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Quality made by
Endress+Hauser
ISO 9001
Technical Information
TI 366C/07/en/06.03
51512476
Compact pH Electrode
PuriSys CPF 201
Compact electrode for pH measurement in pure and
ultrapure water
Application
• Boiler feed water
• Power plant applications
• Pharmaceutical water for injection
(WFI)
Your benefits
• 316 SS low flow assembly:
– stable pH reading
– elimination of flow dependency
errors
• Simple, maintenance-free replacement
electrode
• Temperature compensation
• TOP 68 quick disconnect, water tight
connector
• Patented porous PTFE reference
junction
• Easy installation
PuriSys CPF 201
2 Endress+Hauser
Function and system design
Measuring principle pH measurement
The pH value is used as a unit of measurement for the acidity or alkalinity of a liquid medium. The
membrane glass of the electrode supplies an electrochemical potential which is dependent upon
the pH value of the medium. This potential is generated by the selective penetration of H+
ions
through the outer layer of the membrane. An electrochemical boundary layer with an electric
potential forms at this point. An integrated Ag/AgCl reference system serves as reference
electrode.
The transmitter converts the measured voltage into the corresponding pH value using the Nernst
equation.
Important properties
PuriSys CPF 201
• Reference system
The CPF 201 electrode has a porous Teflon reference junction in a double reference chamber
for long life in all high purity water applications.
• Temperature compensation
In addition, a Pt 100 or Pt 1000 temperature sensor is embedded in the pH glass bulb stem for
quick temperature response.
• Easy connection
The electrode is connected via the water-proof plug-in system TOP 68.
• Flow assembly
The flow cell has been designed to dissipate static electrical charges inherent in flowing water
with low conductivity. The flow assembly design minimizes trapped particles and contaminants.
Measuring system The complete measuring system comprises:
• PuriSys CPF 201 electrode with stainless steel body
• PuriSys CPF 201 stainless steel flow assembly with compression fitting on inlet and outlet
• CPK 9 measuring cable (not included in scope of delivery)
• Transmitter, e.g. Liquisys M CPM 223, Mycom S CPM 153 (not included in scope of delivery)
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01 3 0
pH
ENDRESS+HAUSER
LIQUISYS M
CAL REL
REL1
REL1
ALARM
REL2
REL2E
Setpoint
R232
1
4
PuriSys CPF 201
Endress+Hauser 3
Input
Measured values pH value
Temperature
Measuring range
Response time t90  10 s
Cable specifications The CPF 201 electrode is connected to the measuring transmitter using the CPK 9 measuring
cable (version without potential matching line).
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Wiring of CPK 9 to
transmitter
pH value 0 ... 14 pH
Temperature 2 ... 75 °C / 36 ... 167 °F
Coax BK
Coax WH
GN
WH
YE
Plug
Shield connection
Cable Transmitter
CPK 9 Liquisys M CPM 223 / 253 Mycom S CPM 153
Pin Function Terminal Function Terminal Function
Coax BK Reference Ref Reference Ref Reference
Coax WH pH pH pH pH pH
GN Temp. (Pt 100) 11 TC 11 TC
WH Temp. (Pt 100) 12 TC common 13 TC common
YE Temp. (Pt 100) 13 TC 12 TC
Shield EMC
protection
S Shield Shield connection /
Pg thread
Shield
PuriSys CPF 201
4 Endress+Hauser
Installation
Calibration When installing a new CPF 201 electrode, perform a two-point calibration using pH 4 and 7 buffer
solutions to establish that the electrode and the transmitter are functional together. To do so, refer
to the operating instructions of the transmitter.
Rinse the electrode thoroughly with ultra-pure water to remove all traces of the buffer solutions
prior to inserting the electrode into the flow assembly.
Since the pH variation in ultra-pure water is very small, routine one-point calibration of the
CPF 201 electrode is performed by comparative sample measurement according to the ASTM
test method. When performing sample measurements take note of the following:
• The sample chamber and the sample line must avoid exposure of the ultra-pure water to the
atmosphere.
– Ultra-pure water is highly unbuffered and the slightest amount of contamination can change
the pH value significantly. Specifically, ultra-pure water rapidly absorbs CO2 gas from the
atmosphere which lowers the pH value of the sample.
– The sample may contain volatile substances that will rapidly dissipate when exposed to the
atmosphere.
• The sample to be measured should be at the same temperature as the medium stream because
ultra-pure water has a significant temperature coefficient.
• To obtain repeatable measurement results, the flow rate of the sample chamber must be
stabilised. Also, the pressure must be stable.
Installation instructions The electrode is threaded into the flow assembly and hand-tightened.
When mounting the flow assembly, make sure that the inlet and outlet ports are vertical with the
inlet on the bottom. In this fashion, the electrode mounting hole will be at the top right. This will
ensure that bubbles in the water stream will not collect and interfere with the measurements.
The supplied PVC mounting plate for electrical isolation ensures a noiseless pH reading.
To mount the PVC mounting plate on posts or pipes, use the mounting brackets included in the
package.
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PuriSys CPF 201
Endress+Hauser 5
Environment
Ingress protection IP 68 (1m / 3.28 ft water column, 50 °C / 122 °F, 168 h) / NEMA 6 (TOP 68 plug-in system)
Process
Process temperature max. 75 °C / 167 °F
Process pressure max. 3.45 bar / 50 psi
Medium conductivity  100 µS/cm
Drift  0.02 pH/week at 0.5 µS/cm at 25 °C / 77 °F
Flow rate 50 ... 250 ml/min
Optimum: 150 ml/min
The flow rate must be stable to obtain accurate measurement results.
Mechanical construction
Design, dimensions
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PuriSys CPF 201
6 Endress+Hauser
Weight
Materials
Process connection OD 6 mm stainless steel compression fitting
¼ stainless steel compression fitting
Temperature sensor Pt 100 RTD, Pt 1000 RTD
Cable connection TOP 68 plug-in system
Certificates and approvals
Test report Design according to ASTM standard D 5128, Standard Test Method for On-Line pH
Measurement of Water of Low Conductivity
C07-CPF201xx-06-05-00-en-002.eps

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27.2/
1.07
171/6.73
mm/inch17.5 /
0.69
305 / 12
305/12
73.7 /
2.9
mm / inch
241.3/9.5
Electrode: approx. 213 g
Complete on-line unit
incl. mounting brackets:
approx. 2275 g
Electrode shaft stainless steel SS 316, Viton®
Reference junction Teflon®
Glass bulb pH membrane glass
Reference system KCl/AgCl
Flow assembly stainless steel SS 316, Viton®
Inlet / outlet ports stainless steel SS 316
PuriSys CPF 201
Endress+Hauser 7
Ordering information
Product structure
Scope of delivery The scope of delivery includes:
• 1 CPF 201 electrode
• 1 flow assembly
• 1 PVC mounting plate incl. mounting brackets
• Technical Information TI 366C/07/en
Accessories
Measuring cable ❑ Measuring cable CPK 9 (version without PM)
for electrodes with TOP 68 plug-in head
ordering by product structure, see Technical Information TI 118C/07/en
Buffer solutions Technical buffer solutions, accuracy 0.02 pH, acc. to NIST/DIN
❑ pH 4.0 red, 100 ml (0.026 US gal.), order no. CPY 2-0
❑ pH 4.0 red, 1000 ml (0.264 US gal.), order no. CPY 2-1
❑ pH 7.0 green, 100 ml (0.026 US gal.), order no. CPY 2-2
❑ pH 7.0 green, 1000 ml (0.264 US gal.), order no. CPY 2-3
Technical buffer solutions for single use, accuracy 0.02 pH, acc. to NIST/DIN
❑ pH 4.0 20 x 20 ml (0.005 US gal.), order no. CPY 2-D
❑ pH 7.0 20 x 20 ml (0.005 US gal.), order no. CPY 2-E
O-rings ❑ O-ring set for electrode, TOP 68 plug and flow assembly lid;
order no. 51512789
Flow assembly lid ❑ Flow assembly lid including seal and screws;
order no. 51512795
Compression fittings ❑ Compression fitting ¼;
order no. 51512793
❑ Compression fitting OD 6 mm;
order no. 51512792
Mounting plate ❑ PVC mounting plate incl. screws and mounting brackets;
order no. 51512788
Process adaption
A Compression fitting, OD 6 mm, 316L
B Compression fitting, ¼, 316L
C Replacement electrode
Electrode type / temperature compensation
1 Integrated Pt 100
2 Integrated Pt 1000
Cable connection
A TOP 68, no cable
CPF 201- complete order code
Documentation
Transmitter ❑ Liquisys M CPM 223/253, Technical Information TI 194C/07/en; order no. 51500277
❑ Mycom S CPM 153, Technical Information TI 233C/07/en; oder no. 51503788
Measuring cable ❑ CPK 1-12, Technical Information TI 118C/07/en; order no. 50068526
Endress+Hauser GmbH+Co. KG
Instruments International
P.O. Box 2222
D-79574 Weil am Rhein
Germany
Tel. (07621) 975-02
Tx 773926
Fax (07621) 975 345
e-mail: info@ii.endress.com
Internet:
http://www.endress.com
11.01
TI 366C/07/en/06.03
51512476
Printed in Germany / FM+SGML 6.0 / DT

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Compact pH Electrode for pure and ultrapure water

  • 1. Quality made by Endress+Hauser ISO 9001 Technical Information TI 366C/07/en/06.03 51512476 Compact pH Electrode PuriSys CPF 201 Compact electrode for pH measurement in pure and ultrapure water Application • Boiler feed water • Power plant applications • Pharmaceutical water for injection (WFI) Your benefits • 316 SS low flow assembly: – stable pH reading – elimination of flow dependency errors • Simple, maintenance-free replacement electrode • Temperature compensation • TOP 68 quick disconnect, water tight connector • Patented porous PTFE reference junction • Easy installation
  • 2. PuriSys CPF 201 2 Endress+Hauser Function and system design Measuring principle pH measurement The pH value is used as a unit of measurement for the acidity or alkalinity of a liquid medium. The membrane glass of the electrode supplies an electrochemical potential which is dependent upon the pH value of the medium. This potential is generated by the selective penetration of H+ ions through the outer layer of the membrane. An electrochemical boundary layer with an electric potential forms at this point. An integrated Ag/AgCl reference system serves as reference electrode. The transmitter converts the measured voltage into the corresponding pH value using the Nernst equation. Important properties PuriSys CPF 201 • Reference system The CPF 201 electrode has a porous Teflon reference junction in a double reference chamber for long life in all high purity water applications. • Temperature compensation In addition, a Pt 100 or Pt 1000 temperature sensor is embedded in the pH glass bulb stem for quick temperature response. • Easy connection The electrode is connected via the water-proof plug-in system TOP 68. • Flow assembly The flow cell has been designed to dissipate static electrical charges inherent in flowing water with low conductivity. The flow assembly design minimizes trapped particles and contaminants. Measuring system The complete measuring system comprises: • PuriSys CPF 201 electrode with stainless steel body • PuriSys CPF 201 stainless steel flow assembly with compression fitting on inlet and outlet • CPK 9 measuring cable (not included in scope of delivery) • Transmitter, e.g. Liquisys M CPM 223, Mycom S CPM 153 (not included in scope of delivery) C07-CPF201xx-14-05-00-xx-001.eps iÃÕÀˆ˜}ÊÃÞÃÌi“ÊiÝ“«i £ Õ̏iÌ Ó *6 Ê“œÕ˜Ìˆ˜}Ê«ÌiÊvœÀÊiiVÌÀˆVÊˆÃœÌˆœ˜ Î *ÕÀˆ-ÞÃÊ *ÊÓä£ÊvœÜÊÃÃi“LÞ { ˜iÌ x *ʙʓiÃÕÀˆ˜}ÊVLi È *ÕÀˆ-ÞÃÊ *ÊÓä£ÊiiVÌÀœ`i Ç ˆµÕˆÃÞÃÊÊ *ÊÓÓÎÊÌÀ˜Ã“ˆÌÌiÀ 2 3 5 6 7 01 3 0 pH ENDRESS+HAUSER LIQUISYS M CAL REL REL1 REL1 ALARM REL2 REL2E Setpoint R232 1 4
  • 3. PuriSys CPF 201 Endress+Hauser 3 Input Measured values pH value Temperature Measuring range Response time t90 10 s Cable specifications The CPF 201 electrode is connected to the measuring transmitter using the CPK 9 measuring cable (version without potential matching line). C07-CPK9xxx-03-11-00-en-002.eps *ʙʓiÃÕÀˆ˜}ÊVLi Wiring of CPK 9 to transmitter pH value 0 ... 14 pH Temperature 2 ... 75 °C / 36 ... 167 °F Coax BK Coax WH GN WH YE Plug Shield connection Cable Transmitter CPK 9 Liquisys M CPM 223 / 253 Mycom S CPM 153 Pin Function Terminal Function Terminal Function Coax BK Reference Ref Reference Ref Reference Coax WH pH pH pH pH pH GN Temp. (Pt 100) 11 TC 11 TC WH Temp. (Pt 100) 12 TC common 13 TC common YE Temp. (Pt 100) 13 TC 12 TC Shield EMC protection S Shield Shield connection / Pg thread Shield
  • 4. PuriSys CPF 201 4 Endress+Hauser Installation Calibration When installing a new CPF 201 electrode, perform a two-point calibration using pH 4 and 7 buffer solutions to establish that the electrode and the transmitter are functional together. To do so, refer to the operating instructions of the transmitter. Rinse the electrode thoroughly with ultra-pure water to remove all traces of the buffer solutions prior to inserting the electrode into the flow assembly. Since the pH variation in ultra-pure water is very small, routine one-point calibration of the CPF 201 electrode is performed by comparative sample measurement according to the ASTM test method. When performing sample measurements take note of the following: • The sample chamber and the sample line must avoid exposure of the ultra-pure water to the atmosphere. – Ultra-pure water is highly unbuffered and the slightest amount of contamination can change the pH value significantly. Specifically, ultra-pure water rapidly absorbs CO2 gas from the atmosphere which lowers the pH value of the sample. – The sample may contain volatile substances that will rapidly dissipate when exposed to the atmosphere. • The sample to be measured should be at the same temperature as the medium stream because ultra-pure water has a significant temperature coefficient. • To obtain repeatable measurement results, the flow rate of the sample chamber must be stabilised. Also, the pressure must be stable. Installation instructions The electrode is threaded into the flow assembly and hand-tightened. When mounting the flow assembly, make sure that the inlet and outlet ports are vertical with the inlet on the bottom. In this fashion, the electrode mounting hole will be at the top right. This will ensure that bubbles in the water stream will not collect and interfere with the measurements. The supplied PVC mounting plate for electrical isolation ensures a noiseless pH reading. To mount the PVC mounting plate on posts or pipes, use the mounting brackets included in the package. C07-CPF201xx-11-05-00-xx-001.eps ˜Ã̏Ìˆœ˜Êˆ˜ÊÌ…iÊvœÜÊVi £ Ó Î *6 Ê“œÕ˜Ìˆ˜}Ê«Ìi *ÊÓä£ÊiiVÌÀœ`i œÕ˜Ìˆ˜}Ê…œiÃÊ­LÀVŽiÌÃÊvœÀÊ«œÃÌÊ“œÕ˜Ìˆ˜}Ê ˆ˜VÕ`i`ʈ˜ÊÃVœ«iÊœvÊ`iˆÛiÀÞ® { x È ˜iÌÊ«œÀÌ œÜÊÃÃi“LÞ Õ̏iÌÊ«œÀÌ 6 5 2 1 4 3
  • 5. PuriSys CPF 201 Endress+Hauser 5 Environment Ingress protection IP 68 (1m / 3.28 ft water column, 50 °C / 122 °F, 168 h) / NEMA 6 (TOP 68 plug-in system) Process Process temperature max. 75 °C / 167 °F Process pressure max. 3.45 bar / 50 psi Medium conductivity 100 µS/cm Drift 0.02 pH/week at 0.5 µS/cm at 25 °C / 77 °F Flow rate 50 ... 250 ml/min Optimum: 150 ml/min The flow rate must be stable to obtain accurate measurement results. Mechanical construction Design, dimensions C07-CPF201xx-16-05-00-xx-002.eps *ÊÓä£ÊiiVÌÀœ`iÊ`iÈ}˜ £ /*ÊÈnÊVœ˜˜iVÌœÀ Ó -̈˜iÃÃÊÃÌiiÊLœ`Þ Î ‡Àˆ˜} { /ivœ˜ÊÀiviÀi˜Viʍ՘V̈œ˜Ê˜`Ê«Ê}ÃÃÊLՏLÊ C07-CPF201xx-16-05-00-xx-001.eps *ÊÓä£Êœ˜‡ˆ˜iÊÕ˜ˆÌÊ`iÈ}˜ £ *6 Ê“œÕ˜Ìˆ˜}Ê«Ìi Ó *ʙʓiÃÕÀˆ˜}ÊVLi Î *ÊÓä£ÊiiVÌÀœ`i { ˜iÌÊ«œÀÌ x œÜÊVi È Õ̏iÌÊ«œÀÌ 1 2 3 4 1 2 3 4 5 6
  • 6. PuriSys CPF 201 6 Endress+Hauser Weight Materials Process connection OD 6 mm stainless steel compression fitting ¼ stainless steel compression fitting Temperature sensor Pt 100 RTD, Pt 1000 RTD Cable connection TOP 68 plug-in system Certificates and approvals Test report Design according to ASTM standard D 5128, Standard Test Method for On-Line pH Measurement of Water of Low Conductivity C07-CPF201xx-06-05-00-en-002.eps *ÊÓä£ÊiiVÌÀœ`iÊ`ˆ“i˜Ãˆœ˜Ã C07-CPF201xx-06-05-00-en-001.eps *ÊÓä£Êœ˜‡ˆ˜iÊÕ˜ˆÌÊ`ˆ“i˜Ãˆœ˜Ã 27.2/ 1.07 171/6.73 mm/inch17.5 / 0.69 305 / 12 305/12 73.7 / 2.9 mm / inch 241.3/9.5 Electrode: approx. 213 g Complete on-line unit incl. mounting brackets: approx. 2275 g Electrode shaft stainless steel SS 316, Viton® Reference junction Teflon® Glass bulb pH membrane glass Reference system KCl/AgCl Flow assembly stainless steel SS 316, Viton® Inlet / outlet ports stainless steel SS 316
  • 7. PuriSys CPF 201 Endress+Hauser 7 Ordering information Product structure Scope of delivery The scope of delivery includes: • 1 CPF 201 electrode • 1 flow assembly • 1 PVC mounting plate incl. mounting brackets • Technical Information TI 366C/07/en Accessories Measuring cable ❑ Measuring cable CPK 9 (version without PM) for electrodes with TOP 68 plug-in head ordering by product structure, see Technical Information TI 118C/07/en Buffer solutions Technical buffer solutions, accuracy 0.02 pH, acc. to NIST/DIN ❑ pH 4.0 red, 100 ml (0.026 US gal.), order no. CPY 2-0 ❑ pH 4.0 red, 1000 ml (0.264 US gal.), order no. CPY 2-1 ❑ pH 7.0 green, 100 ml (0.026 US gal.), order no. CPY 2-2 ❑ pH 7.0 green, 1000 ml (0.264 US gal.), order no. CPY 2-3 Technical buffer solutions for single use, accuracy 0.02 pH, acc. to NIST/DIN ❑ pH 4.0 20 x 20 ml (0.005 US gal.), order no. CPY 2-D ❑ pH 7.0 20 x 20 ml (0.005 US gal.), order no. CPY 2-E O-rings ❑ O-ring set for electrode, TOP 68 plug and flow assembly lid; order no. 51512789 Flow assembly lid ❑ Flow assembly lid including seal and screws; order no. 51512795 Compression fittings ❑ Compression fitting ¼; order no. 51512793 ❑ Compression fitting OD 6 mm; order no. 51512792 Mounting plate ❑ PVC mounting plate incl. screws and mounting brackets; order no. 51512788 Process adaption A Compression fitting, OD 6 mm, 316L B Compression fitting, ¼, 316L C Replacement electrode Electrode type / temperature compensation 1 Integrated Pt 100 2 Integrated Pt 1000 Cable connection A TOP 68, no cable CPF 201- complete order code
  • 8. Documentation Transmitter ❑ Liquisys M CPM 223/253, Technical Information TI 194C/07/en; order no. 51500277 ❑ Mycom S CPM 153, Technical Information TI 233C/07/en; oder no. 51503788 Measuring cable ❑ CPK 1-12, Technical Information TI 118C/07/en; order no. 50068526 Endress+Hauser GmbH+Co. KG Instruments International P.O. Box 2222 D-79574 Weil am Rhein Germany Tel. (07621) 975-02 Tx 773926 Fax (07621) 975 345 e-mail: info@ii.endress.com Internet: http://www.endress.com 11.01 TI 366C/07/en/06.03 51512476 Printed in Germany / FM+SGML 6.0 / DT