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Y.Bavaneethan.
Lecturer
Department of Food Technology
SLGTI. SriLanka.
12/4/2017 Y.BAVANEETHAN
INTRODUCTION
โ€ข Fish is highly perishable,
โ€“ proper handling must start from the moment it is
harvested until it reaches the consumerโ€™s table.
โ€“ Lowering the temperature (chilling, refrigeration
and freezing) is the key factor in maintaining the
quality of fresh fish.
โ€ข Chilling is the most common practice in keeping the
freshness of fish.
2Y.BAVANEETHAN12/4/2017
CHILLING
โ€ข Means the reduction of temperature to some
point below (-2 to -40C for superchilling) or
above (between 0 to 50C) the freezing point of
water in the fish muscles.
โ€ข Chilling does not stop spoilage but slows it
down considerably.
3Y.BAVANEETHAN12/4/2017
METHODS OF CHILLING
โ€ข 1. WET ICE (ICING)
- Icing is most common and useful way of
chilling the fish catch.
- Cooling is effected by the direct contact
between the melted ice and the fish.
- When ice is placed in close contact with the
fish;
- heat transferred from the warm fish to the ice
resulting to the melting of ice; in turn the fish is
cooled down by the melted ice.
4Y.BAVANEETHAN12/4/2017
WET ICE (ICING)
5Y.BAVANEETHAN12/4/2017
The following considerations must be taken
when icing fish:
1. Sufficient ice must be used to maintain fish
temperature at 00C.
โ€“ For long term preservation more ice than fish is needed,
atleast usual 1:1 ice: fish ratio.
2. The arrangement of ice and fish must be in such a
way that accumulated water, blood and slimes can be
drained easily.
3. Ice and fish should be placed alternately to avoid
localized heating. Fish must be sufficiently
surrounded with ice on sides, top and bottom.
12/4/2017 Y.BAVANEETHAN 6
4. When packing mixed fish, big fish must be placed at
the bottom and small fish on top.
โ€“ Fish with delicate skin should be packed on top
of fish with scales.
5. Gutted fish must be filled up with ice in the belly
cavity,
โ€“ must be arranged with belly down in a slanting
position inside the container.
7Y.BAVANEETHAN12/4/2017
โ€ข 2. Chilled by Ice Slurry
- This is also termed as โ€œSlush iceโ€ which is a mixture
of seawater and crushed ice used for the chilling of
fish catch.
Advantages of CSW(Chilled Sea Water) over icing:
โ€ข CSW chills fish much faster than wet ice.
โ€ข Fish in CSW do not suffer from physical damage due
to crushing or pressure from other fish.
โ€ข Fish in CSW are washed in the slurry.
โ€ข CSW chilled fish do not necessarily keep longer than
wet iced fish.
8Y.BAVANEETHAN12/4/2017
ICE SLURRY
9Y.BAVANEETHAN12/4/2017
Other Methods
3.Refrigerated Air
โ€ข Air chilling is commonly employed in big commercial
production. Chilled air is circulated by a finned
evaporator and fan situated at one end of the fish
room.
โ€ข These units are often referred to as air blowers.
10Y.BAVANEETHAN12/4/2017
Outdoor Air Cooled Process
Chilling Refrigeration Models
( APS )
11Y.BAVANEETHAN12/4/2017
Refrigerated Air at refrigerator box
12Y.BAVANEETHAN12/4/2017
4. Dry Ice
โ€ข Dry ice is solid carbon dioxide. Cooling is effected by the
evaporation of the dry ice.
โ€ข Due to its very low temperature (-78.90C), dry ice should
not be used in direct contact with fish to avoid cold burns.
COLD BURN
13Y.BAVANEETHAN12/4/2017
โ€ข This method of chilling is preferred for air shipment of
fish, as this does not caused leakage.
โ€ข The use of dry ice is subject to restrictions because it
expands from a solid form into a gas and it may expel
oxygen, posing a hazard to the safety of airplanes
14Y.BAVANEETHAN12/4/2017
5. Gel Ice Mat
โ€ข Gel ice made by freezing a water-based gel.
The advantage of gel ice is that all water is
bound with no chance of water leakage during
thawing . Gel mat chilling is suitable for air
transport of fish.
15Y.BAVANEETHAN12/4/2017
Chilling Equipments
โ€ข Chilling equipment is classified by the method
used to remove heat, into:
โ€“ mechanical refrigerators
โ€“ cryogenic systems.
โ€ข Batch or continuous operation is possible with
both types of equipment.
1. Mechanical refrigerators
โ€ข Mechanical refrigerators have four basic
elements:
โ€“ evaporator, compressor, condenser and expansion
valve.
12/4/2017 Y.BAVANEETHAN 16
12/4/2017 Y.BAVANEETHAN 17
โ€ข The refrigerator material (Copper) should have:
โ€“ low thermal conductivity
โ€“ high rates of heat transfer
โ€“ high thermal efficiencies
โ€ข Refrigerant circulates between the four elements of the
refrigerator.
1. liquid refrigerant evaporates under reduced pressure, and
absorbs latent heat of vaporization and cools the
medium(food).
2. Refrigerant vapour passes from the evaporator to the
compressor where the pressure is increased.
3. The vapour then passes to the condenser where the high
pressure is maintained and the vapour is condensed.
4. The liquid passes through the expansion valve where the
pressure is reduced to restart the refrigeration cycle.12/4/2017 Y.BAVANEETHAN 18
โ€“ low boiling point and high latent heat of vaporization
โ€“ dense vapour to reduce the size of the compressor
โ€“ low toxicity and non-flammable
โ€“ low miscibility with oil in the compressor
โ€“ low cost
โ€ข Ammonia has excellent heat transfer properties and is
not miscible with oil,
โ€“ but it is toxic and flammable, and causes corrosion
of copper pipes.
โ€ข Carbon dioxide is nonflammable and non-toxic,
making it safer,
โ€“ but it requires considerably higher operating
pressures compared to ammonia.
12/4/2017 Y.BAVANEETHAN 19
โ€ขThe important properties of refrigerants are as follows:
โ€ข CFCs are all non-toxic and non-flammable and have
good heat transfer properties and lower costs than other
refrigerants.
โ€“ but, their interaction with ozone in the earthโ€™s atmosphere.
โ€ข Now, ozone-friendly HCFCs(Partially halogenated CFC)
are being developed and are likely to become important
refrigerants.
12/4/2017 Y.BAVANEETHAN 20
Cryogenic chilling
โ€ข A cryogen is a refrigerant that changes phase by
absorbing latent heat to cool the food.
โ€ข Cryogenic chillers use solid carbon dioxide, liquid
carbon dioxide or liquid nitrogen.
โ€ข Solid carbon dioxide removes latent heat of
sublimation.
โ€ข The advantages of carbon dioxide include:
โ€“ higher boiling and sublimation point than nitrogen,
and therefore a less severe effect on the food
โ€“ most heat capacity arises from the conversion of
solid or liquid to gas.
12/4/2017 Y.BAVANEETHAN 21
โ€ข Solid carbon dioxide can be used in the form of โ€˜dry-
iceโ€™ pellets, or
โ€“ liquid carbon dioxide can be injected into air to
produce fine particles of solid carbon dioxide -
โ€˜snowโ€™.
โ€“ which rapidly sublime to gas.
โ€ข Older meat processing, dry-ice pellets layered with
minced meat and filled into containers.
โ€“ However, lack of uniformity distribution of pellets.
โ€“ Result, some meat becoming frozen and some
remaining above 5ยบC
โ€“ Which permitted bacterial growth.
12/4/2017 Y.BAVANEETHAN 22
โ€ข More recently the use of snow horns (Dry Ice Snow),
โ€“ To distribute a fine layer of snow over minced
meat.
โ€“ It is eliminated above problems and resulted in
rapid uniform cooling to 3โ€“4 OC.
โ€ข Applications of cryogenic cooling include sausage
manufacture,
โ€“ where carbon dioxide snow removes the heat
generated during size reduction and mixing
โ€“ And cryogenic grinding where the cryogen reduces
dust levels, prevents dust explosions.
12/4/2017 Y.BAVANEETHAN 23
Types of Insulation
โ€ข The primary aim of using insulation in containers is
to slow down the rate of heat exchange between two
bodies at different temperatures.
โ€ข The efficiency of an insulating material in
preventing heat flow is measured as thermal
conductivity (k).
24Y.BAVANEETHAN12/4/2017
1. Cork and Fiberglass Mat
โ€ข Cork and fiberglass mats have k values of 0.04 and
0.03, respectively. They are good insulating
materials, however, they are highly permeable to
water vapor.
CORK FIBERGLASS MAT COMPOSITED WITH
ALUMINUM FOIL
25Y.BAVANEETHAN12/4/2017
2. Rice Hull, Kapok, Coconut fibers and sawdust
โ€ข These materials are cheap but not water-resistant.
Kapok when compressed loses its insulating power .
RICE HULL
Kapok fiber
26Y.BAVANEETHAN12/4/2017
3. Polystyrene (styrophore)
๏‚ง It is widely used as an insulating material because it
is easy to produce.
27Y.BAVANEETHAN12/4/2017
4. Polyurethane
โ€ข Expanded polyurethane has almost similar
properties (except for its lower compressibility
strength) as that of expanded polystyrene.
โ€ข Polyurethane material can be foamed in situ on to
the surface that needs to be insulated.
28Y.BAVANEETHAN12/4/2017
Effect on foods
โ€ข Chilling foods to correct storage temperature causes
little or no reduction of eating quality or nutritional
properties.
โ€ข Most significant effect of chilling,
โ€“ Foods is hardening due to solidification of fats and
oils.
โ€ข Lipid oxidation is one of the main causes of quality loss
in cookโ€“chilled products,
โ€“ Cooked meats rapidly developed oxidised flavour
termed โ€˜warmed-over flavourโ€™.
12/4/2017 Y.BAVANEETHAN 29
โ€ข Quality deterioration:
โ€“ Evaporation of moisture from unpackaged chilled
meats and cheeses.
โ€“ Rapid staling of sandwich bread at reduced
temperatures and moisture migration from sandwich
fillings.
โ€ข In cookโ€“chill systems, nutritional losses are,
โ€“ insignificant for thiamine, riboflavin and retinol.
โ€“ but vitamin C losses are 3.3โ€“16% day1 at 2ยบC.
โ€ข Vitamin C losses in cookโ€“pasteurizeโ€“chill procedures are
lower than cookedโ€“chilled foods.
โ€“ Spinach lost 66% within 3 days at 2โ€“3ยบC after cookโ€“
chilling compared with 26% loss within 7 days at 24ยบC
after cookโ€“pasteurizingโ€“chilling.
12/4/2017 Y.BAVANEETHAN 30
12/4/2017 Y.BAVANEETHAN 31

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ย 

Chilling

  • 1. 1 Y.Bavaneethan. Lecturer Department of Food Technology SLGTI. SriLanka. 12/4/2017 Y.BAVANEETHAN
  • 2. INTRODUCTION โ€ข Fish is highly perishable, โ€“ proper handling must start from the moment it is harvested until it reaches the consumerโ€™s table. โ€“ Lowering the temperature (chilling, refrigeration and freezing) is the key factor in maintaining the quality of fresh fish. โ€ข Chilling is the most common practice in keeping the freshness of fish. 2Y.BAVANEETHAN12/4/2017
  • 3. CHILLING โ€ข Means the reduction of temperature to some point below (-2 to -40C for superchilling) or above (between 0 to 50C) the freezing point of water in the fish muscles. โ€ข Chilling does not stop spoilage but slows it down considerably. 3Y.BAVANEETHAN12/4/2017
  • 4. METHODS OF CHILLING โ€ข 1. WET ICE (ICING) - Icing is most common and useful way of chilling the fish catch. - Cooling is effected by the direct contact between the melted ice and the fish. - When ice is placed in close contact with the fish; - heat transferred from the warm fish to the ice resulting to the melting of ice; in turn the fish is cooled down by the melted ice. 4Y.BAVANEETHAN12/4/2017
  • 6. The following considerations must be taken when icing fish: 1. Sufficient ice must be used to maintain fish temperature at 00C. โ€“ For long term preservation more ice than fish is needed, atleast usual 1:1 ice: fish ratio. 2. The arrangement of ice and fish must be in such a way that accumulated water, blood and slimes can be drained easily. 3. Ice and fish should be placed alternately to avoid localized heating. Fish must be sufficiently surrounded with ice on sides, top and bottom. 12/4/2017 Y.BAVANEETHAN 6
  • 7. 4. When packing mixed fish, big fish must be placed at the bottom and small fish on top. โ€“ Fish with delicate skin should be packed on top of fish with scales. 5. Gutted fish must be filled up with ice in the belly cavity, โ€“ must be arranged with belly down in a slanting position inside the container. 7Y.BAVANEETHAN12/4/2017
  • 8. โ€ข 2. Chilled by Ice Slurry - This is also termed as โ€œSlush iceโ€ which is a mixture of seawater and crushed ice used for the chilling of fish catch. Advantages of CSW(Chilled Sea Water) over icing: โ€ข CSW chills fish much faster than wet ice. โ€ข Fish in CSW do not suffer from physical damage due to crushing or pressure from other fish. โ€ข Fish in CSW are washed in the slurry. โ€ข CSW chilled fish do not necessarily keep longer than wet iced fish. 8Y.BAVANEETHAN12/4/2017
  • 10. Other Methods 3.Refrigerated Air โ€ข Air chilling is commonly employed in big commercial production. Chilled air is circulated by a finned evaporator and fan situated at one end of the fish room. โ€ข These units are often referred to as air blowers. 10Y.BAVANEETHAN12/4/2017
  • 11. Outdoor Air Cooled Process Chilling Refrigeration Models ( APS ) 11Y.BAVANEETHAN12/4/2017
  • 12. Refrigerated Air at refrigerator box 12Y.BAVANEETHAN12/4/2017
  • 13. 4. Dry Ice โ€ข Dry ice is solid carbon dioxide. Cooling is effected by the evaporation of the dry ice. โ€ข Due to its very low temperature (-78.90C), dry ice should not be used in direct contact with fish to avoid cold burns. COLD BURN 13Y.BAVANEETHAN12/4/2017
  • 14. โ€ข This method of chilling is preferred for air shipment of fish, as this does not caused leakage. โ€ข The use of dry ice is subject to restrictions because it expands from a solid form into a gas and it may expel oxygen, posing a hazard to the safety of airplanes 14Y.BAVANEETHAN12/4/2017
  • 15. 5. Gel Ice Mat โ€ข Gel ice made by freezing a water-based gel. The advantage of gel ice is that all water is bound with no chance of water leakage during thawing . Gel mat chilling is suitable for air transport of fish. 15Y.BAVANEETHAN12/4/2017
  • 16. Chilling Equipments โ€ข Chilling equipment is classified by the method used to remove heat, into: โ€“ mechanical refrigerators โ€“ cryogenic systems. โ€ข Batch or continuous operation is possible with both types of equipment. 1. Mechanical refrigerators โ€ข Mechanical refrigerators have four basic elements: โ€“ evaporator, compressor, condenser and expansion valve. 12/4/2017 Y.BAVANEETHAN 16
  • 18. โ€ข The refrigerator material (Copper) should have: โ€“ low thermal conductivity โ€“ high rates of heat transfer โ€“ high thermal efficiencies โ€ข Refrigerant circulates between the four elements of the refrigerator. 1. liquid refrigerant evaporates under reduced pressure, and absorbs latent heat of vaporization and cools the medium(food). 2. Refrigerant vapour passes from the evaporator to the compressor where the pressure is increased. 3. The vapour then passes to the condenser where the high pressure is maintained and the vapour is condensed. 4. The liquid passes through the expansion valve where the pressure is reduced to restart the refrigeration cycle.12/4/2017 Y.BAVANEETHAN 18
  • 19. โ€“ low boiling point and high latent heat of vaporization โ€“ dense vapour to reduce the size of the compressor โ€“ low toxicity and non-flammable โ€“ low miscibility with oil in the compressor โ€“ low cost โ€ข Ammonia has excellent heat transfer properties and is not miscible with oil, โ€“ but it is toxic and flammable, and causes corrosion of copper pipes. โ€ข Carbon dioxide is nonflammable and non-toxic, making it safer, โ€“ but it requires considerably higher operating pressures compared to ammonia. 12/4/2017 Y.BAVANEETHAN 19 โ€ขThe important properties of refrigerants are as follows:
  • 20. โ€ข CFCs are all non-toxic and non-flammable and have good heat transfer properties and lower costs than other refrigerants. โ€“ but, their interaction with ozone in the earthโ€™s atmosphere. โ€ข Now, ozone-friendly HCFCs(Partially halogenated CFC) are being developed and are likely to become important refrigerants. 12/4/2017 Y.BAVANEETHAN 20
  • 21. Cryogenic chilling โ€ข A cryogen is a refrigerant that changes phase by absorbing latent heat to cool the food. โ€ข Cryogenic chillers use solid carbon dioxide, liquid carbon dioxide or liquid nitrogen. โ€ข Solid carbon dioxide removes latent heat of sublimation. โ€ข The advantages of carbon dioxide include: โ€“ higher boiling and sublimation point than nitrogen, and therefore a less severe effect on the food โ€“ most heat capacity arises from the conversion of solid or liquid to gas. 12/4/2017 Y.BAVANEETHAN 21
  • 22. โ€ข Solid carbon dioxide can be used in the form of โ€˜dry- iceโ€™ pellets, or โ€“ liquid carbon dioxide can be injected into air to produce fine particles of solid carbon dioxide - โ€˜snowโ€™. โ€“ which rapidly sublime to gas. โ€ข Older meat processing, dry-ice pellets layered with minced meat and filled into containers. โ€“ However, lack of uniformity distribution of pellets. โ€“ Result, some meat becoming frozen and some remaining above 5ยบC โ€“ Which permitted bacterial growth. 12/4/2017 Y.BAVANEETHAN 22
  • 23. โ€ข More recently the use of snow horns (Dry Ice Snow), โ€“ To distribute a fine layer of snow over minced meat. โ€“ It is eliminated above problems and resulted in rapid uniform cooling to 3โ€“4 OC. โ€ข Applications of cryogenic cooling include sausage manufacture, โ€“ where carbon dioxide snow removes the heat generated during size reduction and mixing โ€“ And cryogenic grinding where the cryogen reduces dust levels, prevents dust explosions. 12/4/2017 Y.BAVANEETHAN 23
  • 24. Types of Insulation โ€ข The primary aim of using insulation in containers is to slow down the rate of heat exchange between two bodies at different temperatures. โ€ข The efficiency of an insulating material in preventing heat flow is measured as thermal conductivity (k). 24Y.BAVANEETHAN12/4/2017
  • 25. 1. Cork and Fiberglass Mat โ€ข Cork and fiberglass mats have k values of 0.04 and 0.03, respectively. They are good insulating materials, however, they are highly permeable to water vapor. CORK FIBERGLASS MAT COMPOSITED WITH ALUMINUM FOIL 25Y.BAVANEETHAN12/4/2017
  • 26. 2. Rice Hull, Kapok, Coconut fibers and sawdust โ€ข These materials are cheap but not water-resistant. Kapok when compressed loses its insulating power . RICE HULL Kapok fiber 26Y.BAVANEETHAN12/4/2017
  • 27. 3. Polystyrene (styrophore) ๏‚ง It is widely used as an insulating material because it is easy to produce. 27Y.BAVANEETHAN12/4/2017
  • 28. 4. Polyurethane โ€ข Expanded polyurethane has almost similar properties (except for its lower compressibility strength) as that of expanded polystyrene. โ€ข Polyurethane material can be foamed in situ on to the surface that needs to be insulated. 28Y.BAVANEETHAN12/4/2017
  • 29. Effect on foods โ€ข Chilling foods to correct storage temperature causes little or no reduction of eating quality or nutritional properties. โ€ข Most significant effect of chilling, โ€“ Foods is hardening due to solidification of fats and oils. โ€ข Lipid oxidation is one of the main causes of quality loss in cookโ€“chilled products, โ€“ Cooked meats rapidly developed oxidised flavour termed โ€˜warmed-over flavourโ€™. 12/4/2017 Y.BAVANEETHAN 29
  • 30. โ€ข Quality deterioration: โ€“ Evaporation of moisture from unpackaged chilled meats and cheeses. โ€“ Rapid staling of sandwich bread at reduced temperatures and moisture migration from sandwich fillings. โ€ข In cookโ€“chill systems, nutritional losses are, โ€“ insignificant for thiamine, riboflavin and retinol. โ€“ but vitamin C losses are 3.3โ€“16% day1 at 2ยบC. โ€ข Vitamin C losses in cookโ€“pasteurizeโ€“chill procedures are lower than cookedโ€“chilled foods. โ€“ Spinach lost 66% within 3 days at 2โ€“3ยบC after cookโ€“ chilling compared with 26% loss within 7 days at 24ยบC after cookโ€“pasteurizingโ€“chilling. 12/4/2017 Y.BAVANEETHAN 30