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Root canal sealers
INDIAN DENTALACADEMY
Leader in continuing Dental Education
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Contents
 Introduction
 Requirements of sealer
 Functions
 Classification
 Zinc oxide eugenol sealers
 Paraformaldehyde sealers
 Guttapercha based sealers
 Resin sealers
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 Resorbable sealers
- Iodoform pastes
- Biocalex
- Calcium hydroxide
- Calcium phosphate
 GIC and polycarboxylate sealers
 Mixing &placement of sealer
 Tissue tolerance of sealers
 Conclusion
 References
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Introduction
The use of sealer during root canal obturation
enhances the possible attainment of an
impervious seal and serves as filler for canal
irregularities and minor discrepancies between
the root canal and core filling material
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Requirements of root canal sealer
The ideal root canal cement should (Grossman 1940)
 provide an excellent seal when set
 should be tacky when mixed to provide adequate
adhesion among it , the canal walls and the filling
material
 be radiopaque so that it can be visualized in the
radiograph
 be non staining
 particles of powder should be very fine so that they can
mix easily with the liquid
 be dimensionally stable
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 be easily mixed and introduced into the canal
 be easily removed when necessary
 insoluble to tissue fluids
 bactericidal or discourage bacterial growth
 slow setting to ensure sufficient working time
 tissue tolerant , that is non irritating to the
periradicular tissues
 should not provoke an immune response in
periradicular tissues
 non mutagenic nor carcinogenic
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Functions of Sealer
 Cementing the core
 Germicidal
 Fills the discrepancies between the filling
material and the dentin wall.
 Form a bond between the filling material and
the dentin walls
 Radiopacity which discloses the presence of
auxiliary canals, resorptive areas, root
fractures and the shape of the apical foramen.
 Lubricant which aids in the seating of GP
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Classification
ADA specification No 57. classifies endodontic
filling material as follows
Type I. Core and auxiliary points to be used with
sealer cements
Class 1.Metallic
Class 2.Polymeric
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Type II: Sealer cements to be used with core
materials
Class 1. Powder and liquid nonpolymerizing
Class 2. Paste and paste nonpolymerizing
Class 3. Polymer resin system
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Type III: Filling materials to be used without core
materials or sealer cements
Class 1. Powder and liquid nonpolymerizing
Class 2. Paste and paste nonpolymerizing
Class 3. Metal amalgams
Class 4. Polymers
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Based on their prime constituent or structure
1.Zinc oxide –eugenol : Eg. Rickerts , Tubliseal,
Grossman
2. Calcium hydroxide sealers: eg.: CRCS,Apexit
3. Resins: Eg. Diaket, AH26
4.Glass ionomers: Eg.Ketac-Endo
5.Silicones Eg: Lee –Endo fill
6. Gutta percha based: Kloropercha, Eucapercha
7. Dentin adhesive materials: Eg:Cyanoacrylates ,
dentin bonding agents, polycarboxylates
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Based on the addition of medication:
Therapeutic cements
a) supposed to aid in cementogenesis and
dentinogenesis
EG: Calcium hydroxide sealers
b) Suppress post operative pain , contain strong
disinfectants& antiphologistics
Eg: Paraformaldehyde containing sealers
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Based on permeability
a) Highly Permeable: Eg: Calcium phosphate,
Calcium hydroxide etc
b) Moderately permeable : GIC sealers,
Polycarboxylate sealers
Based on Longetivity:
a) Resorbable pastes: Eg: Iodoform pastes,
Calcium hydroxide, Biocalex
b) Partially resorbable: Eg: All the other sealers
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Zinc oxide –Eugenol sealers
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Zinc oxide –Eugenol sealers
 Chisolm introduced zinc oxide and oil of clove (unrefined
eugenol) cement to dentistry in 1873.
Setting reaction:
 combination of chemical process with physical
embedding of, zinc oxide in a matrix of zinc eugenolate.
 excess eugenol is absorbed by zinc oxide and
eugenolate.
 hardening due to formation of Zinc eugenolate and
unreacted eugenol weaken the mass
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Factors influencing the setting reaction:
 presence of water
 Particle size of zinc oxide
 pH
 additives
 method of preparation
 temp and humidity
 time of spatulation
 presence of unreacted eugenol
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General constituents of ZOE sealers
 Mixing vehicle is eugenol
 Zinc oxide is finely sifted to enhance flow
 1mm of ZnO has a radiopacity corresponding to 4 to 5
mm of aluminium
 Effective antimicrobial
 Cytoprotection to cells
ROSIN:
 derived from conifers have 90% resin acid
 Remaining parts volatile &nonvolatile components like
terpene alcohol, aldelhydes and hydrocarbons
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 resin acids are monobasic carboxylic acids
 amphiphilic , carbon groups lipophilic , affecting
the lipids in the cell membrane,increases cell
membrane permeability
 strong antimicrobial effect and cytotoxicity
 reacts under certain conditions , to from resin
acid salt(resinate), this is less soluble in water.
Paraformaldehyde is added for antimicrobial and
mummifying action
Germicides like thymol for anttimicrobial
Corticosteroids for suppression of inflammatory
reactions
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Rickert’s formula (Kerr Pulp canal sealer)
Developed in 1931
Powder
 zinc oxide powder- 41.21 parts
 precipitated silver – 30 parts
 White resin – 16 parts
 thymol iodide- 12.79 parts
Liquid:
 oil of cloves-78 parts
 Canada balsam – 22 parts
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Indications:
 Vertical condensation of warm gutta percha when
large bulk of sealer is needed
 when lateral canals are anticipated, for silverpoints.
Contraindications
has staining qualities , needs to be removed from
crown.
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Advantage: great bulk , so can be pushed into
voids and irregularities
Disadvantage: presence of silver makes the sealer
extremely staining if material enters the tubules
or enters the crown
Properties:
 Excellent lubrication.
 Working time of 30 min
 L:P ratio : 1:1
 Germicidal action
Mixed with a heavy spatula until homogeneity is
obtained
Because of the presence of silver, some granular
appearance remains even after spatulation.www.indiandentalacademy.com
-Rapid setting of Rickerts formula lead to
development of Grossman’s formula in 1936,
known as ProcoSol radiopaque silver cement.
Powder:
 Zinc oxide -45 parts
 Silver (precipitated) -17 parts
 Hydrogenated resin – 36 parts
 Magnesium oxide -2 parts
Liquid:
 Eugenol -90 parts
 Canada Balsam -10 parts
Grossman’s formula
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- Precipitated silver lead to staining , lead to the
development of ProcoSol nonstaining root canal
cement
Powder:
 Zinc oxide , reagent 40 parts
 Staybelite resin 30parts
 Bismuth subcarbonate 15 parts
 Barium sulfate 15 parts
 Sodium borate, anhydrate 1 part (extends the setting
time)
Liquid
 Eugenol or oil of pimenta leaf
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Advantages: plasticity , slow setting time in
the absence of moisture, good sealing
potential because of the small volumetric
change on setting
Cement hardens in app 2 hours at 37
degree and 100% relative humidity
Setting time in canal is less
Begins to set in root canal within 10 to 30
min because of the moisture present in
dentin
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Tubliseal(Kerr , 1961)
Base:
Zinc oxide – 57.4%
Oleo resins- 21.25%
Bismuth trioxide – 7.5%
Oils – 7.5%
Thymol iodide – 3.75%
Modifier – 2.6%
Catalyst:
Eugenol
Polymerized resin
Annidalin
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Indications:
 When extreme lubrication is needed, as in
slightly short master cone, before apical surgery.
Contraindications:
 Irritating to periapical tissues, not to be used if
overfill probable with normal periapical tissue.
 Sets very rapidly when wet
Packaging: two tubes , accelerator and base
 Mixing: mix equal lengths to creamy consistency
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Properties:
Easy to mix
Non staining
Allows maximal condensation and packing
Is white in color with good contrast
Good lubricating qualities
Advantages:
 ease of preparation
High rate of flow, thinner film ,
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Disadvantage:
Irritating to periapical tissues, causing
considerable periapical sensitivity when
used on teeth where pulp was vital and
the periapical tissue normal before
treatment.
Rapid set in the presence of moisture
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Wach’s paste (Wach 1925-1955)
Powder:
 Zinc oxide 10g
 bismuth subnitrate -3.5 g
 bismuth subiodide -0.3 g
 magnesium oxide – 0.5g
 tri calcium phosphate-2 g
Liquid:
 Canada balsam 20 ml
 oil of cloves- 6ml,
 eucalyptol 0.5 ml
 beechwood creosote -0.5 ml.
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Indications: all lateral condensation methods,
especially when chance of overfilling is present
Adhesive , good for lateral compaction in small
canals, softens gutta percha ,
Contraindication: when heavy lubrication is
needed , as with short master cone.
Advantage: smooth consistency without a heavy
body
Canada balsam makes the sealer tacky
Disadvantage: odor of liquid
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Properties:
 medium working time, less lubricating qualities
 Minimal periapical sensitivity
 Increasing the thickness of sealer lessens its
lubricating effect, thus when an overfilling
appears possible , a maximal degree of
thickness should be employed.
 Useful in small curved canals of minimal caliber,
 Has light body , so does not deflect the small
master gutta percha cones used to fill these
canals.
 Its is very sticky , due to Canada balsam, so
paste will remain on reamer until its spun off in
the apical portion,
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Nogenol :
 Base is zinc oxide , barium sulfate , vegetable oil
 Accelerator is : hydrogenated rosin, methyl
abietate, lauric acid, chlorothymol, salicyclic
acid
 Developed to overcome the irritating quality of
eugenol
 Did not set hard, but remained rubbery , water
sorption was high.
 More biocompatible than ZOE cements.
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PARAFORMALDEHYDE ROOT FILLING
MATERIALS
N2(sargenti 1973)
Powder:
 Zinc oxide - 69% Liquid:
 Lead tetroxide-12% Eugenol
 Paraformaldehyde 6.5%
 Bismuth subcarbonate 5%
 Bismuth subnitrate 2%
 Titanium dioxide 2%
 Barium sulphate 2%
 Hydrocortisone 1.2%
 Prednisolone 0.21%
 Phenylmercuric borate 0.09%
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 Known as RC2B &used in sargenti technique
 Contains lead and mercury which are major
systemic poisons
 Loses volume due when exposed to fluid due to
presence of paraformaldehyde
 Coagulation necrosis in 3 days time, which can’t
undergo repair due to formaldehyde
impregnation
 Irreversibly affects nerve endings in tissue area,
thereby masking inflammation process
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 Paraformaldehyde is included to obtain release
of formaldehyde gas for antiseptic and fixative
action
 Corticosteriods for suppressing inflammatory
reaction
 lead as an oxide, which by increasing the
opacity gives the illusion of the materials
compactness, and contribute to the extreme
hardness and slow solubility of the final set.
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ENDOMETHASONE
Powder
 Di –iodothymol 25 g
 Trioxymethylene (paraformaldehyde) -2.2g
 Hydrocortisone acetate – 1 g
 Dexamethasone 0.01g
 Excipient 71.79 g
Liquid
• Eugenol
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Riebler’s paste( Riebler)
Powder
Zinc oxide
Formaldehyde
Barium sulfate
Phenol
Liquid:
Formaldehyde
Sulfuric acid
Ammonia
Glycerin
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SPAD
• it’s a resorcinol –formaldehyde resin
• supplied as powder and two liquids
Powder:
• Zinc oxide – 72.9%
• Barium sulphate -13%
• Titanium dioxide – 6.3%
• Paraformaldehyde – 4.7%
• Hydrocortisone acetate- 2%
• Calcium hydroxide – 0.94%
• Phenyl mercuric borate 0.16%www.indiandentalacademy.com
Liquid (clear)
• Formaldehyde 87%
• Glycerin 13%
Liquid LD (red)
• Glycerin 55%
• Resorcinol 25%
• Hydrochloric acid 20%
• Equal parts of the two liquids mixed with powder.
• Essential reaction to form resin is between
resorcinol and formaldehyde
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 An acidic pH is needed for this reaction, this is
provided by HCl.
 Large amount of zinc oxide is to control the pH
and so prolong the setting time
 inclusion of HCl is not harmful ,pH at the time of
mixing was 5.2 and rose to 6.2 after 2 hrs , due
to the neutralizing effects of Zinc oxide
 setting time of spad is 24 hrs, during this period
there is free unreacted formaldehyde,.
 solubility of spad is 4 % after 24 hrs.
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Tissue response:
 Pulpal necrosis, periapical inflammations and
necrosis,
Toxicologic studies:
 Systemic absorption of lead and
paraformaldehyde
 Heavy metal ions- disseminated throughout the
body
 Irrevisible damage to nerve endings
-paraformaldehyde
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Gutta percha based materials
Chloropercha(Moyco)
 Mixing white gutta percha 9% with chloroform 91%
 Premixed sealer
 Has no adhesive properties
Kloropercha (Nygard –Ostby)
 Powder liquid mixture
 Powder :
Canada balsam -19.6
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Resin – 11.8%
Gutta percha – 19.6%
Zinc oxide – 49%
Liquid:
Chloroform -100 %
 Zinc oxide is added to reduce shrinkage, also
increases radiopacity
 Shrinkage of 7.5% is seen
 Chloroform evaporates leading to loss of volume
and “dropping “ of filling into the periapical area
 Chloroform is toxic
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Eucapercha:
 Eucalyptol is used
 Takes longer than chloroform
 Has antibacterial and anti-inflammatory action
 Segment of gutta percha held over alcohol lamp
for 20 to 30 sec
 Eucapercha dissolves and turns into a cloudy
mass
Indications: ledge formation, perforation, unusual
curvatures, in cases in which the apical foramen
cannot be successfully sealed
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Resin sealers
AH26:
-schroder , 1957
Powder:
 Silver powder – 10%
 Bismuth oxide 60%
 Hexamethylene tetramine -25%
 Titanium oxide – 5%
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Liquid:
 Bisphenoldiglyicdyl ether -100%
Packaging: Powder and liquid
Mixing: mixed to a creamy consistency
Properties:
 Good flow
 Seals well to dentin walls
 Sufficient working time
 Toxicity in the first 24 hrs due to release of
formaldehyde
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 Strong adhesive & contracts on hardening
 Schroder – well tolerated by tissues. Tends to
disintegrate into fine granules which are
phagocytosed
 Hardens slowly at body temperature in 36 to 48
hrs
 Its not sensitive to moisture, will set under
water.
 Will not set if hydrogen peroxide is present
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 Sets slowly in 24 to 36 hrs
 Mixed cement should be warmed on glass slab
over alcohol flame to make it less viscous
 Sold world wide as therma seal
Disadvantages:
 Allergenic /mutagenic potential
 possible formaldehyde release
 silver containing
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• AH PLUS:
 Comes in a paste-paste system
 Added new amines to maintain the natural color
of tooth
 Working time of 4 hrs , setting time of 8 hrs,
half the film thickness, and half the solubility of
regular AH26.
 Non mutagenic , no release of formaldehyde,
radiopaque, can be used with all techniques
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Diaket:
.Introduced by schmidt
Powder:
Zinc oxide
Bismuth phosphate
Liquid:
Dihydroxy dichlorophenylmethane
Propionylacetophenone
Triethanolamine
Caproic acid
Copolymers of vinyl acetate, vinyl chloride, vinyl
isobutylether
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 Polyketone compound with vinyl polymers that
mixed with zinc oxide and bismuth phosphate
forms a adhesive sealer
 Sets quickly in root canal
 Volume stability is good
 Solubility is low
 Powder liquid ratio : 1:2
 Gross overfilling caused modification of apical
cementum and alveolar bone
 Has a tendency to be encapasulated by fibrous
capsule
 Adheres well to dentin
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Lee –Endo Fill
 Used as a sole material or sealer with GP
 Consists of silicone material, silcone based
catalyst plus bismuth subnitrate filler
 Low toxicity
 Sets to pale pink rubbery solid
 Sole filling material : avoid using NaOCl or
peroxide as they affect polymerization
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 Setting time is 8 to 90 min depending on the
catalyst used
 Increased catalyst –increased shrinkage
 Decreased bonding to dentin if not used within
20 min of mixing
 Removed with GG drills and peeso reamers
Adv:
Non discoloring, no shrinkage upon
polymerization, non resorbable ,low viscosity,
good adaptation , good penetration of accessory
canals
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Injection technique of obturating canals
 Greenberg –pressure syringe to extrude cement
into a canal
 Krakow and berk popularized the idea
Hydron:
 Goldman introduced
 Rapid setting hydrophilic plastic material used as
a root canal sealer without the use of a core.
 Grossman defined it as a polymer of hydroxyl-
ethyl methacrylate
 Biocompatible material that conforms to the
shape of the root canal because of its plasticity.
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 Canal must be dry , it sets in the root canal in 10
min
 Requires a special syringe and a needle
 Precaution: it is injected as an unset material
and the polymers that hasten its set can cause
tissue toxicity resulting in inflammation with
marcrophage activity.
 Can cause paraesthesia
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Resorbable root filling materials:
Def: pastes which does not set after being
introduced into the root canal and which is
rapidly removed if forced into the periapical
region .Eg: iodoform and calcium hydroxide
pastes
Mynol Cement:
Powder: Liquid:
Zinc oxide Eugenol
Iodoform Creosote
Rosin Thymol
Bismuth sub nitrate
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Walkhoff Paste
 Devised by walkhoff in 1928
 consists of 60 parts of iodoform and 40 parts of a
solution containing 45 percent parachlorphenol , 49%
camphor , and 6% menthol.
 commercially known as Kri paste
 Used in the walkhoff method of treatment, the paste is
forced beyond the apex, irrespective of the state of the
apex,
 if sinus tract is present, forced paste propelled beyond
the canal until it extrudes into the sinus opening.
 in the absence of sinus tract, opening is made in the
buccal cortical plate over the root apex
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MAISTO’S PASTE
 Zinc oxide – 14g
 Iodoform - 42g
 Thymol-2g
 Chlorophenol camphor- 3 cc
 Lanolin – 0.50g
VITAPEX
 Iodoform -40.4%
 Calcium hydroxide- 30.3%
 Silicone – 22.4%
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Advantages over Zinc oxide eugenol pastes
 Iodoform pastes are easily resorbed from the
periradicular region, cause no foreign body reaction,
removal of paste occurs due to a combination of
leaching, phagocytosis and direct drainage to associated
lymph nodes (Barker&Lockett ), whereas ZOE causes
periradicular irritation.
 paste disappears from the root canal itself, with the
ingrowth of tissue into the canal.
 Bactericidal to microorganism in the root canal and lose
only 20% potency over a 10 year period, ZOE –
bactericidal only in presence of formaldehyde.
 they don’t set as hard as ZOE, so easy removal from the
canal.
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Disadvantage:
 yellowish –brown discoloration if not removed
from the pulp chamber
 lead to a rise in blood level of iodine , should not
be used in patients sensitive to iodine.
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BIOCALEX
Biocalex 6-9 , developed and introduced by
Bernard under the name of ‘ocalex’.
Powder
 Zinc oxide & calcium oxide
Liquid
 Ethylene glycol and water
 used as both intracanal medicament and as root
filling
 paste expands to more than six times its original
volume, penetrating all parts of the root canal
system
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Mechanism of action:
 Calcium oxide and water react with the tooth to
form calcium hydroxide which ionizes to release
OH- ions, which has an antiseptic action , in
addition it decompose necrotic pulpal tissues to
form water and carbon dioxide,
 water combines with residual calcium oxide ,
leads to further calcium hydroxide formation .
 Carbon dioxide reacts with calcium hydroxide to
form calcium carbonate, which is deposited on
the root canal walls.
 Chemical incineration of canal contents occurs,
with sterilization by the action of hydroxyl ions
and sealing of the canal by the deposition of
calcium carbonate
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Adv:
 obviates the need for root canal preparation.
Disadvantage:
 doubts regarding the breakdown of necrotic
pulpal tissue, so making it doubtful whether the
co2 necessary for calcium carbonate formation
is formed.
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Sealapex:
Base:
Calcium hydroxide : 25%
Zinc oxide :6.5%
Catalyst:
Barium sulfate :18.6%
Titanium dioxide : 5.1%
Zinc Stearate :1.0%
Calcium hydroxide cement
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 Osteogenic, possible dissolution , expands on
setting
 In 100% humidity takes upto 3 wks to reach a
final seal.
LIFE: a calcium hydroxide liner is used a sealer
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CRCS(Calciobiotic root canal sealer)
Powder:
Calcium Hydroxide
Zinc oxide
Bismuth dioxide
Barium sulfate
Liquid:
Eugenol
Eucalyptol
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 Takes 3 days to set fully in dry or humid
environments
 Little water sorption
 Stable ,
 Softens gutta percha , good for lateral
compaction , viscous, adhesive
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Apexit
Base:
Calcium hydroxide : 31.9%
Zinc oxide : 5.5%
Calcium oxide : 5.6%
Silicon oxide : 8.1%
Zinc stearate : 2.3%
Hydrogenized colophony : 31.5%
Tricalcium phosphate :4.1%
Polydemethylsiloxane :2.5%
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Activator:
Trimethyl hexanedioldisalicylate : 25%
Bismuth carbonate basic : 18.2%
Bismuth oxide : 18.2%
Silicon dioxide :15%
1,3-Butanedioldisalicylate :11.4%
Hydrogenized colophony :5.4%
Tricalcium phosphate :5.%
Zinc stearate :1.4%
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• DENTALIS:
ZoE, calcium hydroxide, iodoform, sets rapidly and
is very tacky
CH 61
P/L ratio: 1.2g/ml
Powder:
Calcium hydroxide -55%
Bismuth subcarbonate- 30%
Rosin -10
Zinc oxide -5
Liquid:
Fatty acids- 85%
Propylene glycol-15%
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Disadvantages:
 to be effective calcium hydroxide must dissolve and the
solid consequently lose content.
 Calcium hydroxide may dissolve, leaving obturation
voids, which will cause poor seal.
 Have poor cohesive strength
 No proof exists that they have any desirable biologic
effects
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Calcium Phosphate Paste
 ADA- PAFFENBERG DENTAL RESEARCH CENTER
 Developed a simple mixture of calcium
phosphates that sets to become hydroxyapatite
 Two calcium phosphate compounds , one acidic
and one basic when mixed with water they set
into a hardened mass –hydroxyapatite –the
principal mineral in teeth and bones.
 Tetracalcium phosphate is the basic constituent
 Dicalcium phosphate dehydrate or anhydrous
dicalcium phosphate is the acidic component.
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• Water is neither a reactant nor an imp product in the
reaction but merely a vehicle for dissolution of the
reactants
• Setting time extended by adding glycerin to the mixture
• Mild phosphoric acid solution speeds the dissolution of
the components
• Final set calcium phosphate cement consists of nearly all
crystalline material, and porosity is indirect ratio to the
amount of solvent used.
• It is as radiopaque as bone.
• Nearly insoluble in water and is insoluble in saliva and
blood.
• There was no dye penetration into the filler canal wall
interface
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• Tissue reactions: mild irritation after 1 month ,
new bone formation was observed adjacent to
the cement.
• Had no toxicity and all tests for mutagenicity and
potential carcinogenicity of CPC negative
• G-5 and G-6 are apatite sealers.
• BIOSEAL : ZOE to hydroxyapatite
www.indiandentalacademy.com
 CPC: hydroxyapatite is a naturally occurring
product, and that bone grows into and eventually
replaces extruded material , makes it biologically
acceptable.
 Another possibility of using hydroxyapatite
relates to the laser : a cross linked collagen
hydroxyapatite mixture has been placed in the
root canal and melted to place with a laser beam
through a fiber optic.
www.indiandentalacademy.com
 not advocated
 leaching into periradicular tissues
 porosity in paste fills
 most pastes absorb in time – leading to apical
leakage, percolation, ultimate treatment failure
 chemical components of paste causes
immunologic responses.
 Apical control of paste fills is impossible
PASTES AS FILLING MATERIALS:
www.indiandentalacademy.com
Polycarboxylates
 Are effective provided adequate contact is made
with the canal wall
 Disadvantage: need for special plastic
instruments due to its great adhesiveness to
metal
www.indiandentalacademy.com
KETAC-ENDO
 Pitt ford recommended use of GIC
 Chemical bonding to dentinal walls of the root
canal preventing percolation and bacterial
penetration at sealer-dentin interface
 Low toxicity
Disadvantages:
 Difficulty in retrieval
www.indiandentalacademy.com
New sealers
Bis –GMA( difficult to remove)
Isopropyl cyanoacrylate
Polyamide varnish
Dentin bonding agents –good sealers
because of their ability to halt
microleakage
www.indiandentalacademy.com
Problems with dentin bonding agents:
 preparation of dentin to remove smear layer
 radiopacity , metal salts need to be added, which
can affect polymerization
 placement to ensure total, porosity free
placement
 removal in the event of failure
www.indiandentalacademy.com
Mixing of sealer
 Root canal cement is mixed on a sterile glass
slab with a sterile spatula.
 Slab is sterilized by an alcohol scrub and is dried
ant the spatula is passed through an open flame
two of three times. Small increments of powder
are added to the liquid while one spatulates it to
a smooth creamy mix. Spatulation time depends
on the number of drops of liquid used, a min per
drop
www.indiandentalacademy.com
 Completed mix can be tested for proper
consistency by raising the flat blade of the
spatula up form the mixed mass. The cement
should “string out” for at least an inch before
breaking.
 Another test is the suspended mix should cling
to the inverted spatula blade for 10 to 15 sec
before dropping from the spatula
www.indiandentalacademy.com
Placement of sealer
 Reamer : is twirled counterclockwise, pumped
and wiped against the walls
 Absorbent paper points or gutta percha :
pumping
 Lentulo spiral: in a handpiece
Disadv: locking in canal, “whipping up” of cement
in canal causing it to set prematurely
 Ultrasonic file without use of a coolant
www.indiandentalacademy.com
Sealer efficacy:
 Hovland and Dumsha
 “Although all root canal sealers leak to some extent –
there is probably a critical level of leakage that is
unacceptable for healing and therefore result in
endodontic failure. This leakage may occur at the
interface of the dentine and sealer , at the interface of
the solid core and sealer, through the sealer itself ,of by
dissolution of the sealer”
 All sealers leak . some leak more than others mostly
through dissolution.
 The greater the sealer/periradicular tissue , the faster
dissolution takes place
www.indiandentalacademy.com
Tissue tolerance :
Zinc oxide and Eugenol:
 All ZoE sealers dissolve in fluid releasing
eugenol which is irritating.
 Zinc oxide is also toxic due to the effect of zinc
ions.
 CRCS was the least cytotoxic followed by
AH26 ,
 Prraformaldehyde most toxic
 Ketac Endo most biocompatible.
www.indiandentalacademy.com
 In vivo tissue tolerance examination:
 Erausquin and Muruzabal – found that ZOE was
highly irritating to the periradicular tissues and
caused necrosis of bone and cementum.
 Least irritating was Diaket and AH-26 .
 Diaket becomes encapsulated
 AH-26 was resorbed
www.indiandentalacademy.com
Conclusion
The selection of a sealer is based on
amount of lubrication needed, the length
of working time estimated, and the filling
material to be used .
www.indiandentalacademy.com
References
 Pathways of the pulp , Cohen , (4th
,5th
, 6th
, 7th
, 8th
edition)
 Endodontics , Ingle (4th
,5th
edition)
 Endodontic therapy , Weine(5th
and 6th
edition)
 Endodontics in clinical practice , Harty(3rd
&4th
Edition)
 Journal references
www.indiandentalacademy.com

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Root canal sealers /endodontic courses

  • 1. Root canal sealers INDIAN DENTALACADEMY Leader in continuing Dental Education www.indiandentalacademy.com
  • 2. Contents  Introduction  Requirements of sealer  Functions  Classification  Zinc oxide eugenol sealers  Paraformaldehyde sealers  Guttapercha based sealers  Resin sealers www.indiandentalacademy.com
  • 3.  Resorbable sealers - Iodoform pastes - Biocalex - Calcium hydroxide - Calcium phosphate  GIC and polycarboxylate sealers  Mixing &placement of sealer  Tissue tolerance of sealers  Conclusion  References www.indiandentalacademy.com
  • 4. Introduction The use of sealer during root canal obturation enhances the possible attainment of an impervious seal and serves as filler for canal irregularities and minor discrepancies between the root canal and core filling material www.indiandentalacademy.com
  • 5. Requirements of root canal sealer The ideal root canal cement should (Grossman 1940)  provide an excellent seal when set  should be tacky when mixed to provide adequate adhesion among it , the canal walls and the filling material  be radiopaque so that it can be visualized in the radiograph  be non staining  particles of powder should be very fine so that they can mix easily with the liquid  be dimensionally stable www.indiandentalacademy.com
  • 6.  be easily mixed and introduced into the canal  be easily removed when necessary  insoluble to tissue fluids  bactericidal or discourage bacterial growth  slow setting to ensure sufficient working time  tissue tolerant , that is non irritating to the periradicular tissues  should not provoke an immune response in periradicular tissues  non mutagenic nor carcinogenic www.indiandentalacademy.com
  • 7. Functions of Sealer  Cementing the core  Germicidal  Fills the discrepancies between the filling material and the dentin wall.  Form a bond between the filling material and the dentin walls  Radiopacity which discloses the presence of auxiliary canals, resorptive areas, root fractures and the shape of the apical foramen.  Lubricant which aids in the seating of GP www.indiandentalacademy.com
  • 8. Classification ADA specification No 57. classifies endodontic filling material as follows Type I. Core and auxiliary points to be used with sealer cements Class 1.Metallic Class 2.Polymeric www.indiandentalacademy.com
  • 9. Type II: Sealer cements to be used with core materials Class 1. Powder and liquid nonpolymerizing Class 2. Paste and paste nonpolymerizing Class 3. Polymer resin system www.indiandentalacademy.com
  • 10. Type III: Filling materials to be used without core materials or sealer cements Class 1. Powder and liquid nonpolymerizing Class 2. Paste and paste nonpolymerizing Class 3. Metal amalgams Class 4. Polymers www.indiandentalacademy.com
  • 11. Based on their prime constituent or structure 1.Zinc oxide –eugenol : Eg. Rickerts , Tubliseal, Grossman 2. Calcium hydroxide sealers: eg.: CRCS,Apexit 3. Resins: Eg. Diaket, AH26 4.Glass ionomers: Eg.Ketac-Endo 5.Silicones Eg: Lee –Endo fill 6. Gutta percha based: Kloropercha, Eucapercha 7. Dentin adhesive materials: Eg:Cyanoacrylates , dentin bonding agents, polycarboxylates www.indiandentalacademy.com
  • 12. Based on the addition of medication: Therapeutic cements a) supposed to aid in cementogenesis and dentinogenesis EG: Calcium hydroxide sealers b) Suppress post operative pain , contain strong disinfectants& antiphologistics Eg: Paraformaldehyde containing sealers www.indiandentalacademy.com
  • 13. Based on permeability a) Highly Permeable: Eg: Calcium phosphate, Calcium hydroxide etc b) Moderately permeable : GIC sealers, Polycarboxylate sealers Based on Longetivity: a) Resorbable pastes: Eg: Iodoform pastes, Calcium hydroxide, Biocalex b) Partially resorbable: Eg: All the other sealers www.indiandentalacademy.com
  • 14. Zinc oxide –Eugenol sealers www.indiandentalacademy.com
  • 15. Zinc oxide –Eugenol sealers  Chisolm introduced zinc oxide and oil of clove (unrefined eugenol) cement to dentistry in 1873. Setting reaction:  combination of chemical process with physical embedding of, zinc oxide in a matrix of zinc eugenolate.  excess eugenol is absorbed by zinc oxide and eugenolate.  hardening due to formation of Zinc eugenolate and unreacted eugenol weaken the mass www.indiandentalacademy.com
  • 16. Factors influencing the setting reaction:  presence of water  Particle size of zinc oxide  pH  additives  method of preparation  temp and humidity  time of spatulation  presence of unreacted eugenol www.indiandentalacademy.com
  • 17. General constituents of ZOE sealers  Mixing vehicle is eugenol  Zinc oxide is finely sifted to enhance flow  1mm of ZnO has a radiopacity corresponding to 4 to 5 mm of aluminium  Effective antimicrobial  Cytoprotection to cells ROSIN:  derived from conifers have 90% resin acid  Remaining parts volatile &nonvolatile components like terpene alcohol, aldelhydes and hydrocarbons www.indiandentalacademy.com
  • 18.  resin acids are monobasic carboxylic acids  amphiphilic , carbon groups lipophilic , affecting the lipids in the cell membrane,increases cell membrane permeability  strong antimicrobial effect and cytotoxicity  reacts under certain conditions , to from resin acid salt(resinate), this is less soluble in water. Paraformaldehyde is added for antimicrobial and mummifying action Germicides like thymol for anttimicrobial Corticosteroids for suppression of inflammatory reactions www.indiandentalacademy.com
  • 19. Rickert’s formula (Kerr Pulp canal sealer) Developed in 1931 Powder  zinc oxide powder- 41.21 parts  precipitated silver – 30 parts  White resin – 16 parts  thymol iodide- 12.79 parts Liquid:  oil of cloves-78 parts  Canada balsam – 22 parts www.indiandentalacademy.com
  • 20. Indications:  Vertical condensation of warm gutta percha when large bulk of sealer is needed  when lateral canals are anticipated, for silverpoints. Contraindications has staining qualities , needs to be removed from crown. www.indiandentalacademy.com
  • 21. Advantage: great bulk , so can be pushed into voids and irregularities Disadvantage: presence of silver makes the sealer extremely staining if material enters the tubules or enters the crown Properties:  Excellent lubrication.  Working time of 30 min  L:P ratio : 1:1  Germicidal action Mixed with a heavy spatula until homogeneity is obtained Because of the presence of silver, some granular appearance remains even after spatulation.www.indiandentalacademy.com
  • 22. -Rapid setting of Rickerts formula lead to development of Grossman’s formula in 1936, known as ProcoSol radiopaque silver cement. Powder:  Zinc oxide -45 parts  Silver (precipitated) -17 parts  Hydrogenated resin – 36 parts  Magnesium oxide -2 parts Liquid:  Eugenol -90 parts  Canada Balsam -10 parts Grossman’s formula www.indiandentalacademy.com
  • 23. - Precipitated silver lead to staining , lead to the development of ProcoSol nonstaining root canal cement Powder:  Zinc oxide , reagent 40 parts  Staybelite resin 30parts  Bismuth subcarbonate 15 parts  Barium sulfate 15 parts  Sodium borate, anhydrate 1 part (extends the setting time) Liquid  Eugenol or oil of pimenta leaf www.indiandentalacademy.com
  • 24. Advantages: plasticity , slow setting time in the absence of moisture, good sealing potential because of the small volumetric change on setting Cement hardens in app 2 hours at 37 degree and 100% relative humidity Setting time in canal is less Begins to set in root canal within 10 to 30 min because of the moisture present in dentin www.indiandentalacademy.com
  • 25. Tubliseal(Kerr , 1961) Base: Zinc oxide – 57.4% Oleo resins- 21.25% Bismuth trioxide – 7.5% Oils – 7.5% Thymol iodide – 3.75% Modifier – 2.6% Catalyst: Eugenol Polymerized resin Annidalin www.indiandentalacademy.com
  • 26. Indications:  When extreme lubrication is needed, as in slightly short master cone, before apical surgery. Contraindications:  Irritating to periapical tissues, not to be used if overfill probable with normal periapical tissue.  Sets very rapidly when wet Packaging: two tubes , accelerator and base  Mixing: mix equal lengths to creamy consistency www.indiandentalacademy.com
  • 27. Properties: Easy to mix Non staining Allows maximal condensation and packing Is white in color with good contrast Good lubricating qualities Advantages:  ease of preparation High rate of flow, thinner film , www.indiandentalacademy.com
  • 28. Disadvantage: Irritating to periapical tissues, causing considerable periapical sensitivity when used on teeth where pulp was vital and the periapical tissue normal before treatment. Rapid set in the presence of moisture www.indiandentalacademy.com
  • 29. Wach’s paste (Wach 1925-1955) Powder:  Zinc oxide 10g  bismuth subnitrate -3.5 g  bismuth subiodide -0.3 g  magnesium oxide – 0.5g  tri calcium phosphate-2 g Liquid:  Canada balsam 20 ml  oil of cloves- 6ml,  eucalyptol 0.5 ml  beechwood creosote -0.5 ml. www.indiandentalacademy.com
  • 30. Indications: all lateral condensation methods, especially when chance of overfilling is present Adhesive , good for lateral compaction in small canals, softens gutta percha , Contraindication: when heavy lubrication is needed , as with short master cone. Advantage: smooth consistency without a heavy body Canada balsam makes the sealer tacky Disadvantage: odor of liquid www.indiandentalacademy.com
  • 31. Properties:  medium working time, less lubricating qualities  Minimal periapical sensitivity  Increasing the thickness of sealer lessens its lubricating effect, thus when an overfilling appears possible , a maximal degree of thickness should be employed.  Useful in small curved canals of minimal caliber,  Has light body , so does not deflect the small master gutta percha cones used to fill these canals.  Its is very sticky , due to Canada balsam, so paste will remain on reamer until its spun off in the apical portion, www.indiandentalacademy.com
  • 32. Nogenol :  Base is zinc oxide , barium sulfate , vegetable oil  Accelerator is : hydrogenated rosin, methyl abietate, lauric acid, chlorothymol, salicyclic acid  Developed to overcome the irritating quality of eugenol  Did not set hard, but remained rubbery , water sorption was high.  More biocompatible than ZOE cements. www.indiandentalacademy.com
  • 33. PARAFORMALDEHYDE ROOT FILLING MATERIALS N2(sargenti 1973) Powder:  Zinc oxide - 69% Liquid:  Lead tetroxide-12% Eugenol  Paraformaldehyde 6.5%  Bismuth subcarbonate 5%  Bismuth subnitrate 2%  Titanium dioxide 2%  Barium sulphate 2%  Hydrocortisone 1.2%  Prednisolone 0.21%  Phenylmercuric borate 0.09% www.indiandentalacademy.com
  • 34.  Known as RC2B &used in sargenti technique  Contains lead and mercury which are major systemic poisons  Loses volume due when exposed to fluid due to presence of paraformaldehyde  Coagulation necrosis in 3 days time, which can’t undergo repair due to formaldehyde impregnation  Irreversibly affects nerve endings in tissue area, thereby masking inflammation process www.indiandentalacademy.com
  • 35.  Paraformaldehyde is included to obtain release of formaldehyde gas for antiseptic and fixative action  Corticosteriods for suppressing inflammatory reaction  lead as an oxide, which by increasing the opacity gives the illusion of the materials compactness, and contribute to the extreme hardness and slow solubility of the final set. www.indiandentalacademy.com
  • 36. ENDOMETHASONE Powder  Di –iodothymol 25 g  Trioxymethylene (paraformaldehyde) -2.2g  Hydrocortisone acetate – 1 g  Dexamethasone 0.01g  Excipient 71.79 g Liquid • Eugenol www.indiandentalacademy.com
  • 37. Riebler’s paste( Riebler) Powder Zinc oxide Formaldehyde Barium sulfate Phenol Liquid: Formaldehyde Sulfuric acid Ammonia Glycerin www.indiandentalacademy.com
  • 38. SPAD • it’s a resorcinol –formaldehyde resin • supplied as powder and two liquids Powder: • Zinc oxide – 72.9% • Barium sulphate -13% • Titanium dioxide – 6.3% • Paraformaldehyde – 4.7% • Hydrocortisone acetate- 2% • Calcium hydroxide – 0.94% • Phenyl mercuric borate 0.16%www.indiandentalacademy.com
  • 39. Liquid (clear) • Formaldehyde 87% • Glycerin 13% Liquid LD (red) • Glycerin 55% • Resorcinol 25% • Hydrochloric acid 20% • Equal parts of the two liquids mixed with powder. • Essential reaction to form resin is between resorcinol and formaldehyde www.indiandentalacademy.com
  • 40.  An acidic pH is needed for this reaction, this is provided by HCl.  Large amount of zinc oxide is to control the pH and so prolong the setting time  inclusion of HCl is not harmful ,pH at the time of mixing was 5.2 and rose to 6.2 after 2 hrs , due to the neutralizing effects of Zinc oxide  setting time of spad is 24 hrs, during this period there is free unreacted formaldehyde,.  solubility of spad is 4 % after 24 hrs. www.indiandentalacademy.com
  • 41. Tissue response:  Pulpal necrosis, periapical inflammations and necrosis, Toxicologic studies:  Systemic absorption of lead and paraformaldehyde  Heavy metal ions- disseminated throughout the body  Irrevisible damage to nerve endings -paraformaldehyde www.indiandentalacademy.com
  • 42. Gutta percha based materials Chloropercha(Moyco)  Mixing white gutta percha 9% with chloroform 91%  Premixed sealer  Has no adhesive properties Kloropercha (Nygard –Ostby)  Powder liquid mixture  Powder : Canada balsam -19.6 www.indiandentalacademy.com
  • 43. Resin – 11.8% Gutta percha – 19.6% Zinc oxide – 49% Liquid: Chloroform -100 %  Zinc oxide is added to reduce shrinkage, also increases radiopacity  Shrinkage of 7.5% is seen  Chloroform evaporates leading to loss of volume and “dropping “ of filling into the periapical area  Chloroform is toxic www.indiandentalacademy.com
  • 44. Eucapercha:  Eucalyptol is used  Takes longer than chloroform  Has antibacterial and anti-inflammatory action  Segment of gutta percha held over alcohol lamp for 20 to 30 sec  Eucapercha dissolves and turns into a cloudy mass Indications: ledge formation, perforation, unusual curvatures, in cases in which the apical foramen cannot be successfully sealed www.indiandentalacademy.com
  • 45. Resin sealers AH26: -schroder , 1957 Powder:  Silver powder – 10%  Bismuth oxide 60%  Hexamethylene tetramine -25%  Titanium oxide – 5% www.indiandentalacademy.com
  • 46. Liquid:  Bisphenoldiglyicdyl ether -100% Packaging: Powder and liquid Mixing: mixed to a creamy consistency Properties:  Good flow  Seals well to dentin walls  Sufficient working time  Toxicity in the first 24 hrs due to release of formaldehyde www.indiandentalacademy.com
  • 47.  Strong adhesive & contracts on hardening  Schroder – well tolerated by tissues. Tends to disintegrate into fine granules which are phagocytosed  Hardens slowly at body temperature in 36 to 48 hrs  Its not sensitive to moisture, will set under water.  Will not set if hydrogen peroxide is present www.indiandentalacademy.com
  • 48.  Sets slowly in 24 to 36 hrs  Mixed cement should be warmed on glass slab over alcohol flame to make it less viscous  Sold world wide as therma seal Disadvantages:  Allergenic /mutagenic potential  possible formaldehyde release  silver containing www.indiandentalacademy.com
  • 49. • AH PLUS:  Comes in a paste-paste system  Added new amines to maintain the natural color of tooth  Working time of 4 hrs , setting time of 8 hrs, half the film thickness, and half the solubility of regular AH26.  Non mutagenic , no release of formaldehyde, radiopaque, can be used with all techniques www.indiandentalacademy.com
  • 50. Diaket: .Introduced by schmidt Powder: Zinc oxide Bismuth phosphate Liquid: Dihydroxy dichlorophenylmethane Propionylacetophenone Triethanolamine Caproic acid Copolymers of vinyl acetate, vinyl chloride, vinyl isobutylether www.indiandentalacademy.com
  • 51.  Polyketone compound with vinyl polymers that mixed with zinc oxide and bismuth phosphate forms a adhesive sealer  Sets quickly in root canal  Volume stability is good  Solubility is low  Powder liquid ratio : 1:2  Gross overfilling caused modification of apical cementum and alveolar bone  Has a tendency to be encapasulated by fibrous capsule  Adheres well to dentin www.indiandentalacademy.com
  • 52. Lee –Endo Fill  Used as a sole material or sealer with GP  Consists of silicone material, silcone based catalyst plus bismuth subnitrate filler  Low toxicity  Sets to pale pink rubbery solid  Sole filling material : avoid using NaOCl or peroxide as they affect polymerization www.indiandentalacademy.com
  • 53.  Setting time is 8 to 90 min depending on the catalyst used  Increased catalyst –increased shrinkage  Decreased bonding to dentin if not used within 20 min of mixing  Removed with GG drills and peeso reamers Adv: Non discoloring, no shrinkage upon polymerization, non resorbable ,low viscosity, good adaptation , good penetration of accessory canals www.indiandentalacademy.com
  • 54. Injection technique of obturating canals  Greenberg –pressure syringe to extrude cement into a canal  Krakow and berk popularized the idea Hydron:  Goldman introduced  Rapid setting hydrophilic plastic material used as a root canal sealer without the use of a core.  Grossman defined it as a polymer of hydroxyl- ethyl methacrylate  Biocompatible material that conforms to the shape of the root canal because of its plasticity. www.indiandentalacademy.com
  • 55.  Canal must be dry , it sets in the root canal in 10 min  Requires a special syringe and a needle  Precaution: it is injected as an unset material and the polymers that hasten its set can cause tissue toxicity resulting in inflammation with marcrophage activity.  Can cause paraesthesia www.indiandentalacademy.com
  • 56. Resorbable root filling materials: Def: pastes which does not set after being introduced into the root canal and which is rapidly removed if forced into the periapical region .Eg: iodoform and calcium hydroxide pastes Mynol Cement: Powder: Liquid: Zinc oxide Eugenol Iodoform Creosote Rosin Thymol Bismuth sub nitrate www.indiandentalacademy.com
  • 57. Walkhoff Paste  Devised by walkhoff in 1928  consists of 60 parts of iodoform and 40 parts of a solution containing 45 percent parachlorphenol , 49% camphor , and 6% menthol.  commercially known as Kri paste  Used in the walkhoff method of treatment, the paste is forced beyond the apex, irrespective of the state of the apex,  if sinus tract is present, forced paste propelled beyond the canal until it extrudes into the sinus opening.  in the absence of sinus tract, opening is made in the buccal cortical plate over the root apex www.indiandentalacademy.com
  • 58. MAISTO’S PASTE  Zinc oxide – 14g  Iodoform - 42g  Thymol-2g  Chlorophenol camphor- 3 cc  Lanolin – 0.50g VITAPEX  Iodoform -40.4%  Calcium hydroxide- 30.3%  Silicone – 22.4% www.indiandentalacademy.com
  • 59. Advantages over Zinc oxide eugenol pastes  Iodoform pastes are easily resorbed from the periradicular region, cause no foreign body reaction, removal of paste occurs due to a combination of leaching, phagocytosis and direct drainage to associated lymph nodes (Barker&Lockett ), whereas ZOE causes periradicular irritation.  paste disappears from the root canal itself, with the ingrowth of tissue into the canal.  Bactericidal to microorganism in the root canal and lose only 20% potency over a 10 year period, ZOE – bactericidal only in presence of formaldehyde.  they don’t set as hard as ZOE, so easy removal from the canal. www.indiandentalacademy.com
  • 60. Disadvantage:  yellowish –brown discoloration if not removed from the pulp chamber  lead to a rise in blood level of iodine , should not be used in patients sensitive to iodine. www.indiandentalacademy.com
  • 61. BIOCALEX Biocalex 6-9 , developed and introduced by Bernard under the name of ‘ocalex’. Powder  Zinc oxide & calcium oxide Liquid  Ethylene glycol and water  used as both intracanal medicament and as root filling  paste expands to more than six times its original volume, penetrating all parts of the root canal system www.indiandentalacademy.com
  • 62. Mechanism of action:  Calcium oxide and water react with the tooth to form calcium hydroxide which ionizes to release OH- ions, which has an antiseptic action , in addition it decompose necrotic pulpal tissues to form water and carbon dioxide,  water combines with residual calcium oxide , leads to further calcium hydroxide formation .  Carbon dioxide reacts with calcium hydroxide to form calcium carbonate, which is deposited on the root canal walls.  Chemical incineration of canal contents occurs, with sterilization by the action of hydroxyl ions and sealing of the canal by the deposition of calcium carbonate www.indiandentalacademy.com
  • 63. Adv:  obviates the need for root canal preparation. Disadvantage:  doubts regarding the breakdown of necrotic pulpal tissue, so making it doubtful whether the co2 necessary for calcium carbonate formation is formed. www.indiandentalacademy.com
  • 64. Sealapex: Base: Calcium hydroxide : 25% Zinc oxide :6.5% Catalyst: Barium sulfate :18.6% Titanium dioxide : 5.1% Zinc Stearate :1.0% Calcium hydroxide cement www.indiandentalacademy.com
  • 65.  Osteogenic, possible dissolution , expands on setting  In 100% humidity takes upto 3 wks to reach a final seal. LIFE: a calcium hydroxide liner is used a sealer www.indiandentalacademy.com
  • 66. CRCS(Calciobiotic root canal sealer) Powder: Calcium Hydroxide Zinc oxide Bismuth dioxide Barium sulfate Liquid: Eugenol Eucalyptol www.indiandentalacademy.com
  • 67.  Takes 3 days to set fully in dry or humid environments  Little water sorption  Stable ,  Softens gutta percha , good for lateral compaction , viscous, adhesive www.indiandentalacademy.com
  • 68. Apexit Base: Calcium hydroxide : 31.9% Zinc oxide : 5.5% Calcium oxide : 5.6% Silicon oxide : 8.1% Zinc stearate : 2.3% Hydrogenized colophony : 31.5% Tricalcium phosphate :4.1% Polydemethylsiloxane :2.5% www.indiandentalacademy.com
  • 69. Activator: Trimethyl hexanedioldisalicylate : 25% Bismuth carbonate basic : 18.2% Bismuth oxide : 18.2% Silicon dioxide :15% 1,3-Butanedioldisalicylate :11.4% Hydrogenized colophony :5.4% Tricalcium phosphate :5.% Zinc stearate :1.4% www.indiandentalacademy.com
  • 70. • DENTALIS: ZoE, calcium hydroxide, iodoform, sets rapidly and is very tacky CH 61 P/L ratio: 1.2g/ml Powder: Calcium hydroxide -55% Bismuth subcarbonate- 30% Rosin -10 Zinc oxide -5 Liquid: Fatty acids- 85% Propylene glycol-15% www.indiandentalacademy.com
  • 71. Disadvantages:  to be effective calcium hydroxide must dissolve and the solid consequently lose content.  Calcium hydroxide may dissolve, leaving obturation voids, which will cause poor seal.  Have poor cohesive strength  No proof exists that they have any desirable biologic effects www.indiandentalacademy.com
  • 72. Calcium Phosphate Paste  ADA- PAFFENBERG DENTAL RESEARCH CENTER  Developed a simple mixture of calcium phosphates that sets to become hydroxyapatite  Two calcium phosphate compounds , one acidic and one basic when mixed with water they set into a hardened mass –hydroxyapatite –the principal mineral in teeth and bones.  Tetracalcium phosphate is the basic constituent  Dicalcium phosphate dehydrate or anhydrous dicalcium phosphate is the acidic component. www.indiandentalacademy.com
  • 73. • Water is neither a reactant nor an imp product in the reaction but merely a vehicle for dissolution of the reactants • Setting time extended by adding glycerin to the mixture • Mild phosphoric acid solution speeds the dissolution of the components • Final set calcium phosphate cement consists of nearly all crystalline material, and porosity is indirect ratio to the amount of solvent used. • It is as radiopaque as bone. • Nearly insoluble in water and is insoluble in saliva and blood. • There was no dye penetration into the filler canal wall interface www.indiandentalacademy.com
  • 74. • Tissue reactions: mild irritation after 1 month , new bone formation was observed adjacent to the cement. • Had no toxicity and all tests for mutagenicity and potential carcinogenicity of CPC negative • G-5 and G-6 are apatite sealers. • BIOSEAL : ZOE to hydroxyapatite www.indiandentalacademy.com
  • 75.  CPC: hydroxyapatite is a naturally occurring product, and that bone grows into and eventually replaces extruded material , makes it biologically acceptable.  Another possibility of using hydroxyapatite relates to the laser : a cross linked collagen hydroxyapatite mixture has been placed in the root canal and melted to place with a laser beam through a fiber optic. www.indiandentalacademy.com
  • 76.  not advocated  leaching into periradicular tissues  porosity in paste fills  most pastes absorb in time – leading to apical leakage, percolation, ultimate treatment failure  chemical components of paste causes immunologic responses.  Apical control of paste fills is impossible PASTES AS FILLING MATERIALS: www.indiandentalacademy.com
  • 77. Polycarboxylates  Are effective provided adequate contact is made with the canal wall  Disadvantage: need for special plastic instruments due to its great adhesiveness to metal www.indiandentalacademy.com
  • 78. KETAC-ENDO  Pitt ford recommended use of GIC  Chemical bonding to dentinal walls of the root canal preventing percolation and bacterial penetration at sealer-dentin interface  Low toxicity Disadvantages:  Difficulty in retrieval www.indiandentalacademy.com
  • 79. New sealers Bis –GMA( difficult to remove) Isopropyl cyanoacrylate Polyamide varnish Dentin bonding agents –good sealers because of their ability to halt microleakage www.indiandentalacademy.com
  • 80. Problems with dentin bonding agents:  preparation of dentin to remove smear layer  radiopacity , metal salts need to be added, which can affect polymerization  placement to ensure total, porosity free placement  removal in the event of failure www.indiandentalacademy.com
  • 81. Mixing of sealer  Root canal cement is mixed on a sterile glass slab with a sterile spatula.  Slab is sterilized by an alcohol scrub and is dried ant the spatula is passed through an open flame two of three times. Small increments of powder are added to the liquid while one spatulates it to a smooth creamy mix. Spatulation time depends on the number of drops of liquid used, a min per drop www.indiandentalacademy.com
  • 82.  Completed mix can be tested for proper consistency by raising the flat blade of the spatula up form the mixed mass. The cement should “string out” for at least an inch before breaking.  Another test is the suspended mix should cling to the inverted spatula blade for 10 to 15 sec before dropping from the spatula www.indiandentalacademy.com
  • 83. Placement of sealer  Reamer : is twirled counterclockwise, pumped and wiped against the walls  Absorbent paper points or gutta percha : pumping  Lentulo spiral: in a handpiece Disadv: locking in canal, “whipping up” of cement in canal causing it to set prematurely  Ultrasonic file without use of a coolant www.indiandentalacademy.com
  • 84. Sealer efficacy:  Hovland and Dumsha  “Although all root canal sealers leak to some extent – there is probably a critical level of leakage that is unacceptable for healing and therefore result in endodontic failure. This leakage may occur at the interface of the dentine and sealer , at the interface of the solid core and sealer, through the sealer itself ,of by dissolution of the sealer”  All sealers leak . some leak more than others mostly through dissolution.  The greater the sealer/periradicular tissue , the faster dissolution takes place www.indiandentalacademy.com
  • 85. Tissue tolerance : Zinc oxide and Eugenol:  All ZoE sealers dissolve in fluid releasing eugenol which is irritating.  Zinc oxide is also toxic due to the effect of zinc ions.  CRCS was the least cytotoxic followed by AH26 ,  Prraformaldehyde most toxic  Ketac Endo most biocompatible. www.indiandentalacademy.com
  • 86.  In vivo tissue tolerance examination:  Erausquin and Muruzabal – found that ZOE was highly irritating to the periradicular tissues and caused necrosis of bone and cementum.  Least irritating was Diaket and AH-26 .  Diaket becomes encapsulated  AH-26 was resorbed www.indiandentalacademy.com
  • 87. Conclusion The selection of a sealer is based on amount of lubrication needed, the length of working time estimated, and the filling material to be used . www.indiandentalacademy.com
  • 88. References  Pathways of the pulp , Cohen , (4th ,5th , 6th , 7th , 8th edition)  Endodontics , Ingle (4th ,5th edition)  Endodontic therapy , Weine(5th and 6th edition)  Endodontics in clinical practice , Harty(3rd &4th Edition)  Journal references www.indiandentalacademy.com