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As part of CIE’s continual commitment to maintaining best practice in assessment, CIE uses
different variants of some question papers for our most popular assessments with large and
widespread candidature. The question papers are closely related and the relationships between
them have been thoroughly established using our assessment expertise. All versions of the
paper give assessment of equal standard.
The content assessed by the examination papers and the type of questions is unchanged.
This change means that for this component there are now two variant Question Papers, Mark
Schemes and Principal Examiner’s Reports where previously there was only one. For any
individual country, it is intended that only one variant is used. This document contains both
variants which will give all Centres access to even more past examination material than is usually
the case.
The diagram shows the relationship between the Question Papers, Mark Schemes and Principal
Examiners’ Reports that are available.

Question Paper

Mark Scheme

Principal Examiner’s
Report
Introduction

Introduction

Introduction

First variant Question Paper

First variant Mark Scheme

First variant Principal
Examiner’s Report

Second variant Question
Paper

Second variant Mark
Scheme

Second variant Principal
Examiner’s Report

Who can I contact for further information on these changes?
Please direct any questions about this to CIE’s Customer Services team at:
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The titles for the variant items should correspond with the table above, so that at the top of the
first page of the relevant part of the document and on the header, it has the words:
•

First variant Question Paper / Mark Scheme / Principal Examiner’s Report

•

Second variant Question Paper / Mark Scheme / Principal Examiner’s Report

or

as appropriate.
First Variant Question Paper

UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
International General Certificate of Secondary Education

*5310297965*

0620/31

CHEMISTRY

May/June 2009

Paper 3 (Extended)

1 hour 15 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
For Examiner's Use
DO NOT WRITE IN ANY BARCODES.
Answer all questions.
A copy of the Periodic Table is printed on page 16.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part
questions.

1
2
3
4
5
6
7
8
9
Total

This document consists of 15 printed pages and 1 blank pages.
IB09 06_0620_31/5RP
© UCLES 2009

[Turn over
2
1

Some grass is crushed and mixed with the solvent, propanone. The colour pigments are
extracted to give a deep green solution.
(a) (i) Draw a labelled diagram to describe how you could show that there is more than
one coloured pigment in the green solution.

[3]
(ii) Given a pure sample of chlorophyll, how could you show that the green solution
from the grass contained chlorophyll?

[2]

(b) Explain the role of chlorophyll in green plants.

[3]

[Total: 8]

© UCLES 2009

0620/31/M/J/09

For
Examiner's
Use
3
2

The results of experiments on electrolysis using inert electrodes are given in the table.

For
Examiner's
Use

Complete the table; the first line has been completed as an example.
electrolyte

molten lead(II)
bromide

change at negative
electrode

change at positive
electrode

change to
electrolyte

lead formed

bromine formed

used up

potassium formed

iodine formed

used up

hydrogen formed

bromine formed

potassium hydroxide
formed

dilute aqueous
sodium chloride

aqueous copper(II)
sulfate

[Total: 8]

© UCLES 2009

0620/31/M/J/09

[Turn over
4
3

The following is a list of the electron distributions of atoms of unknown elements.
element

For
Examiner's
Use

electron distribution

A

2,5

B

2,8,4

C

2,8,8,2

D

2,8,18,8

E

2,8,18,8,1

F

2,8,18,18,7

(a) Choose an element from the list for each of the following descriptions.
(i) It is a noble gas.
(ii) It is a soft metal with a low density.
(iii) It can form a covalent compound with element A.
(iv) It has a giant covalent structure similar to diamond.
(v) It can form a negative ion of the type X3-.

[5]

(b) Elements C and F can form an ionic compound.
(i) Draw a diagram that shows the formula of this compound, the charges on the ions
and the arrangement of the valency electrons around the negative ion.
Use o to represent an electron from an atom of C.
Use x to represent an electron from an atom of F.

[3]
(ii) Predict two properties of this compound.

[2]

[Total: 10]

© UCLES 2009

0620/31/M/J/09
5
4

The reactivity series of metals given below contains both familiar and unfamiliar elements.
For most of the unfamiliar elements, which are marked *, their common oxidation states are
given.
* barium

Ba

* lanthanum

La

For
Examiner's
Use

(+3)

magnesium
zinc
* chromium

Cr (+2), (+3), (+6)

iron
copper
* palladium

(+2)

Choose metal(s) from the above list to answer the following questions.
(i) Which two metals would not react with dilute hydrochloric acid?
[2]
(ii) Which two unfamiliar metals (*) would react with cold water?
[2]
(iii) What is the oxidation state of barium?
[1]
(iv) Name an unfamiliar metal (*) whose oxide cannot be reduced by carbon.
[1]
(v) Why should you be able to predict that metals such as iron and chromium have
more than one oxidation state?

[1]

[Total: 7]

© UCLES 2009

0620/31/M/J/09

[Turn over
6

5

For
Examiner's
Use

Insoluble salts are made by precipitation.
(a) A preparation of the insoluble salt calcium fluoride is described below.
To 15 cm3 of aqueous calcium chloride, 30 cm3 of aqueous sodium fluoride is added.
The concentration of both solutions is 1.00 mol / dm3. The mixture is filtered and the
precipitate washed with distilled water. Finally, the precipitate is heated in an oven.
(i) Complete the equation.
Ca2+ + ...…….F-

………......

[2]

(ii) Why is the volume of sodium fluoride solution double that of the calcium chloride
solution?

[1]
(iii) Why is the mixture washed with distilled water?

[1]
(iv) Why is the solid heated?

[1]

© UCLES 2009

0620/31/M/J/09
7
(b) The formulae of insoluble compounds can be found by precipitation reactions.
To 12.0 cm3 of an aqueous solution of the nitrate of metal T was added 2.0 cm3 of
aqueous sodium phosphate, Na3PO4. The concentration of both solutions was
1.00 mol / dm3. When the precipitate had settled, its height was measured.

For
Examiner's
Use

solution
precipitate of
the phosphate
of metal T

height of
precipitate

The experiment was repeated using different volumes of the phosphate solution. The
results are shown on the following graph.
16
12
height of
precipitate
/ mm

8
4
0
0

2

4

6

8

10

volume of phosphate solution / cm

12

14

3

What is the formula of the phosphate of metal T? Give your reasoning.

[3]

[Total: 8]

© UCLES 2009

0620/31/M/J/09

[Turn over
8
6

Ammonia is manufactured by the Haber process.
N2(g) +

3H2(g)

2NH3(g)

For
Examiner's
Use

the forward reaction is exothermic

(a) (i) Name the raw materials from which nitrogen and hydrogen are obtained.
nitrogen from

[1]

hydrogen from

[1]

(ii) Name the catalyst used in this process.
[1]
(iii) What is the most important use of ammonia?
[1]

(b) The following graph shows how the percentage of ammonia in the equilibrium mixture
changes with temperature.

% ammonia
at equilibrium

0
0

temperature

(i) Explain the term equilibrium.

[2]
(ii) How does the percentage of ammonia vary with temperature?
[1]

© UCLES 2009

0620/31/M/J/09
9
(c) (i) Sketch a graph which shows how the percentage of ammonia in the equilibrium
mixture varies with pressure.

For
Examiner's
Use

% ammonia
at equilibrium

0
0

pressure

[1]
(ii) Explain why the graph has the shape shown.

[2]

[Total: 10]

© UCLES 2009

0620/31/M/J/09

[Turn over
10
7

Hydrogen reacts with the halogens to form hydrogen halides.
(a) Bond energy is the amount of energy, in kJ, that must be supplied (endothermic) to
break one mole of a bond.
bond

bond energy in kJ / mol

H─H

+436

Cl─Cl

+242

H─Cl

+431

Use the above data to show that the following reaction is exothermic.
H─H

+

Cl─Cl

2H─Cl

[3]

© UCLES 2009

0620/31/M/J/09

For
Examiner's
Use
11
(b) They react with water to form acidic solutions.
HCl

+

H2O

H3O+

+

Cl -

HF

+

H2O

H3O+

+

For
Examiner's
Use

F-

(i) Explain why water behaves as a base in both of these reactions.

[2]
(ii) At equilibrium, only 1% of the hydrogen chloride exists as molecules, the rest has
formed ions. In the other equilibrium, 97% of the hydrogen fluoride exists as
molecules, only 3% has formed ions.
What does this tell you about the strength of each acid?

[2]
(iii) How would the pH of these two solutions differ?
[1]

[Total: 8]

© UCLES 2009

0620/31/M/J/09

[Turn over
12
8

Lactic acid can be made from corn starch.
CH3

CH

For
Examiner's
Use

COOH

OH
lactic acid

It polymerises to form the polymer, polylactic acid (PLA ) which is biodegradable.
(a) Suggest two advantages that PLA has compared with a polymer made from petroleum.

[2]

(b) The structure of PLA is given below.
CH3
O

O

CH

C

CH3
O

CH

(i) What type of compound contains the group that is circled?
[1]
(ii) Complete the following sentence.
Lactic acid molecules can form this group because they contain both an
group and an

group.

[2]

(iii) Is the formation of PLA, an addition or condensation polymerisation? Give a
reason for your choice.

[2]

© UCLES 2009

0620/31/M/J/09
13
(c) When lactic acid is heated, acrylic acid is formed.
H
C

C

H

H

H

OH

H

lactic acid

H
C

COOH

For
Examiner's
Use

H

C
COOH

acrylic acid

(i) Complete the word equation for the action of heat on lactic acid.
lactic acid →

+

[1]

(ii) Describe a test that would distinguish between lactic acid and acrylic acid.
test
result for lactic acid
result for acrylic acid

[3]

(iii) Describe a test, other than using an indicator, which would show that both
chemicals contain an acid group.
test
result
[2]

[Total: 13]

© UCLES 2009

0620/31/M/J/09

[Turn over
14
9

Quantities of chemicals, expressed in moles, can be used to find the formula of a
compound, to establish an equation and to determine reacting masses.
(a) A compound contains 72% magnesium and 28% nitrogen. What is its empirical
formula?

[2]

(b) A compound contains only aluminium and carbon. 0.03 moles of this compound reacted
with excess water to form 0.12 moles of Al(OH)3 and 0.09 moles of CH4.
Write a balanced equation for this reaction.

[2]

(c) 0.07 moles of silicon reacts with 25 g of bromine.
Si

+

2Br2

SiBr4

(i) Which one is the limiting reagent? Explain your choice.

[3]
(ii) How many moles of SiBr4 are formed?
[1]

[Total: 8]

© UCLES 2009

0620/31/M/J/09

For
Examiner's
Use
15
BLANK PAGE

0620/31/M/J/09
© UCLES 2009

24

40

Sodium

Calcium

88

0620/31/M/J/09

89

Key

b

X

a

b = proton (atomic) number

X = atomic symbol

a = relative atomic mass

*58-71 Lanthanoid series
90-103 Actinoid series

88

Ac

Actinium

Ra

Radium

Fr

Francium

87

*

Hafnium

72

Lanthanum

57

Hf

La

40

Zirconium

Zr

91

Titanium

178

Yttrium

22

48

Ti

139

39

Y

89

Scandium

21

227

Barium

Caesium

56

Cs

45

Sc

226

55

137

Ba

133

Strontium

Rubidium

38

Rb

37

Sr

85

20

Potassium

19

Ca

39

Magnesium

Na

12

Mg

23

Beryllium

4

Lithium

K

11

3

9

Be

7

II

Li

I

93

Ta

181

Niobium

Nb

90

58

73

52

96

Mo

W

184

141

Pa

Thorium

55

Tc
186

Re

144

Nd

92

60

Uranium

U

238

Neodymium

75

Rhenium

43

Technetium

25

Manganese

Mn
29

30

65

8

9

VII

2

0

Ru

101

Iron

190

Pm

Osmium

Os

Np
93

Neptunium

61

Promethium

76

44

Ruthenium

26

56

Fe

Sm

150

Iridium

Pu
94

Plutonium

62

Eu

152

Platinum

Am
95

Americium

63

Europium

78

195

Pt

Ir

46

Palladium

Pd

106

Nickel

Ni

192

Samarium

77

45

Rhodium

Rh

103

Cobalt

Co

Gd

157

Gold

Au

197

Silver

96

64

Curium

Cm

Gadolinium

79

47

Ag

108

Copper

Cu

201

Bk

Terbium

Tb

159

Mercury

Hg

97

Berkelium

65

80

48

Cadmium

Cd

112

Zinc

Zn

11

70

Dy

162

Thallium

Tl

204

Indium

Cf
98

Californium

66

Es

Holmium

Ho

165

Lead

Pb

207

Tin

99

Einsteinium

67

82

50

119

Sn

In

32

Germanium

Ge

73

Silicon

115

Gallium

Ga

Dysprosium

81

49

31

13

Aluminium

Si

Al
14

28

Carbon

27

Boron

12

C

14

75

Sb

122

Arsenic

As

Bi

209

Fermium

Fm

Erbium

Er

167

Bismuth

100

68

83

51

Antimony

33

15

Phosphorus

P

31

Nitrogen

N

Se

79

Sulfur

S

32

Oxygen

Po

169

Md

Thulium

Tm

101

Mendelevium

69

84

Polonium

52

Tellurium

Te

128

Selenium

34

16

16

O

Yb

173

Astatine

At

Iodine

I

127

Bromine

Br

80

Chlorine

No
102

Nobelium

70

Ytterbium

85

53

35

17

Cl

35.5

Fluorine

F

19

Lr

Lutetium

Lu

175

Radon

Rn

Xenon

Xe

131

Krypton

Kr

84

Argon

Ar

40

Neon

103

Lawrencium

71

86

54

36

18

10

Ne

20

Helium

Hydrogen

B

4

28

64

7

VI

He

27

59

6

V

H

59

5

IV

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).

91

Protactinium

Th

232

Praseodymium

Cerium

59

Pr

Ce

74

Tungsten

42

Molybdenum

24

Chromium

Cr

140

Tantalum

41

23

Vanadium

V

51

1

III
1

Group

DATA SHEET
The Periodic Table of the Elements

16

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
Second Variant Question Paper

UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
International General Certificate of Secondary Education

*0583100121*

0620/32

CHEMISTRY

May/June 2009

Paper 3 (Extended)

1 hour 15 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
For Examiner's Use
DO NOT WRITE IN ANY BARCODES.
Answer all questions.
A copy of the Periodic Table is printed on page 16.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part
questions.

1
2
3
4
5
6
7
8
9
Total

This document consists of 15 printed pages and 1 blank page.
IB09 06_0620_32/4RP
© UCLES 2009

[Turn over
2
1

Some grass is crushed and mixed with the solvent, propanone. The colour pigments are
extracted to give a deep green solution.
(a) (i) Draw a labelled diagram to describe how you could show that there is more than
one coloured pigment in the green solution.

[3]
(ii) Given a pure sample of chlorophyll, how could you show that the green solution
from the grass contained chlorophyll?

[2]

(b) Explain the role of chlorophyll in green plants.

[3]

[Total: 8]

© UCLES 2009

0620/32/M/J/09

For
Examiner's
Use
3
2

The results of experiments on electrolysis using inert electrodes are given in the table.

For
Examiner's
Use

Complete the table; the first line has been completed as an example.
electrolyte

change at negative
electrode

change at positive
electrode

change to electrolyte

lead formed

bromine formed

used up

lithium formed

chlorine formed

used up

hydrogen formed

molten lead(II)
bromide

bromine formed

potassium hydroxide
formed

dilute aqueous sodium
chloride

aqueous copper(II)
sulfate

[Total: 8]

© UCLES 2009

0620/32/M/J/09

[Turn over
4
3

The following is a list of the electron distributions of atoms of unknown elements.
element

For
Examiner's
Use

electron distribution

A

2,6

B

2,8,4

C

2,8,8,2

D

2,8,18,8

E

2,8,18,8,1

F

2,8,18,18,7

(a) Choose an element from the list for each of the following descriptions.
(i) It is a noble gas.
(ii) It is a soft metal with a low density.
(iii) It can form a covalent compound with element A.
(iv) It has a giant covalent structure similar to diamond.
(v) It is a diatomic gas with molecules of the type X2.

[5]

(b) Elements C and A can form an ionic compound.
(i) Draw a diagram that shows the formula of this compound, the charges on the ions
and the arrangement of the valency electrons around the negative ion.
Use o to represent an electron from an atom of C.
Use x to represent an electron from an atom of A.

[3]
(ii) Predict two properties of this compound.

[2]

[Total: 10]
© UCLES 2009

0620/32/M/J/09
5
4

The reactivity series of metals given below contains both familiar and unfamiliar elements.
For most of the unfamiliar elements, which are marked *, their common oxidation states are
given.
* barium

Ba

* lanthanum

La

For
Examiner's
Use

(+3)

magnesium
zinc
* chromium

Cr (+2), (+3), (+6)

iron
copper
* palladium

(+2)

Choose metal(s) from the above list to answer the following questions.
(i) Which two metals would not react with dilute hydrochloric acid?
[2]
(ii) Which two unfamiliar metals (*) would react with cold water?
[2]
(iii) What is the oxidation state of barium?
[1]
(iv) Name an unfamiliar metal (*) whose oxide cannot be reduced by carbon.
[1]
(v) Why should you be able to predict that metals such as iron and chromium have
more than one oxidation state?

[1]

[Total: 7]

© UCLES 2009

0620/32/M/J/09

[Turn over
6
5

Insoluble salts are made by precipitation.

For
Examiner's
Use

(a) A preparation of the insoluble salt iron fluoride is described below.
To 15 cm3 of aqueous iron(III) chloride, 45 cm3 of aqueous sodium fluoride is added.
The concentration of both solutions is 1.00 mol / dm3. The mixture is filtered and the
precipitate washed with distilled water. Finally, the precipitate is heated in an oven.
(i) Complete the equation.
Fe3+ + ...…….F-

………......

[2]

(ii) Why is the volume of sodium fluoride solution three times that of the iron(III)
chloride solution?

[1]
(iii) Why is the mixture washed with distilled water?

[1]
(iv) Why is the solid heated?

[1]

© UCLES 2009

0620/32/M/J/09
7
(b) The formulae of insoluble compounds can be found by precipitation reactions.
To 18.0 cm3 of an aqueous solution of the nitrate of metal T was added 2.0 cm3 of
aqueous sodium phosphate, Na3PO4. The concentration of both solutions was
1.00 mol / dm3. When the precipitate had settled, its height was measured.

For
Examiner's
Use

solution
precipitate of
the phosphate
of metal T

height of
precipitate

The experiment was repeated using different volumes of the phosphate solution. The
results are shown on the following graph.
16
12
height of
precipitate
/ mm

8
4
0
0

2

4

6

8

10

volume of phosphate solution / cm

12

14

3

What is the formula of the phosphate of metal T? Give your reasoning.

[3]

[Total: 8]

© UCLES 2009

0620/32/M/J/09

[Turn over
8
6

Ammonia is manufactured by the Haber process.
N2(g) +

3H2(g)

2NH3(g)

For
Examiner's
Use

the forward reaction is exothermic

(a) (i) Name the raw materials from which nitrogen and hydrogen are obtained.
nitrogen from

[1]

hydrogen from

[1]

(ii) Name the catalyst used in this process.
[1]
(iii) What is the most important use of ammonia?
[1]

(b) The following graph shows how the percentage of ammonia in the equilibrium mixture
changes with pressure.

% ammonia
at equilibrium

0
0

pressure

(i) Explain the term equilibrium.

[2]
(ii) How does the percentage of ammonia vary with pressure?
[1]

© UCLES 2009

0620/32/M/J/09
9
(c) (i) Sketch a graph which shows how the percentage of ammonia in the equilibrium
mixture varies with temperature.

For
Examiner's
Use

% ammonia
at equilibrium

0
0

temperature

[1]
(ii) Explain why the graph has the shape shown.

[2]

[Total: 10]

© UCLES 2009

0620/32/M/J/09

[Turn over
10
7

Hydrogen reacts with the halogens to form hydrogen halides.
(a) Bond energy is the amount of energy, in kJ, that must be supplied (endothermic) to
break one mole of a bond.
bond

bond energy in kJ / mol

H─H

+436

F─F

+158

H─F

+562

Use the above data to show that the following reaction is exothermic.
H─H

+

F─F

2H─F

[3]

© UCLES 2009

0620/32/M/J/09

For
Examiner's
Use
11
(b) They react with water to form acidic solutions.
HCl

+

H2O

H3O+

+

Cl -

HF

+

H2O

H3O+

+

For
Examiner's
Use

F-

(i) Explain why water behaves as a base in both of these reactions.

[2]
(ii) At equilibrium, only 1% of the hydrogen chloride exists as molecules, the rest has
formed ions. In the other equilibrium, 97% of the hydrogen fluoride exists as
molecules, only 3% has formed ions.
What does this tell you about the strength of each acid?

[2]
(iii) How would the pH of these two solutions differ?
[1]

[Total: 8]

© UCLES 2009

0620/32/M/J/09

[Turn over
12
8

Lactic acid can be made from corn starch.
CH3

CH

For
Examiner's
Use

COOH

OH
lactic acid

It polymerises to form the polymer, polylactic acid (PLA ) which is biodegradable.
(a) Suggest two advantages that PLA has compared with a polymer made from petroleum.

[2]

(b) The structure of PLA is given below.
CH3
O

O

CH

C

CH3
O

CH

(i) What type of compound contains the group that is circled?
[1]
(ii) Complete the following sentence.
Lactic acid molecules can form this group because they contain both an
group and an

group.

[2]

(iii) Is the formation of PLA, an addition or condensation polymerisation? Give a
reason for your choice.

[2]

© UCLES 2009

0620/32/M/J/09
13
(c) When lactic acid is heated, acrylic acid is formed.
H
C

C

H

H

H

OH

H

lactic acid

H
C

COOH

For
Examiner's
Use

H

C
COOH

acrylic acid

(i) Complete the word equation for the action of heat on lactic acid.
lactic acid →

+

[1]

(ii) Describe a test that would distinguish between lactic acid and acrylic acid.
test
result for lactic acid
result for acrylic acid

[3]

(iii) Describe a test, other than using an indicator, which would show that both
chemicals contain an acid group.
test
result
[2]

[Total: 13]

© UCLES 2009

0620/32/M/J/09

[Turn over
14
9

Quantities of chemicals, expressed in moles, can be used to find the formula of a
compound, to establish an equation and to determine reacting masses.
(a) A compound contains 72% magnesium and 28% nitrogen. What is its empirical
formula?

[2]

(b) A compound contains only aluminium and carbon. 0.03 moles of this compound reacted
with excess water to form 0.12 moles of Al(OH)3 and 0.09 moles of CH4.
Write a balanced equation for this reaction.

[2]

(c) 0.08 moles of silicon reacts with 7.2 g of fluorine.
Si

+

2F2

SiF4

(i) Which one is the limiting reagent? Explain your choice.

[3]
(ii) How many moles of SiF4 are formed?
[1]

[Total: 8]

© UCLES 2009

0620/32/M/J/09

For
Examiner's
Use
15
BLANK PAGE

0620/32/M/J/09
© UCLES 2009

24

40

Sodium

Calcium

88

0620/32/M/J/09

89

Key

b

X

a

b = proton (atomic) number

X = atomic symbol

a = relative atomic mass

*58-71 Lanthanoid series
90-103 Actinoid series

88

Ac

Actinium

Ra

Radium

Fr

Francium

87

*

Hafnium

72

Lanthanum

57

Hf

La

40

Zirconium

Zr

91

Titanium

178

Yttrium

22

48

Ti

139

39

Y

89

Scandium

21

227

Barium

Caesium

56

Cs

45

Sc

226

55

137

Ba

133

Strontium

Rubidium

38

Rb

37

Sr

85

20

Potassium

19

Ca

39

Magnesium

Na

12

Mg

23

Beryllium

4

Lithium

K

11

3

9

Be

7

II

Li

I

93

Ta

181

Niobium

Nb

90

58

73

52

96

Mo

W

184

141

Pa

Thorium

55

Tc
186

Re

144

Nd

92

60

Uranium

U

238

Neodymium

75

Rhenium

43

Technetium

25

Manganese

Mn
29

30

65

8

9

VII

2

0

Ru

101

Iron

190

Pm

Osmium

Os

Np
93

Neptunium

61

Promethium

76

44

Ruthenium

26

56

Fe

Sm

150

Iridium

Ir

192

Pu
94

Plutonium

62

Samarium

77

45

Rhodium

Rh

103

Cobalt

Co

195

Eu

152

Platinum

Pt

Am
95

Americium

63

Europium

78

46

Palladium

Pd

106

Nickel

Ni

Gd

157

Gold

Au

197

Silver

96

64

Curium

Cm

Gadolinium

79

47

Ag

108

Copper

Cu

201

Bk

Terbium

Tb

159

Mercury

Hg

97

Berkelium

65

80

48

Cadmium

Cd

112

Zinc

Zn

11

70

Dy

162

Thallium

Tl

204

Indium

In

115

Gallium

Ga

Cf
98

Californium

66

Dysprosium

81

49

31

13

Aluminium

119

Es

Holmium

Ho

165

Lead

Pb

207

Tin

Sn

99

Einsteinium

67

82

50

32

Germanium

Ge

73

Silicon

Si

Al
14

28

Carbon

27

Boron

12

C

14

75

Sb

122

Arsenic

As

Bi

209

Fermium

Fm

Erbium

Er

167

Bismuth

100

68

83

51

Antimony

33

15

Phosphorus

P

31

Nitrogen

N

Se

79

Sulfur

S

32

Oxygen

Po

169

Md

Thulium

Tm

101

Mendelevium

69

84

Polonium

52

Tellurium

Te

128

Selenium

34

16

16

O

Yb

173

Astatine

At

Iodine

I

127

Bromine

Br

80

Chlorine

No
102

Nobelium

70

Ytterbium

85

53

35

17

Cl

35.5

Fluorine

F

19

Lr

Lutetium

Lu

175

Radon

Rn

Xenon

Xe

131

Krypton

Kr

84

Argon

Ar

40

Neon

103

Lawrencium

71

86

54

36

18

10

Ne

20

Helium

Hydrogen

B

4

28

64

7

VI

He

27

59

6

V

H

59

5

IV

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).

91

Protactinium

Th

232

Praseodymium

Cerium

59

Pr

Ce

74

Tungsten

42

Molybdenum

24

Chromium

Cr

140

Tantalum

41

23

Vanadium

V

51

1

III
1

Group

DATA SHEET
The Periodic Table of the Elements

16

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

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0620 s09 qp_3

  • 1. w w ap eP m e tr .X w om .c s er Location Entry Codes As part of CIE’s continual commitment to maintaining best practice in assessment, CIE uses different variants of some question papers for our most popular assessments with large and widespread candidature. The question papers are closely related and the relationships between them have been thoroughly established using our assessment expertise. All versions of the paper give assessment of equal standard. The content assessed by the examination papers and the type of questions is unchanged. This change means that for this component there are now two variant Question Papers, Mark Schemes and Principal Examiner’s Reports where previously there was only one. For any individual country, it is intended that only one variant is used. This document contains both variants which will give all Centres access to even more past examination material than is usually the case. The diagram shows the relationship between the Question Papers, Mark Schemes and Principal Examiners’ Reports that are available. Question Paper Mark Scheme Principal Examiner’s Report Introduction Introduction Introduction First variant Question Paper First variant Mark Scheme First variant Principal Examiner’s Report Second variant Question Paper Second variant Mark Scheme Second variant Principal Examiner’s Report Who can I contact for further information on these changes? Please direct any questions about this to CIE’s Customer Services team at: international@cie.org.uk The titles for the variant items should correspond with the table above, so that at the top of the first page of the relevant part of the document and on the header, it has the words: • First variant Question Paper / Mark Scheme / Principal Examiner’s Report • Second variant Question Paper / Mark Scheme / Principal Examiner’s Report or as appropriate.
  • 2. First Variant Question Paper UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education *5310297965* 0620/31 CHEMISTRY May/June 2009 Paper 3 (Extended) 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name on all the work you hand in. Write in dark blue or black pen. You may use a pencil for any diagrams, graphs or rough working. Do not use staples, paper clips, highlighters, glue or correction fluid. For Examiner's Use DO NOT WRITE IN ANY BARCODES. Answer all questions. A copy of the Periodic Table is printed on page 16. At the end of the examination, fasten all your work securely together. The number of marks is given in brackets [ ] at the end of each question or part questions. 1 2 3 4 5 6 7 8 9 Total This document consists of 15 printed pages and 1 blank pages. IB09 06_0620_31/5RP © UCLES 2009 [Turn over
  • 3. 2 1 Some grass is crushed and mixed with the solvent, propanone. The colour pigments are extracted to give a deep green solution. (a) (i) Draw a labelled diagram to describe how you could show that there is more than one coloured pigment in the green solution. [3] (ii) Given a pure sample of chlorophyll, how could you show that the green solution from the grass contained chlorophyll? [2] (b) Explain the role of chlorophyll in green plants. [3] [Total: 8] © UCLES 2009 0620/31/M/J/09 For Examiner's Use
  • 4. 3 2 The results of experiments on electrolysis using inert electrodes are given in the table. For Examiner's Use Complete the table; the first line has been completed as an example. electrolyte molten lead(II) bromide change at negative electrode change at positive electrode change to electrolyte lead formed bromine formed used up potassium formed iodine formed used up hydrogen formed bromine formed potassium hydroxide formed dilute aqueous sodium chloride aqueous copper(II) sulfate [Total: 8] © UCLES 2009 0620/31/M/J/09 [Turn over
  • 5. 4 3 The following is a list of the electron distributions of atoms of unknown elements. element For Examiner's Use electron distribution A 2,5 B 2,8,4 C 2,8,8,2 D 2,8,18,8 E 2,8,18,8,1 F 2,8,18,18,7 (a) Choose an element from the list for each of the following descriptions. (i) It is a noble gas. (ii) It is a soft metal with a low density. (iii) It can form a covalent compound with element A. (iv) It has a giant covalent structure similar to diamond. (v) It can form a negative ion of the type X3-. [5] (b) Elements C and F can form an ionic compound. (i) Draw a diagram that shows the formula of this compound, the charges on the ions and the arrangement of the valency electrons around the negative ion. Use o to represent an electron from an atom of C. Use x to represent an electron from an atom of F. [3] (ii) Predict two properties of this compound. [2] [Total: 10] © UCLES 2009 0620/31/M/J/09
  • 6. 5 4 The reactivity series of metals given below contains both familiar and unfamiliar elements. For most of the unfamiliar elements, which are marked *, their common oxidation states are given. * barium Ba * lanthanum La For Examiner's Use (+3) magnesium zinc * chromium Cr (+2), (+3), (+6) iron copper * palladium (+2) Choose metal(s) from the above list to answer the following questions. (i) Which two metals would not react with dilute hydrochloric acid? [2] (ii) Which two unfamiliar metals (*) would react with cold water? [2] (iii) What is the oxidation state of barium? [1] (iv) Name an unfamiliar metal (*) whose oxide cannot be reduced by carbon. [1] (v) Why should you be able to predict that metals such as iron and chromium have more than one oxidation state? [1] [Total: 7] © UCLES 2009 0620/31/M/J/09 [Turn over
  • 7. 6 5 For Examiner's Use Insoluble salts are made by precipitation. (a) A preparation of the insoluble salt calcium fluoride is described below. To 15 cm3 of aqueous calcium chloride, 30 cm3 of aqueous sodium fluoride is added. The concentration of both solutions is 1.00 mol / dm3. The mixture is filtered and the precipitate washed with distilled water. Finally, the precipitate is heated in an oven. (i) Complete the equation. Ca2+ + ...…….F- ………...... [2] (ii) Why is the volume of sodium fluoride solution double that of the calcium chloride solution? [1] (iii) Why is the mixture washed with distilled water? [1] (iv) Why is the solid heated? [1] © UCLES 2009 0620/31/M/J/09
  • 8. 7 (b) The formulae of insoluble compounds can be found by precipitation reactions. To 12.0 cm3 of an aqueous solution of the nitrate of metal T was added 2.0 cm3 of aqueous sodium phosphate, Na3PO4. The concentration of both solutions was 1.00 mol / dm3. When the precipitate had settled, its height was measured. For Examiner's Use solution precipitate of the phosphate of metal T height of precipitate The experiment was repeated using different volumes of the phosphate solution. The results are shown on the following graph. 16 12 height of precipitate / mm 8 4 0 0 2 4 6 8 10 volume of phosphate solution / cm 12 14 3 What is the formula of the phosphate of metal T? Give your reasoning. [3] [Total: 8] © UCLES 2009 0620/31/M/J/09 [Turn over
  • 9. 8 6 Ammonia is manufactured by the Haber process. N2(g) + 3H2(g) 2NH3(g) For Examiner's Use the forward reaction is exothermic (a) (i) Name the raw materials from which nitrogen and hydrogen are obtained. nitrogen from [1] hydrogen from [1] (ii) Name the catalyst used in this process. [1] (iii) What is the most important use of ammonia? [1] (b) The following graph shows how the percentage of ammonia in the equilibrium mixture changes with temperature. % ammonia at equilibrium 0 0 temperature (i) Explain the term equilibrium. [2] (ii) How does the percentage of ammonia vary with temperature? [1] © UCLES 2009 0620/31/M/J/09
  • 10. 9 (c) (i) Sketch a graph which shows how the percentage of ammonia in the equilibrium mixture varies with pressure. For Examiner's Use % ammonia at equilibrium 0 0 pressure [1] (ii) Explain why the graph has the shape shown. [2] [Total: 10] © UCLES 2009 0620/31/M/J/09 [Turn over
  • 11. 10 7 Hydrogen reacts with the halogens to form hydrogen halides. (a) Bond energy is the amount of energy, in kJ, that must be supplied (endothermic) to break one mole of a bond. bond bond energy in kJ / mol H─H +436 Cl─Cl +242 H─Cl +431 Use the above data to show that the following reaction is exothermic. H─H + Cl─Cl 2H─Cl [3] © UCLES 2009 0620/31/M/J/09 For Examiner's Use
  • 12. 11 (b) They react with water to form acidic solutions. HCl + H2O H3O+ + Cl - HF + H2O H3O+ + For Examiner's Use F- (i) Explain why water behaves as a base in both of these reactions. [2] (ii) At equilibrium, only 1% of the hydrogen chloride exists as molecules, the rest has formed ions. In the other equilibrium, 97% of the hydrogen fluoride exists as molecules, only 3% has formed ions. What does this tell you about the strength of each acid? [2] (iii) How would the pH of these two solutions differ? [1] [Total: 8] © UCLES 2009 0620/31/M/J/09 [Turn over
  • 13. 12 8 Lactic acid can be made from corn starch. CH3 CH For Examiner's Use COOH OH lactic acid It polymerises to form the polymer, polylactic acid (PLA ) which is biodegradable. (a) Suggest two advantages that PLA has compared with a polymer made from petroleum. [2] (b) The structure of PLA is given below. CH3 O O CH C CH3 O CH (i) What type of compound contains the group that is circled? [1] (ii) Complete the following sentence. Lactic acid molecules can form this group because they contain both an group and an group. [2] (iii) Is the formation of PLA, an addition or condensation polymerisation? Give a reason for your choice. [2] © UCLES 2009 0620/31/M/J/09
  • 14. 13 (c) When lactic acid is heated, acrylic acid is formed. H C C H H H OH H lactic acid H C COOH For Examiner's Use H C COOH acrylic acid (i) Complete the word equation for the action of heat on lactic acid. lactic acid → + [1] (ii) Describe a test that would distinguish between lactic acid and acrylic acid. test result for lactic acid result for acrylic acid [3] (iii) Describe a test, other than using an indicator, which would show that both chemicals contain an acid group. test result [2] [Total: 13] © UCLES 2009 0620/31/M/J/09 [Turn over
  • 15. 14 9 Quantities of chemicals, expressed in moles, can be used to find the formula of a compound, to establish an equation and to determine reacting masses. (a) A compound contains 72% magnesium and 28% nitrogen. What is its empirical formula? [2] (b) A compound contains only aluminium and carbon. 0.03 moles of this compound reacted with excess water to form 0.12 moles of Al(OH)3 and 0.09 moles of CH4. Write a balanced equation for this reaction. [2] (c) 0.07 moles of silicon reacts with 25 g of bromine. Si + 2Br2 SiBr4 (i) Which one is the limiting reagent? Explain your choice. [3] (ii) How many moles of SiBr4 are formed? [1] [Total: 8] © UCLES 2009 0620/31/M/J/09 For Examiner's Use
  • 17. © UCLES 2009 24 40 Sodium Calcium 88 0620/31/M/J/09 89 Key b X a b = proton (atomic) number X = atomic symbol a = relative atomic mass *58-71 Lanthanoid series 90-103 Actinoid series 88 Ac Actinium Ra Radium Fr Francium 87 * Hafnium 72 Lanthanum 57 Hf La 40 Zirconium Zr 91 Titanium 178 Yttrium 22 48 Ti 139 39 Y 89 Scandium 21 227 Barium Caesium 56 Cs 45 Sc 226 55 137 Ba 133 Strontium Rubidium 38 Rb 37 Sr 85 20 Potassium 19 Ca 39 Magnesium Na 12 Mg 23 Beryllium 4 Lithium K 11 3 9 Be 7 II Li I 93 Ta 181 Niobium Nb 90 58 73 52 96 Mo W 184 141 Pa Thorium 55 Tc 186 Re 144 Nd 92 60 Uranium U 238 Neodymium 75 Rhenium 43 Technetium 25 Manganese Mn 29 30 65 8 9 VII 2 0 Ru 101 Iron 190 Pm Osmium Os Np 93 Neptunium 61 Promethium 76 44 Ruthenium 26 56 Fe Sm 150 Iridium Pu 94 Plutonium 62 Eu 152 Platinum Am 95 Americium 63 Europium 78 195 Pt Ir 46 Palladium Pd 106 Nickel Ni 192 Samarium 77 45 Rhodium Rh 103 Cobalt Co Gd 157 Gold Au 197 Silver 96 64 Curium Cm Gadolinium 79 47 Ag 108 Copper Cu 201 Bk Terbium Tb 159 Mercury Hg 97 Berkelium 65 80 48 Cadmium Cd 112 Zinc Zn 11 70 Dy 162 Thallium Tl 204 Indium Cf 98 Californium 66 Es Holmium Ho 165 Lead Pb 207 Tin 99 Einsteinium 67 82 50 119 Sn In 32 Germanium Ge 73 Silicon 115 Gallium Ga Dysprosium 81 49 31 13 Aluminium Si Al 14 28 Carbon 27 Boron 12 C 14 75 Sb 122 Arsenic As Bi 209 Fermium Fm Erbium Er 167 Bismuth 100 68 83 51 Antimony 33 15 Phosphorus P 31 Nitrogen N Se 79 Sulfur S 32 Oxygen Po 169 Md Thulium Tm 101 Mendelevium 69 84 Polonium 52 Tellurium Te 128 Selenium 34 16 16 O Yb 173 Astatine At Iodine I 127 Bromine Br 80 Chlorine No 102 Nobelium 70 Ytterbium 85 53 35 17 Cl 35.5 Fluorine F 19 Lr Lutetium Lu 175 Radon Rn Xenon Xe 131 Krypton Kr 84 Argon Ar 40 Neon 103 Lawrencium 71 86 54 36 18 10 Ne 20 Helium Hydrogen B 4 28 64 7 VI He 27 59 6 V H 59 5 IV The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.). 91 Protactinium Th 232 Praseodymium Cerium 59 Pr Ce 74 Tungsten 42 Molybdenum 24 Chromium Cr 140 Tantalum 41 23 Vanadium V 51 1 III 1 Group DATA SHEET The Periodic Table of the Elements 16 Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
  • 18. Second Variant Question Paper UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education *0583100121* 0620/32 CHEMISTRY May/June 2009 Paper 3 (Extended) 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name on all the work you hand in. Write in dark blue or black pen. You may use a pencil for any diagrams, graphs or rough working. Do not use staples, paper clips, highlighters, glue or correction fluid. For Examiner's Use DO NOT WRITE IN ANY BARCODES. Answer all questions. A copy of the Periodic Table is printed on page 16. At the end of the examination, fasten all your work securely together. The number of marks is given in brackets [ ] at the end of each question or part questions. 1 2 3 4 5 6 7 8 9 Total This document consists of 15 printed pages and 1 blank page. IB09 06_0620_32/4RP © UCLES 2009 [Turn over
  • 19. 2 1 Some grass is crushed and mixed with the solvent, propanone. The colour pigments are extracted to give a deep green solution. (a) (i) Draw a labelled diagram to describe how you could show that there is more than one coloured pigment in the green solution. [3] (ii) Given a pure sample of chlorophyll, how could you show that the green solution from the grass contained chlorophyll? [2] (b) Explain the role of chlorophyll in green plants. [3] [Total: 8] © UCLES 2009 0620/32/M/J/09 For Examiner's Use
  • 20. 3 2 The results of experiments on electrolysis using inert electrodes are given in the table. For Examiner's Use Complete the table; the first line has been completed as an example. electrolyte change at negative electrode change at positive electrode change to electrolyte lead formed bromine formed used up lithium formed chlorine formed used up hydrogen formed molten lead(II) bromide bromine formed potassium hydroxide formed dilute aqueous sodium chloride aqueous copper(II) sulfate [Total: 8] © UCLES 2009 0620/32/M/J/09 [Turn over
  • 21. 4 3 The following is a list of the electron distributions of atoms of unknown elements. element For Examiner's Use electron distribution A 2,6 B 2,8,4 C 2,8,8,2 D 2,8,18,8 E 2,8,18,8,1 F 2,8,18,18,7 (a) Choose an element from the list for each of the following descriptions. (i) It is a noble gas. (ii) It is a soft metal with a low density. (iii) It can form a covalent compound with element A. (iv) It has a giant covalent structure similar to diamond. (v) It is a diatomic gas with molecules of the type X2. [5] (b) Elements C and A can form an ionic compound. (i) Draw a diagram that shows the formula of this compound, the charges on the ions and the arrangement of the valency electrons around the negative ion. Use o to represent an electron from an atom of C. Use x to represent an electron from an atom of A. [3] (ii) Predict two properties of this compound. [2] [Total: 10] © UCLES 2009 0620/32/M/J/09
  • 22. 5 4 The reactivity series of metals given below contains both familiar and unfamiliar elements. For most of the unfamiliar elements, which are marked *, their common oxidation states are given. * barium Ba * lanthanum La For Examiner's Use (+3) magnesium zinc * chromium Cr (+2), (+3), (+6) iron copper * palladium (+2) Choose metal(s) from the above list to answer the following questions. (i) Which two metals would not react with dilute hydrochloric acid? [2] (ii) Which two unfamiliar metals (*) would react with cold water? [2] (iii) What is the oxidation state of barium? [1] (iv) Name an unfamiliar metal (*) whose oxide cannot be reduced by carbon. [1] (v) Why should you be able to predict that metals such as iron and chromium have more than one oxidation state? [1] [Total: 7] © UCLES 2009 0620/32/M/J/09 [Turn over
  • 23. 6 5 Insoluble salts are made by precipitation. For Examiner's Use (a) A preparation of the insoluble salt iron fluoride is described below. To 15 cm3 of aqueous iron(III) chloride, 45 cm3 of aqueous sodium fluoride is added. The concentration of both solutions is 1.00 mol / dm3. The mixture is filtered and the precipitate washed with distilled water. Finally, the precipitate is heated in an oven. (i) Complete the equation. Fe3+ + ...…….F- ………...... [2] (ii) Why is the volume of sodium fluoride solution three times that of the iron(III) chloride solution? [1] (iii) Why is the mixture washed with distilled water? [1] (iv) Why is the solid heated? [1] © UCLES 2009 0620/32/M/J/09
  • 24. 7 (b) The formulae of insoluble compounds can be found by precipitation reactions. To 18.0 cm3 of an aqueous solution of the nitrate of metal T was added 2.0 cm3 of aqueous sodium phosphate, Na3PO4. The concentration of both solutions was 1.00 mol / dm3. When the precipitate had settled, its height was measured. For Examiner's Use solution precipitate of the phosphate of metal T height of precipitate The experiment was repeated using different volumes of the phosphate solution. The results are shown on the following graph. 16 12 height of precipitate / mm 8 4 0 0 2 4 6 8 10 volume of phosphate solution / cm 12 14 3 What is the formula of the phosphate of metal T? Give your reasoning. [3] [Total: 8] © UCLES 2009 0620/32/M/J/09 [Turn over
  • 25. 8 6 Ammonia is manufactured by the Haber process. N2(g) + 3H2(g) 2NH3(g) For Examiner's Use the forward reaction is exothermic (a) (i) Name the raw materials from which nitrogen and hydrogen are obtained. nitrogen from [1] hydrogen from [1] (ii) Name the catalyst used in this process. [1] (iii) What is the most important use of ammonia? [1] (b) The following graph shows how the percentage of ammonia in the equilibrium mixture changes with pressure. % ammonia at equilibrium 0 0 pressure (i) Explain the term equilibrium. [2] (ii) How does the percentage of ammonia vary with pressure? [1] © UCLES 2009 0620/32/M/J/09
  • 26. 9 (c) (i) Sketch a graph which shows how the percentage of ammonia in the equilibrium mixture varies with temperature. For Examiner's Use % ammonia at equilibrium 0 0 temperature [1] (ii) Explain why the graph has the shape shown. [2] [Total: 10] © UCLES 2009 0620/32/M/J/09 [Turn over
  • 27. 10 7 Hydrogen reacts with the halogens to form hydrogen halides. (a) Bond energy is the amount of energy, in kJ, that must be supplied (endothermic) to break one mole of a bond. bond bond energy in kJ / mol H─H +436 F─F +158 H─F +562 Use the above data to show that the following reaction is exothermic. H─H + F─F 2H─F [3] © UCLES 2009 0620/32/M/J/09 For Examiner's Use
  • 28. 11 (b) They react with water to form acidic solutions. HCl + H2O H3O+ + Cl - HF + H2O H3O+ + For Examiner's Use F- (i) Explain why water behaves as a base in both of these reactions. [2] (ii) At equilibrium, only 1% of the hydrogen chloride exists as molecules, the rest has formed ions. In the other equilibrium, 97% of the hydrogen fluoride exists as molecules, only 3% has formed ions. What does this tell you about the strength of each acid? [2] (iii) How would the pH of these two solutions differ? [1] [Total: 8] © UCLES 2009 0620/32/M/J/09 [Turn over
  • 29. 12 8 Lactic acid can be made from corn starch. CH3 CH For Examiner's Use COOH OH lactic acid It polymerises to form the polymer, polylactic acid (PLA ) which is biodegradable. (a) Suggest two advantages that PLA has compared with a polymer made from petroleum. [2] (b) The structure of PLA is given below. CH3 O O CH C CH3 O CH (i) What type of compound contains the group that is circled? [1] (ii) Complete the following sentence. Lactic acid molecules can form this group because they contain both an group and an group. [2] (iii) Is the formation of PLA, an addition or condensation polymerisation? Give a reason for your choice. [2] © UCLES 2009 0620/32/M/J/09
  • 30. 13 (c) When lactic acid is heated, acrylic acid is formed. H C C H H H OH H lactic acid H C COOH For Examiner's Use H C COOH acrylic acid (i) Complete the word equation for the action of heat on lactic acid. lactic acid → + [1] (ii) Describe a test that would distinguish between lactic acid and acrylic acid. test result for lactic acid result for acrylic acid [3] (iii) Describe a test, other than using an indicator, which would show that both chemicals contain an acid group. test result [2] [Total: 13] © UCLES 2009 0620/32/M/J/09 [Turn over
  • 31. 14 9 Quantities of chemicals, expressed in moles, can be used to find the formula of a compound, to establish an equation and to determine reacting masses. (a) A compound contains 72% magnesium and 28% nitrogen. What is its empirical formula? [2] (b) A compound contains only aluminium and carbon. 0.03 moles of this compound reacted with excess water to form 0.12 moles of Al(OH)3 and 0.09 moles of CH4. Write a balanced equation for this reaction. [2] (c) 0.08 moles of silicon reacts with 7.2 g of fluorine. Si + 2F2 SiF4 (i) Which one is the limiting reagent? Explain your choice. [3] (ii) How many moles of SiF4 are formed? [1] [Total: 8] © UCLES 2009 0620/32/M/J/09 For Examiner's Use
  • 33. © UCLES 2009 24 40 Sodium Calcium 88 0620/32/M/J/09 89 Key b X a b = proton (atomic) number X = atomic symbol a = relative atomic mass *58-71 Lanthanoid series 90-103 Actinoid series 88 Ac Actinium Ra Radium Fr Francium 87 * Hafnium 72 Lanthanum 57 Hf La 40 Zirconium Zr 91 Titanium 178 Yttrium 22 48 Ti 139 39 Y 89 Scandium 21 227 Barium Caesium 56 Cs 45 Sc 226 55 137 Ba 133 Strontium Rubidium 38 Rb 37 Sr 85 20 Potassium 19 Ca 39 Magnesium Na 12 Mg 23 Beryllium 4 Lithium K 11 3 9 Be 7 II Li I 93 Ta 181 Niobium Nb 90 58 73 52 96 Mo W 184 141 Pa Thorium 55 Tc 186 Re 144 Nd 92 60 Uranium U 238 Neodymium 75 Rhenium 43 Technetium 25 Manganese Mn 29 30 65 8 9 VII 2 0 Ru 101 Iron 190 Pm Osmium Os Np 93 Neptunium 61 Promethium 76 44 Ruthenium 26 56 Fe Sm 150 Iridium Ir 192 Pu 94 Plutonium 62 Samarium 77 45 Rhodium Rh 103 Cobalt Co 195 Eu 152 Platinum Pt Am 95 Americium 63 Europium 78 46 Palladium Pd 106 Nickel Ni Gd 157 Gold Au 197 Silver 96 64 Curium Cm Gadolinium 79 47 Ag 108 Copper Cu 201 Bk Terbium Tb 159 Mercury Hg 97 Berkelium 65 80 48 Cadmium Cd 112 Zinc Zn 11 70 Dy 162 Thallium Tl 204 Indium In 115 Gallium Ga Cf 98 Californium 66 Dysprosium 81 49 31 13 Aluminium 119 Es Holmium Ho 165 Lead Pb 207 Tin Sn 99 Einsteinium 67 82 50 32 Germanium Ge 73 Silicon Si Al 14 28 Carbon 27 Boron 12 C 14 75 Sb 122 Arsenic As Bi 209 Fermium Fm Erbium Er 167 Bismuth 100 68 83 51 Antimony 33 15 Phosphorus P 31 Nitrogen N Se 79 Sulfur S 32 Oxygen Po 169 Md Thulium Tm 101 Mendelevium 69 84 Polonium 52 Tellurium Te 128 Selenium 34 16 16 O Yb 173 Astatine At Iodine I 127 Bromine Br 80 Chlorine No 102 Nobelium 70 Ytterbium 85 53 35 17 Cl 35.5 Fluorine F 19 Lr Lutetium Lu 175 Radon Rn Xenon Xe 131 Krypton Kr 84 Argon Ar 40 Neon 103 Lawrencium 71 86 54 36 18 10 Ne 20 Helium Hydrogen B 4 28 64 7 VI He 27 59 6 V H 59 5 IV The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.). 91 Protactinium Th 232 Praseodymium Cerium 59 Pr Ce 74 Tungsten 42 Molybdenum 24 Chromium Cr 140 Tantalum 41 23 Vanadium V 51 1 III 1 Group DATA SHEET The Periodic Table of the Elements 16 Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.