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Patricia Overmeyer
U.S. EPA/Office of Brownfields and Land
                            Revitalization
Vapor intrusion generally occurs when there is a
 migration of volatile chemicals from contaminated
 groundwater or soil into an overlying building.

Volatile chemicals can emit vapors that may migrate
 through subsurface soils and into indoor air spaces
 of overlying buildings in ways similar to that of radon
 gas seeping into homes.

Volatile chemicals may include volatile organic
 compounds, select semivolatile organic compounds,
 and some inorganic analytes, such as elemental
 mercury, radon, and hydrogen sulfide.
All Appropriate Inquiries Rule
 Identify conditions indicative of releases or
 threatened releases of hazardous substances. (40
 CFR 312.1(c))

ASTM E1527-05
 Identify recognized environmental conditions – or
 the presence or likely presence of any hazardous
 substances or petroleum products on a property
 under conditions that indicate an existing
 release, a past release or a material threat of a
 release…into structures on the property or inot
 the ground, ground water, or surface water….
A Phase I Site Assessment (or AAI Investigation)
 is not intended to:
 • Verify or document a specific release
 • Verify or document the presence of specific
   contamination
 • Document a specific source of a potential release
 • Document the extent of a release
   Conditions indicative of a release that could
    result in vapor intrusion, or
   Presence or likely presence under conditions
    that indicate… a release that could lead to
    vapor intrusion
    Could be:
    ◦ Presence of USTs containing hydrocarbons
    ◦ Documentation of hydrocarbon releases at a nearby
      property
   Goal of Phase I / AAI is not:
    ◦ To determine the presence of vapor intrusion (or
      the presence of any other release or result of a
      release)
    ◦ Document the presence of vapors or document
      vapor intrusion events
   Updating EPA’s 2002 Draft Guidance on
    Subsurface Vapor Intrusion
   Developing guidance on petroleum vapor
    intrusion
   Hazardous Ranking System (HRS) Rulemaking
   Developing technical documents and tools
   Planning to issue final Subsurface Vapor
    Intrusion Guidance by November 30, 2012.
   A request for public input was announced in
    the Federal Register on March 17, 2011 (76
    FR 14660).
   Comment period ended on May 14, 2011, all
    comments received will be considered in
    developing the final guidance. Comments can
    be viewed at Regulations.gov (EPA-HQ-
    RCRA-2002-0033).
   Petroleum hydrocarbons and chlorinated
    hydrocarbons behave differently in respect to
    VI pathway.
    The guidance will focus on
    federally‐regulated (Subtitle I) UST sites,
    which are typically gas stations.
   The guidance will contain information and
    practices that will be useful at other sites
    (e.g., fuel terminals and airport hydrant
    systems) where petroleum contamination is
    of potential concern.
   EPA is working toward a proposed rulemaking to
    add a new screening component to OSWER's
    Hazard Ranking System (HRS).
   Would allow sites impacted by vapor intrusion or
    intrusion of other subsurface contamination to
    be evaluated for placement on the Superfund
    National Priorities List (NPL).
   Through this change, the HRS could directly
    consider the human exposure to contaminants
    that enter building structures from the
    subsurface environment.
   The Brownfields and Land Revitalization
    Technology Support Center published
    Brownfields Technology Primer: Vapor
    Intrusion Considerations for Redevelopment.
    ◦ Provides an overview of vapor intrusion and how it
      can affect redevelopment.
    ◦ Summarizes techniques for quickly and cost
      effectively assessing the potential for vapor
      intrusion.
   Background Indoor Air Concentrations of Volatile
    Organic Compounds in North American
    Residences (1990 – 2005): A Compilation of
    Statistics for Assessing Vapor Intrusion

    ◦ Summary of indoor air studies that measured
      background concentrations of VOCs in the indoor
      air of thousands of North American residences
      and an evaluation and compilation of the
      statistical information reported in these studies.
    ◦ Illustrates ranges and variability of VOC
      concentrations in indoor air resulting from
      sources other than vapor intrusion.
   EPA's Vapor Intrusion Database: Evaluation
    and Characterization of Attenuation Factors
    for Chlorinated Volatile Organic Compounds
    and Residential Buildings

   Conceptual Model Scenarios for the Vapor
    Intrusion Pathway
Rich Kapuscinski, Office of Solid Waste
Emergency Response
kapuscinski.rich@epa.gov
 (703) 305-7411
 Websites:
 http://www.epa.gov/oswer/vaporintrusion/
 http://www.epa.gov/oust/cat/pvi/index.htm

Patricia Overmeyer
Overmeyer.patricia@epa.gov

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Phase I site assessments and vapor intrusion

  • 1. Patricia Overmeyer U.S. EPA/Office of Brownfields and Land Revitalization
  • 2. Vapor intrusion generally occurs when there is a migration of volatile chemicals from contaminated groundwater or soil into an overlying building. Volatile chemicals can emit vapors that may migrate through subsurface soils and into indoor air spaces of overlying buildings in ways similar to that of radon gas seeping into homes. Volatile chemicals may include volatile organic compounds, select semivolatile organic compounds, and some inorganic analytes, such as elemental mercury, radon, and hydrogen sulfide.
  • 3.
  • 4. All Appropriate Inquiries Rule Identify conditions indicative of releases or threatened releases of hazardous substances. (40 CFR 312.1(c)) ASTM E1527-05 Identify recognized environmental conditions – or the presence or likely presence of any hazardous substances or petroleum products on a property under conditions that indicate an existing release, a past release or a material threat of a release…into structures on the property or inot the ground, ground water, or surface water….
  • 5. A Phase I Site Assessment (or AAI Investigation) is not intended to: • Verify or document a specific release • Verify or document the presence of specific contamination • Document a specific source of a potential release • Document the extent of a release
  • 6. Conditions indicative of a release that could result in vapor intrusion, or  Presence or likely presence under conditions that indicate… a release that could lead to vapor intrusion Could be: ◦ Presence of USTs containing hydrocarbons ◦ Documentation of hydrocarbon releases at a nearby property
  • 7. Goal of Phase I / AAI is not: ◦ To determine the presence of vapor intrusion (or the presence of any other release or result of a release) ◦ Document the presence of vapors or document vapor intrusion events
  • 8. Updating EPA’s 2002 Draft Guidance on Subsurface Vapor Intrusion  Developing guidance on petroleum vapor intrusion  Hazardous Ranking System (HRS) Rulemaking  Developing technical documents and tools
  • 9. Planning to issue final Subsurface Vapor Intrusion Guidance by November 30, 2012.  A request for public input was announced in the Federal Register on March 17, 2011 (76 FR 14660).  Comment period ended on May 14, 2011, all comments received will be considered in developing the final guidance. Comments can be viewed at Regulations.gov (EPA-HQ- RCRA-2002-0033).
  • 10. Petroleum hydrocarbons and chlorinated hydrocarbons behave differently in respect to VI pathway.  The guidance will focus on federally‐regulated (Subtitle I) UST sites, which are typically gas stations.  The guidance will contain information and practices that will be useful at other sites (e.g., fuel terminals and airport hydrant systems) where petroleum contamination is of potential concern.
  • 11. EPA is working toward a proposed rulemaking to add a new screening component to OSWER's Hazard Ranking System (HRS).  Would allow sites impacted by vapor intrusion or intrusion of other subsurface contamination to be evaluated for placement on the Superfund National Priorities List (NPL).  Through this change, the HRS could directly consider the human exposure to contaminants that enter building structures from the subsurface environment.
  • 12. The Brownfields and Land Revitalization Technology Support Center published Brownfields Technology Primer: Vapor Intrusion Considerations for Redevelopment. ◦ Provides an overview of vapor intrusion and how it can affect redevelopment. ◦ Summarizes techniques for quickly and cost effectively assessing the potential for vapor intrusion.
  • 13. Background Indoor Air Concentrations of Volatile Organic Compounds in North American Residences (1990 – 2005): A Compilation of Statistics for Assessing Vapor Intrusion ◦ Summary of indoor air studies that measured background concentrations of VOCs in the indoor air of thousands of North American residences and an evaluation and compilation of the statistical information reported in these studies. ◦ Illustrates ranges and variability of VOC concentrations in indoor air resulting from sources other than vapor intrusion.
  • 14. EPA's Vapor Intrusion Database: Evaluation and Characterization of Attenuation Factors for Chlorinated Volatile Organic Compounds and Residential Buildings  Conceptual Model Scenarios for the Vapor Intrusion Pathway
  • 15. Rich Kapuscinski, Office of Solid Waste Emergency Response kapuscinski.rich@epa.gov (703) 305-7411 Websites: http://www.epa.gov/oswer/vaporintrusion/ http://www.epa.gov/oust/cat/pvi/index.htm Patricia Overmeyer Overmeyer.patricia@epa.gov