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Unit 3, Part 2 Quantum Mechanics Chemistry Notes
Light & Wave Motion ,[object Object],[object Object],[object Object],[object Object],[object Object]
A Typical Wave http://www.pas.rochester.edu/~afrank/A105/LectureV/FG03_003_PCT.gif
Wave Descriptions ,[object Object],[object Object],[object Object]
The Nature of Light ,[object Object],[object Object]
The Electromagnetic Spectrum ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The Electromagnetic Spectrum http://www.yorku.ca/eye/spectrum.gif
Looking At Wavelength ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],http://www2.glenbrook.k12.il.us/gbssci/phys/Class/sound/u11l2a2.gif
Visible Light Spectrum ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Long Short
Absorption & Emission Spectra ,[object Object],[object Object],[object Object],[object Object],[object Object]
Absorption & Emission Spectra ,[object Object],[object Object],[object Object]
Absorption & Emission Spectra http://www.astro.columbia.edu/~archung/labs/fall2001/images/spectrum_line.gif
Hydrogen Atom Example Notice the spectral lines in the same positions? These represent specific energy level changes of the electrons in the atom. http://www.solarobserving.com/pics/hydrogen-spectra.jpg Dark Line Bright Line
The Bohr Model http://library.thinkquest.org/19662/images/eng/pages/model-bohr-2.jpg Light Energy Released Light Energy Taken In
Bohr Model of Atom ,[object Object],[object Object],[object Object]
Ground State vs. Excited State http://imagine.gsfc.nasa.gov/docs/teachers/lessons/xray_spectra/images/emit.gif http://content.answers.com/main/content/wp/en/thumb/c/c4/180px-Energylevels.png Ground State = lowest energy level Excited State = a higher energy level Higher energy levels are closer together…
Energy Levels Are Quantized ,[object Object],[object Object],[object Object]
Chemical Behavior of Atom ,[object Object],[object Object]
Locating Electrons in an Atom ,[object Object],[object Object],[object Object]
The Electron Configuration ,[object Object],[object Object],[object Object],[object Object]
Electrons & Energy Levels ,[object Object],[object Object],[object Object]
The Hydrogen Example ,[object Object],[object Object],[object Object],[object Object]
Quantum Numbers ,[object Object],[object Object],[object Object],[object Object],[object Object]
Quantum Number Analogy ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Electron Configurations Written ,[object Object],[object Object],[object Object],[object Object]
Quantum Number (n) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Quantum Number ( l ) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Quantum Number (m) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Orbital Shapes http://lincoln.pps.k12.or.us/lscheffler/OrbitalShapesOverheads_files/image002.jpg
Quantum Number (s) ,[object Object],[object Object],[object Object]
3d ___  ___  ___  ___  ___ 4s  ___ 3p ___  ___  ___ Principle Energy Level (n) Energy Sublevel (l) Orbital (m) holds 2 electrons total
Example Orbital Diagrams 1s 1s2s 1s2s2p http://www.uwgb.edu/dutchs/PETROLGY/WhatElmsLookLike.HTM
Electron Configuration Guidelines ,[object Object],[object Object],[object Object]
Electron Configuration Guidelines ,[object Object],[object Object],[object Object],[object Object],[object Object]
Electron Configuration Guidelines ,[object Object],[object Object],[object Object],[object Object]
Electron Configuration Guidelines ,[object Object],[object Object],[object Object],[object Object]
Electron Configuration Guidelines Place one electron in each   orbital before pairing! Degenerate  Orbitals:  All 3 have the same energy and appear at the same level Hund’s Rule
Electron Configuration Guidelines ,[object Object],[object Object],[object Object]
Orbital Filling Clues http://pegasus.cc.ucf.edu/~jparadis/chem2045/chapter06.html
Electron Configuration Guidelines ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Orbital Filling Diagrams ,[object Object],[object Object],[object Object],[object Object]
Exceptions You Need to Know ,[object Object],[object Object],[object Object],[object Object]

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Quantum Mechanics

  • 1. Unit 3, Part 2 Quantum Mechanics Chemistry Notes
  • 2.
  • 3. A Typical Wave http://www.pas.rochester.edu/~afrank/A105/LectureV/FG03_003_PCT.gif
  • 4.
  • 5.
  • 6.
  • 7. The Electromagnetic Spectrum http://www.yorku.ca/eye/spectrum.gif
  • 8.
  • 9.
  • 10.
  • 11.
  • 12. Absorption & Emission Spectra http://www.astro.columbia.edu/~archung/labs/fall2001/images/spectrum_line.gif
  • 13. Hydrogen Atom Example Notice the spectral lines in the same positions? These represent specific energy level changes of the electrons in the atom. http://www.solarobserving.com/pics/hydrogen-spectra.jpg Dark Line Bright Line
  • 14. The Bohr Model http://library.thinkquest.org/19662/images/eng/pages/model-bohr-2.jpg Light Energy Released Light Energy Taken In
  • 15.
  • 16. Ground State vs. Excited State http://imagine.gsfc.nasa.gov/docs/teachers/lessons/xray_spectra/images/emit.gif http://content.answers.com/main/content/wp/en/thumb/c/c4/180px-Energylevels.png Ground State = lowest energy level Excited State = a higher energy level Higher energy levels are closer together…
  • 17.
  • 18.
  • 19.
  • 20.
  • 21.
  • 22.
  • 23.
  • 24.
  • 25.
  • 26.
  • 27.
  • 28.
  • 30.
  • 31. 3d ___ ___ ___ ___ ___ 4s ___ 3p ___ ___ ___ Principle Energy Level (n) Energy Sublevel (l) Orbital (m) holds 2 electrons total
  • 32. Example Orbital Diagrams 1s 1s2s 1s2s2p http://www.uwgb.edu/dutchs/PETROLGY/WhatElmsLookLike.HTM
  • 33.
  • 34.
  • 35.
  • 36.
  • 37. Electron Configuration Guidelines Place one electron in each orbital before pairing! Degenerate Orbitals: All 3 have the same energy and appear at the same level Hund’s Rule
  • 38.
  • 39. Orbital Filling Clues http://pegasus.cc.ucf.edu/~jparadis/chem2045/chapter06.html
  • 40.
  • 41.
  • 42.