-­‐  Colorimeter   Field  Kit  –  Colorimeter   camera   to  survive  many  water  borne  illnesses.    USF  is  seeking   w/  HACH  Chemicals     w/  Leadquick  Chemicals   to  iden+fy  which  method  would  be  most  efficient  yet   1  mg/L   TBA   Not  in  range   Not  a5empted   Not  aWempted     effec+ve  to  use  in  the  field  where  electricity  is  usually   not  available.   150  μg/L   TBA   Not  in  range   123   100,  55,  75   100  μg/L     TBA   95   Not  a5empted   63,  55,  43   Objec2ve   50  μg/L   10  μg/L   TBA   TBA   44,  42,  49,  44   7,  3   30   Not  a5empted   34,  29,  32   <3,  <3,  <3   To  compare  results  given  by  3  different  methods  on  the  7  different  lead   concentra+on  levels  in  drinking  water  and  conclude  which  method  is   5  μg/L   TBA   6,  5   Not  a5empted   <3,  <3,  <3   most  effec+ve  to  be  used  in  the  field  in  Madagascar.   2  μg/L   TBA   14,  20   Not  a5empted   Not  aWempted   0  μg/L   TBA   48,  14   Not  a5empted   <3,  <3,  <3   For  more  informa+on  about  the  program  visit:  h5p://wareret.net.    The  Water  Awareness  Research  and  Educa+on  (WARE)  Research  Experience  for  Teachers  (RET)  is  funded  by  the  Na+onal  Science  Founda+on  under  award  number  1200682.