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FDEP Multi Media Inspector Training
Goals for Training ,[object Object],[object Object],[object Object],[object Object]
Learning Objectives ,[object Object],[object Object]
Pulp and Paper Mills in Florida ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],International Paper, Cantonment Smurfit-Stone, Fernandina Beach Rayonier, Fernandina Beach Buckeye, Perry Smurfit-Stone, Panama City Georgia-Pacific, Palatka Packaging Corp of America, Valdosta Smurfit-Stone, Jacksonville
Pulp and Paper Mills in Florida ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pulp and Paper Mills in Florida ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Recovery Boiler Liquor Evaporator Causticizing Woodyard Bleaching Pulping Paper Machine Power and Steam Generation ,[object Object],[object Object],[object Object],[object Object],[object Object],Brown Pulp Chips Logs Pulp and Paper Products Bleach Pulp WBL HBL Green Liquor White Liquor Steam BL Soap Digester Relief Gases
Mill Tour ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Woodyard Operations
What is wood? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Wood Characteristics ,[object Object],[object Object],[object Object],[object Object],5-10 mg/100 mm 15-35 mg/100 mm Coarseness 0.6 – 1.5 mm 2-6 mm Fiber length 5% +/- 3% 3% +/- 2% Extractives 20% +/- 4% 28% +/- 3% Lignin content 45% +/- 2% 42% +/- 2% Cellulose content Hardwoods Softwoods Parameter
Typical Woodyard Log Storage Receiving ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Debarking Chipping Chip Screening Overs = oversized chips for further processing Unders = undersized chips sent to bark pile Accepts = correct chip size sent to chip pile Chip Pile Bark Pile Digesters
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Environmental Impacts Use of Bark as Fuel Control Runoff at Transfer Points Control of Particulate Matter (PM) and Visible Emissions (VE) Debarking Housekeeping Monitor Emissions Heavy Equipment Control of runoff Control of Particulate Matter (PM) and Visible Emissions (VE) Bark Storage Control of runoff Control of Particulate Matter (PM) and Visible Emissions (VE) Chip Storage Disposal of Defective Chips as Fuel Control Runoff at Transfer Points Control of Particulate Matter (PM) and Visible Emissions (VE) Chipping Disposal of Defective Logs Control of runoff Dust Control Log Storage Hazardous Waste Disposal of Defective Logs Control of runoff Dust Control Log Handling Solid Waste Wastewater Stormwater Air Activity
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Log Flume Log Flume Chipping and Debarking Operations
Debarking Drum Outside of Debarking Drum
Debarking Drum Waste Pile Transfer Tube
Chip Storage Open Chip Bin Storage Central column feeds chips to screener and digester
Pulping Operations
Overview of Pulping ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Kraft Pulping Pulp Chips Digester White Liquor Weak Black Liquor Pulp Blow Tanks Brown Stock Washers Pulp Shower Water Black Liquor Black Liquor Black Liquor Weak Black Liquor Storage To Evaporators
Sulfite Pulping Pulp Chips Digesters Cooking Acid Pulp Blow Pits Red Stock Washers Pulp Shower Water Liquor Liquor Black Liquor Liquor Storage To Evaporators
Typical Pulp Washing Hot Stock Refining Blow Tank 1 st  Stage Filtrate 2 nd  Stage Filtrate 3 rd  Stage Filtrate 3 rd  Stage   Washer 2 nd  Stage   Washer 1 st  Stage Washer Water Pulp Pulp Shower Water Shower Water Pulp w/ Black Liquor Filtrate 12-14% Filtrate xx% Filtrate xx%
Environmental Impacts Collection and  Control of Pulping Liquor (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (HVLC) Liquor Storage Collection and  Control of Pulping Liquor (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (HVLC) Brown Stock Washers Collection and  Control of Pulping Liquor (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (LVHC) Blow Tanks Hazardous Waste Collection and  Control of Pulping Liquor (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (LVHC) Digesters Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Brown Stock Washer Washer Hood Washer Drum
Batch Digester Cap Chip Loading Capping Valve
Batch Digesters Digester Body
Continuous Digester Kaymr
Recycle Pulper Bales of post consumer waste paper on conveyer Ragger
Waste Paper Cleaners
Waste Paper Fines Separator
Bleaching Operations
Bleaching Stages Hypochlorite is a true bleaching agent by destroying certain chromophoric groups of lignin. Hypochlorite is used in limited bleaching applications where high pulp yield is critical.  Since Hypochlorite  attacks the lignin vigorously, some cellulose is also attacked in the process. Hypochlorite (H) Alkali or caustic soda (sodium hydroxide) is effective at solubilizing degraded lignin products.  Oxygen, hydrogen peroxide or both are often added to the caustic solution to enhance the removal of organic waste. Extraction  (E, E O , E P , E OP ) Chlorine dioxide (ClO2) is a highly selective chemical that can both de-lignify and brighten pulp. It oxidizes lignin, but does not add chlorine atoms onto lignin fragments; however, small amounts of elemental chlorine and other chlorine compounds formed during the chlorine dioxide bleaching process react with degraded lignin to form chlorinated organic compounds. Chlorine Dioxide (D) Elemental chlorine (Cl2) is an effective de-lignifying agent. As it breaks lignin bonds, it adds chlorine atoms to the lignin degradation products, thus producing significant amounts of chlorinated organic material. Elemental Chlorine (C) Description Stage (Symbol)
Bleaching Stages (cont.) Ozone (O 3 ) is also an effective delignifying agent. It also brightens the pulp as well. Ozone has not been used in the past because mills have not been able to improve its selectivity - ozone attacks the cellulose fiber as well as the lignin. Recent technological developments, however, have solved this problem and have allowed mills to take advantage of this cost-effective bleaching agent. Ozone (Z) Hydrogen peroxide (H 2 O 2 ) is mainly used to brighten pulps in the final bleaching stages. Peroxide is often used at the end of a conventional bleaching sequence to prevent the pulp from losing brightness over time. Researchers have found operating conditions under which peroxide will delignify pulp, and are working on technologies that will consume less. Hydrogen Peroxide (P) Oxygen (O 2 ) is an inexpensive, highly effective delignifying agent that is usually used at the beginning of the bleaching process. It has intermediate selectivity. Oxygen (O) Description Stage (Symbol)
Modern Bleach Plant Design
Typical Bleach Plant 1 st  Stage Washer Tower 1 st  Stage Filtrate 2 nd  Stage Washer Tower 3 rd  Stage Washer Tower 4 th  Stage Washer Tower 2 nd  Stage Filtrate 4 th  Stage Filtrate 3 rd  Stage Filtrate See Typical Bleaching Stage
Typical Bleaching Stage Washer Bleaching Tower (up flow) Filtrate Tank Chemical Mixer Steam Mixer Pulp Bleaching Chemical Next Bleaching Stage Steam To Bleach Plant Scrubber To Bleach Plant Scrubber To Bleach Plant Scrubber ,[object Object],[object Object],Filtrate
Oxygen Delignification ,[object Object],[object Object],[object Object],Discharge Tank Oxygen Delignification  Towers –  Two Stage System
Chlorine Dioxide Washer Washer Hood Inlet Flow
Environmental Impacts Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) ClO 2  Production Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) Filtrate Tanks Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) Washers Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) Towers Hazardous Waste Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) Mixers Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object]
Paper Machine / Pulp Dryer
Fourdrinier Paper Machine Spreads Pulp Stock onto Wire Table 3% Solids 7% Solids 40% -50% of Pulp Stock is Solids 95% of Pulp Stock is Solids Smoothes Surface of Paper Collects Paper Product
Environmental Impacts Rewinder Broke and Coating Residue Disposal Defective Paper Wastepaper Disposal Collection and Control of Vent Gases Drying Broke and Coating Residue Disposal Defective Paper Wastepaper Disposal Collection and Control of Vent Gases Pressing Broke and Coating Residue Disposal   Prevention of Leaks and Spills Head box Hazardous Waste Disposal of Defective Stock Prevention of Leaks and Spills Collection of Volatile Gases Stock Preparation Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object]
High Density Pulp Storage Storage Tank Agitation Zone
Paper Machine Fourdrinier Headbox Dryline
Evaporator Operations
Evaporator Operations ,[object Object],[object Object],[object Object],[object Object],[object Object]
Typical Evaporator Effect 5 Surface Condenser Steam Heavy Liquor ,[object Object],[object Object],[object Object],Effect 2 Effect 1 Effect 3 Effect 4 Pulping Condensates NCG System Hotwell Clean Condensates
Multiple Effect Evaporators Vapor Dome Tube Bundles Vapor Lines
Evaporator Hotwell NCG Collection Hotwell Condensate Collection
Environmental Impacts Prevention of organic gas leaks NCG System Prevention of leaks and spills of condensate Prevention of leaks of Hotwell gases Hotwell Prevention of leaks and spills of condensate Prevention of air leaks Evaporator Effects Hazardous Waste Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Prevention of volatile organic compound leaks and spills Weak Liquor Storage Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Recovery Boiler Operations
Recovery Boiler Operations ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Kraft Recovery Boiler NCDE Recovery Boiler ESP Saltcake Mix Tank Drying Reducing Oxidizing Flue Gas Black Liquor Feed Recycle To Stack Chemical Make-up HB Liquor Smelt Bed To Smelt Dissolving Tank 3 o  Air 2 o  Air 1 o  Air
Environmental Impacts Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Release of particulate matter Smelt Dissolving Tank Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Multiple regulations requiring ESP Recovery Boiler Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Prevention of leaks and spills of volatile components in black liquor Saltcake Mix Tank Hazardous Waste Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Prevention of leaks and spills of any volatile compounds Heavy Liquor Storage Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Causticizing  Operations
Typical Causticizing Operation White Liquor Clarifier Green Liquor Clarifier Slaker Causticizer From Recovery Area Dregs Washer Weak Wash Storage Lime Mud Filter Lime Mud Washer Lime Kiln Lime Silo To Digester Make Up Water NCG Collection
Environmental Impacts Not applicable unless the materials fail paint filter test and have a pH >12.5 Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Multiple regulations requiring ESP and/or scrubber Lime Kiln Not applicable unless the materials fail paint filter test and have a pH >12.5 Excess lime mud may be landfilled. Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Typically no controls Mud Filter Not applicable unless the materials fail paint filter test and have a pH >12.5 Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Typically no controls Causticizer Not applicable unless the materials fail paint filter test and have a pH >12.5 Grits are landfilled after washing and elementary neutralization Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Typically controlled by scrubber or spray Slaker Not applicable unless the materials fail paint filter test and have a pH >12.5 Hazardous Waste Dregs are landfilled after elementary neutralization Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Typically no controls GL/WL Clarifiers Dregs Washer Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Lime Kiln Lime Kiln Tube Washing and Causticizing Operations
Lime Kiln Lime Kiln Tube Motor and Drive Units Fire Hood
Power and Utility  Operations
Power and Steam Generation Boilers Steam Condensate from mill High Pressure Steam Turbines Electrical Power Low Pressure Steam Kraft Mill Processes
Environmental Impacts Solids in steam water carried to turbines Potential release of oils to receiving waters Turbine Generators Solids in steam water carried to turbines Potential release of oils to receiving waters Control of Carbon Monoxide production Combustion Turbine Disposal of Boiler chemicals and fuels Disposal of bottom and fly ash – landfilled Control of non-contact cooling water, scrubber and boiler blowdown Potential release of oils to receiving waters Control of Particulate Matter Emissions Power Boiler Disposal of Boiler chemicals and fuels Hazardous Waste Disposal of bottom and fly ash – landfilled Control of non-contact cooling water, scrubber and boiler blowdown Potential release of oils to receiving waters Control of Particulate Matter Emissions Combination Boiler Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object]
Power Boilers Power Plant
Acid Tanker Unloading Acid Storage Tank
By-product Recovery
Typical Turpentine Recovery (Kraft) Decanter Cyclone Separator Digester Storage Condenser Relief To HVLC System Turpentine To Condensate Collection To Condensate Collection Truck or Rail Car Loading Black Liquor Black Liquor Secondary Containment
Turpentine Decanter Decanter Storage Containment
Environmental Impacts Spills are very toxic to WWT system Secondary containment required Collection and Control of Vent Gases (LVLC) Turpentine Storage Spills are very toxic to WWT system Secondary containment required Collection and Control of Vent Gases (LVHC) Turpentine recovery Hazardous Waste Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Typical Tall Oil Recovery (Kraft) Reactor Sulfuric Acid Black Liquor Soap Tall Oil Brine Tall Oil Storage Decanter or Centrifuge Secondary Containment To  Recovery Boiler Truck or Rail Car Loading
Tall Oil Plant
Environmental Impacts Spills are very toxic to WWT system Prevention of leaks and spills into stormwater system (SWP 3 ) Tall Oil Storage Spills are very toxic to WWT system Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and control in tall oil plant scrubber Acidulation Spills to process sewers cause release of TRS Prevention of leaks and spills into stormwater system (SWP 3 ) Acid Storage Hazardous Waste Spills are very toxic to WWT system Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (HVLC) Soap Storage Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Environmental Control
Environmental Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Environmental Impacts Ash emissions into wastewater system Ash emissions into stormwater system Uncontrolled emissions of ash NCG Incineration Untreated or untested sludge applied to land Prevention of leaks and spills into effluent system (BMP) Contamination of stormwater system by run-off Uncontrolled hazardous sludge Land Application Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and control of pulping condensate Condensate Treatment Untreated or untested sludge landfilled Excessive buildup of solid residuals Prevention of leaks and spills into effluent system (BMP) Contamination of stormwater system by run-off Odorous emissions Landfill Operations Uncontrolled sludge spills and leaks Hazardous Waste Collection of entering solid residuals Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and control of emitted gases Wastewater Treatment Solid Waste Wastewater Stormwater Air Activity
Environmental Issues ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pollution Prevention & Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Visual Assessment Tips ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Primary Clarifier Clarifier Unit Wastewater Body
Stormwater Collection System Stormwater Collection Operations Good Vegetation Control
Stormwater Collection System Stormwater Collection Tunnel Good Vegetation Control
Inlet Pond Inlet Water for Mill Operations
Pond Outlet Standpipe Standpipe
Effluent Monitoring Station Effluent Monitoring Operations
Truck Product Loading
Rail Product Loading
Pollution Control Technology
Pollution Control Technology ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Electrostatic Precipitator (ESP) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Electrostatic Precipitator (ESP) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Electrostatic Precipitator (ESP) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Electrostatic Precipitator (ESP) Particulate Laden Flue Gas Positively Charge Collection Plates Discharge Electrodes (-) Clean Gas Particulate Matter Zone 1 Zone 3 Zone 2 Zone 4 Chamber 1 Chamber 2 Chamber 3
Electrostatic Precipitator (ESP) ESP Collection Plates Internals of ESP
Electrostatic Precipitator (ESP) Dry Bottom ESP ESP Hopper
Venturi Scrubbers ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Venturi Scrubbers ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Venturi Scrubbers Cyclonic  Separator Contaminated Gas Inlet Scrubbing Liquid Clean Gas Outlet to Atmosphere Body Gas and Liquid start mixing Venturi  Max Liquid and Gas Contact Concentrated Liquid for Disposal or Recycle To WWT Facility Elbow Tank
Venturi Scrubbers Back Body and Venturi Sections Cyclonic Separator Contaminated Gas Inlet
Packed Bed Scrubbers ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Packed Bed Scrubbers Packed  Bed Contaminated Gas Inlet Concentrated Liquid for Disposal or Recycle Scrubbing Liquid Clean Gas Outlet to Atmosphere
Packed Bed Scrubbers Back Inlet Gas from Operations Packed Bed Column Exhaust to Atmosphere
Incinerators ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Incinerators ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Incinerators ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Incinerators Back Inlet Gas Flow Primary Burner Outlet Gas Flow
Steam Stripper ,[object Object],[object Object],[object Object],[object Object]
Steam Stripper ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Steam Stripper ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Steam Stripper Stage Trays Inlet Steam Cleaned Condensate Contaminated Condensate Steam containing condensate pollutants Reflux Condenser Heat Exchanger
Steam Stripper Back Stripping Column Reflux Condenser
Baghouse ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Baghouse ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Baghouse Back Dust Hopper Clean Air to Atmosphere Particulate Laden Gas Filter Bags Shaker Device
Baghouse Back
Non-Condensable Gas (NCG) Collection Systems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
LVHC (NCG) Collection Systems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
LVHC (NCG) Collection Systems Digester Wood White Liquor Turpentine Recovery System Washer System Part of HVLC System Pulp Weak Black Liquor Blow Heat Accumulator Blow Tank Multiple Effect Evaporators Pulp Liquor Pulp Liquor Back LVHC Collection
HVLC (NCG) Collection Systems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
HVLC (NCG) Collection Systems Pulp Washing System Knotter System Pulp Liquor from Blow Tanks Storage Tank Weak Black Liquor Screening System Decker To Multiple Effect Evaporators Oxygen Delignification System Washer Back HVLC Collection HVLC Collection HVLC Collection
Condensate Collection Systems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Condensate (NCG) Collection Systems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Condensate Collection Systems Back Turpentine Decanter Cyclone Separator Digester Turpentine Storage Condenser Relief Condensate Collection Condensate Collection Loading Condensate Collection Effect 5 Surface Condenser Steam Effect 2 Effect 1 Effect 3 Effect 4 Condensate Collection Hotwell Clean Condensates Wood Liquor
Non-Condensable Gas (NCG) Collection Systems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Total Reduced Sulfur (TRS) Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Total Reduced Sulfur (TRS) Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Total Reduced Sulfur (TRS) Control ,[object Object],[object Object],[object Object],[object Object]
Total Reduced Sulfur (TRS) Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advances in Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advances in Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advances in Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advances in Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Paper Machine Whitewater
Advances in Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advances in Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Advances in Pollution Control ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

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Env 02

  • 1. FDEP Multi Media Inspector Training
  • 2.
  • 3.
  • 4.
  • 5.
  • 6.
  • 7.
  • 8.
  • 10.
  • 11.
  • 12.
  • 13.
  • 14. Environmental Impacts Use of Bark as Fuel Control Runoff at Transfer Points Control of Particulate Matter (PM) and Visible Emissions (VE) Debarking Housekeeping Monitor Emissions Heavy Equipment Control of runoff Control of Particulate Matter (PM) and Visible Emissions (VE) Bark Storage Control of runoff Control of Particulate Matter (PM) and Visible Emissions (VE) Chip Storage Disposal of Defective Chips as Fuel Control Runoff at Transfer Points Control of Particulate Matter (PM) and Visible Emissions (VE) Chipping Disposal of Defective Logs Control of runoff Dust Control Log Storage Hazardous Waste Disposal of Defective Logs Control of runoff Dust Control Log Handling Solid Waste Wastewater Stormwater Air Activity
  • 15.
  • 16.
  • 17. Log Flume Log Flume Chipping and Debarking Operations
  • 18. Debarking Drum Outside of Debarking Drum
  • 19. Debarking Drum Waste Pile Transfer Tube
  • 20. Chip Storage Open Chip Bin Storage Central column feeds chips to screener and digester
  • 22.
  • 23. Kraft Pulping Pulp Chips Digester White Liquor Weak Black Liquor Pulp Blow Tanks Brown Stock Washers Pulp Shower Water Black Liquor Black Liquor Black Liquor Weak Black Liquor Storage To Evaporators
  • 24. Sulfite Pulping Pulp Chips Digesters Cooking Acid Pulp Blow Pits Red Stock Washers Pulp Shower Water Liquor Liquor Black Liquor Liquor Storage To Evaporators
  • 25. Typical Pulp Washing Hot Stock Refining Blow Tank 1 st Stage Filtrate 2 nd Stage Filtrate 3 rd Stage Filtrate 3 rd Stage Washer 2 nd Stage Washer 1 st Stage Washer Water Pulp Pulp Shower Water Shower Water Pulp w/ Black Liquor Filtrate 12-14% Filtrate xx% Filtrate xx%
  • 26. Environmental Impacts Collection and Control of Pulping Liquor (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (HVLC) Liquor Storage Collection and Control of Pulping Liquor (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (HVLC) Brown Stock Washers Collection and Control of Pulping Liquor (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (LVHC) Blow Tanks Hazardous Waste Collection and Control of Pulping Liquor (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (LVHC) Digesters Solid Waste Wastewater Stormwater Air Activity
  • 27.
  • 28.
  • 29.
  • 30. Brown Stock Washer Washer Hood Washer Drum
  • 31. Batch Digester Cap Chip Loading Capping Valve
  • 34. Recycle Pulper Bales of post consumer waste paper on conveyer Ragger
  • 36. Waste Paper Fines Separator
  • 38. Bleaching Stages Hypochlorite is a true bleaching agent by destroying certain chromophoric groups of lignin. Hypochlorite is used in limited bleaching applications where high pulp yield is critical. Since Hypochlorite attacks the lignin vigorously, some cellulose is also attacked in the process. Hypochlorite (H) Alkali or caustic soda (sodium hydroxide) is effective at solubilizing degraded lignin products. Oxygen, hydrogen peroxide or both are often added to the caustic solution to enhance the removal of organic waste. Extraction (E, E O , E P , E OP ) Chlorine dioxide (ClO2) is a highly selective chemical that can both de-lignify and brighten pulp. It oxidizes lignin, but does not add chlorine atoms onto lignin fragments; however, small amounts of elemental chlorine and other chlorine compounds formed during the chlorine dioxide bleaching process react with degraded lignin to form chlorinated organic compounds. Chlorine Dioxide (D) Elemental chlorine (Cl2) is an effective de-lignifying agent. As it breaks lignin bonds, it adds chlorine atoms to the lignin degradation products, thus producing significant amounts of chlorinated organic material. Elemental Chlorine (C) Description Stage (Symbol)
  • 39. Bleaching Stages (cont.) Ozone (O 3 ) is also an effective delignifying agent. It also brightens the pulp as well. Ozone has not been used in the past because mills have not been able to improve its selectivity - ozone attacks the cellulose fiber as well as the lignin. Recent technological developments, however, have solved this problem and have allowed mills to take advantage of this cost-effective bleaching agent. Ozone (Z) Hydrogen peroxide (H 2 O 2 ) is mainly used to brighten pulps in the final bleaching stages. Peroxide is often used at the end of a conventional bleaching sequence to prevent the pulp from losing brightness over time. Researchers have found operating conditions under which peroxide will delignify pulp, and are working on technologies that will consume less. Hydrogen Peroxide (P) Oxygen (O 2 ) is an inexpensive, highly effective delignifying agent that is usually used at the beginning of the bleaching process. It has intermediate selectivity. Oxygen (O) Description Stage (Symbol)
  • 41. Typical Bleach Plant 1 st Stage Washer Tower 1 st Stage Filtrate 2 nd Stage Washer Tower 3 rd Stage Washer Tower 4 th Stage Washer Tower 2 nd Stage Filtrate 4 th Stage Filtrate 3 rd Stage Filtrate See Typical Bleaching Stage
  • 42.
  • 43.
  • 44. Chlorine Dioxide Washer Washer Hood Inlet Flow
  • 45. Environmental Impacts Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) ClO 2 Production Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) Filtrate Tanks Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) Washers Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) Towers Hazardous Waste Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection of vent gases for regulated stages (MACT) Mixers Solid Waste Wastewater Stormwater Air Activity
  • 46.
  • 47.
  • 48.
  • 49. Paper Machine / Pulp Dryer
  • 50. Fourdrinier Paper Machine Spreads Pulp Stock onto Wire Table 3% Solids 7% Solids 40% -50% of Pulp Stock is Solids 95% of Pulp Stock is Solids Smoothes Surface of Paper Collects Paper Product
  • 51. Environmental Impacts Rewinder Broke and Coating Residue Disposal Defective Paper Wastepaper Disposal Collection and Control of Vent Gases Drying Broke and Coating Residue Disposal Defective Paper Wastepaper Disposal Collection and Control of Vent Gases Pressing Broke and Coating Residue Disposal Prevention of Leaks and Spills Head box Hazardous Waste Disposal of Defective Stock Prevention of Leaks and Spills Collection of Volatile Gases Stock Preparation Solid Waste Wastewater Stormwater Air Activity
  • 52.
  • 53.
  • 54.
  • 55. High Density Pulp Storage Storage Tank Agitation Zone
  • 56. Paper Machine Fourdrinier Headbox Dryline
  • 58.
  • 59.
  • 60. Multiple Effect Evaporators Vapor Dome Tube Bundles Vapor Lines
  • 61. Evaporator Hotwell NCG Collection Hotwell Condensate Collection
  • 62. Environmental Impacts Prevention of organic gas leaks NCG System Prevention of leaks and spills of condensate Prevention of leaks of Hotwell gases Hotwell Prevention of leaks and spills of condensate Prevention of air leaks Evaporator Effects Hazardous Waste Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Prevention of volatile organic compound leaks and spills Weak Liquor Storage Solid Waste Wastewater Stormwater Air Activity
  • 63.
  • 64.
  • 65.
  • 67.
  • 68. Kraft Recovery Boiler NCDE Recovery Boiler ESP Saltcake Mix Tank Drying Reducing Oxidizing Flue Gas Black Liquor Feed Recycle To Stack Chemical Make-up HB Liquor Smelt Bed To Smelt Dissolving Tank 3 o Air 2 o Air 1 o Air
  • 69. Environmental Impacts Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Release of particulate matter Smelt Dissolving Tank Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Multiple regulations requiring ESP Recovery Boiler Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Prevention of leaks and spills of volatile components in black liquor Saltcake Mix Tank Hazardous Waste Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Prevention of leaks and spills of any volatile compounds Heavy Liquor Storage Solid Waste Wastewater Stormwater Air Activity
  • 70.
  • 71.
  • 72.
  • 74. Typical Causticizing Operation White Liquor Clarifier Green Liquor Clarifier Slaker Causticizer From Recovery Area Dregs Washer Weak Wash Storage Lime Mud Filter Lime Mud Washer Lime Kiln Lime Silo To Digester Make Up Water NCG Collection
  • 75. Environmental Impacts Not applicable unless the materials fail paint filter test and have a pH >12.5 Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Multiple regulations requiring ESP and/or scrubber Lime Kiln Not applicable unless the materials fail paint filter test and have a pH >12.5 Excess lime mud may be landfilled. Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Typically no controls Mud Filter Not applicable unless the materials fail paint filter test and have a pH >12.5 Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Typically no controls Causticizer Not applicable unless the materials fail paint filter test and have a pH >12.5 Grits are landfilled after washing and elementary neutralization Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Typically controlled by scrubber or spray Slaker Not applicable unless the materials fail paint filter test and have a pH >12.5 Hazardous Waste Dregs are landfilled after elementary neutralization Good housekeeping and spill control practices Prevention of leaks and spills into stormwater system (SWP 3 ) Typically no controls GL/WL Clarifiers Dregs Washer Solid Waste Wastewater Stormwater Air Activity
  • 76.
  • 77.
  • 78.
  • 79. Lime Kiln Lime Kiln Tube Washing and Causticizing Operations
  • 80. Lime Kiln Lime Kiln Tube Motor and Drive Units Fire Hood
  • 81. Power and Utility Operations
  • 82. Power and Steam Generation Boilers Steam Condensate from mill High Pressure Steam Turbines Electrical Power Low Pressure Steam Kraft Mill Processes
  • 83. Environmental Impacts Solids in steam water carried to turbines Potential release of oils to receiving waters Turbine Generators Solids in steam water carried to turbines Potential release of oils to receiving waters Control of Carbon Monoxide production Combustion Turbine Disposal of Boiler chemicals and fuels Disposal of bottom and fly ash – landfilled Control of non-contact cooling water, scrubber and boiler blowdown Potential release of oils to receiving waters Control of Particulate Matter Emissions Power Boiler Disposal of Boiler chemicals and fuels Hazardous Waste Disposal of bottom and fly ash – landfilled Control of non-contact cooling water, scrubber and boiler blowdown Potential release of oils to receiving waters Control of Particulate Matter Emissions Combination Boiler Solid Waste Wastewater Stormwater Air Activity
  • 84.
  • 85.
  • 86.
  • 88. Acid Tanker Unloading Acid Storage Tank
  • 90. Typical Turpentine Recovery (Kraft) Decanter Cyclone Separator Digester Storage Condenser Relief To HVLC System Turpentine To Condensate Collection To Condensate Collection Truck or Rail Car Loading Black Liquor Black Liquor Secondary Containment
  • 91. Turpentine Decanter Decanter Storage Containment
  • 92. Environmental Impacts Spills are very toxic to WWT system Secondary containment required Collection and Control of Vent Gases (LVLC) Turpentine Storage Spills are very toxic to WWT system Secondary containment required Collection and Control of Vent Gases (LVHC) Turpentine recovery Hazardous Waste Solid Waste Wastewater Stormwater Air Activity
  • 93.
  • 94.
  • 95.
  • 96. Typical Tall Oil Recovery (Kraft) Reactor Sulfuric Acid Black Liquor Soap Tall Oil Brine Tall Oil Storage Decanter or Centrifuge Secondary Containment To Recovery Boiler Truck or Rail Car Loading
  • 98. Environmental Impacts Spills are very toxic to WWT system Prevention of leaks and spills into stormwater system (SWP 3 ) Tall Oil Storage Spills are very toxic to WWT system Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and control in tall oil plant scrubber Acidulation Spills to process sewers cause release of TRS Prevention of leaks and spills into stormwater system (SWP 3 ) Acid Storage Hazardous Waste Spills are very toxic to WWT system Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and Control of Vent Gases (HVLC) Soap Storage Solid Waste Wastewater Stormwater Air Activity
  • 99.
  • 100.
  • 101.
  • 103.
  • 104. Environmental Impacts Ash emissions into wastewater system Ash emissions into stormwater system Uncontrolled emissions of ash NCG Incineration Untreated or untested sludge applied to land Prevention of leaks and spills into effluent system (BMP) Contamination of stormwater system by run-off Uncontrolled hazardous sludge Land Application Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and control of pulping condensate Condensate Treatment Untreated or untested sludge landfilled Excessive buildup of solid residuals Prevention of leaks and spills into effluent system (BMP) Contamination of stormwater system by run-off Odorous emissions Landfill Operations Uncontrolled sludge spills and leaks Hazardous Waste Collection of entering solid residuals Prevention of leaks and spills into effluent system (BMP) Prevention of leaks and spills into stormwater system (SWP 3 ) Collection and control of emitted gases Wastewater Treatment Solid Waste Wastewater Stormwater Air Activity
  • 105.
  • 106.
  • 107.
  • 108. Primary Clarifier Clarifier Unit Wastewater Body
  • 109. Stormwater Collection System Stormwater Collection Operations Good Vegetation Control
  • 110. Stormwater Collection System Stormwater Collection Tunnel Good Vegetation Control
  • 111. Inlet Pond Inlet Water for Mill Operations
  • 112. Pond Outlet Standpipe Standpipe
  • 113. Effluent Monitoring Station Effluent Monitoring Operations
  • 117.
  • 118.
  • 119.
  • 120.
  • 121. Electrostatic Precipitator (ESP) Particulate Laden Flue Gas Positively Charge Collection Plates Discharge Electrodes (-) Clean Gas Particulate Matter Zone 1 Zone 3 Zone 2 Zone 4 Chamber 1 Chamber 2 Chamber 3
  • 122. Electrostatic Precipitator (ESP) ESP Collection Plates Internals of ESP
  • 123. Electrostatic Precipitator (ESP) Dry Bottom ESP ESP Hopper
  • 124.
  • 125.
  • 126. Venturi Scrubbers Cyclonic Separator Contaminated Gas Inlet Scrubbing Liquid Clean Gas Outlet to Atmosphere Body Gas and Liquid start mixing Venturi Max Liquid and Gas Contact Concentrated Liquid for Disposal or Recycle To WWT Facility Elbow Tank
  • 127. Venturi Scrubbers Back Body and Venturi Sections Cyclonic Separator Contaminated Gas Inlet
  • 128.
  • 129. Packed Bed Scrubbers Packed Bed Contaminated Gas Inlet Concentrated Liquid for Disposal or Recycle Scrubbing Liquid Clean Gas Outlet to Atmosphere
  • 130. Packed Bed Scrubbers Back Inlet Gas from Operations Packed Bed Column Exhaust to Atmosphere
  • 131.
  • 132.
  • 133.
  • 134. Incinerators Back Inlet Gas Flow Primary Burner Outlet Gas Flow
  • 135.
  • 136.
  • 137.
  • 138. Steam Stripper Stage Trays Inlet Steam Cleaned Condensate Contaminated Condensate Steam containing condensate pollutants Reflux Condenser Heat Exchanger
  • 139. Steam Stripper Back Stripping Column Reflux Condenser
  • 140.
  • 141.
  • 142. Baghouse Back Dust Hopper Clean Air to Atmosphere Particulate Laden Gas Filter Bags Shaker Device
  • 144.
  • 145.
  • 146. LVHC (NCG) Collection Systems Digester Wood White Liquor Turpentine Recovery System Washer System Part of HVLC System Pulp Weak Black Liquor Blow Heat Accumulator Blow Tank Multiple Effect Evaporators Pulp Liquor Pulp Liquor Back LVHC Collection
  • 147.
  • 148. HVLC (NCG) Collection Systems Pulp Washing System Knotter System Pulp Liquor from Blow Tanks Storage Tank Weak Black Liquor Screening System Decker To Multiple Effect Evaporators Oxygen Delignification System Washer Back HVLC Collection HVLC Collection HVLC Collection
  • 149.
  • 150.
  • 151. Condensate Collection Systems Back Turpentine Decanter Cyclone Separator Digester Turpentine Storage Condenser Relief Condensate Collection Condensate Collection Loading Condensate Collection Effect 5 Surface Condenser Steam Effect 2 Effect 1 Effect 3 Effect 4 Condensate Collection Hotwell Clean Condensates Wood Liquor
  • 152.
  • 153.
  • 154.
  • 155.
  • 156.
  • 157.
  • 158.
  • 159.
  • 160.
  • 162.
  • 163.
  • 164.