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Griffin House
Market Street
Charlbury
Oxford OX7 3PJ
United Kingdom
Tel: (44) 1608 810110Dust and Air Quality Innovation and Expertise
Tel: +44 (0) 01608 810110 Web: www.dustscan.co.uk
What is in my dust?
Andrew Green
Senior Consultant โ€“ Air Quality and Exposure
07 June 2018
About Me
โ€ข Studied Environmental Science at University of
Portsmouth (2011-2014)
โ€ข Graduated with BSc First Class
โ€ข Joined DustScan later in 2014 as a Technical Assistant
โ€ข DustScan specialise in air quality and dust consultancy as
well as providing bespoke dust monitoring equipment
โ€ข Progressed over last 3.5 years to level of Senior
Consultant
โ€ข Previously attended IAQM meet-ups and wanted to get
involved
My role and technical responsibilities
โ€ข Air Quality Assessments for projects including industrial,
commercial and residential
โ€ข Workplace Monitoring and Assessments for exposure to
substances, including dust
โ€ข Project Proposals and Management
โ€ข Supervising analytical work and reviewing reports
What is Dust?
โ€ข It is widely accepted that dust is particles less than 75 ยตm
โ€ข Naturally occurring, caused by a number of processes
including abrasion, erosion and combustion
โ€ข Courser dust is responsible for loss of amenity
(Nuisance/disamenity)
โ€ข Particulate matter regarded as fine particles, categorised
by size fraction.
โ€ข PM10 - aerodynamic diameter less than 10 ยตm
โ€ข PM2.5 - aerodynamic diameter less than 2.5 ยตm
Objectives and Standards
โ€ข No Standards for nuisance dust but various guidance
(IAQM, EA) on recommended monitoring
โ€ข There is a case for further investigation into dust nuisance
and loss of amenity
โ€ข Environmental Standards included air quality objectives for
PM10 and target values for PM2.5
โ€ข Target values for some metals, including Pb, Cu and Ni
โ€ข Workplace (indoor) standards include all inhalable and all
respirable dust which are measured against workplace
exposure limits (WELs) set out by HSL in EH40/2005
โ€ข Other standards and objectives in different countries
Investigating Dust Sources
โ€ข Whatโ€™s the reason for investigating? E.g. Occupational
concern, nuisance concern
โ€ข Understand background sources, local geology and soils
โ€ข Identify onsite activities that could produce dust
โ€ข Who/what are the receptors? E.g. Workers, businesses,
general public
โ€ข Consider control measures implemented and effectiveness
of mitigation
โ€ข Assess suitable method for monitoring and investigation
Methods of Dust Analysis
โ€ข Optical Light Microscopy: Visual interpretation using
different lighting conditions and high magnification
โ€ข Scanning Electron Microscopy: Higher magnification,
some chemical data available when coupled with energy
dispersive spectrometry
โ€ข X-Ray Diffraction: analysis on particle structure, used on
respirable samples for indentifying RCS
โ€ข Inductively Coupled Plasma โ€“ Mass Spectrometry:
Quantifies proportions of elemental composition
Case Study 1: Provenance of Warehouse
Dusts
โ€ข Forklift truck tyres: rubber dust
โ€ข Forklift truck brakes: metal
โ€ข Concrete floor: mineral dust including calcite (CaCO3) and
possible quartz (SiO2)
โ€ข Packaging, pallets and contents: cellulose fibres
โ€ข Large doors: dust from yard and external sources
โ€ข History of site: previous uses
โ€ข Diesel forklift trucks or HGVs: Diesel Engine Exhaust
Emissions (DEEE)
Case Study 1: Microscopy
Figure 1: Example of warehouse dust under reflected
light
Rubber
(tyre)
crumb
Blue pallet
fibre
Cementitio
us material
Cellulose
fibre
Metal
fragment
Case Study 1: SEM-EDS
Figure 2: SEM high resolution
image of warehouse dust
Figure 3: False-colour element maps showing
carbon (C), iron and aluminium (Fe, Al),
calcium and oxygen (Ca, O) and silicon and
oxygen (Si, O)
Case Study 2: Source of metals in PM10
โ€ข Previous study found elevated levels of certain elements
in PM10 samples, some metals above target values
โ€ข Metal foundry identified as potential source
โ€ข Installed directional and depositional dust monitors along
with gravimetric PM10 samplers
โ€ข SEM-EDS and ICP-MS used to investigate elemental
concentrations in alloys
Case Study 2: SEM-EDS
Figure 4: SEM image of PM10 filter
Case Study 2: SEM-EDS
2 4 6 8 10 12 14
keV
0.0
0.2
0.4
0.6
0.8
1.0
cps/eV
C
O
Si K
K
Fe
Fe
Mg
Na
N
Cl
Cl
Ca
Ca
Al
S
S
Ti
Ti
Ni
Ni
Zn
Zn
Cr
Cr
Cu
Cu
Figure 5: Energy Dispersive Spectrograph of PM10 filter
So...Whatโ€™s in my house dust?
โ€ข Appling knowledge of dust sources, analysis through analytical
techniques including microscopy and SEM
โ€ข Mostly dead human skin cells: organic material
โ€ข Clothing fibres: fabric, cotton, wool
โ€ข Carpet fibres, flakes of paint, plasterboard (gypsum)
โ€ข Cellulose fibres from paper/cardboard/wood
โ€ข Other organic material from food, plants, invertebrate
โ€ข Material from outside: usually consists of minerals from local soils
and rocks
โ€ข Urban areas: can contain tyre rubber, exhaust condensate and
other road dusts
โ€ข Rural areas: can contain agricultural dust such as higher
proportions of organic fibres and pollen at certain times of the
year
โ€ข Extreme events e.g. Sahara dust, volcanic dust
Thank you for listening
โ€ข LinkedIn: www.linkedin.com/in/andrew-
green-1b422876/
โ€ข Website: www.dustscan.co.uk
โ€ข Email: andrewg@dustscan.co.uk

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What is in my dust? - Andrew Green

  • 1. Griffin House Market Street Charlbury Oxford OX7 3PJ United Kingdom Tel: (44) 1608 810110Dust and Air Quality Innovation and Expertise Tel: +44 (0) 01608 810110 Web: www.dustscan.co.uk What is in my dust? Andrew Green Senior Consultant โ€“ Air Quality and Exposure 07 June 2018
  • 2. About Me โ€ข Studied Environmental Science at University of Portsmouth (2011-2014) โ€ข Graduated with BSc First Class โ€ข Joined DustScan later in 2014 as a Technical Assistant โ€ข DustScan specialise in air quality and dust consultancy as well as providing bespoke dust monitoring equipment โ€ข Progressed over last 3.5 years to level of Senior Consultant โ€ข Previously attended IAQM meet-ups and wanted to get involved
  • 3. My role and technical responsibilities โ€ข Air Quality Assessments for projects including industrial, commercial and residential โ€ข Workplace Monitoring and Assessments for exposure to substances, including dust โ€ข Project Proposals and Management โ€ข Supervising analytical work and reviewing reports
  • 4. What is Dust? โ€ข It is widely accepted that dust is particles less than 75 ยตm โ€ข Naturally occurring, caused by a number of processes including abrasion, erosion and combustion โ€ข Courser dust is responsible for loss of amenity (Nuisance/disamenity) โ€ข Particulate matter regarded as fine particles, categorised by size fraction. โ€ข PM10 - aerodynamic diameter less than 10 ยตm โ€ข PM2.5 - aerodynamic diameter less than 2.5 ยตm
  • 5. Objectives and Standards โ€ข No Standards for nuisance dust but various guidance (IAQM, EA) on recommended monitoring โ€ข There is a case for further investigation into dust nuisance and loss of amenity โ€ข Environmental Standards included air quality objectives for PM10 and target values for PM2.5 โ€ข Target values for some metals, including Pb, Cu and Ni โ€ข Workplace (indoor) standards include all inhalable and all respirable dust which are measured against workplace exposure limits (WELs) set out by HSL in EH40/2005 โ€ข Other standards and objectives in different countries
  • 6. Investigating Dust Sources โ€ข Whatโ€™s the reason for investigating? E.g. Occupational concern, nuisance concern โ€ข Understand background sources, local geology and soils โ€ข Identify onsite activities that could produce dust โ€ข Who/what are the receptors? E.g. Workers, businesses, general public โ€ข Consider control measures implemented and effectiveness of mitigation โ€ข Assess suitable method for monitoring and investigation
  • 7. Methods of Dust Analysis โ€ข Optical Light Microscopy: Visual interpretation using different lighting conditions and high magnification โ€ข Scanning Electron Microscopy: Higher magnification, some chemical data available when coupled with energy dispersive spectrometry โ€ข X-Ray Diffraction: analysis on particle structure, used on respirable samples for indentifying RCS โ€ข Inductively Coupled Plasma โ€“ Mass Spectrometry: Quantifies proportions of elemental composition
  • 8. Case Study 1: Provenance of Warehouse Dusts โ€ข Forklift truck tyres: rubber dust โ€ข Forklift truck brakes: metal โ€ข Concrete floor: mineral dust including calcite (CaCO3) and possible quartz (SiO2) โ€ข Packaging, pallets and contents: cellulose fibres โ€ข Large doors: dust from yard and external sources โ€ข History of site: previous uses โ€ข Diesel forklift trucks or HGVs: Diesel Engine Exhaust Emissions (DEEE)
  • 9. Case Study 1: Microscopy Figure 1: Example of warehouse dust under reflected light Rubber (tyre) crumb Blue pallet fibre Cementitio us material Cellulose fibre Metal fragment
  • 10. Case Study 1: SEM-EDS Figure 2: SEM high resolution image of warehouse dust Figure 3: False-colour element maps showing carbon (C), iron and aluminium (Fe, Al), calcium and oxygen (Ca, O) and silicon and oxygen (Si, O)
  • 11. Case Study 2: Source of metals in PM10 โ€ข Previous study found elevated levels of certain elements in PM10 samples, some metals above target values โ€ข Metal foundry identified as potential source โ€ข Installed directional and depositional dust monitors along with gravimetric PM10 samplers โ€ข SEM-EDS and ICP-MS used to investigate elemental concentrations in alloys
  • 12. Case Study 2: SEM-EDS Figure 4: SEM image of PM10 filter
  • 13. Case Study 2: SEM-EDS 2 4 6 8 10 12 14 keV 0.0 0.2 0.4 0.6 0.8 1.0 cps/eV C O Si K K Fe Fe Mg Na N Cl Cl Ca Ca Al S S Ti Ti Ni Ni Zn Zn Cr Cr Cu Cu Figure 5: Energy Dispersive Spectrograph of PM10 filter
  • 14. So...Whatโ€™s in my house dust? โ€ข Appling knowledge of dust sources, analysis through analytical techniques including microscopy and SEM โ€ข Mostly dead human skin cells: organic material โ€ข Clothing fibres: fabric, cotton, wool โ€ข Carpet fibres, flakes of paint, plasterboard (gypsum) โ€ข Cellulose fibres from paper/cardboard/wood โ€ข Other organic material from food, plants, invertebrate โ€ข Material from outside: usually consists of minerals from local soils and rocks โ€ข Urban areas: can contain tyre rubber, exhaust condensate and other road dusts โ€ข Rural areas: can contain agricultural dust such as higher proportions of organic fibres and pollen at certain times of the year โ€ข Extreme events e.g. Sahara dust, volcanic dust
  • 15. Thank you for listening โ€ข LinkedIn: www.linkedin.com/in/andrew- green-1b422876/ โ€ข Website: www.dustscan.co.uk โ€ข Email: andrewg@dustscan.co.uk