3. - Properties Of Oxygen v/s Ozone
3
Properties Oxygen Ozone
Molecular Formula O2 O3
Molecular Weight 32 48
Color Colorless Light Blue
Smell Odorless Zero Restriction
Smell Identification Odorless Photocopy Machine &
Smell After Lightning Strom
Solubility In Water [0⁰C] 0.049 0.64
Density [G/L] 1.429 2.144
Boiling Point -183⁰C -111.9⁰C
Flammability None None
Flash Point Not Applicable Not Applicable
Self-Ignition Temperature Not Applicable Not Applicable
Hazardous Decomposition None None
Electrochemical Potential [eV] 1.23 2.07
4. - How Is Ozone Made?
4
Corona Discharge - Lightning UV Light - Sun
In Nature It Is Produced
In Two Ways
185 nm UV light in Sun Breaks-up
Oxygen molecule to form Ozone
Corona discharge from Lightning
passing through air
5. - How Is Ozone Made By Us?
5
Method 1: Corona Discharge
Advantages Of Corona Discharge
• Higher Ozone Concentration
• Best For Water & Waste Water
Treatment
• Fast on Organics & Odor
• Consistent Ozone Production
Advantages Of UV Type
• Simple Construction
• Lower Cost of Ozone Generation
• Output Less Affected By Humidity
Method 2: U.V. Light
Oxygen
Turns into
Ozone In
presence
of 185 nm
UV light
Oxygen
UV Lamp
High Voltage
Ground Electrode
6. - Advantages Of Ozone
6
• Powerful Oxidant | Sanitizer | Disinfection
• Kill pathogens in seconds
• Micro-flocculent
• Ozone reaction does not alter pH
• Excellent at oxidizing on metals
• Reaction By-product is least harmful
• Reverts back to harmless oxygen
• No need to store
Oxidizer Potential [V]
OH 2.86
Ozone 2.07
Hydrogen Peroxide 1.77
Permaganate 1.67
Hyprochlorous Acid 1.49
Chlorine Gas 1.36
Hypobromous Acid 1.33
Oxygen 1.23
Bromine 1.09
Hypoiodous Acid 0.99
Chlorine Dioxide 0.95
Hypochlorite 0.94
Chlorite 0.76
Iodine 0.54
7. - Negatives Of Ozone
7
Short Half Life | Can Not Be Storage & Transported | Oxidized Materials
Ozone Half Life
Dissolved In Water
⁰C Time
15 30 min.
20 20 min.
25 15 min.
30 12 min.
35 8 min.
8. - Ozone Safety
8
• Inhalation
• Skin
• Eye Contact
• Ingestion
Concentration
[ppm]
Observed Effect
0.005 – 0.02 Threshold Of Odor, normal person
0.1 Max. 8 Hrs. exposure limit
> 0.1 Minor irritation – Eye | Nose | Throat, Headache,
Short of Breath
0.5 – 1.0 Breathing Disorder, lung irritation, sever fatigue, dry
cough, chest pain
1 – 10 Headache, respiratory irritation, Possible Coma
10 Immediate danger to life & health
15 - 20 Lethal to small animals in few hours
9. - Ozone Material Compatibility
9
Excellent [A] Good [B] Fair [C] Poor [D]
Butyle Glass Santoprene ABS Plastic Acetal [Delrin] Buna-N [Nitrile]
Chemraz Hastelloy-C Silicone Aluminium Cast Ion Magnesium
C-PVC HDPE SS 316 Brass GI - Water Natural Rubber
Durachlor-51 Inconel Titanium Bronze Hypalon Nylon
Durlon-9000 Kalrez Vamac Copper Hytrel Polyamide
EPDM Kel-F PCTFE Viton LLDP Monel Mild Steel [MS]
EPR PEEK Polyacrylate Neoprene Zinc
Ethylene-Propylene Polycarbonate Polyethylene [Water] Polyethylene [Air]
Flexelene Polyurethane Polysulfide Polypropylene
Flurosilicone PTFE-Teflon PVC
GI – Air PVDF-Kynar SS 304
10. - Action of Ozone on Bacteria
10
1. Healthy Bacteria
2. Ozone comes in contact
3. Oxidative Burst
4. Hole - Injured Bacteria
5. Bacteria looses its shape
6. Cell Dies
11. - Ozone Generation [Corona Discharge]
11
Ambient Air Ozonator Ozone
Ambient
Air
Air Dryer Dry Air Ozonator Ozone
Ambient Air
Air
Compressor
Oxy.
Concentrator
Oxygen
Ozone
Generator
Ozone
Displayed in Yellow are Equipment
13. - Ozone – Applied & Dissolved
13
Applied Ozone Dissolved Ozone
Ozone Which
is Dissolved
in water
is only useful
14. - Ozone Solubility In Water
14
1. Dissolution Efficiency
• Quality Of Feed Gas
• Ozone Concentration
• Water Pressure
• Gas Pressure
• Temperature
• Dissolution Efficiency Of The Device
2. Implementation - Integration | Retrofitting | Augmentation
16. - Ozone Bubble Size
16
Cube : 1.0 mm3
Bubble Dia : 1.0 mm
Total bubbles : 1.0 no.
Surface Area : 3.14 mm2
Total S. Area : 3.14 mm2
Cube : 1.0 mm3
Bubble Dia : 0.5 mm
Total bubbles : 8.0 nos.
Surface Area : 0.786 mm2
Total S. Area : 6.29 mm2
Cube : 1.0 mm3
Bubble Dia : 0.1 mm
Total bubbles : 1000 nos.
Surface Area : 0.0314 mm2
Total S. Area : 31.43 mm2
1.0
mm
26. - Ozone Application – Water
26
Water
Raw Water Treatment
Process Water Treatment
Ozone Enrich Process Water
Waste Water
Gray Water Treatment
Sewage Water Treatment
Industrial Effluent
35. - Ozone Application – Waste Water Treatment
35
Sewage Treatment Plant
Industrial Waste Water
Laundry Waste water Recycle
Grey Water Treatment & Reuse
36. Thank You
36
Solution Engineer : Mr. Sunil Shah
Contact : +91-93212 34527
Mail ID : sunilshah@chemtronicsindia.com
URL : www.chemtronicsindia.com
www.ozonegeneratorindia.com
www.m.chemtronicsindia.com
Hinweis der Redaktion
Oxygen, is forced between high voltage electric plates to simulate corona discharge. The Oxygen Molecules is broken apart & recombines to form Ozone