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Safe Chemical Handling & Initial Spill Response

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David Horowitz
David Horowitz

This presentation was prepared for the Sixteenth Annual Southeastern Massachusetts Drinking Water Fair held on June 16, 2011 at the Massachusetts Maritime Academy. The event was hosted by the Barnstable County Water Utilities Association and the Plymouth County Water Works Association. Attendees received Training Contact Hours (TCHs).

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Barnstable County Water Utilities Association Safe Chemical Handling and Initial Spill Response June 16, 2011 David P. Horowitz, P.E., CSP Tighe & Bond, Inc. 413.572.3211 [email_address] @dphorowitz on Twitter & YouTube
Take Away Message ,[object Object],[object Object],[object Object]
Introduction / Objectives ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Common Chemical Uses ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Select only the closest or the best answer ,[object Object],[object Object],[object Object],[object Object],[object Object]
Material Safety Data Sheet ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MSDS - Key Sections ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MSDS - Key Sections ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Hazard Types ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Globally Harmonized Systems ,[object Object]
WHAT? ,[object Object]
[object Object],[object Object],[object Object],WHEN?
ANTICIPATED IMPLEMENTATION ,[object Object],[object Object],[object Object],[object Object]
WHY? ,[object Object],[object Object],[object Object]
WHO? ,[object Object],[object Object],[object Object],[object Object]
INTERNATIONAL PARTICIPATION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
PROPOSED MODIFICATIONS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
SAFETY DATA SHEETS ,[object Object],[object Object]
It’s Movie Time!
Chemical Specifics ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Potassium Permanganate ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Aluminum Sulfate ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],Select only the closest or the best answer
Sodium Hypochlorite ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Chlorine Gas / Liquid ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What does OSHA say about a chlorine spill? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What Does OSHA Say? Chlorine (Continued) ,[object Object],[object Object],[object Object]
Sodium Hydroxide ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Hydrofluosilic Acid ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Sulfuric Acid ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
True/False ,[object Object],[object Object],[object Object]
Ammonia – Aqueous / Anhydrous ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Fuel Oil – Diesel or Heating ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What’s the best way to respond to a spill? ,[object Object]
Chemical Feed System Designs ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Design Considerations/Flexibility ,[object Object],[object Object],[object Object],[object Object],[object Object]
Chemical Compatibility ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Simple System (Manufacturer Provided)
Transfer Pump Design Considerations ,[object Object],[object Object],[object Object],[object Object],[object Object]
Metering Pump Design ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Chemical Feed System Operation ,[object Object],[object Object],[object Object]
Secondary Containment ,[object Object],[object Object],[object Object],[object Object]
 
Five Effective Generic BMPs ,[object Object],[object Object],[object Object],[object Object],[object Object]
Spill Prevention Measures ,[object Object],[object Object],[object Object],[object Object],[object Object]
 
If You Have A Spill - Emergency Chemical Response ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Actions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
SPEP – General Policy ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Don’t get tunnel vision ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The chemical may be the least of your problems ,[object Object],[object Object],[object Object],[object Object],[object Object]
RECOGNITION & IDENTIFICATION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
RECOGNITION CLUES ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
PSYCHOLOGICAL FACTORS ,[object Object],[object Object],[object Object],[object Object]
 
 
 
KEYS TO SAFE RESPONSE ,[object Object],[object Object],[object Object],[object Object],[object Object]
SPEP – Respond Within Your Capabilities ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
SPEP – Response Procedure ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
SPEP – Actions At The Scene ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
SPEP – Response To Threats To The Water Supply ,[object Object],[object Object],[object Object],[object Object],[object Object]
Site Activities ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Isolate Environmental Receptors ,[object Object],[object Object],[object Object],[object Object],[object Object]
Site Conditions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Spill Reporting ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Spill Reporting Chemical CAS # DEP RQ (Lbs) Sulfuric Acid 7664-93-9 50 Sodium Hydroxide 1310-73-2 50 Potassium Permanganate 7722-64-7 10 Aluminum Sulfate 10043-01-3 100 Sodium Hypochlorite 07681-52-9 10 Chlorine Gas 7782-50-5 5 Hydrofluorosilicic Acid 16961-83-4 10     DEP RQ (Gal) Oil - Diesel & Heating   10
Spill Reporting ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Chemical CAS # DEP RQ (Lbs) Sulfuric Acid 7664-93-9 50
Spill Reporting Chemical Conc (Typ) Density DEP RQ (Lbs) DEP RQ (Gal) Sulfuric Acid 90% 1.84 50 3.3 Sodium Hydroxide 50% 1.53 50 3.9 Aluminum Sulfate 28% 1.33 100 9.0 Sodium Hypochlorite 12.5% 1.20 10 1.0 Hydrofluorosilicic Acid 25% 1.22 10 1.0       DEP RQ (Gal) DEP RQ (Gal) Oil - Diesel & Heating     10 10
VAPOR DENSITY ,[object Object],[object Object],[object Object],[object Object]
SPECIFIC GRAVITY ,[object Object],[object Object],[object Object],[object Object]
Select only the closest or the best answer ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Conclusions / Key Points ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Pop Quiz ,[object Object]
Which of the following is a corrosive chemical ,[object Object],[object Object],[object Object],[object Object]
Which of the following exposures can be controlled with chemical gloves? ,[object Object],[object Object],[object Object],[object Object]
What is the primary hazard for sodium hypochlorite ,[object Object],[object Object],[object Object],[object Object]
What document should be the primary resource for chemical hazard info ,[object Object],[object Object],[object Object],[object Object]
Which of the following should be done first in a chemical emergency ,[object Object],[object Object],[object Object],[object Object]
Once human health is protected, what is the next objective ,[object Object],[object Object],[object Object],[object Object]
What should be done with waste generated from spill response ,[object Object],[object Object],[object Object],[object Object]
If you feel the effects of chemical exposure, what should you do next ,[object Object],[object Object],[object Object],[object Object]
Which of the following is most hazardous when combined with a fuel oil spill ,[object Object],[object Object],[object Object],[object Object]
Questions / Thanks David P. Horowitz, P.E., CSP Tighe & Bond, Inc. 413.572.3211 [email_address]

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Safe Chemical Handling & Initial Spill Response

  • 1. Barnstable County Water Utilities Association Safe Chemical Handling and Initial Spill Response June 16, 2011 David P. Horowitz, P.E., CSP Tighe & Bond, Inc. 413.572.3211 [email_address] @dphorowitz on Twitter & YouTube
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  • 67. Spill Reporting Chemical CAS # DEP RQ (Lbs) Sulfuric Acid 7664-93-9 50 Sodium Hydroxide 1310-73-2 50 Potassium Permanganate 7722-64-7 10 Aluminum Sulfate 10043-01-3 100 Sodium Hypochlorite 07681-52-9 10 Chlorine Gas 7782-50-5 5 Hydrofluorosilicic Acid 16961-83-4 10     DEP RQ (Gal) Oil - Diesel & Heating   10
  • 68.
  • 69. Spill Reporting Chemical Conc (Typ) Density DEP RQ (Lbs) DEP RQ (Gal) Sulfuric Acid 90% 1.84 50 3.3 Sodium Hydroxide 50% 1.53 50 3.9 Aluminum Sulfate 28% 1.33 100 9.0 Sodium Hypochlorite 12.5% 1.20 10 1.0 Hydrofluorosilicic Acid 25% 1.22 10 1.0       DEP RQ (Gal) DEP RQ (Gal) Oil - Diesel & Heating     10 10
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  • 84. Questions / Thanks David P. Horowitz, P.E., CSP Tighe & Bond, Inc. 413.572.3211 [email_address]