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Electron
Configuration,
Periodic Properties,
and Trends
Chapter 5
1.
ATOMIC
RADIUS
Atomic Radius (Covalent
Radius)
• Defined as ______ the distance
               half
  between the nuclei of identical atoms
  that are bonded together
• Ex. Cl2
          Cl         Cl




              ½
          distance
Atomic Radius Trend

                           Increases
                           down and
                           to the left




               Francium
• Largest : ____________
                Helium
• Smallest : __________
Atomic Radius Trend
• REASON: increasing __________
                            nuclear
  charge (protons) – pulls the
  electrons _________ to the nucleus.
     closer
• Example: Which element has a
  larger atomic radius – Silicon or
             Silicon
  Sulfur? __________
• Example: Which element has a
  larger atomic radius – Sodium or
  Potassium? _____________
                   Potassium
2. IONIZATION
  ENERGY
IONIZATION ENERGY
  • Ion : an atom or group of bonded atoms
    that have a __________ or __________
                  negative       positive
    charge.

  Ex.

Na+                   Cl-
11 protons = 11 +     17 protons = 17 +
10 electrons = 10 -   18 electrons = 18 -
              1+                     1-
IONIZATION ENERGY
• Ionization Energy : the energy required to
  remove ____ ________ from a neutral
            one  electron
  atom.
• Trend: Increases up and to the right
Ionization Energy
• Lowest ionization energy : _____________
                                  Francium
              Group : _____________
                          Alkali Metals
• Highest ionization energy: _____________
                                    Helium
              Group : _____________
                           Noble Gas
Ex. What has the higher ionization energy –
  Aluminum or Phosphorus?
               _____________
                  Phosphorus
Ex. What has the lower ionization energy –
  Calcium or Strontium?
               _____________
                   Strontium
3. Electronegativity
Electronegativity
• Definition: the measure of the ability of
  an atom in a chemical compound to
  _______ electrons closer to it.
   attract




• _______ _______ don’t form
    Noble   Gases
  compounds, so they are not included.
Electronegativity Periodic
          Trend
• Trend : Increases up and to the right
Electronegativity
• Highest Electronegativity : ________
                               Fluorine


• Lowest Electronegativity : ________
                              Francium


• Only element with 4.0 : __________
                            Fluorine


• Only elements in the 3’s :
   Oxygen    Chlorine        Nitrogen
 _________, _________, __________.
4. METALLIC
 ACTIVITY
METALLIC ACTIVITY TREND




 • Largest : ____________
              Francium
              Helium
 • Smallest : __________
5. IONIC RADII
Ionic Radii
• Positive ion : ________
                   cation          Na+
                             ex. ______
• Negative ion : _______
                   anion     ex. ______
                                   Cl-


                 lose
• Neutral atoms _____ an electron to become
    positive
  __________ ions.

 Ex.
    K (19 electrons)         K+ (18 electrons) + 1e-

                 gain
• Neutral atoms _____ an electron to become
    negative
  __________ ions.

 Ex.
   Cl (17 electrons) + 1e-        Cl- (18 electrons)
Ionic Radii
• Positive ions, ex. ___, are ________
                      Na+       smaller
  than a neutral atom of that same
  element. (LOSE an electron)

• Negative ions, ex. ____, are _______
                      Cl-       larger
  than a neutral atom of the same
  element. (GAIN an electron)
REVIEW
Atomic Radius
Ionization Energy
Electronegativity

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Periodic trends

  • 3. Atomic Radius (Covalent Radius) • Defined as ______ the distance half between the nuclei of identical atoms that are bonded together • Ex. Cl2 Cl Cl ½ distance
  • 4. Atomic Radius Trend Increases down and to the left Francium • Largest : ____________ Helium • Smallest : __________
  • 5. Atomic Radius Trend • REASON: increasing __________ nuclear charge (protons) – pulls the electrons _________ to the nucleus. closer • Example: Which element has a larger atomic radius – Silicon or Silicon Sulfur? __________ • Example: Which element has a larger atomic radius – Sodium or Potassium? _____________ Potassium
  • 6. 2. IONIZATION ENERGY
  • 7. IONIZATION ENERGY • Ion : an atom or group of bonded atoms that have a __________ or __________ negative positive charge. Ex. Na+ Cl- 11 protons = 11 + 17 protons = 17 + 10 electrons = 10 - 18 electrons = 18 - 1+ 1-
  • 8. IONIZATION ENERGY • Ionization Energy : the energy required to remove ____ ________ from a neutral one electron atom. • Trend: Increases up and to the right
  • 9. Ionization Energy • Lowest ionization energy : _____________ Francium Group : _____________ Alkali Metals • Highest ionization energy: _____________ Helium Group : _____________ Noble Gas Ex. What has the higher ionization energy – Aluminum or Phosphorus? _____________ Phosphorus Ex. What has the lower ionization energy – Calcium or Strontium? _____________ Strontium
  • 11. Electronegativity • Definition: the measure of the ability of an atom in a chemical compound to _______ electrons closer to it. attract • _______ _______ don’t form Noble Gases compounds, so they are not included.
  • 12. Electronegativity Periodic Trend • Trend : Increases up and to the right
  • 13. Electronegativity • Highest Electronegativity : ________ Fluorine • Lowest Electronegativity : ________ Francium • Only element with 4.0 : __________ Fluorine • Only elements in the 3’s : Oxygen Chlorine Nitrogen _________, _________, __________.
  • 15. METALLIC ACTIVITY TREND • Largest : ____________ Francium Helium • Smallest : __________
  • 17. Ionic Radii • Positive ion : ________ cation Na+ ex. ______ • Negative ion : _______ anion ex. ______ Cl- lose • Neutral atoms _____ an electron to become positive __________ ions. Ex. K (19 electrons) K+ (18 electrons) + 1e- gain • Neutral atoms _____ an electron to become negative __________ ions. Ex. Cl (17 electrons) + 1e- Cl- (18 electrons)
  • 18. Ionic Radii • Positive ions, ex. ___, are ________ Na+ smaller than a neutral atom of that same element. (LOSE an electron) • Negative ions, ex. ____, are _______ Cl- larger than a neutral atom of the same element. (GAIN an electron)