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JAMES A. CRAIG

OMEGA 2011
 World Energy Production
 World Energy Consumption
 Types of Energy
 Biomass
 Hydropower

 Nuclear
 Renewable (Geothermal, Wind, Solar)
 Fossil

 Future Energy Use
 Energy production has steadily increased.
 According to US DOE
 215.4 quadrillion BTU in 1970.
 417.1 quadrillion BTU in 2003.
 Primary energy has increased by 94% from 1970 to 2003.
World primary energy production by source (1970 – 2003)
Source: US DOE (Annual Energy Review, 2004)
Top energy producing countries (2003)
Source: US DOE (Annual Energy Review, 2004)
 Energy consumption is directly related to quality of

life.
 Quality of life is quantified (by UN) using HDI
(Human Development Index).
 Factors considered in HDI include:
 Life expectancy
 Education
 GDP – output of goods & services (economic growth).
UN HDI versus annual energy consumed per capita (1999)
Sources: UN Human Development Report (2001) & US DOE (2002)
World primary energy consumption by region (1980 – 2003)
Source: US DOE (International Energy Annual, 2003)
 Types to consider:
 Biomass
 Hydropower
 Nuclear
 Renewable (Geothermal, Wind, Solar)
 Fossil
 Biomass (biological mass) refers to organic material

(e.g. plant, animal waste, wood, algae & seaweed, and
garbage).
 They are basically used for lighting, cooking, heating,
& making simple artefacts.
 Biomass can be converted to biofuel by
thermochemical conversion and biochemical
conversion.
Thermochemical Conversion
 Heating biomass in an oxygen-free or low-oxygen

atmosphere.
 Materials are transformed into simpler substances that
can be used as fuels.
 Examples include charcoal and methanol.
 Anaerobic digestion (in sewage treatment plants) is
used to generate methane gas.
Biochemical Conversion
 Uses enzymes, fungi, or other microorganisms.
 High-moisture biomass is converted into liquid or

gaseous fuels.
 Example includes using bacteria to convert manure,
agricultural wastes, paper, and algae into methane.
 Using yeast to decompose carbohydrates (e.g. corn and
sugar), yielding ethyl alcohol (ethanol). Ethanol can be
mixed with gasoline to create gasohol.
 Disadvantages of Biomass
 Deforestation from cutting down trees, which can in

turn leads to soil erosion and mudslides.
 Pollution of environment from burning of wood.
 Hydropower was originally used to turn waterwheels of

mills to grind grains.
 Dams (hydropower plants) are built to convert the
energy of flowing water into mechanical energy
(turning turbines) to create electricity.
 In 2006, the world’s largest dam (3 Gorges Dam) was
completed on the Yangtze River, China. Capacity is
84.7 billion kWh/year of electricity.
Size

Electricity Generating Capacity (MW)

Micro

< 0.1

Small

0.1 – 30

Large

> 30
 Advantage
 Low operating costs.

 Disadvantages
 Expensive to build
 Drought conditions can affect water supply
 Reliance on rain and melting snow
 Environmental concerns (ruined streams, dried up

waterfalls, and altered aquatic habitats).
 Nuclear energy can be obtained from 2 principal types

of reactions:
 Fission – splitting of 1 large nucleus into 2 smaller

nuclei.
 Fusion – joining of 2 small nuclei into 1 large nucleus.
 Nuclear reactors are designed primarily for electricity

generation.
 They also provide power for ships (submarines &
aircraft carriers) and serve as training & research
facilities .
Pressurized water reactor
Source: US DOE (DOE/EP0026, 1981)
The Palo Verde Nuclear Power Facility in Arizona, USA.
Core of the
reactor
Top 10 producers of electrical energy from nuclear energy (2000)
Source: US DOE (EIA website, 2002)
Dependence of nations on nuclear energy (2000)
Source: US DOE (EIA website, 2002)
 Advantages
 A long-term source of abundant energy
 Power plants do not produce greenhouse gases (CO2 and

methane).
 Disadvantages
 Waste disposal: end products of nuclear fission are

highly radioactive and have half-life in thousands of
years.
 Nuclear plants can contaminate air, water, the ground,
and the biosphere.
 Renewable energy is naturally regenerated.

 Sources include:
 Geothermal – heat of the earth.
 Wind
 Solar – the sun

 Sometimes, hydropower and biomass are included in

this category.
 Geothermal energy is the natural, internal heat of

Earth trapped in rock formations deep underground.
 Only a fraction of it can be extracted.
 Examples are hot springs, geysers, and fumaroles.
 Hot water or steam from these sources are used for
heating buildings and processing food.
 Pressurized hot water or steam can be directed toward

turbines for electricity generation.
 Geothermal energy is usable only when it is
concentrated in one spot (thermal reservoir).
 There are 4 types of reservoirs:
 Hydrothermal reservoirs
 Dry rock reservoirs

 Geopressurized reservoirs
 Magma
Hydrothermal Reservoirs
 Underground pools of hot water covered by a
permeable formation through which steam
escapes.
 At the surface, the steam is purified and piped
directly to electrical generating station.
 Cheapest and simplest form of geothermal energy.
Dry Rock
 Most common geothermal sources.
 Typical more than 6,000 ft below the surface.
 Water is injected into hot rock formations and the
resulting steam or water is collected.
Geopressurized Reservoirs
 They contain hot water & methane gas.
 Supplies of geopressurized energy remain
uncertain.
 Drilling is expensive.
Magma
 Molten or partially liquefied rock.
 Found from 10,000 ft – 30,000 ft below the surface.
 Temperature ranges from 900 oC – 1,205 oC.
 Extraction is still in the experimental stages.
 Disadvantages
 Geothermal plants are not efficient.
 They must be built near a geothermal source, so

accessibility to consumers is a challenge.
 Noise pollution.
 Harmful pollutants may be released: NH3, H2S, arsenic,
boron, & radon.
 Collapse of the land & water shortages due to massive
water withdrawal.
 Historical applications include sailing and driving

windmills.
 Early windmills were used to pump water and grind
grain in mills.
 When “harvested” by turbines, wind can be used to
generate electricity.
 A wind farm (or park) is a collection of wind turbines.
The areal extent of the farm depends on the radius of
the rotor blades.
 Advantages
 Clean energy. No emission of greenhouse gases.

 Disadvantages
 Rotating blades can kill birds, interfering with migration

patterns of birds.
 Noise pollution.
A wind farm in Albany
 The luminosity of sun ≈ 3.8 x 1026 W.
 Radiation from sun is comparable to the radiation

emitted by a black body at 6,000 oK.
 Solar constant (≈ 1,370 W/m2) is the amount of
radiation from the sun that reaches the earth’s
atmosphere.
 In the atmosphere, solar radiation can be absorbed or
scattered away from the earth’s surface by atmospheric
particles (air, water vapour, dust particles, and
aerosols).
Passive solar
 Building design with environmental factors that enable

the capture or exclusion of solar energy.
 Mechanical devices are not used in applications.
 Examples are roof overhang & thermal insulation.
Roof overhang

L

S
W

tan  S tan W

Thermal insulation

H wall

Thigh  Tlow 
Twall
 kwall A
 kwall A
hwall
hwall
Active solar
 Building design & construction of systems that collect

and convert solar energy into other forms of energy
(heat & electrical energy).
 Mechanical devices are used in applications.
 Examples are solar heat collector & solar power plant.
Solar heat collector
Solar power plant
 Fossils are dead, decayed, & transformed organisms

(plants & animals).
 Fossil energy comes from the combustion of fossil
fuels.
 Fossil fuels include:
 Coal
 Hydrocarbon (crude oil & natural gas)

 Fuel fuels are still the primary fuels for generating

power.
Fossils
 Coal is a black, combustible, mineral solid.
 Coal is formed from organic debris by coalification






process.
It developed over millions of years in an airless space
under increased temperature & pressure.
Organisms that form coal include: algae, zooplankton,
phytoplankton, bacteria decay of plants, & animals.
Coal is used as a fuel and in the production of coal gas,
water gas, coal-tar compounds, & coke.
There are 4 types of coal: anthracite, bituminous, subbituminous, & lignite.
Anthracite
 Hard coal & jet-black. Highest ranked.
 Moisture content < 15%
 Heating value ≈ 22 million – 28 million BTU/ton.
 Used for electricity generation & space heating.
Bituminous
 Soft coal, dense & black.
 Moisture content < 20%
 Heating value ≈ 19 million – 30 million BTU/ton.
 Used for electricity generation, space heating, & coke
production.
Sub-bituminous
 Dull black. Also known as black lignite.
 Moisture content = 20% – 30%
 Heating value ≈ 16 million – 24 million BTU/ton.
 Used for electricity generation & space heating.
Lignite
 Brownish-black. Lowest ranked.
 Moisture content high
 Heating value ≈ 9 million – 17 million BTU/ton.
 Used for electricity generation.
Coal Mining
 The method used depends on the terrain & the depth
of the coal. There are 2 methods:
 Underground Mining – coal depth > 200 ft below

surface. Some coal must be left untouched to form
pillars that prevent the mines from caving in. Popular
till early 1970s.
 Surface Mining – coal depth < 200 ft. There 2 types:

area surface mining & contour surface mining.
 Coal is transported to consumers by ground

transportation, especially by trains.
Shaft mine (underground)
Slope mine (underground)
Drift mine (underground)
Area surface mine (surface)
Contour mine (surface)
Top coal producing countries (2003)

Top coal consuming countries (2003)
 Hydrocarbons are organic compounds, composed

entirely of carbon and hydrogen.
 They may also contain impurities like sulphur,
nitrogen, oxygen, & metals.
 Another name for hydrocarbon is petroleum.
Element
Carbon

Composition (% by mass)
84 – 87%

Hydrogen

11 – 14%

Sulphur

0.6 – 8%

Nitrogen

0.02 – 1.7%

Oxygen

0.08 – 1.8%

Metals

0 – 0.14%
Phases of Hydrocarbon
 Gas – natural gas (free or associated)
 Liquid – crude oil
 Solid – tar sand, asphalt, pitch blend, waxy crude
Components (%)
Phase

Carbon

Hydrogen

Sulphur

Nitrogen

Oxygen

Gas

65 – 80

1 – 25

Traces

1 – 15

--

Liquid

82 – 87

11 – 15

0.1 – 6

0.1 – 1.5

0.1 – 4.5

Solid

80 – 85

8 – 11

2–8

0–2

--
Content (% in Volume)

Constituents

Wet

Dry

Hydrocarbons
Methane

84.6

96

Ethane

6.4

2

Propane

5.3

0.6

i-Butane

1.2

0.18

n-Butane

1.4

0.12

i-Pentane

0.4

0.14

n-Pentane

0.2

0.06

Hexanes

0.4

0.01

Heptanes

0.1

0.08

Non-Hydrocarbons
Carbon Dioxide

0.5

Helium

0.05

Hydrogen Sulphide

0.5

Nitrogen

0.1

Argon

0.005

Radon, Krypton, Xenon

Traces

Composition of
typical natural
gas
Classes of Hydrocarbon
 Paraffins
 Saturated hydrocarbons
 CnH2n+2
 Examples are methane (CH4) & ethane (C2H6).

 Naphthenes
 Saturated hydrocarbons with a ring structure.

 CnH2n
 Example is cyclopentane (C5H10).

 Aromatic
 Unsaturated hydrocarbons with one or more carbon rings.

 Example is benzene (C6H6).
Major Impurities & Their Sources
 H2 – volcanic activity releases & radioactivity.
 N2 – atmospheric; carried by run of water.
 CO2 – since hydrocarbon is a covalent bond, ions
released can combine to form CO2.
 H2S – free sulphur plus hydrogen.
 He – radioactivity from volcanic activity.
 S – free sulphur.
Effects of Major Impurities
 H2 – reduces gas combustibility. Forms water.
 N2 – affects Energy output per unit volume.
 CO2 – negligible effect.
 H2S – causes bronchi constriction.
 He – negligible effect.
 S – causes coking & plugging, increases power
consumption in refinery cost, reduces crude oil value.
Fluid Classifications
Phase

No surface liquids

Wet gas

> 100,000

Condensate

3,000 – 100,000

Volatile oil

1,500 – 3,000

Black oil

100 – 1,500

Heavy oil

Liquid

Separator GOR (SCF/STB)

Dry gas
Gas

Fluid Type

0

 Also, natural gas can be classified by quality:
 Sweet gas – little or no H2S present in the gas.
 Sour gas – appreciable amount of H2S present in the gas.
Density of Crude Oil
O

API 

141.5
 131.5
S .G.@60 o F

O

Baume 

140
 130
S .G.@60 o F

 Degree API is widely used.
 10 – 20 oAPI ► Heavy crude.

 20 – 30 oAPI ► Medium crude.
 30 – 40 oAPI ► Light crude.
 > 40 oAPI ► Very light crude and condensate
Density of Gas (Gas Specific Gravity)
M a  gas  M a  gas 
g 

M a  air 
29

 Ma = apparent molecular weight.
Nc

M a   yi M i
i 1

 Nc = number of components
 yi = mole fraction of component i

 Mi = molecular weight of component i
Uses of Hydrocarbons
 Energy – to run internal combustion (IC) engines.
 IC engines are found in

automobiles, ships, tractors, generators, & armoured
tanks.
 Raw materials – used as raw materials in

manufacturing of many products.
Cooking gas
Gasoline

Refinery

Jet fuel
Kerosene

Diesel
Others
Solvent for paints

Crude oil

Insecticides
Enamel, Medicines
Synthetic fibers
Detergents

Petrochemical
plant

Weed killers & fertilizers
Cosmetics, Plastics

Synthetic rubber
Polish, Roofing
Protective paints
Photographic films
World crude oil production, OPEC, MMBbl/day (1960 – 2004)
World crude oil production, non-OPEC, MMBbl/day (1960 – 2004)
Top crude oil-producing countries (2004)
World petroleum consumption, OECD (2003)
World oil reserves. Source: Oil & Gas Journal
Middle East – 57% of World oil reserves
North America – 18% of World oil reserves
Central & South America – 8% of World oil reserves
Eastern Europe & Former USSR – 7% of World oil reserves
Africa – 6% of World oil reserves
Asia & Oceania – 3% of World oil reserves
Western Europe – 1% of World oil reserves
 Disadvantages of fossil energy
 Non-renewable – limited.
 Pollution – emission (carbon based) from burning fossil

fuel reacts with oxygen & nitrogen in the atmosphere to
form Greenhouse gases (CO2, CO, NOx), leading to
Global warming.
 These gases trap the solar energy reflected by the earth’s
surface and reradiate the energy in the form of infrared
radiation.
 Carbon sequestration is a means of capturing &
storing greenhouse gases in geologic formations.
The carbon cycle
 Today’s Energy
 85.5 percent → fossil fuels (oil, gas, coal)
 14.5 percent → nuclear and all other sources

 By 2025
 87 percent → fossil fuels (oil, gas, coal)
 13 percent → nuclear and all other sources

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1. World Energy

  • 2.  World Energy Production  World Energy Consumption  Types of Energy  Biomass  Hydropower  Nuclear  Renewable (Geothermal, Wind, Solar)  Fossil  Future Energy Use
  • 3.  Energy production has steadily increased.  According to US DOE  215.4 quadrillion BTU in 1970.  417.1 quadrillion BTU in 2003.  Primary energy has increased by 94% from 1970 to 2003.
  • 4. World primary energy production by source (1970 – 2003) Source: US DOE (Annual Energy Review, 2004)
  • 5. Top energy producing countries (2003) Source: US DOE (Annual Energy Review, 2004)
  • 6.  Energy consumption is directly related to quality of life.  Quality of life is quantified (by UN) using HDI (Human Development Index).  Factors considered in HDI include:  Life expectancy  Education  GDP – output of goods & services (economic growth).
  • 7. UN HDI versus annual energy consumed per capita (1999) Sources: UN Human Development Report (2001) & US DOE (2002)
  • 8.
  • 9. World primary energy consumption by region (1980 – 2003) Source: US DOE (International Energy Annual, 2003)
  • 10.  Types to consider:  Biomass  Hydropower  Nuclear  Renewable (Geothermal, Wind, Solar)  Fossil
  • 11.  Biomass (biological mass) refers to organic material (e.g. plant, animal waste, wood, algae & seaweed, and garbage).  They are basically used for lighting, cooking, heating, & making simple artefacts.  Biomass can be converted to biofuel by thermochemical conversion and biochemical conversion.
  • 12. Thermochemical Conversion  Heating biomass in an oxygen-free or low-oxygen atmosphere.  Materials are transformed into simpler substances that can be used as fuels.  Examples include charcoal and methanol.  Anaerobic digestion (in sewage treatment plants) is used to generate methane gas.
  • 13. Biochemical Conversion  Uses enzymes, fungi, or other microorganisms.  High-moisture biomass is converted into liquid or gaseous fuels.  Example includes using bacteria to convert manure, agricultural wastes, paper, and algae into methane.  Using yeast to decompose carbohydrates (e.g. corn and sugar), yielding ethyl alcohol (ethanol). Ethanol can be mixed with gasoline to create gasohol.
  • 14.  Disadvantages of Biomass  Deforestation from cutting down trees, which can in turn leads to soil erosion and mudslides.  Pollution of environment from burning of wood.
  • 15.  Hydropower was originally used to turn waterwheels of mills to grind grains.  Dams (hydropower plants) are built to convert the energy of flowing water into mechanical energy (turning turbines) to create electricity.  In 2006, the world’s largest dam (3 Gorges Dam) was completed on the Yangtze River, China. Capacity is 84.7 billion kWh/year of electricity. Size Electricity Generating Capacity (MW) Micro < 0.1 Small 0.1 – 30 Large > 30
  • 16.
  • 17.
  • 18.  Advantage  Low operating costs.  Disadvantages  Expensive to build  Drought conditions can affect water supply  Reliance on rain and melting snow  Environmental concerns (ruined streams, dried up waterfalls, and altered aquatic habitats).
  • 19.  Nuclear energy can be obtained from 2 principal types of reactions:  Fission – splitting of 1 large nucleus into 2 smaller nuclei.  Fusion – joining of 2 small nuclei into 1 large nucleus.  Nuclear reactors are designed primarily for electricity generation.  They also provide power for ships (submarines & aircraft carriers) and serve as training & research facilities .
  • 20. Pressurized water reactor Source: US DOE (DOE/EP0026, 1981)
  • 21.
  • 22. The Palo Verde Nuclear Power Facility in Arizona, USA.
  • 24. Top 10 producers of electrical energy from nuclear energy (2000) Source: US DOE (EIA website, 2002)
  • 25. Dependence of nations on nuclear energy (2000) Source: US DOE (EIA website, 2002)
  • 26.  Advantages  A long-term source of abundant energy  Power plants do not produce greenhouse gases (CO2 and methane).  Disadvantages  Waste disposal: end products of nuclear fission are highly radioactive and have half-life in thousands of years.  Nuclear plants can contaminate air, water, the ground, and the biosphere.
  • 27.  Renewable energy is naturally regenerated.  Sources include:  Geothermal – heat of the earth.  Wind  Solar – the sun  Sometimes, hydropower and biomass are included in this category.
  • 28.  Geothermal energy is the natural, internal heat of Earth trapped in rock formations deep underground.  Only a fraction of it can be extracted.  Examples are hot springs, geysers, and fumaroles.  Hot water or steam from these sources are used for heating buildings and processing food.
  • 29.  Pressurized hot water or steam can be directed toward turbines for electricity generation.  Geothermal energy is usable only when it is concentrated in one spot (thermal reservoir).  There are 4 types of reservoirs:  Hydrothermal reservoirs  Dry rock reservoirs  Geopressurized reservoirs  Magma
  • 30.
  • 31. Hydrothermal Reservoirs  Underground pools of hot water covered by a permeable formation through which steam escapes.  At the surface, the steam is purified and piped directly to electrical generating station.  Cheapest and simplest form of geothermal energy. Dry Rock  Most common geothermal sources.  Typical more than 6,000 ft below the surface.  Water is injected into hot rock formations and the resulting steam or water is collected.
  • 32. Geopressurized Reservoirs  They contain hot water & methane gas.  Supplies of geopressurized energy remain uncertain.  Drilling is expensive. Magma  Molten or partially liquefied rock.  Found from 10,000 ft – 30,000 ft below the surface.  Temperature ranges from 900 oC – 1,205 oC.  Extraction is still in the experimental stages.
  • 33.  Disadvantages  Geothermal plants are not efficient.  They must be built near a geothermal source, so accessibility to consumers is a challenge.  Noise pollution.  Harmful pollutants may be released: NH3, H2S, arsenic, boron, & radon.  Collapse of the land & water shortages due to massive water withdrawal.
  • 34.  Historical applications include sailing and driving windmills.  Early windmills were used to pump water and grind grain in mills.  When “harvested” by turbines, wind can be used to generate electricity.  A wind farm (or park) is a collection of wind turbines. The areal extent of the farm depends on the radius of the rotor blades.
  • 35.
  • 36.  Advantages  Clean energy. No emission of greenhouse gases.  Disadvantages  Rotating blades can kill birds, interfering with migration patterns of birds.  Noise pollution.
  • 37. A wind farm in Albany
  • 38.  The luminosity of sun ≈ 3.8 x 1026 W.  Radiation from sun is comparable to the radiation emitted by a black body at 6,000 oK.  Solar constant (≈ 1,370 W/m2) is the amount of radiation from the sun that reaches the earth’s atmosphere.  In the atmosphere, solar radiation can be absorbed or scattered away from the earth’s surface by atmospheric particles (air, water vapour, dust particles, and aerosols).
  • 39.
  • 40. Passive solar  Building design with environmental factors that enable the capture or exclusion of solar energy.  Mechanical devices are not used in applications.  Examples are roof overhang & thermal insulation.
  • 41. Roof overhang L S W  tan  S tan W Thermal insulation H wall Thigh  Tlow  Twall  kwall A  kwall A hwall hwall
  • 42. Active solar  Building design & construction of systems that collect and convert solar energy into other forms of energy (heat & electrical energy).  Mechanical devices are used in applications.  Examples are solar heat collector & solar power plant.
  • 45.
  • 46.  Fossils are dead, decayed, & transformed organisms (plants & animals).  Fossil energy comes from the combustion of fossil fuels.  Fossil fuels include:  Coal  Hydrocarbon (crude oil & natural gas)  Fuel fuels are still the primary fuels for generating power.
  • 48.  Coal is a black, combustible, mineral solid.  Coal is formed from organic debris by coalification     process. It developed over millions of years in an airless space under increased temperature & pressure. Organisms that form coal include: algae, zooplankton, phytoplankton, bacteria decay of plants, & animals. Coal is used as a fuel and in the production of coal gas, water gas, coal-tar compounds, & coke. There are 4 types of coal: anthracite, bituminous, subbituminous, & lignite.
  • 49. Anthracite  Hard coal & jet-black. Highest ranked.  Moisture content < 15%  Heating value ≈ 22 million – 28 million BTU/ton.  Used for electricity generation & space heating. Bituminous  Soft coal, dense & black.  Moisture content < 20%  Heating value ≈ 19 million – 30 million BTU/ton.  Used for electricity generation, space heating, & coke production.
  • 50. Sub-bituminous  Dull black. Also known as black lignite.  Moisture content = 20% – 30%  Heating value ≈ 16 million – 24 million BTU/ton.  Used for electricity generation & space heating. Lignite  Brownish-black. Lowest ranked.  Moisture content high  Heating value ≈ 9 million – 17 million BTU/ton.  Used for electricity generation.
  • 51. Coal Mining  The method used depends on the terrain & the depth of the coal. There are 2 methods:  Underground Mining – coal depth > 200 ft below surface. Some coal must be left untouched to form pillars that prevent the mines from caving in. Popular till early 1970s.  Surface Mining – coal depth < 200 ft. There 2 types: area surface mining & contour surface mining.  Coal is transported to consumers by ground transportation, especially by trains.
  • 55. Area surface mine (surface)
  • 57. Top coal producing countries (2003) Top coal consuming countries (2003)
  • 58.  Hydrocarbons are organic compounds, composed entirely of carbon and hydrogen.  They may also contain impurities like sulphur, nitrogen, oxygen, & metals.  Another name for hydrocarbon is petroleum. Element Carbon Composition (% by mass) 84 – 87% Hydrogen 11 – 14% Sulphur 0.6 – 8% Nitrogen 0.02 – 1.7% Oxygen 0.08 – 1.8% Metals 0 – 0.14%
  • 59. Phases of Hydrocarbon  Gas – natural gas (free or associated)  Liquid – crude oil  Solid – tar sand, asphalt, pitch blend, waxy crude Components (%) Phase Carbon Hydrogen Sulphur Nitrogen Oxygen Gas 65 – 80 1 – 25 Traces 1 – 15 -- Liquid 82 – 87 11 – 15 0.1 – 6 0.1 – 1.5 0.1 – 4.5 Solid 80 – 85 8 – 11 2–8 0–2 --
  • 60. Content (% in Volume) Constituents Wet Dry Hydrocarbons Methane 84.6 96 Ethane 6.4 2 Propane 5.3 0.6 i-Butane 1.2 0.18 n-Butane 1.4 0.12 i-Pentane 0.4 0.14 n-Pentane 0.2 0.06 Hexanes 0.4 0.01 Heptanes 0.1 0.08 Non-Hydrocarbons Carbon Dioxide 0.5 Helium 0.05 Hydrogen Sulphide 0.5 Nitrogen 0.1 Argon 0.005 Radon, Krypton, Xenon Traces Composition of typical natural gas
  • 61. Classes of Hydrocarbon  Paraffins  Saturated hydrocarbons  CnH2n+2  Examples are methane (CH4) & ethane (C2H6).  Naphthenes  Saturated hydrocarbons with a ring structure.  CnH2n  Example is cyclopentane (C5H10).  Aromatic  Unsaturated hydrocarbons with one or more carbon rings.  Example is benzene (C6H6).
  • 62. Major Impurities & Their Sources  H2 – volcanic activity releases & radioactivity.  N2 – atmospheric; carried by run of water.  CO2 – since hydrocarbon is a covalent bond, ions released can combine to form CO2.  H2S – free sulphur plus hydrogen.  He – radioactivity from volcanic activity.  S – free sulphur.
  • 63. Effects of Major Impurities  H2 – reduces gas combustibility. Forms water.  N2 – affects Energy output per unit volume.  CO2 – negligible effect.  H2S – causes bronchi constriction.  He – negligible effect.  S – causes coking & plugging, increases power consumption in refinery cost, reduces crude oil value.
  • 64. Fluid Classifications Phase No surface liquids Wet gas > 100,000 Condensate 3,000 – 100,000 Volatile oil 1,500 – 3,000 Black oil 100 – 1,500 Heavy oil Liquid Separator GOR (SCF/STB) Dry gas Gas Fluid Type 0  Also, natural gas can be classified by quality:  Sweet gas – little or no H2S present in the gas.  Sour gas – appreciable amount of H2S present in the gas.
  • 65. Density of Crude Oil O API  141.5  131.5 S .G.@60 o F O Baume  140  130 S .G.@60 o F  Degree API is widely used.  10 – 20 oAPI ► Heavy crude.  20 – 30 oAPI ► Medium crude.  30 – 40 oAPI ► Light crude.  > 40 oAPI ► Very light crude and condensate
  • 66. Density of Gas (Gas Specific Gravity) M a  gas  M a  gas  g   M a  air  29  Ma = apparent molecular weight. Nc M a   yi M i i 1  Nc = number of components  yi = mole fraction of component i  Mi = molecular weight of component i
  • 67. Uses of Hydrocarbons  Energy – to run internal combustion (IC) engines.  IC engines are found in automobiles, ships, tractors, generators, & armoured tanks.  Raw materials – used as raw materials in manufacturing of many products.
  • 68. Cooking gas Gasoline Refinery Jet fuel Kerosene Diesel Others Solvent for paints Crude oil Insecticides Enamel, Medicines Synthetic fibers Detergents Petrochemical plant Weed killers & fertilizers Cosmetics, Plastics Synthetic rubber Polish, Roofing Protective paints Photographic films
  • 69. World crude oil production, OPEC, MMBbl/day (1960 – 2004)
  • 70. World crude oil production, non-OPEC, MMBbl/day (1960 – 2004)
  • 71. Top crude oil-producing countries (2004)
  • 73. World oil reserves. Source: Oil & Gas Journal
  • 74. Middle East – 57% of World oil reserves
  • 75. North America – 18% of World oil reserves
  • 76. Central & South America – 8% of World oil reserves
  • 77. Eastern Europe & Former USSR – 7% of World oil reserves
  • 78. Africa – 6% of World oil reserves
  • 79. Asia & Oceania – 3% of World oil reserves
  • 80. Western Europe – 1% of World oil reserves
  • 81.  Disadvantages of fossil energy  Non-renewable – limited.  Pollution – emission (carbon based) from burning fossil fuel reacts with oxygen & nitrogen in the atmosphere to form Greenhouse gases (CO2, CO, NOx), leading to Global warming.  These gases trap the solar energy reflected by the earth’s surface and reradiate the energy in the form of infrared radiation.  Carbon sequestration is a means of capturing & storing greenhouse gases in geologic formations.
  • 83.  Today’s Energy  85.5 percent → fossil fuels (oil, gas, coal)  14.5 percent → nuclear and all other sources  By 2025  87 percent → fossil fuels (oil, gas, coal)  13 percent → nuclear and all other sources