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Intermolecular
                forces
13-Nov-12                    1
Overview
                         intramolecular
                         bonds

  attraction in
  molecules

                         intermolecular
                         forces




13-Nov-12                                 2
Intermolecular forces is much weaker than intramolecular
            forces

13-Nov-12                            KARBOHIDRAT                       3
INTERMOLECULAR FORCES ---- attraction that exist
                              between molecule

   1. GAYA VAN DER WAALS

   •        GAYA DIPOLE-DIPOLE
   •        GAYA LONDON (DISPERSI)


   2. IKATAN HIDROGEN


13-Nov-12                                             4
1. Gaya dipole-dipole....dipole-dipole force
2. Gaya london (dispersi)....dispersion force
4. Ikatan hidrogen......hydrogen bonding
5. Ikatan ionik....ionic bonding
6. Jaringan ikatan kovalen.....covalent network




13-Nov-12                                         5
What should be discussed :
  1. What ?
  2. When?
  3. Example?
  4. Power?



13-Nov-12                      6
London dispersion force

      •The attraction between atoms and molecules caused by
      the formation of instantaneous atoms in the atoms and
      molecules

      •Two non polar molecule

      •Caused by momentary dipole




13-Nov-12                                                     7
13-Nov-12   KARBOHIDRAT   8
13-Nov-12   KARBOHIDRAT   9
polarizability
• the ease with which
  an atom or molecule can
  be distorted to have
  an instantaneous dipole.




13-Nov-12           KARBOHIDRAT   10
Polarizability increases
       with: greater number of
       electrons


         Dispersion forces usually
        increase with molar mass.




13-Nov-12                      KARBOHIDRAT   11
Effects on boiling points




13-Nov-12                               12
Dipole-dipole force
• The force that exist between negative and positive ends of a
  polar molecule.
• Between two polar molecule



                                      +     -
                  +          -




                      Opposite attraction

13-Nov-12                                                        13
13-Nov-12   KARBOHIDRAT   14
Hydrogen bonding
• A form of dipole attraction in which hydrogen atom bonded to
  a strongly electronegative atom
• H + F, O, N .... HF, NH3, H2O
• Works like dipole-dipole but 5 times stronger




13-Nov-12                  KARBOHIDRAT                      15
Ionic bonding
• The forces holding ions together in ionic solids
  are electrostatic forces




13-Nov-12             KARBOHIDRAT                16
•100 % covalent bond
       •There are no intermolecular force
       •Only compounds of C only (diamond, graphite)
            and Si (usually with Oxygen)
       • very strong attraction




13-Nov-12                      KARBOHIDRAT             17
13-Nov-12   KARBOHIDRAT   18
13-Nov-12   KARBOHIDRAT   19
power


      Jaringan ikatan kovalen > Ikatan ionik > Ikatan
      hidrogen > dipol-dipol > gaya london




13-Nov-12                                           20

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Intermolecular Forces (Gaya Antarmolekul)

  • 1. Intermolecular forces 13-Nov-12 1
  • 2. Overview intramolecular bonds attraction in molecules intermolecular forces 13-Nov-12 2
  • 3. Intermolecular forces is much weaker than intramolecular forces 13-Nov-12 KARBOHIDRAT 3
  • 4. INTERMOLECULAR FORCES ---- attraction that exist between molecule 1. GAYA VAN DER WAALS • GAYA DIPOLE-DIPOLE • GAYA LONDON (DISPERSI) 2. IKATAN HIDROGEN 13-Nov-12 4
  • 5. 1. Gaya dipole-dipole....dipole-dipole force 2. Gaya london (dispersi)....dispersion force 4. Ikatan hidrogen......hydrogen bonding 5. Ikatan ionik....ionic bonding 6. Jaringan ikatan kovalen.....covalent network 13-Nov-12 5
  • 6. What should be discussed : 1. What ? 2. When? 3. Example? 4. Power? 13-Nov-12 6
  • 7. London dispersion force •The attraction between atoms and molecules caused by the formation of instantaneous atoms in the atoms and molecules •Two non polar molecule •Caused by momentary dipole 13-Nov-12 7
  • 8. 13-Nov-12 KARBOHIDRAT 8
  • 9. 13-Nov-12 KARBOHIDRAT 9
  • 10. polarizability • the ease with which an atom or molecule can be distorted to have an instantaneous dipole. 13-Nov-12 KARBOHIDRAT 10
  • 11. Polarizability increases with: greater number of electrons Dispersion forces usually increase with molar mass. 13-Nov-12 KARBOHIDRAT 11
  • 12. Effects on boiling points 13-Nov-12 12
  • 13. Dipole-dipole force • The force that exist between negative and positive ends of a polar molecule. • Between two polar molecule + - + - Opposite attraction 13-Nov-12 13
  • 14. 13-Nov-12 KARBOHIDRAT 14
  • 15. Hydrogen bonding • A form of dipole attraction in which hydrogen atom bonded to a strongly electronegative atom • H + F, O, N .... HF, NH3, H2O • Works like dipole-dipole but 5 times stronger 13-Nov-12 KARBOHIDRAT 15
  • 16. Ionic bonding • The forces holding ions together in ionic solids are electrostatic forces 13-Nov-12 KARBOHIDRAT 16
  • 17. •100 % covalent bond •There are no intermolecular force •Only compounds of C only (diamond, graphite) and Si (usually with Oxygen) • very strong attraction 13-Nov-12 KARBOHIDRAT 17
  • 18. 13-Nov-12 KARBOHIDRAT 18
  • 19. 13-Nov-12 KARBOHIDRAT 19
  • 20. power Jaringan ikatan kovalen > Ikatan ionik > Ikatan hidrogen > dipol-dipol > gaya london 13-Nov-12 20